• 폴리머
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• 제26권4호
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• pp.501-507
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• 2002

본 논문에서는 bisphenol-S (BPS)와 epichlorohydrin (ECH)를 NaOH의 촉매하에서 중합시켜 diglycidylether of bisphenol-S (DGEBS) 에폭시 수지를 합성하였다. IR, NMR spectra 분석, 그리고 원소분석에 의해 합성한 DGEBS 에폭시 수지의 화학구조를 확인하였다 산무수화물계 phthalic anhydride (PA)와 tetrahydrophthalic anhydride (THPA)를 경화제로 사용하여 DSC에 의한 열분석을 통하여 DGEBS 에폭시 수지의 경화 동력학과 유리전이온도 ($T_g$)를 고찰하였으며, TGA 열분석을 사용하여 경화된 시편의 열안정성을 측정하였다. 실험 결과 DGEBS/PA계의 경화 활성화 에너지 ($E_a$)는 DGEBS/THPA계보다 높았지만 ($T_g$), 열분해 개시온도 (IDT), 그리고 분해 활성화 에너지 ($E_t$)는 DGEBS/THPA계보다 낮았다. 이는 경화제의 ring strain에 의하여 DGEBS/THPA계의 가교 밀도가 증가하였기 때문인 것으로 사료된다.

• 호남수학학술지
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• 제32권3호
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• pp.467-480
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• 2010

There are various papers on finding all the derivations of a non-associative algebra and an anti-symmetrized algebra (see [2], [3], [4], [5], [6], [10], [13], [15], [16]). We and all the derivations of the growing algebra WN($e^{{\pm}x_1x_2x_3}$, 0, 3)[1] with the set of all right annihilators $T_3$ = $\{id,\;\partial_1,\;\partial_2,\;\partial_3\}$ in the paper. The dimension of $Der_{non}$(WN($e^{{\pm}x_1x_2x_3}$, 0, 3)$_{[1]}$) of the algebra WN($e^{{\pm}x_1x_2x_3}$, 0, 3)$_{[1]}$ is one and every derivation of the algebra WN($e^{{\pm}x_1x_2x_3}$, 0, 3)$_{[1]}$ is outer. We show that there is a class P of purely outer algebras in this work.

• Journal of the Korean Wood Science and Technology
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• 제26권4호
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• pp.20-25
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• 1998

Radial variation of crystalline state in a stem of Chamaecyparis obtusa E. was examined by x-ray diffraction analyses. Relative crystallinity and degree of crystallite orientation showed significant differences between juvenile and adult wood. That is, Relative crystallinity increased with increasing the age from pith to about 20th annual ring, after which it reached a more or less constant value. On the other hand, degree of crystallite orientation decreased outward from pith to about 10 years and presented almost a constant value thereafter. Crystal width by Scherrer's equation did not show any significant differences between juvenile and adult wood. Therefore, it was considered that crystallinity index and degree of crystallite orientation by x-ray diffraction method could be used for evaluating wood quality.

• 한국패류학회지
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• 제29권2호
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• pp.121-127
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• 2013

본 연구에서는 신석기시대의 서산 대죽리 패총에서 출토된 말백합의 패각에 나타난 윤문을 판독하여 성장식을 추정하고 현재의 말백합 개체군과의 성장을 비교하였다. 패총 출토 패각의 수는 총 206개체였다. 각 연령군별로 각장과 윤경 간에 대응성을 보였고, 각 윤문군이 비교적 뚜렷이 구분되어 윤문판독의 타당성이 확인되어 판독된 윤문을 연륜으로 간주하였다. 패총 출토 말백합의 윤문은 2-5개까지 확인되어 2-5세군으로 구성되었음을 알 수 있었다. 패총 개체군의 성장식은 $SL_t=102.9025[1-e^{-0.18657(t+1.0906)}]$ 이었으며, 현생 개체군은 $SL_t=104.2583[1-e^{-0.2277(t+0.7499)}]$ 이었다. 각장 (SL) 과 각고 (SH) 간의 상대성장식은 패총 개체군 SH = 0.7791SL + 3.6636 ($R^2$ = 0.946) 이었으며, 현생 개체군은 SH = 0.8103SL + 0.5145 ($R^2$ = 0.991) 이었다. 두 개체군의 성장계수 (k) 는 차이가 없었고 (p < 0.05), 극한각장 ($SL_{\infty}$) 은 차이가 있었으나 (p > 0.05) 전체적으로 두 개체군의 상대성장식의 차이는 크지 않아 성장의 차이는 없다고 할 수 있다. 이는 두 개체군의 서식 환경이 비슷하다는 것을 의미한다. 따라서 신석기시대의 대죽리 패총이 형성될 당시 인근 연안의 해수온은 현재의 김제 연안지역과 비슷하게 높았을 가능성이 있는 것으로 추정된다.

