• 제목/요약/키워드: effective diffusion

검색결과 844건 처리시간 0.03초

12% Cr 강의 크리이프중 전위거동에 관한 연구 (Study on the Dislocation Behavior during Creep in 12% Chromium Steel)

  • 오세욱;장윤석
    • 한국해양공학회지
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    • 제4권2호
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    • pp.262-262
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    • 1990
  • In order to check the effect of dislocation behavior on creep rate in 12% Chromium steel, 14 samples of different compositions were examined by creep rupture test, and subgrain sizes, distribution of dislocations and precipitates were checked. And, authors reviewed the behaviors of dislocations, the formation and growth of subgrains and precipitates during creep. The results are as the following: 1) Creep rates calculated by .epsilon. over dot = .rho.bv show 10-15% higher values than actual data measured. However, authors conclude that the density and velocity of dislocations together with subgrain size are important factors governing deformation during creep in 12% chromium steel. 2) The values of the strength of obstacles in the mobility of dislocations are more clearly depended on the effective stress in the range of $10{\pm}5kgf/mm^{2}$ and increase with the increase of temperature. 3) Creep rates decrease with the smaller sizes of subgrains formed and can result in the longer creep rupture lives(hours). The smaller subgrains can be made by forming shorter free gliding distances of dislocations with very fine precipitates formed in the matrix during creep by applying proper alloy design. 4) Dislocation mobility gets hindered by precipitates occurring, which are coarsened by the softening process governed by diffusion during long time creep.

12% Cr 강의 크리이프중 전위거동에 관한 연구 (Study on the Dislocation Behavior during Creep in 12% Chromium Steel)

  • 오세욱;장윤석
    • 한국해양공학회지
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    • 제4권2호
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    • pp.112-120
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    • 1990
  • In order to check the effect of dislocation behavior on creep rate in 12% Chromium steel, 14 samples of different compositions were examined by creep rupture test, and subgrain sizes, distribution of dislocations and precipitates were checked. And, authors reviewed the behaviors of dislocations, the formation and growth of subgrains and precipitates during creep. The results are as the following: 1) Creep rates calculated by .epsilon. over dot = .rho.bv show 10-15% higher values than actual data measured. However, authors conclude that the density and velocity of dislocations together with subgrain size are important factors governing deformation during creep in 12% chromium steel. 2) The values of the strength of obstacles in the mobility of dislocations are more clearly depended on the effective stress in the range of $10{\pm}5kgf/mm^{2}$ and increase with the increase of temperature. 3) Creep rates decrease with the smaller sizes of subgrains formed and can result in the longer creep rupture lives(hours). The smaller subgrains can be made by forming shorter free gliding distances of dislocations with very fine precipitates formed in the matrix during creep by applying proper alloy design. 4) Dislocation mobility gets hindered by precipitates occurring, which are coarsened by the softening process governed by diffusion during long time creep.

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CF4 기체에서의 전리와 부착계수 (Ionization and Attachment Coefficients in CF4)

  • 김상남
    • 전기학회논문지P
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    • 제60권1호
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    • pp.27-31
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    • 2011
  • In this paper, the electron transport characteristics in $CF_4$ has been analysed over the E/N range 1~300[Td] by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, longitudinal diffusion coefficient, the ratio of the diffusion coefficient to the mobility, electron ionization and attachment coefficients, effective ionization coefficient, mean energy, collision frequency and the electron energy distribution function. The electron energy distribution function has been analysed in $CF_4$ at E/N=5, 10, 100, 200 and 300[Td] for a case of the equilibrium region in the mean electron energy and respective set of electron collision cross sections. The results of Boltzmann equation and Monte Carlo simulation have been compared with experimental data by Y. Nakamura and M. Hayashi. The swarm parameter from the swarm study are expected to serve as a critical test of current theories of low energy electron scattering by atoms and molecules, in particular, as well as crucial information for quantitative simulations of weakly ionized plasmas.

