• Title/Summary/Keyword: effective diffusion coefficients

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A MODEL STUDY ON MULTISTEP RECOVERY OF ACTINIDES BASED ON THE DIFFERENCE IN DIFFUSION COEFFICIENTS WITHIN LIQUID METAL

  • CHUN, YOUNG-MIN;SHIN, HEON-CHEOL
    • Nuclear Engineering and Technology
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    • v.47 no.5
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    • pp.588-595
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    • 2015
  • This study presents an effective method for additional recovery of residual actinides in liquid electrodes after the electrowinning process of pyroprocessing. The major distinctive feature of this method is a reactor with multiple reaction cells separated by partition walls in order to improve the recovery yield, thereby using the interelement difference in diffusion coefficients within the liquid electrode and controlling the selectivity and purity of element recovery. Through an example of numerical simulation of the diffusion scenarios of individual elements, we verified that the proposed method could effectively separate the actinides (U and Pu) and rare-earth elements contained in liquid cadmium. We performed a five-step consecutive recovery process using a simplified conceptual reaction cell and recovered 58% of the initial amount of actinides (U + Pu) in high purity (${\geq}99%$).

Advective-diffusive Characteristics of Waste Landfill Liner to Inorganic Chemicals (매립지 차수재의 무기화합물에 대한 이류-확산 특성)

  • 장연수;류정훈;류정훈
    • Journal of the Korean Geotechnical Society
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    • v.20 no.3
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    • pp.5-11
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    • 2004
  • Characteristics of advective-diffusive transport of inorganic chemicals in clayey soils as well as in two hardened barrier materials of silica and lime are analyzed from the laboratory column test and compared with those of pure diffusive column test. The results show that the average dispersion coefficients of three materials are $4.39\times l0^{-10}\textrm{m}^2 /s,\; 1.98\times l0^{-10}\textrm{m}^2 /s,\; 1.99\times l0^{-10}\textrm{m}^2 /s$, respectively, and the value of clay is higher than that of hardened barrier materials. There was no significant difference between the dispersion coefficients of advective-diffusive column tests and the effective diffusion coefficients from the pure diffusive column tests, if advective velocity was lower than l0$^{-7}$$m^2$/s. The range of dispersion coefficients of advective-diffusive column tests was narrower than that of diffusion coefficients of pure diffusion tests.

The Study of the Control Mechanism of Heel-rise Posture in Dance Major Student and Non-dance Majors (무용전공자와 일반인의 Heel-rise 자세 조절 메커니즘에 관한 연구)

  • Jung, Mi-Ra
    • Korean Journal of Applied Biomechanics
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    • v.17 no.2
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    • pp.83-91
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    • 2007
  • This experiment studied the change in a human's control of his or her static posture by analyzing the stabilogram diffusion and, by using the said study, evaluated the control ability of different groups with different experiences. The postures had a rising requirement of heel-rise according to three conditions: heel-toe, ball, toe; the groups were divided into dance major student and non-dance majors. The results of the critical points according to posture did not show a direct relation with the change in postures that had a rising requirement of heel-rise. The diffusion coefficient(D) had greater stochastic activity for short-term regions that utilize open-loop controls without feedback than for long-term regions that used closed-loop controls with feedback to maintain balance. The directional results of the body undergoing disturbance showed that A/P direction's diffusion coefficient (D) was larger than that of M/L direction. Both feet's planar diffusion coefficients were a linear combination of the diffusion coefficients calculated for the x and y axis. In studying the different abilities to control posture between a dance major student and a non-dance majors, a comparison of open-loop control's diffusion coefficient(D) was effective, and dance major student had superior control ability to that of non-dance majors.

RELATIONSHIP BETWEEN ERROR DIFFUSION COEFFICIENTS, OBJECT SIZE AND OBJECT POSITION FOR CGH

  • Nishi, Susumu;Tanaka, Ken-ichi
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2009.01a
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    • pp.492-497
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    • 2009
  • Computer-Generated Hologram (CGH) is made for three dimensional image of a virtual object. Error diffusion method is used for the phase quantization of CGH, and it is known to be effective to the image quality improvement of the reconstructed image. However, the image quality of the reconstructed image from the CGH using error diffusion method depends on the selection of error diffusion coefficient. In this paper, we derived the relational expression to obtain the error diffusion coefficient from the position of the input object and size of the input object for CGH. As a result, the method of this thesis was able to obtain an excellent reconstructed image compared with the case to derive the error diffusion coefficient from only the position of the input image.

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Temperature Effect on Effective Diffusion Coefficients of Zn and Cd through Column Diffusion Tests (칼럼 확산 실험을 통한 아연 및 카드뮴의 유효확산계수에 미치는 온도영향)

  • Dho, Nam-Young;Lee, Seung-Rae
    • Journal of the Korean GEO-environmental Society
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    • v.3 no.1
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    • pp.13-26
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    • 2002
  • In this study, column diffusion tests for Cd and Zn were conducted at $15^{\circ}C$ and $55^{\circ}C$ to investigate a temperature effect on effective diffusion coefficient. An increase in temperature from $15^{\circ}C$ to $55^{\circ}C$ caused up to ten times larger diffusion coefficient for each heavy metal. Besides, it caused the increased retardation of heavy metals, and hence the effective diffusion coefficient should be overestimated as we use an overestimated retardation factor to calibrate the coefficient. The results of sequential extraction analyses showed that Zn was occluded in carbonate phase and this trend was getting prominent with the increase in temperature. As for Cd, it was partitioned mainly in the exchangeable phase(over 60%) at any temperature.

