• Elastomers and Composites
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• v.48 no.1
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• pp.67-75
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• 2013

E-TPE (Engineering Thermoplastic Polyether Ester) was Ester Elastomer with functional groups as recycling and fast processability. In addition, if the car's lightweight enough to highlight eco-friendly materials that help to improve fuel economy has become. Have all the attributes of the rubber and engineering plastics E-TPE the available temperature area is spacious, heat resistance and oil resistance is excellent but getting attention as a new material in the field of auto parts in the field of electrical and electronic domestic depends entirely on imports by the lack of core technology and has been research and development is urgently needed. In this study, the hard segments, polyester (TPEE) as the base soft elastomers of the segments Ethylen-prophylene-Copolymer and CSM (Choloro sulphonated polyethylene Rubber), VAMAC (Ethylene Acrylic Rubber), NBR (Acrylonitrin Butadiene Rubber), 1, 3-Phenylene-bisoxazoline is dealing with Dynamic Vulcanized by content and added rubber properties, thermal variation observed. As a result, the properties of the dynamic vulcanization with NBR compared to other rubber heat resistance and oil resistance is on the increase.

• Resources Recycling
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• v.19 no.6
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• pp.51-60
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• 2010

A study on the recovery of cobalt and lithium from Lithium Ion Battery(LIB) scraps has been carried out by a physical treatment - leaching - solvent extraction process. The cathode scraps of LIB in production were used as a material of this experiment. The best condition for recovering cobalt from the anode scraps was acquired in each process. The cathode scraps are dissolved in 2M sulfuric acid solution with hydrogen peroxide at $95^{\circ}C$, 700 rpm. The cobalt is concentrated from the leaching solution by means of a solvent extraction circuit with bis(2-ethylhexyl) phosphoric acid(D2EHPA) and PC88A in kerosene, and then cobalt and lithium are recovered as cobalt hydroxide and lithium carbonate by precipitation technology. The purity of cobalt oxide powder was over 99.98% and the average particle size after milling was about 10 lim. The over all recoveries are over 95% for cobalt and lithium. The pilot test of mechanical separation was carried out for the recovery of cobalt from the scraps. The $Co_3O_4$ powder was made by the heat treatment of $Co(OH)_2$ and the average particle size was about 10 ${\mu}m$ after grinding. The recovery was over 99% for cobalt and lithium each other and the purity of cobalt oxide was over 99.98%.

• Resources Recycling
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• v.23 no.4
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• pp.21-29
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• 2014

Nickel, cobalt and manganese-based(NCM, $Li(Ni_xCo_yMn_z)O_2$) cathode active materials of spent lithium-ion batteries contained valuable metals such as cobalt(15 ~ 20%), nickel(25 ~ 30%), manganese(10 ~ 15%) and lithium(5 ~ 10%). It was investigated the eco-friendly leaching process for the recovery of valuable metal from spent lithium-ion battery NCM cathode active materials by DL-malic acid($C_4H_5O_6$) as an organic leachant in this research. The experiments were carried out to optimize the process parameters for the recovery of cobalt, nickel and lithium by varying the concentration of lixivant, reductant concentration, solid/liquid ratio and temperature. The leaching solution was analyzed using ICP-OES(Inductively Coupled Plasma Optic Emission Spectrometer). Cathode active materials of 5 wt. % were introduced into the leaching solution which was 2 M DL-malic acid in addition of 5 vol. % $H_2O_2$ at $80^{\circ}C$ and it resulted in the recovery of 99.10% cobalt, 99.80% nickel and 99.75% lithium in 120 min. $H_2O_2$ in DL-malic acid solution acts as an effective reducing agents, which enhance the leaching of metals.

