• Title/Summary/Keyword: effective diffusion

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A Modified Enskog-Like Equation of Self-Diffusion Coefficients for Penetrable-Sphere Model Fluids

  • Suh, Soong-Hyuck;Liu, Hong-Lai
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1336-1340
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    • 2011
  • Molecular dynamics simulations have been performed to investigate the transport properties of self-diffusion coefficients in the penetrable-sphere model system. The resulting simulation data for the product of the packing fraction and the self-diffusion coefficient exhibit a transition from an increasing function of density in lower repulsive systems, where the soft-type collisions are dominant, to a decreasing function in higher repulsive systems, where most particle collisions are the hard-type reflections due to the low-penetrability effects. A modified Enskog-like equation implemented by the effective packing fraction with the mean-field energy correction is also proposed, and this heuristic approximation yields a reasonably good result even in systems of high densities and high repulsive energy barriers.

A Study on the Chloride Ion Diffusion Coefficient of Concrete by Submergence in Salt Water (침적시험에 의한 콘크리트의 염소이온 확산계수 평가)

  • 김동석;양승규;정연식;유재상;이종열;본간건일
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.297-300
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    • 2003
  • A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon. In this study, It is evaluated the diffusion coefficient of chloride ion in non-steady state by Fick's second law. Submergence method in salt water carried out in this experiment. Two types of cement which is different in mineral composition were used. In addition, the effect of mineral admixtures of blast-furnace slag and meta-kaolin was studied. In conclusion, the diffusion coefficient of chloride ion is much affected according to cement type and mineral admixtures, also, it is proved that meta-kaolin as well as blast-furnace slag is effective in preventing penetration of chloride ion.

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A MODEL STUDY ON MULTISTEP RECOVERY OF ACTINIDES BASED ON THE DIFFERENCE IN DIFFUSION COEFFICIENTS WITHIN LIQUID METAL

  • CHUN, YOUNG-MIN;SHIN, HEON-CHEOL
    • Nuclear Engineering and Technology
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    • v.47 no.5
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    • pp.588-595
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    • 2015
  • This study presents an effective method for additional recovery of residual actinides in liquid electrodes after the electrowinning process of pyroprocessing. The major distinctive feature of this method is a reactor with multiple reaction cells separated by partition walls in order to improve the recovery yield, thereby using the interelement difference in diffusion coefficients within the liquid electrode and controlling the selectivity and purity of element recovery. Through an example of numerical simulation of the diffusion scenarios of individual elements, we verified that the proposed method could effectively separate the actinides (U and Pu) and rare-earth elements contained in liquid cadmium. We performed a five-step consecutive recovery process using a simplified conceptual reaction cell and recovered 58% of the initial amount of actinides (U + Pu) in high purity (${\geq}99%$).

Improvement in Image Classification by GRF-based Anisotropic Diffusion Restoration (GRF기반이방성 분산 복원에 의한 분류 결과 향상)

  • 이상훈
    • Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
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    • 2004.03a
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    • pp.523-528
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    • 2004
  • This study proposed an anisotropic diffusion restoration fer image classification. The anisotropic diffusion restoration uses a probabilistic model based on Markov random field, which represents geographical connectedness existing in many remotely sensed images, and restores them through an iterative diffusion processing. In every iteration, the bonding-strength coefficient associated with the spatial connectedness is adaptively estimated as a function of brightness gradient. This study made experiments on the satellite images remotely sensed on the Korean peninsula. The experimental results show that the proposed approach is also very effective on image classification in remote sensing.

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Fundamental Study on the Production of TiFe Hydrogen Alloy by the Reduction-Diffusion Process (환원확산법에 의한 TiFe 수소 흡장합금의 제조에 관한 기초적 연구)

  • 권호영;일본명;일본명
    • Journal of the Korean Society of Safety
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    • v.8 no.2
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    • pp.3-9
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    • 1993
  • For comparison, we used Ca and Mg as reducers to produce TiFe hydrogen stroage alloy from Fe and TiO$_2$by the Reduction-Diffusion process. The results obtained were as follow. \circled1 Ca was found to be effective both for reduction and diffusion processes. Moreover, Ca oxide was easily removed in an NH$_4$Cl solution after the reaction. \circled2 In the case of using Ca as a reducer, the Reduction-Diffusion process is considered to take place in the foiling three steps. First, TiO$_2$is reduced to Ti by Ca over 100$0^{\circ}C$. Second, the atomic Ti drifts in the Ca melt and meets Fe particles. Finally, the atomic Ti diffuses in to the Fe particles. \circled3 In the case of using Mg as a reducer, We found that the reduction reaction of TiO$_2$went well. But the reduced Ti scarcely diffused into Fe particles. This was probably because no Mg melt was formed due to the high vapor pressure of Mg.