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Experimental Study of the Relationship between Weight Variation and Thermal Conductivity in Polyurethane Foam (단열재의 무게변화와 열전도도와의 상관관계에 관한 실험적 연구)

  • Lee, Hyo-Jin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.27 no.5
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    • pp.241-246
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    • 2015
  • Cellular foamed insulation such as polyurethane foam ages and degrades the thermal conductivity. Aging of foam is a result from the diffusion of gases, initially consisting of $CO_2$ but eventually replaced by air from the environment. The variation of the cell gas content with time is primarily influenced by the increase of thermal conductivity of the cellular foam. The weight of foam also changes as the gas diffuses and exchanges. In this study, a weight measurement method has been proposed to evaluate the effective diffusion coefficients of $CO_2$ and Air, $D_{CO2}=7.08504E-11$ and $D_{air}=4.86086E-12$, respectively and are compared with the gas analysis method.

Pseudo-Binary Diffusion Coefficients of Organic Aroma Component - I. The Diffusion Coefficient of Benzaldehyde in Aqueous Sugar Solution - (유기방향물질의 의사 2성분계 확산계수 - 제1보 : 설탕수용액중 Benzaldehyde의 확산계수 -)

  • Kang, An-Soo;Lee, Tae-Hee
    • Korean Journal of Food Science and Technology
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    • v.14 no.4
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    • pp.315-323
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    • 1982
  • The measurement of cell constant in a diaphragm-cell method is the most important factor. In order to get the correct cell constant, the diffusion coefficients of potassium chloride were measured, at various concentration and temperature of potassium chloride solution, and at the stirring rate in the cell. The pseudo-binary diffusion coefficients of organic aroma component (benzaldehyde) in sugar solution has been measured at various concentration and temperature with the cell constant obtained above. Experimental results were compared and discussed with the semi-empirical epuations from literatures. And, especially, the diffusion coefficient of benzaldehyde, $D_{ba}$ for a small solute diffusing in a viscous solvent of larger molecules is proportional to the -0.82 power of the viscosity of aqueous sugar solution, ${\mu}$ at constant temperature, $D_{ba}{\mu}^{0.82}=constant$.

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Ionization and Attachment Coefficients in CF4 (CF4 기체에서의 전리와 부착계수)

  • Kim, Sang-Nam
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.60 no.1
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    • pp.27-31
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    • 2011
  • In this paper, the electron transport characteristics in $CF_4$ has been analysed over the E/N range 1~300[Td] by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, longitudinal diffusion coefficient, the ratio of the diffusion coefficient to the mobility, electron ionization and attachment coefficients, effective ionization coefficient, mean energy, collision frequency and the electron energy distribution function. The electron energy distribution function has been analysed in $CF_4$ at E/N=5, 10, 100, 200 and 300[Td] for a case of the equilibrium region in the mean electron energy and respective set of electron collision cross sections. The results of Boltzmann equation and Monte Carlo simulation have been compared with experimental data by Y. Nakamura and M. Hayashi. The swarm parameter from the swarm study are expected to serve as a critical test of current theories of low energy electron scattering by atoms and molecules, in particular, as well as crucial information for quantitative simulations of weakly ionized plasmas.

Prediction of chloride ingress into saturated concrete on the basis of a multi-species model by numerical calculations

  • Nguyen, T.Q.;Baroghel-Bouny, V.;Dangla, P.
    • Computers and Concrete
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    • v.3 no.6
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    • pp.401-422
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    • 2006
  • A multi-species model based on the Nernst-Planck equation has been developed by using a finite volume method. The model makes it possible to simulate transport due to an electrical field or by diffusion and to predict chloride penetration through water saturated concrete. The model is used in this paper to assess and analyse chloride diffusion coefficients and chloride binding isotherms. The experimental assessment of the effective chloride diffusion coefficient consists in measuring the chloride penetration depth by using a colorimetric method. The effective diffusion coefficient determined numerically allows to correctly reproduce the chloride penetration depth measured experimentally. Then, a new approach for the determination of chloride binding, based on non-steady state diffusion tests, is proposed. The binding isotherm is identified by a numerical inverse method from a single experimental total chloride concentration profile obtained at a given exposure time and from Freundlich's formula. In order to determine the initial pore solution composition (required as initial conditions for the model), the method of Taylor that describes the release of alkalis from cement and alkali sorption by the hydration products is used here. Finally, with these input data, prediction of total and water-soluble chloride concentration profiles has been performed. The method is validated by comparing the results of numerical simulations to experimental results obtained on various types of concretes and under different exposure conditions.

Modeling the effect of mass transfer on the kinetics of fructo-oligosaccharide production by immobilized cells (고정화 세포에 의한 Fructo-oligosaccharides 생산 반응메카니즘에서 물질전달 영향에 대한 수학적 모델)

  • 윤종원;전영중이민규송승구
    • KSBB Journal
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    • v.8 no.3
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    • pp.266-271
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    • 1993
  • The effective diffusion coefficients of glucose, sucrose and fructo-oligosaccharides in Ca-alginate gel beads at high concentration of sucrose solutions were investigated at $50^{\circ}C$. A mathematical model for the kinetics of fructo-oligosaccharide production using immobilized cells was proposed and compared with experimental results varying the bead size, the substrate concentration and the bead ratio. Very low values of diffusion coefficients ranging $1.2-7.6\times10^{-7}\textrm{cm}^2$/sec were obtained, and the predicted results were in good agreement with experimental ones in all cases tested.

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