• 제목/요약/키워드: electro-conductivity

검색결과 150건 처리시간 0.034초

고분자전해질 연료전지에서 고분자막을 통한 물의 이동 (Transport of Water through Polymer Membrane in Proton Exchange Membrane Fuel Cells)

  • 이대웅;황병찬;임대현;정회범;유승을;구영모;박권필
    • Korean Chemical Engineering Research
    • /
    • 제57권3호
    • /
    • pp.338-343
    • /
    • 2019
  • 고분자전해질 연료전지에서 전해질막의 물이동과 함수율은 고분자막의 성능에 많은 영향을 미친다. 본 연구에서는 간단한 방법에 의해 물이동에 관한 고분자막의 물성(전기삼투계수, 물 확산계수)을 측정하고 이들을 이용해 막을 통한 물의 이동량과 이온전도도를 모델식에 의해 모사한 후 실험값과 비교하였다. 물이동의 구동력은 전기삼투와 확산만이 라고 본 1차원 정상상태 지배방정식을 매트랩으로 수치해석하였다. $144{\mu}m$ 두께의 고분자막의 전기삼투계수를 수소펌핑셀에서 구한 결과 1.11을 얻었다. 물확산계수를 상대습도의 함수로 나타냈고 물확산에 대한 활성화에너지는 $2,889kJ/mol{\cdot}K$였다. 이들 계수를 적용해 모사한 물이동량과 이온전도도 결과는 실험값과 잘 일치함을 보였다.

Nano-structured Carbon Support for Pt/C Anode Catalyst in Direct Methanol Fuel Cell

  • Choi Jae-Sik;Kwon Heock-Hoi;Chung Won Seob;Lee Ho-In
    • 한국분말재료학회지
    • /
    • 제12권2호
    • /
    • pp.117-121
    • /
    • 2005
  • Platinum catalysts for the DMFC (Direct Methanol Fuel Cell) were impregnated on several carbon supports and their catalytic activities were evaluated with cyclic voltammograms of methanol electro-oxidation. To increase the activities of the Pt/C catalyst, carbon supports with high electric conductivity such as mesoporous carbon, carbon nanofiber, and carbon nanotube were employed. The Pt/e-CNF (etched carbon nanofiber) catalyst showed higher maximum current density of $70 mA cm^{-2}$ and lower on-set voltage of 0.54 V vs. NHE than the Pt/Vulcan XC-72 in methanol oxidation. Although the carbon named by CNT (carbon nanotube) series turned out to have larger BET surface area than the carbon named by CNF (carbon nanofiber) series, the Pt catalysts supported on the CNT series were less active than those on the CNF series due to their lower electric conductivity and lower availability of pores for Pt loading. Considering that the BET surface area and electric conductivity of the e-CNF were similar to those of the Vulcan XC-72, smaller Pt particle size of the Pt/e-CNF catalyst and stronger metal-support interaction were believed to be the main reason for its higher catalytic activity.

글자 모양의 자수형 도전사 UHF RFID 태그 안테나 디자인 (Design of Electro-Thread Embroidery UHF RFID Tag Antennas with Character Shapes)

  • 최재한;정유정
    • 한국전자파학회논문지
    • /
    • 제20권10호
    • /
    • pp.1114-1120
    • /
    • 2009
  • 전도성을 띄는 다양한 도전사(electro-thread)의 도전율을 분석하여, 그 특성에 맞게 T 매칭 구조가 없는 글자 모양에 T매칭 구조를 인가하여 닦을 수 있는 자수형 UHF RFID tag 안테나를 설계하였다. 도전사를 이용한 RFID tag 안테나는 기존의 태그와는 달리 착용감과 구부러짐의 변화에 문제가 없어 옷에 자수하여 입을 수 있는 안테나로 사용되기가 쉽다. 자수형 태그의 모양은 일반 의류에 적용하기 쉬운 영어 알파벳 'F'와 한글 자음 'ㄹ' 형태로 설계하였다. 설계된 태그를 최적화하여 제작하였으며 제작한 태그의 특성과 인식 거리 패턴을 측정하였다. 또한 물 비눗물과 소금물에 태그가 젖었을 때 인식 거리를 측정하였다.