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On the use of spectral algorithms for the prediction of short-lived volatile fission product release: Methodology for bounding numerical error

  • Zullo, G.;Pizzocri, D.;Luzzi, L.
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1195-1205
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    • 2022
  • Recent developments on spectral diffusion algorithms, i.e., algorithms which exploit the projection of the solution on the eigenfunctions of the Laplacian operator, demonstrated their effective applicability in fast transient conditions. Nevertheless, the numerical error introduced by these algorithms, together with the uncertainties associated with model parameters, may impact the reliability of the predictions on short-lived volatile fission product release from nuclear fuel. In this work, we provide an upper bound on the numerical error introduced by the presented spectral diffusion algorithm, in both constant and time-varying conditions, depending on the number of modes and on the time discretization. The definition of this upper bound allows introducing a methodology to a priori bound the numerical error on short-lived volatile fission product retention.

A Study on Chloride Diffusion in Concrete Containing Lightweight Aggregate Using Crushed Stone-powder (폐석분을 활용한 경량골재 콘크리트의 염화물 확산에 관한 연구)

  • Lee, Dae-Hyuk;Yoon, Sang-Chen;Jeong, Yong;Shin, Jae-Kyung;Jee, Nam-Yong
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.255-262
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    • 2010
  • The purpose of this study is to provide preliminary data on chloride diffusion of lightweight aggregate concrete containing crushed stone-powder. Accordingly, the study performed experiments using concrete aggregates of Crushed Aggregate (CG), Single-sized Lightweight Aggregate (SLG), Continuous Graded Lightweight Aggregate (CLG), and using water-binder ratio of 0.4, 0.5, 0.6, and using binder of FA and BFS. The chloride diffusion coefficient is calculated according to the NT BUILD 492. Diffusion coefficient of SLG and CLG were higher than that of CG concrete, but the difference was not significant. Also, chloride diffusion coefficient data indicated that it was highly affected by water-binder ratio, and it decreased with the decrease in waterbinder ratio. The admixture substitution of FA15% was effective in decreasing the diffusion coefficient only with water-binder ratio of 0.4 while admixture substitution of FA10+BFS20% was effective with all levels of water-binder ratio. The result of study shows lightweight aggregate concrete containing crushed stone-powder has slightly higher chloride diffusion coefficient than CG concrete, but the difference is not significant such that it can be overcome by adjusting water-binder ratio and admixture substitution. In addition, the data indicate the chloride diffusion coefficient of lightweight aggregate concrete can be estimated from the strength of lightweight aggregate.

Diffusion of Phenol in Apples (사과 내에서 페놀의 확산)

  • Park, Hyeon Ju;Choi, Dong Ho;Chung, Kyong-Hwan;Song, Yo Soon;Seo, Gon
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.572-578
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    • 2006
  • The accumulation of phenol in apples was measured by exposing them to phenol vapor at $25^{\circ}C$. The effective diffusivities of phenol in the rind and flesh of apples were estimated by comparing the experimentally determined fractional uptake curve with the simulated ones based on a consecutive diffusion model in the rind and flesh. Phenol was detected in the flesh of apples after 5 day exposure due to its slow diffusion in the rind. The consecutive diffusion model of phenol in apples simulated well the measured fractional uptake curve when the effective diffusivities of phenol in the rind and flesh were assumed to be $5.0{\times}10^{-13}m^2/s$ and $1.5{\times}10^{-10}m^2/s$, respectively.

The Government's Role Model for The Effective Adoption of The UIT (유비쿼터스 정보기술의 효과적 도입을 위한 정부역할 모형)

  • Kim, Tae-Jin
    • Spatial Information Research
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    • v.18 no.4
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    • pp.55-64
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    • 2010
  • Since 2004, as Ubiquitous Information Technology that is new information technology paradigm has emerged, the necessity of government's role has been raised. In order to understand the government's role model for the effective use of the Ubiquitous Information Technology, this article closely analysed the process of the information policy in Korea. To accomplish these purpose the literature review and the exploratory research were used. The intent of this study was to analyze the government's role in the process of the information policy. Following are the major findings of this study. First. the government's role in driving the new information policy must be considered for the effective adopt and diffusion of the new information technology'. Second, three stages(adopt, diffusion, evaluation) are considered in the process of Korea information policy. Third, the revised government's role model is needed for the effective use of the new information technology in the future. In this study, I suggested the revised government's role model, that is consist of four stages. plan. adopt. diffusion, and performance and evaluation stage.

The Characteristics of Turbulent Diffusion Flame Impinging on the Wall (벽면 충돌 난류 확산화염의 특성)

  • Park, Yong Youl;Kim, Ho Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.2
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    • pp.175-184
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    • 1999
  • A theoretical study on the turbulent round jet diffusion flame impinging on the wall was carried out to predict the characteristics and structure of Impinging jet flame and heat transfer to the wall. Finite chemistry via Arrhenius equation and eddy dissipation model was adopted as a combustion model, and the Favre averaging and $k-{\varepsilon}$ model were Introduced In the theoretical modeling. The SIMPLE algorithm was applied to the calculation. All the transport properties were considered as the variable depending on the temperature and composition. For the parametric study, the distance from nozzle to impinging wall and Reynolds number at nozzle exit were chosen 88 the major parameters. As the results of the present study, the characteristics of flow fields, the distributions of main variables and each chemical species and the flame shapes were obtained. The heat transfer rate from the flame to the wall and the effective heating area were calculated to investigate the Influences of the major parameters on the heat transfer characteristics.