• Title/Summary/Keyword: effective diffusion

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Condensable Gas Separation using Phenol! Alumina Composite Activated Carbon Hollow Fiber Membranes (페놀수지/알루미나 복합 활성탄소중공사막을 이용한 응축성 기체 분리)

  • Shin, Kyung-Yong;Park, You-In;Kim, Beom-Sik;Koo, Kee-Kahb
    • Membrane Journal
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    • v.20 no.4
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    • pp.312-319
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    • 2010
  • Carbon membrane materials have received considerable attention for the gas separation including hydrocarbon mixture of ingredients of the volatile organic compounds(VOCs) because they possess their higher selectivity, permeability, and thermal stability than the polymeric membranes. The use of activated carbon membranes makes it possible to separate continuously the VOCs mixture by the selective adsorption-diffusion mechanism which the condensable components are preferentially adsorbed in to the micropores of the membrane. The activated carbon hollow fiber membranes with uniform adsorptive micropores on the wall of open pores and the surface of the membranes have been fabricated by the carbonization of a thin film of phenolic resin deposited on porous alumina hollow fiber membrane. Oxidation, carbonization, and activation processing variables were controlled under different conditions in order to improve the separation characteristics of the activated carbon membrane. Properties of activated carbon hollow fiber membranes and the characterization of a gas permeation by pyrolysis conditions were studied. As the result, the activated carbon hollow fiber membranes with good separation capabilities by the molecular size mechanism as well as selective adsorption on the pores surface followed by surface diffusion effective in the recovery hydrocarbons have been obtained. Therefore, these activated carbon membranes prepared in this study are shown as promising candidate membrane for separation of VOCs.

Mechanism of Action of Fatty Alcohol Ethoxylate on Foliar Penetration of Dimethomorph into Cucumber (Fatty Alcohol Ethoxylate에 의해 유도되는 Dimethomorph의 오이 엽면 침투 기작)

  • Yu, Ju-Hyun
    • The Korean Journal of Pesticide Science
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    • v.12 no.2
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    • pp.127-133
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    • 2008
  • The foliar uptake of dimethomorph into cucumber was assessed by spray application of aqueous dimethomorph solution containing fatty alcohol ethoxylate (FAE) or fatty acid alkyl ester as activator adjuvants. Afterward, the possible mechanism of action of FAE on foliar penetration of active ingredient was suggested by speculating on the effect of lipophile and hydrophile of FAEs. The amount of absorbed dimethomorph induced by polyoxyethylene mono-9-octadecenyl ether (6 moles ethylene oxide, $C_{18=9}E_6$) was linearly related to the concentrations of surfactant as well as dimethomorph in spray solution, suggesting that it is simply a diffusion phenomenon of the solute molecule through a cuticular membrane from leaf surface. Octadecanol attached to FAE was most effective lipophile on the leaf penetration of dimethomorph. And, the more ethylene oxide had the polyoxyethylene chain of FAE up to 20 moles, the higher the uptake rate was. Therefore, the role of lipophile of FAE on dimethomorph penetration to cucumber leaf, probably, is to modify the physico-chemical properties of cuticular membrane to be permeable to dimethomorph, and the polyoxyethylene chain having less than 20 moles ethylene oxide, which is moderately permeable to cuticular membrane by its molar volume, is to let the physically-modified cuticular membrane to be maintained for a longtime.

Antimicrobial Effect of Garlic Extract against Pathogenic Bacteria (병원성 세균에 대한 마늘추출물의 항균효과)

  • Moon, Weon-Hee;Yook, Keun-Dol
    • Journal of Digital Convergence
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    • v.12 no.10
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    • pp.477-484
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    • 2014
  • The purpose of this study is to verify the antimicrobial effect of garlic and black garlic against pathogenic bacteria. For the comparative analysis of antibacterial effects of garlic, Ampicillin $10{\mu}g$ (BBL) was used as control antibiotics. Research experiments were conducted on each of November 2013 and January 2014. Susceptibility to the antimicrobial effect was measured through Kirby-Bauer disc diffusion method and verified according to the standard proposed by the CLSI. Antimicrobial effect of fresh garlic was higher regardless of the method to extract than Ampicillin $10{\mu}g$. In contrast, the manufacturing methods of the black garlic had no effective differentiations. In antimicrobial susceptibility test, black garlic showed resistance to all of 4 strains. However, in the ethanol-extract of fermented black garlic(natural aging of 15 days.) was found the small changes of the growth-inhibition-zone against S. aureus (8 mm)and E. coli(7 mm). This study proposes a variety attempts about the extraction methods of black garlic for the possibility of food preservation.

