• Title/Summary/Keyword: effective diffusion

검색결과 844건 처리시간 0.032초

Optimization of Washing Process for the Recycling of Potassium in the Manufacturing of Activated Carbon (활성탄 제조공정의 칼륨 재이용을 위한 세척공정 최적화)

  • Lee, Gi-bbum;Jung, Hee-Suk;Hong, Bum-ui;Kim, Seokhwi;Choi, Suk-soon
    • Journal of the Korea Organic Resources Recycling Association
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    • 제25권3호
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    • pp.63-71
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    • 2017
  • In this study, washing parameters such as washing time, agitation velocity, and cycles were optimized for high surface area of the activated carbon (AC) by KOH activation. Even though AC with high surface area showed at higher washing efficiency, over 90% on washing efficiency was regulated by the intra-particle diffusion due to high tortuosity of the pore structures on AC. In addition, we can obtain $K_2CO_3$ through the evaporation from the wastewater and use it for chemical activation of AC. The AC with $K_2CO_3$ activation has specific surface area values of $2,219m^2/g$ equally that of KOH activation. Considering that $K_2CO_3$ is an effective alternative as a KOH, our results demonstrated that the process by recycling wastewater on AC production could be applicable for near-zero wastes.

Heat-treatment of Diffusional Behaviors of Plasma Spray Coated Layer for Fabrication of Abrasive Plates for Diamond (다이아몬드 가공을 위한 연마판의 제조 및 플라즈마 용사 코팅층의 열처리 거동)

  • Choi, Kwangsu;Yang, Seunga;Lee, Jong wan;Kim, Minkyu;Lee, Seong jun;Park, Joon Sik
    • Journal of the Korean Society for Heat Treatment
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    • 제30권6호
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    • pp.264-270
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    • 2017
  • In this study, while the abrasive plates for diamond have been prepared through mechanical alloying and sintering of elemental powders, a fabrication route of plasma thermal coatings has been adopted for the first time. When diamond knife is sharped or polished, a metal plate has been applied, which is made of mechanical alloying and sintering. In this study, in order to develop a cost - effective manufacturing process, plasma coatings of FeCrNi and Ti on cast iron plate were applied together with Al intermediate layer coatings. The plasma coatings were successfully performed, and the optimum coating layer conditions were discussed in terms of micro-structural observations at the interfaces.

CNT-PDMS Composite Thin-Film Transmitters for Highly Efficient Photoacoustic Energy Conversion

  • Song, Ju Ho;Heo, Jeongmin;Baac, Hyoung Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.297.2-297.2
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    • 2016
  • Photoacoustic generation of ultrasound is an effective approach for development of high-frequency and high-amplitude ultrasound transmitters. This requires an efficient energy converter from optical input to acoustic output. For such photoacoustic conversion, various light-absorbing materials have been used such as metallic coating, dye-doped polymer composite, and nanostructure composite. These transmitters absorb laser pulses with 5-10 ns widths for generation of tens-of-MHz frequency ultrasound. The short optical pulse leads to rapid heating of the irradiated region and therefore fast thermal expansion before significant heat diffusion occurs to the surrounding. In this purpose, nanocomposite thin films containing gold nanoparticles, carbon nanotubes (CNTs), or carbon nanofibers have been recently proposed for high optical absorption, efficient thermoacosutic transfer, and mechanical robustness. These properties are necessary to produce a high-amplitude ultrasonic output under a low-energy optical input. Here, we investigate carbon nanotube (CNT)-polydimethylsiloxane (PDMS) composite transmitters and their nanostructure-originated characteristics enabling extraordinary energy conversion. We explain a thermoelastic energy conversion mechanism within the nanocomposite and examine nanostructures by using a scanning electron microscopy. Then, we measure laser-induced damage threshold of the transmitters against pulsed laser ablation. Particularly, laser-induced damage threshold has been largely overlooked so far in the development of photoacoustic transmitters. Higher damage threshold means that transmitters can withstand optical irradiation with higher laser energy and produce higher pressure output proportional to such optical input. We discuss an optimal design of CNT-PDMS composite transmitter for high-amplitude pressure generation (e.g. focused ultrasound transmitter) useful for therapeutic applications. It is fabricated using a focal structure (spherically concave substrate) that is coated with a CNT-PDMS composite layer. We also introduce some application examples of the high-amplitude focused transmitter based on the CNT-PDMS composite film.