어플라이언스 시스템의 혁신특성과 품질이 채택의도에 미치는 영향에 관한 연구 (A Study on the Effects of Innovation Characteristics and Quality of Appliance Systems on Intention to Adopt)

  • 유응준;김용희;박영주;최정일
    • 품질경영학회지
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    • 제43권3호
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    • pp.421-438
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    • 2015
  • Purpose: The purpose of this study was to grasp the level of effects innovative features and quality of the appliance system on organizational performance and ultimately analyze the willingness of the IT staff to adopt an appliance system. Methods: The survey was conducted on 350 vendors' clients and partners who currently use an appliance system from March to May 2014. A total of 331 effective questionnaires were collected and analyzed using PASW18 and SmartPLS. Results: The results show that relative advantage, facilitating condition and trialability and quality factors all had an effect on organizational performance expectations. Further, when an appliance system is adopted, it was shown that cost and reliability emphasized by a vendor did not produce any significant effects on organizational performance expectations. Conclusion: This study is significant as it is the first to combine such models as Innovation Diffusion Theory, Information Systems Success Model, and Unified Theory of Acceptance and Use of Technology with a new external variable. In addition, it illustrated how variables affect the adoption of an appliance system such as a new innovation system.

나노 CMOS 소자 적용을 위한 질소 분위기에서 형성된 질화막을 이용한 폴리실리콘 적층 구조 (A Stacked Polusilicon Structure by Nitridation in N2 Atmosphere for Nano-scale CMOSFETs)

  • 호원준;이희덕
    • 한국전기전자재료학회논문지
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    • 제18권11호
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    • pp.1001-1006
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    • 2005
  • A new fabrication method is proposed to form the stacked polysilicon gate by nitridation in $N_2$ atmosphere using conventional LP-CVD system. Two step stacked layers with an amorphous layer on top of a polycrystalline layer as well as three step stacked layers with polycrystalline films were fabricated using the proposed method. SIMS profile showed that the proposed method would successfully create the nitrogen-rich layers between the stacked polysilicon layers, thus resulting in effective retardation of dopant diffusion. It was observed that the dopants in stacked films were piled-up at the interface. TEM image also showed clear distinction of stacked layers, their plane grain size and grain mismatch at interface layers. Therefore, the number of stacked polysilicon layers with different crystalline structures, interface position and crystal phase can be easily controlled to improve the device performance and reliability without any negative effects in nano-scale CMOSFETs.

EVALUATION OF IN VITRO SKIN PERMEATION OF UV FILTERS

  • Song, Young-Sook;Kim, Hyo-Joong;Lee, Cheon-Koo;Cho, Wan-Goo;Kang, She-Hoon
    • 대한화장품학회지
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    • 제24권3호
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    • pp.38-44
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    • 1998
  • The skin permeation and the skin primary irritation of two UV filters from caprylic capryl triglyceride (oil), oil in water (O/W) and water in oil (W/O) emulsions, were evaluated. We selected octyl moth-oxycinnamate (OMC) broadly used in cosmetics and polymeric sunscreen agent (PSA, average MW: 2,000) synthesized by the coupling reaction of 2-ethylhexyl 4-hydroxycinnamate with poly vinylbenzyl chloride, as model UV filters. For in vitro skin permeation experiments, Franz diffusion cells (effective diffusion area:1.766cm) and the excised skin of female hairless mouse aged 8 weeks were used. Oil or emulsion containing UV filters was applied in the donor compartment. The skin primary irritation was evaluated with fe-male guinea pigs (8-10 weeks,350-400 g). In oil and emulsions, the skin permeability and the skin primary irritation of PSA were lower than those of OMC. The skin permeability of UV filters was lower when they were in oil-in-water emulsion (OIW) than water-in-oil emulsion (W/O). We suggest that O/W system would be more useful when compared with W/O system, and PSA could be a good candidate for a future sunscreen agent for reducing the skin irritation.

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Effect of Die-upset Process on Magnetic Properties and Deformation Behavior of Nanostructured Nd-Fe-B Magnets

  • Zhao, R.;Zhang, W.C.;Li, J.J.;Wang, H.J.;Zhu, M.G.;Li, W.
    • Journal of Magnetics
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    • 제16권3호
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    • pp.294-299
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    • 2011
  • Nd-Fe-B high performance magnets were prepared by die-upset forging. The effects of the deformation parameters on magnetic properties and flow stress were studied. Deformation temperatures in the range of $600{\sim}900^{\circ}C$ enable to achieve an effective anisotropy and temperature $800^{\circ}C$ proves to be suitable for deformation of Nd-Fe-B magnets. The amount of c-axis alignment along the press direction seems to depend on the amount of deformation and a saturation behavior is shown at deformation ratio of 75%. Magnetic properties are also related to strain rate, and maximum energy product is attained at an optimum strain rate of ${\varphi}=1{\times}10^{-2}s^{-1}$. By analyzing the relationship of stress and strain at different deformation temperature during die-upset forging process, deformation behavior of Nd-Fe-B magnets was studied and parameters for describing plastic deformation were obtained. Nd-rich boundary liquid phase, which is additionally decreasing the flow stress during deformation, is supposed to play the role of diffusion path and enhance the diffusion rate.