Probabilistic Service Life Analysis of GGBFS Concrete Exposed to Carbonation Cold Joint and Loading Conditions (탄산화에 노출된 GGBFS 콘크리트의 콜드 조인트 및 하중 재하를 고려한 확률론적 내구수명 해석)

  • Kim, Tae-Hoon;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.39-46
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    • 2020
  • Carbonation is a deterioration which degrades structural and material performance by permitting CO2 and corrosion of embedded steel. Service life evaluation through deterministic method is conventional, however the researches with probabilistic approach on service life considering loading and cold joint effect on carbonation have been performed very limitedly. In this study, probabilistic service life evaluation was carried out through MCS (Monte Carlo Simulation) which adopted random variables such as cover depth, CO2 diffusion coefficient, exterior CO2 concentration, and internal carbonatable materials. Probabilistic service life was derived by changing mean value and COV (Coefficient of variation) from 100 % to 300 % and 0.1 ~ 0.2, respectively. From the analysis, maximum reduction ratio (47.7%) and minimum reduction ratio (11.4%) of service life were obtained in cover depth and diffusion coefficient, respectively. In the loading conditions of 30~60% for compressive and tensile stress, GGBFS concrete was effective to reduce cold joint effect on carbonation. In the tensile condition, service life decreased linearly regardless of material types. Additionally service life rapidly decreased due to micro crack propagation in the all cases when 60% loading was considered in compressive condition.

A Study on the Fine Dust Removal Equipment of Pressurized Water type for the Removal of Exhaust Gas Fine Dust and Volatile Organic Compounds from the Non-industrial combustion plant (비산업 연소 사업장 배출 가스상 미세먼지와 휘발성 유기 화합물 제거를 위한 가압수식 미세먼지 제거 장치 연구)

  • Youn, Jae-Seo;Kim, Sang-Min;Lee, Ye-Ji;Noh, Seong-Yeo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.11
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    • pp.506-512
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    • 2018
  • The fine dust generated in the home and restaurant business occupies a low ratio of about 4% of the total fine dust emissions. However, at the foodservice business, the rate of change of the pollutant concentration is very high, so that the temporary fine dust concentration can be measured up to 60 times. The pollutants generated from non-industrial combustion plants consist of particulate fine dust and gaseous organic compounds. To remove these pollutants, cleaning dust collection system, which is an effective system for simultaneous removal of gaseous and particulate matter, is applied. This is a method of increasing the probability of diffusion capture of the Brownian motion by pressurized liquid injection method using the atomizing nozzle. The dust removal efficiency of the fine dust collecting system was analyzed by nozzle spraying air pressure condition and angle using the manufactured fine dust removing system. As a result, it was confirmed that the efficiency of removal of fine dust and gaseous organic compounds was more than 90%. The developed system is expected to be highly usable in the future because it can remove particulate dust from the existing plant hood system without any installation cost.

A Study on the Ventilation Effects of the Shaft Development at a Local Limestone Mine (국내 석회석 광산 수갱 굴착에 의한 통기효과 분석 연구)

  • Lee, Changwoo;Nguyen, Van Duc;Kubuya, Kiro Rocky;Kim, Chang O
    • Tunnel and Underground Space
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    • v.28 no.6
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    • pp.609-619
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    • 2018
  • This study was carried out at a local limestone mine to analyze the ventilation efficiency of the shaft equipped with a main fan. The results show that its ventilation efficiency is clearly verified for the natural as well as the mechanical ventilation. The airflow rate of $11.7m^3/s$ was induced by the natural ventilation force and the maximum quantity is almost same as the airflow rate estimated by monitoring the average temperatures in the upcast and downcast air columns. Meanwhile, the airflow rate exhausted by the main fan through the shaft was $20.3{\sim}24.8m^3/s$; variation of the quantity was caused by the upward shift of the mine ventilation characteristic curve due to the frequent movement of the equipment. This indicates efforts are required to reduce the ventilation resistance and raise the quantity supplied by the main fan. The turbulent diffusion coefficients along the 1912 m long airway from the portal to the shaft bottom was estimated to be $15m^2/s$ and $18m^2/s$. Since these higher coefficients imply that contaminants will be dispersed at a faster velocity than the airflow, prompt exhaust method should be planned for the effective air quality control. The ventilation shaft and main fan are definitely what local limestone mines inevitably need for better working environment and sustainable development.