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Antioxidant Activity and Antimicrobial Effect for Foodborne Pathogens from Extract and Fractions of Sanguisorba officinalis L. (지유 추출물 및 분획물의 항산화 활성과 식중독 원인균에 대한 항균활성)

  • Seo, Go Eun;Kim, Sun Min;Pyo, Byoung Sik;Yang, Sun A
    • Korean Journal of Medicinal Crop Science
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    • 제24권4호
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    • pp.303-308
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    • 2016
  • Background: This study aimed to investigate the antioxidat and antimicrobial activities of the methanol extract and its fractions prepared from the roots of Sanguisorba officinalis L. Methods and Results: The antioxidant activities were compared by evaluating the DPPH radical and nitric oxide (NO) scavenging ability. Measurement of DPPH radical scavenging ability showed that the $SC_{50}$ values of the ethyl acetate fraction was $3.85{\mu}g/m{\ell}$. The ethyl acetate fraction exhibited the most effective DPPH radical scavenging ability compared with the other samples. As for the NO scavenging ability, at all tested concentrations, the ethyl acetate fraction showed a higher scavenging activity than that of the extract and other fractions. These results are related to the total phenolic compound and flavonoid contents of the ethyl acetate fraction. Antimicrobial activity against foodborne pathogens was investigated using the disc diffusion assay. The ethyl acetate fraction showed the highest antimicrobial activity against gram-positive Staphylococcus aureus and Bacillus cereus. However, the chloroform fraction had a higher antimicrobial activity against gram-negative Vibrio vulnificus than that of the extract and other fractions. Conclusions: The results show that the ethyl acetate fraction had a higher antioxidant as well as antimicrobial activity, than did the other samples. Therefore, the ethyl acetate fraction has potential application in the food industry.

A Study on the Electrochemical Characterization of Stainless Steel in Triethanolamine Solution (트리에탄올아민용액에서 스테인리스강의 전기 화학적 특성)

  • Park, Jin-Hyeog;Lee, Jong-Ho;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • 제32권2호
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    • pp.275-280
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    • 2015
  • In this study, the current-voltage curves for stainless steel in the triethanolamine(TEA) solution was measured using the conventional three electrodes of cyclic voltammetry. Stainless steel as working electrode, Ag/AgCl electrode as reference electrode and Pt wire as counter electrode were used respectively. As a result, the C-V characteristics of stainless steel were to be for an irreversible process due to the oxidation current from cyclic voltammogram, using triethanolamine solutions. Effective diffusivity of corrosion inhibitors was decreased with increasing concentration. And the concentration of 0.5 N $NaClO_4$, $2.5{\times}10^{-3}M$ TEA solution when the corrosion inhibition effect is most great, and 1.5 N $NaClO_4$, $1.0{\times}10^{-3}M$ TEA solution, the lowest corrosion inhibition effect.

The Effect of Personal Value Disposition on the Consumer Attitude of Advertising Appeal Type (개인의 가치성향이 광고 소구유형에 따라 소비자 태도에 미치는 영향)

  • Sung, Ki-Hyeok
    • The Journal of the Korea Contents Association
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    • 제9권12호
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    • pp.154-163
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    • 2009
  • A new advertising, unlike traditional advertising, has a unique characteristics as a consumer's life styles are changed. This study explores consumer attitude affected by personal value disposition of each advertising creative appeal types. Personal value disposition implies directions of creative and determines advertising effect. So, personal value disposition deserves special consideration of not only print media, but broadcast media and internet media. In the present study, Research has been performed for a diffusion analysis based upon a survey of 338 individuals who were selected randomly. Test advertisement of MP3 Player has been used because involvement of products takes a neutral attitude comparatively. Result from the experiment show that, individualism-rational appeal is the most effective for consumers attitude. Groupism-rational appeals affects consumer's attitude, either. Groupism-emotional appeal has a partial effect and individualism-emotional appeal has no statistical significance. This experiment can be a foundation stone of personal value disposition studies.

Characterization and Solution Behavior of Polyethylene-based Ionomer Particles in Water (물에서의 폴리에틸렌계 아이오노머 입자 특성과 용액 거동)

  • Yeo, Sang Ihn;Woo, Kyu Whan
    • Journal of the Korean Chemical Society
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    • 제42권5호
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    • pp.512-518
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    • 1998
  • In this study, various thermodynamic and hydrodynamic parameters characterizing the solution properties of polyethylene ionomer particles in water were determined at $30^{\circ}C$ by means of light scattering and viscosity measurements. Based on the experimental data, we investigated the solution behavior of three kinds of polyethylene ionomers, which are different in composition of the pendant ionic groups of COOK, COOH and $CONH_{2}$, and characterized their particle properties. Ionomers containing 7.6 mol% potassium salt only behave as flexible coils in a relatively good solvent state. On the other hand, two ionomers containing 3.8 mol% amide group together with potassium salt form the compact particles. In addition, the concentration dependence of the effective diffusion coefficient $(D_{eff})$ and the reduced viscosity of the latter ionomers showed the opposite trend from the former, indicating that the composition of the pendant ionic groups have a great influence on the interparticle interaction of ionomers formed in water.

