• Bulletin of the Korean Chemical Society
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• v.18 no.3
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• pp.296-300
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• 1997

The intracluster ion/molecule reactions within 1,1-difluoroethene homocluster have been studied by electron-impact quadrupole mass spectrometry. When CH2CF2 seeded in helium is expanded and ionized by electron impact, two different types of ion/molecule association (polymerization) reaction products, i.e., (CH2CF2)n+ (n≥l) and (CF2CH2)qX+ (X=fragment species, q≤n), are formed. The higher association products, (CH2CF2)n+ (n=3, 4), have shown stronger intensities over the lower association product, (CH2CF2)2+, in the low electron impact energy region ( < 39 eV). These stronger intensities are interpreted in terms of the stabilization of these ions due to the ring formations over the dimer ion in this energy region. The evidence of ring formation mechanism is on the basis of the intensity distribution of fragments at various electron impact energy. In another typical branched-chain growth reaction of these compounds, the F-shift reaction path is found to be more favorable energetically than the H-shift via the fragment patterns of clusters and semi-empirical calculation.

• Applied Chemistry for Engineering
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• v.20 no.3
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• pp.335-338
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• 2009

As important intermediates for blue emitting materials of organic light-emitting diodes, bromotriphenylethylene derivatives for distrylarylenes are prepared by reactions of bromobenzophenone with benzylphosphonates. The reaction produces a 60 : 40 mixture of (Z)- and (E)-geometric isomers that are difficult to be resolved. The (Z)-isomer is successfully isolated by a selective recrystallization process using 2-propanol as a solvent. The X-ray structure analysis of (Z)-isomer shows that dihedral angles between tert-butylphenyl ring and bromophenyl ring and between bromophenyl ring and phenyl ring are $56.5(4)^{\circ}$ and $74.1(4)^{\circ}$, respectively.

• The Korean Journal of Malacology
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• v.21 no.1
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• pp.57-64
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• 2005

Samples of Corbicula japonica Prime of Jujin estuary in Gochang were collected from July 2000 to September 2001. Age of C. japonica was determined from the rings on the shell. The relationship between shell length and ring radius in each ring group was expressed as a regression line. Therefore, there is a correspondence in each ring formation. Based on the monthly variation of the marginal index (MI') of the shell, it is assumed that the ring of this species was formed once a year during the period of February and March. The relationship between shell length (SL; mm) and total weight (TW; g) was expressed by the following equation: TW = 1.0942 ${\times}10^{-4}SL^{3.3217}$ ($r^2$ = 0.9905). Shell length (SL) and shell height (SH; mm) was highly correlated with shell height as the following equation: SH = 0.9174 SL - 0.9935 ($r^2$ = 0.9885). The shell length (SL) - shell width (SW) relation was also expressed by the following equation; SW = 0.5925 SL - 1.1706 ($r^2$ = 0.9726). Growth curves for shell length and total weight fitted to the von Bertalanffy's growth curve were expressed as: $$SL_t = 46.4861[1-e^{-0.3383(t+0.0958)}]$$, $$TW_t = 34.54[1-e^{-0.3383(t+0.0958)}]^3.3217$$.

• Korean Journal of Pharmacognosy
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• v.17 no.2
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• pp.178-183
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• 1986

It was our working hypothesis that introduction of 11-keto groups to 12-oleanene/ursene series of triterpenoids should endow them with corticoid-like activities, since pharmacological actions of glycyrrhetinic acid (GA) are known to be caused by inhibition on $corticoid-{\delta}^4-reductase$. 11-Keto-triterpenoids derived artificially in these studies, such as 11, 19-diketo-18, 19-secoursolic acid methyl ester(I), $11-keto-{\beta}-boswellic$ acid derivatives (IIa-IIc), 11-Keto-presenegenin dimethyl ester (III), II-keto-oleanolic acid derivatives (IVa-IVd) and 11-keto-hederagenin (V) possess the fundamental functions of ${\alpha},\;{\beta}-unsaturated$ ketone on C-11 and hydroxyl group on C-3, as like GA (VI). Additionally, they involve the carboxyl groups on rings A (II, III), D (I, III, IV, V) and E (VI), and the hydroxyl groups on rings A (III, V) and C (III). All the compounds competitively inhibited $corticoid-5{\beta}-reductase$, and the highest inhibitory potency appeared in I. All of them except $3,\;11-diketo-{\beta}-boswellic$ acid methyl ester (IIc) were more effective about five times to twice than GA. On carrageenin-induced edema test, compounds I and IVa-IVd showed anti-inflammatory activities, but III enhanced rather edema. Structure-activity relations were found in the aspects of hydrophilicity of ring A and hydrophobicity of rings C/D. The more they were hydrophilic in ring A and hydrophobic in rings C/D, the more they inhibited the enzyme. And the more they were hydrophobic in rings C/D, the more they exhibited antiiflammatory activities. However, the increased hydrophilicity in ring A resulted in increasing edema, probably due to a nonspecific inhibition on $aldosterone-5{\beta}-reductase$.