• Applied Chemistry for Engineering
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• v.16 no.6
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• pp.800-808
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• 2005

The compounding resin for biodegradable wrap was developed, and its manufacturing process and physical properties were studied. For these purposes, following factors were optimized: the types and amounts of raw resin material, anti-oxidants, and lubricants used. In this work, the stable compounding resin used to make biodegradable wrap was based on poly(butylene adipate-co-butylenesuccinate) (PBAS) and poly(butyleneadipate-co-butylene succinate-co-butyleneterephthalate) (PBAST). The improved properties of resin with an additive were investigated by melting flow index (MFI). From these results, the physical properties of compounding resin, based on PBAST, were more than those of PBAS. For PBAS, the Irganox 1010, 1076 and Irgafos TNPP as the first and second anti-oxidants, respectively, were good. For PBAST, the good first and second anti-oxidants, respectively, were Irganox 1076 and Mark PEP 36. The good lubricants for feeding PBAS and PBAST were glycerol monostearate and palmityl alcohol, respectively. The stability and tensile strength experiment of wrap were also investigated by the elution of heavy metals and universal testing machine (UTM), respectively. The decomposition ratio of developed wrap was increased proportional to the reclaiming time. The degradation ratio of compounding resin sample was about 60% after 40 days.

• Journal of the Korean GEO-environmental Society
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• v.17 no.5
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• pp.27-36
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• 2016

Low Impact Development (LID) techniques are eco-friendly storm water management process for water circulation restoration and non-point pollutant reduction. In this study, four LID techniques (Small constructed wetland, Infiltration trench box, Infiltration trench, Vegetated swale) were selected and installed as a real size at the real site. All facilities were evaluated as monitoring under the real environmental climate situation and an artificial rain with exceeding design rainfall. In various rainfall, runoff reduction efficiency and non-point pollutant removal efficiency are increased to the bigger Surface Area of LID (SA)/Catchment Area (CA) ratio and the bigger Storage Volume of LID (SV)/Catchment Area (CA) ratio. Runoff did not occur at all rainfall event (max. 17.2 mm) in infiltration trench and vegetated swale. But Small constructed wetland was more efficient at less than 10 mm, a efficiency of infiltration trench box was similar at different rainfall. Although different conditions (such as structural material of LID, rainfall flow rate, antecedent dry periods), LID techniques are good effects not only water circulation improvement but also water quality improvement.

• Journal of the Korean Wood Science and Technology
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• v.47 no.6
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• pp.709-720
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• 2019

Due to global warming and abnormal climate, the incidence and scale of green tracts in rivers and water intake dam are increasing every year. Therefore, in this study, developed eco friendly positively charged Torrefied Wood Flour(TWF) coagulant by reusing wood damaged by blight as a natural material. In order to evaluate the effect of coagulant on water ecosystem, green algae contaminated water was collected and TOC showed high removal rate of 86% ~ 92% under 1% and 5% TWF C-PAM treatment condition. The $NH_3-N$ showed 53% removal efficiency. The average pH of the polluted water was 7.9 in the case of hydrogen ion concentration, and the pH of the treated water was in the range of 6.5 ~ 7.7, It was found to be suitable for water quality standards. In ecotoxicity tests, all the results of the experiment showed that both the number of green algae and that of treated water were not affected by the survival of the daphnia. Therefore, as a result of the analyzing, developed paste type TWF coagulants is considered to be able to remove algae using natural resources.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.2
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• pp.5-12
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• 2019

The study is carried out to survey the proper management and to propose an eco - friendly separation system through efficient screening and resource recovery of excavated materials containing waste from various excavating fields such as reconstruction of landfill sites for reuse, reclamation of unsanitary landfill and residential land development of waste dumping sites. The current status and screening process and analytical characteristics of the excavated materials containing waste were reviewed. Through the analysis of the samples such as separated combustibles, recyclable soils and residues collected from the on-site visits we were able to understand the characteristics of separated materials and excavated materials containing waste such as calorific value, elementary composition, TOC, foreign material content and LOI. It has been found that elimination of the moisture of excavations, removal of attached soil from the surfaces of the excavated combustibles and the quantitative supply method of the input devices are the main operating factors as essential factors for the optimal separation of excavated materials containing waste. For efficient management and recycling of excavated materials containing, it is necessary to set criteria of ash content in separated combustibles and criteria organic matter content in separated soils.