벌크 마이크로 머시닝을 이용한 고감도 미세 칼로리미터의 설계 및 제작 (Design and fabrication of a highly sensitive microcalorimetric biosensor by bulk micromachining)

  • 윤승일;김정훈;곽봉섭;김용준;정효일
    • 센서학회지
    • /
    • 제15권3호
    • /
    • pp.164-167
    • /
    • 2006
  • Calorimeter is one of widely used biosensors. Conventional or existing calorimeters are realized directly on a silicon wafer which has very high thermal conductivity. It results in decreasing temperature difference between junctions and it makes a sensitivity of calorimeter to be decreased. In this study, the microcalorimeter was made by using MEMS(Micro Electro Mechanical Systems)-technology and hot junctions of the microcalorimeter are released from a silicon substrate to reduce loss of generated heat by reactions between biomolecules. Sensitivity of the released microcalorimeter was 18 mV/M which is 1.5 times higher than another calorimeters on silicon substrate by reactions between biotin and streptavidin.

A Study on the Characteristics of Two-Phase Flow by Driven Bubbles in a Liquid Bath

  • Oh, Yool-Kwon;Seo, Dong-Pyo
    • International Journal of Air-Conditioning and Refrigeration
    • /
    • 제13권1호
    • /
    • pp.44-50
    • /
    • 2005
  • In the present study, the characteristics of upward bubble flow were experimentally investigated in a liquid bath. An electro-conductivity probe was used to measure local volume fraction and bubble frequency. Since the gas was concentrated at the near the nozzle, the flow parameters were high near the nozzle. In general their axial and radial values tended to decrease with increasing distance. For visualization of flow characteristics, a Particle Image Velocimetry (PIV) and a thermo-vision camera were used in the present study. The experimental results showed that heat transfer from bubble surface to water was largely completed within z = 10 mm from the nozzle, and then the temperature of bubble surface reached that of water rapidly. Due to the centrifugal force, the flow was more developed near the wall than at bubble-water plume. Vortex flow in the bottom region was relatively weaker than that in the upper region.

DC 전압이 유입변압기 절연시스템에 미치는 영향에 관한 연구 (Study on the effect of DC voltage in oil-immersed transformer insulation system)

  • 장효재;김용한;석복렬
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2011년도 제42회 하계학술대회
    • /
    • pp.1552-1553
    • /
    • 2011
  • The HVDC transformer which is one of the main equipments for HVDC(High Voltage Direct Current) electric power transmission systems is exposed to not only AC voltage but also the inflowing DC voltage which comes from the DC-AC converter systems. Therefore, the HVDC transformer insulation system is required to withstand the electric field stress under AC, DC and DC polarity reversal conditions. However the electric field distributions under those conditions are different because the AC electric field and DC electric field are governed by permittivity and conductivity, respectively. In this study, the changes of electric potential and electric field of conventional AC transformer insulation system under DC polarity reversal test condition were analyzed by FEM(Finite Element Method). The DC electric field stress was concentrated in the solid insulators while the AC electric field stress was concentrated in the mineral oil. In addition, the electric stress under that condition which is affected by the surface charge accumulation at the interfaces between insulators was evaluated. The stress in some parts could be higher than that of AC and DC condition, during polarity reversal test. The result of this study would be helpful for the HVDC transformer insulation system design.

  • PDF

전기전도성을 가지는 매크로다공성 알루미노실리케이트-탄소 복합체 제조 (Synthesis of Electro-conducting Macroporous Aluminosilicate-Carbon Nanocomposite)

  • 최광민;조우석;김종영;정종열;백승우;이규형
    • 한국전기전자재료학회논문지
    • /
    • 제30권2호
    • /
    • pp.67-73
    • /
    • 2017
  • Recently, macroporous ceramic materials with high electrical conductivity and mechanical strength are urgently needed for semiconductor and display manufacturing devices. In this work, we obtained electro-conducting macroporous aluminosilicate ceramics having surface resistivity of 108~1,010 ohm by dispersing electro-conducting carbon in ceramic matrix. By addition of 0.5~3.0 wt% frit glass, chemical bonding between grains was strengthened, and flexural strength was enhanced up to 160 MPa as a result. We evaluated the characteristics of present ceramics as vacuum chuck module for liquid crystal display display manufacturing devices.