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Effect of various chromatographic terpenoid fractions of Luffa cylindrica seeds on in-vitro antimicrobial studies

  • Nagarajan, K.;Saxena, Pallavi;Mazumder, Avijit;Ghosh, L.K.;Devi, G. Uma
    • Advances in Traditional Medicine
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    • 제10권1호
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    • pp.21-28
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    • 2010
  • The objective of the present investigation is to evaluate the antimicrobial potency of the terpenoid fractions isolated from Luffa cylindrica seeds against various pathogenic microbes. The seeds were powdered and extracted with methanol in soxhlet appratus based on phytochemical screening. Three terpenoid components were isolated by column chromatography and identified by thin layer chromatography and chemical analysis which were designated as ${LCSF_4}^*$, ${LCSF_6}^*$ & ${LCSF_8}^*$ respectively. Disc diffusion method was employed to determine the antimicrobial effectiveness of test compounds I, II and III $({LCSF_4}^*,\;{LCSF_6}^*\;&\;{LCSF_8}^*)$ against 6 microbial species viz., Staphylococcus (S.) aureus, Bacillus (B.) subtilis, Escherichia (E.) coli, Pseudomonas (P.) aeruginosa, Candida (C.) albicans and Aspergillus niger. The disc was saturated with $100{\mu}l$ of each compound, allowed to dry and introduced on the upper layer of seeded agar plate. The plates were incubated overnight at $37^{\circ}C$. Microbial growth was determined by measuring the zonal inhibition diameters. Compound I showed maximum potency against gram positive S. aureus (21 mm) in comparison with standard ciprofloxacin (38 mm), whereas the same compound was completely devoid of activity against both the fungi tested. Compound II was found to be highly sensitive against both the gram negative E. coli (20 mm) and P. aeruginosa (22 mm). Compound II was found to exhibit maximum potency against the fungi C. albicans (15 mm) and A. niger (20 mm). Compound III was found to be very effective against both the gram positive S. aureus (20 mm) and B. subtilis (15 mm) respectively.

Effect of the Pore Structure on the Anodic Property of SOFC (SOFC 음극의 기공구조가 음극특성에 미치는 영향)

  • 허장원;이동석;이종호;김재동;김주선;이해원;문주호
    • Journal of the Korean Ceramic Society
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    • 제39권1호
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    • pp.86-91
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    • 2002
  • Solid Oxide Fuel Cells (SOFC) are of great interest of next generation energy conversion system due to their high energy efficiency and environmental friendliness. The basic SOFC unit consists of anode, cathode and solid electrolyte. Among these components, anode plays the most important role for the oxidation of fuel to generate electricity and also behaves as a substrate of the whole cell. It is normally requested that the anode materials should have the high electrical conductivity and gas permeability to reduce the polarization loss of the cell. In this study, the effect of pore former on the microstructure of anode substrate was investigated and thus on the electrical conductivity and the gas permeability. According to the results, microstructure and electrical conductivity of anode substrate were greatly influenced by the shape of pore former and especially by the anisotrpy of the pore former. The use of anisotropic pore former is supposed to deteriorate the cell performance by which the electrical conduction path is disconnected but also the effective gas diffusion path for the fuel is reduced.

A Study on Failure Mechanism of Reinforced Earth Retaining Wall under Strip Load (대상하중하의 보강토옹벽의 파괴 메카니즘에 관한 연구)

  • 유남재;김영길
    • Geotechnical Engineering
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    • 제7권4호
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    • pp.35-48
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    • 1991
  • Based on centrifuge model tests, the failure mechanism of reinforced earth retaining wall under strip load was investigated in this paper. Tests were performed by changing the materials of reinforcing strips, strip lengths, and strip arrangements. The strips were strain-gauged to measure the tensions in strips. The results were analyzed and compared with various design methosds in use to verify their feasibility. Consequently, a centrifuge model test was an effective method of investigating the behavior of reinforced earth retaining wall. The 2 : 1 stress diffusion method showed comparable results with tests in estimating the capacity of the reinforced earth wall under strip load. The superposition of tensions due to selfweight of the backfill and strip load was valid to estimate total tensions mobilized in strips. Using the elasticity theory to estimate the maximum tension mobilized in strips due to surcharge, while solutions of Boussinesq and Westergaard underestimated less tensions than the measured valises, Frohlich solution showed the comparable results with tests.

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