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.331-337
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• 2019

Titania has become the most applicable material for photocatalytic application. Nevertheless, titania has the weak point in its wide band gap energy that is mainly activated by UV irradiation. There have been vast research challenges in order to make the wide band gap energy of titania narrow that could be activated in the presence of visible light. Various modifications of titania surface were popular because titania needs to change its surface to respond in visible light. Among the methodological approaches, N-doping to titania can be the alternative candidate because it is facile process and eco-friendly. The activated electron from valence band in N-doped $TiO_2$ migrates to conduction band in the presence of visible light irradiation, which shows photocatalytic activity as well. In this study, focused on the evaluation of nitrogen state after N-doping through brief review. Arguments are still existed in nitrogen states and their different effects on photocatalytic activity. In particular, two nitrogen states are generally reported; substitutional and interstitial states. The research articles regarding N-doped $TiO_2$ are continuously appearing because the potential application of water split in visible light is still fascinate. The future of N-doped $TiO_2$ is also presented by referrals based on various literature.

• Journal of the Korean Wood Science and Technology
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• v.49 no.4
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• pp.315-327
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• 2021

Purpose of this study is reviewing the use method for the sawdust (sawmilling by-product) and rice husk (Agriculture by-product) by adding charcoal, an eco-friendly material. Mixed composite boards were manufactured with those materials with each density and mixing ratio, and bending performance was investigated. When the addition ratio of sawdust, rice husk and charcoal is 50:20:20 and the resin addition ratio is 10%, as the density of the prepared mixed board ranges from 0.5 g/cm³ to 0.7 g/cm³, the bending strength was 0.42~3.24 N/mm², dynamic modulus of elasticity was 94.5~888.4 N/mm², and the static modulus of elasticity was in the range of 31.4~220.7 N/mm². As the density increased, the bending performance increased, indicating that the density had a significant effect on the bending performance. In a board prepared by setting the density of 0.6 g/cm³, the addition ratio of sawdust to 50%, and the addition ratio of rice husk and charcoal at different ratios, the bending performance showed a tendency to decrease as the addition ratio of charcoal increased. The relationship between the addition ratio of rice husk and charcoal, bending strength, resonance frequency, and dynamic and static bending modulus showed a rather low correlation with the values of the coefficient of determination (R²) of 0.4562, 0.4310, 0.4589, and 0.5847, respectively. Thus, we found that the effect of the addition ratio on the bending performance was small.

• Korean Journal of Heritage: History & Science
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• v.54 no.1
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• pp.18-31
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• 2021

Linoleum is a resilient, hygienic, and eco-friendly floor covering. It was developed in England by Frederick Walton in 1863. Made of cork flour, linseed oil, and burlap as its main materials, the flexible and waterproof linoleum became globally popular in the early 20th century. Unlike the vinyl coverings, the burlap-backed linoleum was used not only in commercial spaces but also in household areas like kitchens, bathrooms, and even living rooms. As a global product, linoleum was imported and used in Korean palaces like Deoksugung and Changdeokgung in the early modern period. According to the record Deoksugung Won-Ahn, linoleum was applied to the major buildings, including Hamnyeongjeon, Deokhongjeon, and Jeonggwanheon, and various other venues. The linoleum used in these places are mainly monochrome blue and brown color, which probably means that they are from England. The trade records in the early 20th century show that linoleum was imported mainly from England and America. The Ewangjik building floor plan in the Changdeokgung Palace shows that linoleum was used extensively. There are even some originals, which were laid in 1920 and left in the Changdeokgung Palace. When Daejojeon and Huijeongdang were rebuilt in 1920, the interior was outfitted with western features and linoleum was used in areas such as bathrooms, the tonsorial parlor, and one of the rooms on the west side of Huijeongdang. In situ in the Daejojeon and Huijeongdang areas in the Changdeokgung Palace are monochrome, patterned black, and stylized floral tile patterned, which are closely similar to American products made by ALC and Armstrong company. This study will help us better understand linoleum's characteristics, its uses and the material itself. It will also form the basis for the restoration of Changdeokgung Palace as well as other modern interiors with linoleum flooring in the future.