• 한국패류학회지
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• 제19권2호
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• pp.125-132
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• 2003

1999년 1월부터 12월까지 매월 충남 보령연안에 서식하는 살조개 총 2,591 개체를 채집하여 연령과 성장에 관하여 조사하였다. 살조개의 패각에 나타나는 윤문은 연 1회 형성되었으며, 윤문형성 시기는 2-3월 중인 것으로 조사되었다. 각고(SH)에 대한 각장 (SL), 각폭 (SW) 및 총중량 (TW) 사이의 상대성장 관계는 각각 SL = 1.1067 SH + 1.778, SW = 0.6758 SH - 0.9824, TW = 0.0007 SH$^{2.8919}$이었고, 연령 (t) 에 대한 각고와 총중량으로부터 구한 von Bertalanffy 성장식은 SH$_t$ = 81.546(1-e$^{-0.176(t+0.381)}$), $_t$ = 81.546(1-e$^{-0.176(t+0.381)}$)이었다.

• Archives of Pharmacal Research
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• 제15권3호
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• pp.256-262
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• 1992

For the evaluation of the role of substituents of ar-turmerone for its anticancer activity, ar-turmerone (1a) and its analogs like 2-methyl-6-(4'-methyphenyl)-2-octen-4-one (1b), 2-methyl-6-phenyl-2-hepten-4-one (1c), 2-methyl-6-phenyl-2-octen-4-one (1d) and 2 methyl-6-(trans-4'-methylcyclohexyl)-2-hepten-4-one (1e) were preparedd and their cytotoxic activities against $L_{1210}$ cell were determined. Omission of methyl group at para-position dose not variate the cytotoxicity of ar-turmerone. Elongation of alkyl group at 6-position decreases $ED_{50}$ value. Saturation of aromatic ring of ar-turmerone markedly decreases the cytotoxicity. Therefore the smaller size of alkyl group at 6-position and aromatic ring of ar-turmerone should be essential for exhibiting its anticancer activity.

• Journal of Astronomy and Space Sciences
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• 제18권1호
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• pp.27-32
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• 2001

A statistical study has been performed of the magnetic storm recovery phase using the Dst index for 102 storm events in the interval January 1996 to December 1998. In 43 cases (or 42%) out of our 102 events, the recovery phase exhibits fast recovery (kaking about 8 hours or less) at its initial stage or for the entire recovery period. Since this fast recovery can be explained by the fast charge exchange less of $O^{+}$ ions which mostly com from the ionosphere, and since a fraction of $H^{+}$ ions is of ionospheric origin as well, our statistical result supports the view that the source of ring current ions in many magnetic storms can be terrestrial.

• Archives of Pharmacal Research
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• 제7권2호
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• pp.115-120
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• 1984

The crystals of bromhexine-HCl, $C_{14}$ H$_{21}$ N$_{2}$Br$_{2}$Cl, are orthohombic, space group Pca2 with a = 14.598(2)A, b=12.461(3)A, c =9 9.186(1) A and Z = 4. Intensity dat for 967 reflections (Fobs > 6.sigma.(F)) were collected on a Rigaku-Denki automatic four circle diffractometer. The structure was solved by the Patterson and Fourier methods. Refinements were carried out to the final R value of 0.082. The cyclohexane ring has a normal chair form and the benzene ring is planar. There are three independenet hydrogen bounds in the structure. One is an intermolecular hydrogen bond (N-H... Cl) and the others are intramolecular hydrogen bonds (N-H...Br, N$^{+}$-H...Cl$^{[-10]}$ ) Apart from the hydrogen bounding system the molecules are held together in the crystal by van der Waals force.e.

• 비파괴검사학회지
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• 제13권1호
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• pp.21-28
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• 1993

If the infinitesimal delamination exists and the two waves can hardly be distinguished from each other on account of being much closer, we cannot measure the thickness of delamination by the time difference method. On this study, we calculated the thickness of infinitesimal delamination model by means of measuring echo height due to the deflection of material particles and utilized Newton Ring for optical measurement as a delamination model. From the result of Newton Ring expressed in the delamination model, we can calculate the infinitesimal delamination thickness up to $0.2{\sim}0.3{\mu}m$ due to the difference of acoustic impedance by the ratio of the echo height to the total reflection.

• 상하수도학회지
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• 제19권1호
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• pp.98-105
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• 2005

The effects of chlorination on the elimination of three estrogenic chemicals such as $17{\beta}$-estradiol (E2), nonylphenol (NP) and bis-phenol A (BPA) were investigated using yeast two-hybrid assay (YTA), estrogen receptor competition assay (ER-CA), and high-performance liquid chromatography/mass spectrometer (LC/MS). Results of YTA, ECA and the analysis of LC/MS indicated that the estrogenic activity of above mentioned three endocrine disruptors were significantly reduced as the result of chlorination. The decrease in estrogenic activity paralleled with decrease in estrogenic chemicals under the influence of free chlorine. One common characteristic of estrogenic chemicals is the presence of a phenolic ring. Considering that a phenolic ring is likely to undergo some sort of transformation in aqueous chlorination solution, the above mentioned results may be applied to the rest of the other estrogenic chemicals in natural waters.