• BMB Reports
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• v.44 no.11
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• pp.725-729
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• 2011

We report a novel mechanism of a CDH1 splicing mutation in a patient with signet ring cell carcinoma of the stomach. A 27-year-old man complaining of aggravated dyspepsia was diagnosed with signet ring cell carcinoma. Both his father and uncle had died of stomach cancer at a young age. DNA sequencing analysis of the CDH1 gene revealed a splice site mutation (c.833-2A>G). By RNA/cDNA sequencing analysis, CDH1 c.833-2A>G generated a new acceptor site within intron 6, causing the insertion of a 79-bp intronic sequence between exon 6 and 7 (r.833-79_833-1ins), and resulting in a frame shift. E-cadherin immunohistochemical staining revealed a loss of CDH1 expression. This study reveals the disease-causing mechanism of this splicing mutation, and emphasizes the need for functional studies using RNA samples for the accurate interpretation of detected splicing variant. This is the first reported case of a CDH1 mutation in a Korean patient.

• Journal of Digital Convergence
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• v.14 no.2
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• pp.169-173
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• 2016

With the rapid growth of IT technology and development of online shopping, e-commerce activity through online environment is going to grow in various forms. And then the intense competition also more deepen in the companies within the online market. The study on the various contents production and environment configuration for sale strategies has been made. Among online market products, it is needed to develop marketing strategies for online sales related to rings products. In this paper, through the analysis of online content and components of companies, it has obtained the appropriate components in the ring industry. In particular, aiming to young customers, we looked about components suitable for them and built site. As a result based on the above analysis, we anticipate that it will be able to see forward to a competitive ring marketing.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.27 no.1
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• pp.88-93
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• 2003

The aim of this paper is to investigate the friction characteristics of piston assembly, which composed of ring pack and piston skirt. The friction force of piston assembly was measured by using the movable liner in the single cylinder engine, and the various parameters were tested. The friction force was suddenly increased at the expansion stroke due to higher cylinder pressure. The viscous friction was dominant at the mid stroke, but the boundary friction was dominant at the top and bottom dead centers. Through the experiment, we could validate previous theoretical study, and confirm that th e radial clearance and ring tension were very effective to reduce friction loss of piston assembly.

• Journal of the Korean Mathematical Society
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• v.48 no.1
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• pp.207-222
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• 2011

Let R be a commutative ring and let M be a GV -torsionfree R-module. Then M is said to be a $\omega$-module if $Ext_R^1$(R/J, M) = 0 for any J $\in$ GV (R), and the w-envelope of M is defined by $M_{\omega}$ = {x $\in$ E(M) | Jx $\subseteq$ M for some J $\in$ GV (R)}. In this paper, $\omega$-modules over commutative rings are considered, and the theory of $\omega$-operations is developed for arbitrary commutative rings. As applications, we give some characterizations of $\omega$-Noetherian rings and Krull rings.

• Bulletin of the Korean Mathematical Society
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• v.54 no.1
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• pp.319-329
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• 2017

Let I denote an ideal of a Noetherian local ring (R, m). Let M denote a finitely generated R-module. We study the endomorphism ring of the local cohomology module $H^c_I(M)$, c = grade(I, M). In particular there is a natural homomorphism $$Hom_{\hat{R}^I}({\hat{M}}^I,\;{\hat{M}}^I){\rightarrow}Hom_R(H^c_I(M),\;H^c_I(M))$$, $where{\hat{\cdot}}^I$ denotes the I-adic completion functor. We provide sufficient conditions such that it becomes an isomorphism. Moreover, we study a homomorphism of two such endomorphism rings of local cohomology modules for two ideals $J{\subset}I$ with the property grade(I, M) = grade(J, M). Our results extends constructions known in the case of M = R (see e.g. [8], [17], [18]).

• The Journal of the Acoustical Society of Korea
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• v.20 no.4E
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• pp.45-51
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• 2001

This paper examines the dispersion relation governing the wave propagation on cylindrical shells. The assumption of thin shells allows the dispersion relation to be separated into three relations related to the propagation of flexural waves and two types of membrane waves. Those relations are used to identify the characteristics of the wave number curves. The dispersion relation provides two and three closed wave number curves below and above the ring frequency. Above the ring frequency three wave number curves are clearly identified to be those of flexural, shear and longitudinal waves, respectively. Below the ring frequency, the characteristics of two wave number curves are identified with dependence of the direction of wave propagation.