전기화학 기계적 연마를 이용한 Cu 배선의 평탄화 (Planarizaiton of Cu Interconnect using ECMP Process)

  • 정석훈;서헌덕;박범영;박재홍;정해도
    • 한국전기전자재료학회논문지
    • /
    • 제20권3호
    • /
    • pp.213-217
    • /
    • 2007
  • Copper has been used as an interconnect material in the fabrication of semiconductor devices, because of its higher electrical conductivity and superior electro-migration resistance. Chemical mechanical polishing(CMP) technique is required to planarize the overburden Cu film in an interconnect process. Various problems such as dishing, erosion, and delamination are caused by the high pressure and chemical effects in the Cu CMP process. But these problems have to be solved for the fabrication of the next generation semiconductor devices. Therefore, new process which is electro-chemical mechanical polishing(ECMP) or electro-chemical mechanical planarization was introduced to solve the technical difficulties and problems in CMP process. In the ECMP process, Cu ions are dissolved electrochemically by the applying an anodic potential energy on the Cu surface in an electrolyte. And then, Cu complex layer are mechanically removed by the mechanical effects between pad and abrasive. This paper focuses on the manufacturing of ECMP system and its process. ECMP equipment which has better performance and stability was manufactured for the planarization process.

Through-Silicon Via를 활용한 3D NAND Flash Memory의 전열 어닐링 발열 균일성 개선 (Electro-Thermal Annealing of 3D NAND Flash Memory Using Through-Silicon Via for Improved Heat Distribution)

  • 손영서;이광선;김유진;박준영
    • 한국전기전자재료학회논문지
    • /
    • 제36권1호
    • /
    • pp.23-28
    • /
    • 2023
  • This paper demonstrates a novel NAND flash memory structure and annealing configuration including through-silicon via (TSV) inside the silicon substrate to improve annealing efficiency using an electro-thermal annealing (ETA) technique. Compared with the conventional ETA which utilizes WL-to-WL current flow, the proposed annealing method has a higher annealing temperature as well as more uniform heat distribution, because of thermal isolation on the silicon substrate. In addition, it was found that the annealing temperature is related to the electrical and thermal conductivity of the TSV materials. As a result, it is possible to improve the reliability of NAND flash memory. All the results are discussed based on 3-dimensional (3-D) simulations with the aid of the COMSOL simulator.

금속분리판의 Electro Polishing 및 CrN 코팅을 통한 PEMFC 성능 향상을 위한 연구 (A Study to Improve PEMFC Performance by Using Electro Polishing and CrN Coating on Metal Bipolar Plate)

  • 황성택;천승호;송준석;윤영훈;김병헌;장하;김대웅;현덕수;오병수
    • 한국자동차공학회논문집
    • /
    • 제22권4호
    • /
    • pp.65-71
    • /
    • 2014
  • As an important component of a fuel cell, the bipolar plate comprises a large proportion in the fuel cell's volume, weight and price. The bipolar plate is the most widely used; however, graphite bipolar plate is large in volume, brittle and therefore easily broken during assembling. In addition, due to its poor machinability, production costs a lot, unless mass production. Compared with the graphite bipolar plate, the metal bipolar plate has good machinability, high electric conductivity and strong mechanical strength; however, it corrodes easily and has a high contact resistance, so in order to prevent corrosion and reduce the contact resistance, the basic metal needs to be processed by use of electro polishing and coating. The water which is produced by electrochemical reactions in the fuel cell must be discharged smoothly. In this study, in order to prevent corrosion the processes of electro polishing and CrN coating were used. According to the presence or absence of these processes, the contact angles can be measured and different metal bipolar plates can be made, these plates can be used for comparing and analyzing the performance of the fuel cell.