Adsorption Characteristics of Brilliant Green by Coconut Based Activated Carbon : Equilibrium, Kinetic and Thermodynamic Parameter Studies (야자계 입상 활성탄에 의한 brilliant green의 흡착 특성 : 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.25 no.3
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    • pp.198-205
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    • 2019
  • The adsorption equilibrium, kinetic, and thermodynamic parameters of brilliant green adsorbed by coconut based granular activated carbon were determined from various initial concentrations ($300{\sim}500mg\;L^{-1}$), contact time (1 ~ 12 h), and adsorption temperature (303 ~ 323 K) through batch experiments. The equilibrium adsorption data were analyzed by Langmuir, Freundlich, Temkin, Harkins-Jura, and Elovich isotherm models. The estimated Langmuir dimensionless separation factor ($R_L=0.018{\sim}0.040$) and Freundlich constant ($n^{-1}=0.176{\sim}0.206$) show that adsorption of brilliant green by activated carbon is an effective treatment process. Adsorption heat constants ($B=12.43{\sim}17.15J\;mol^{-1}$) estimated by the Temkin equation corresponded to physical adsorption. The isothermal parameter ($A_{HJ}$) by the Harkins-Jura equation showed that the heterogeneous pore distribution increased with increasing temperature. The maximum adsorption capacity by the Elovich equation was found to be much smaller than the experimental value. The adsorption process was best described by the pseudo second order model, and intraparticle diffusion was a rate limiting step in the adsorption process. The intraparticle diffusion rate constant increased because the dye activity increased with increases in the initial concentration. Also, as the initial concentration increased, the influence of the boundary layer also increased. Negative Gibbs free energy ($-10.3{\sim}-11.4kJ\;mol^{-1}$), positive enthalpy change ($18.63kJ\;mol^{-1}$), and activation energy ($26.28kJ\;mol^{-1}$) indicate respectively that the adsorption process is spontaneous, endothermic, and physical adsorption.

A Comparative Study of Text analysis and Network embedding Methods for Effective Fake News Detection (효과적인 가짜 뉴스 탐지를 위한 텍스트 분석과 네트워크 임베딩 방법의 비교 연구)

  • Park, Sung Soo;Lee, Kun Chang
    • Journal of Digital Convergence
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    • v.17 no.5
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    • pp.137-143
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    • 2019
  • Fake news is a form of misinformation that has the advantage of rapid spreading of information on media platforms that users interact with, such as social media. There has been a lot of social problems due to the recent increase in fake news. In this paper, we propose a method to detect such false news. Previous research on fake news detection mainly focused on text analysis. This research focuses on a network where social media news spreads, generates qualities with DeepWalk, a network embedding method, and classifies fake news using logistic regression analysis. We conducted an experiment on fake news detection using 211 news on the Internet and 1.2 million news diffusion network data. The results show that the accuracy of false network detection using network embedding is 10.6% higher than that of text analysis. In addition, fake news detection, which combines text analysis and network embedding, does not show an increase in accuracy over network embedding. The results of this study can be effectively applied to the detection of fake news that organizations spread online.

Evaluation of 12nm Ti Layer for Low Temperature Cu-Cu Bonding (저온 Cu-Cu본딩을 위한 12nm 티타늄 박막 특성 분석)

  • Park, Seungmin;Kim, Yoonho;Kim, Sarah Eunkyung
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.3
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    • pp.9-15
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    • 2021
  • Miniaturization of semiconductor devices has recently faced a physical limitation. To overcome this, 3D packaging in which semiconductor devices are vertically stacked has been actively developed. 3D packaging requires three unit processes of TSV, wafer grinding, and bonding, and among these, copper bonding is becoming very important for high performance and fine-pitch in 3D packaging. In this study, the effects of Ti nanolayer on the antioxidation of copper surface and low-temperature Cu bonding was investigated. The diffusion rate of Ti into Cu is faster than Cu into Ti in the temperature ranging from room temperature to 200℃, which shows that the titanium nanolayer can be effective for low-temperature copper bonding. The 12nm-thick titanium layer was uniformly deposited on the copper surface, and the surface roughness (Rq) was lowered from 4.1 nm to 3.2 nm. Cu bonding using Ti nanolayer was carried out at 200℃ for 1 hour, and then annealing at the same temperature and time. The average shear strength measured after bonding was 13.2 MPa.

Experimental Study for Consolidating Materials for Conservation Treatment of Woodblock (목판 문화재 보존처리를 위한 강화처리제 연구)

  • Jo, Sang Yoon;Park, Jung Hae;Kim, Soo Chul
    • Journal of Conservation Science
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    • v.38 no.2
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    • pp.166-179
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    • 2022
  • A test piece was produced using deteriorated pine tree for the conservation treatment of woodblocks cultural heritage, and weight change, color change and penetration diffusion characteristics of the test piece according to the application of Dammar, Wax, Paraloid B-72, Animal glue and H.P.C treatment agent. As a result, it was confirmed that Dammar is the most suitable treatment agent for the strengthening of the material while maintaining the original color of the wood. A test piece was produced using deteriorated porous natural wood, which the damage condition is similar to that of woodblocks cultural heritage and the main tree of woodblocks cultural heritage based on above result, and the application of each Dammar concentration (2%, 5%) and wetting of each Dammar concentration (10%, 15%) were conducted in order to find out the application concentration and treatment method of Dammar, and weight change, penetration diffusion characteristics, etc. were observed. As a result, it was found that the Dammar 2% application was the best as an effective method for the strengthening of the material while maintaining the original color of the wood. Therefore, it is judged that Dammar 2% application is most suitable for the strengthening treatment of woodblocks cultural heritage with severe insect damage and degradation.