Template-Assisted Electrochemical Growth of Hydrous Ruthenium Oxide Nanotubes

  • Cho, Sanghyun;Liu, Lichun;Yoo, Sang-Hoon;Jang, Ho-Young;Park, Sungho
    • Bulletin of the Korean Chemical Society
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    • 제34권5호
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    • pp.1462-1466
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    • 2013
  • We demonstrate that ruthenium oxide ($RuO_2$) nanotubes with controlled dimensions can be synthesized using facile electrochemical means and anodic aluminum oxide (AAO) templates. $RuO_2$ nanotubes were formed using a cyclic voltammetric deposition technique and an aqueous plating solution composed of $RuCl_3$. Linear sweep voltammetry (LSV) was used to determine the effective electrochemical oxidation potential of $Ru^{3+}$ to $RuO_2$. The length and wall thickness of $RuO_2$ nanotubes can be adjusted by varying the range and cycles of the electrochemical cyclic voltammetric potentials. Thick-walled $RuO_2$ nanotubes were obtained using a wide electrochemical potential range (-0.2~1 V). In contrast, an electrochemical deposition potential range from 0.8 to 1 V produced thin-walled and longer $RuO_2$ nanotubes in an identical number of cycles. The dependence of wall thickness and length of $RuO_2$ nanotubes on the range of cyclic voltammetric electrochemical potentials was attributed to the distinct ionic diffusion times. This significantly improves the ratio of surface area to mass of materials synthesized using AAO templates. Furthermore, this study is directive to the controlled synthesis of other metal oxide nanotubes using a similar strategy.

엔트로피 해석과 PIV를 이용한 HCCI 엔진용 스월 인젝터의 분무 특성 해석에 관한 연구 (A Study on the Spray Characteristics of Swirl Injector for Use a HCCI Engine using Entropy Analysis and PIV Technique)

  • 안용흠;이창희;이기형;이창식
    • 한국자동차공학회논문집
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    • 제12권1호
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    • pp.39-47
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    • 2004
  • The objective of this study is to analyse the spray characteristics according to the injection duration under ambient pressure condition and to investigate the relationship between vorticity and entropy for controlling diffusion process that is the most important thing during the intake stroke injection process. Therefore, the spray velocity was obtained by using the PIV method that has been an useful optical diagnostics technology, and vorticity calculated from spray velocity component with vorticity algorithm. In addition, the homogeneous diffusion rate of spray was quantified by using the entropy analysis based on the Boltzmann's statistical thermodynamics. From these method, we found that as injection duration increases, spray velocity increases and the location of vortex is moved to the downstream of spray. In the same condition, as the entropy decrease, mean vorticity increases. This means that the concentration of spray droplets caused by the increase of injection duration is more effective than the increase of momentum dissipation.

Time-Delay and Amplitude Modified BP Imaging Algorithm of Multiple Targets for UWB Through-the-Wall Radar Imaging

  • Zhang, Huamei;Li, Dongdong;Zhao, Jinlong;Wang, Haitao
    • Journal of Information Processing Systems
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    • 제13권4호
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    • pp.677-688
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    • 2017
  • In order to solve the undetected probability of multiple targets in ultra-wideband (UWB) through-the-wall radar imaging (TWRI), a time-delay and amplitude modified back projection (BP) algorithm is proposed. The refraction point is found by Fermat's principle in the presence of a wall, and the time-delay is correctly compensated. On this basis, transmission loss of the electromagnetic wave, the absorption loss of the refraction wave, and the diffusion loss of the spherical wave are analyzed in detail. Amplitude compensation is deduced and tested on a model with a single-layer wall. The simulating results by finite difference time domain (FDTD) show that it is effective in increasing the scattering intensity of the targets behind the wall. Compensation for the diffusion loss in the spherical wave also plays a main role. Additionally, the two-layer wall model is simulated. Then, the calculating time and the imaging quality are compared between a single-layer wall model and a two-layer wall model. The results illustrate the performance of the time-delay and amplitude-modified BP algorithm with multiple targets and multiple-layer walls of UWB TWRI.