• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3553-3558
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• 2014

The reduced graphene oxide(rGO)/aluminum phosphate($AlPO_4$)-coated $LiMn_{1.5}Ni_{0.5}O_4$ (LMNO) cathode material has been developed by hydroxide precursor method for LMNO and by a facile solution based process for the coating with GO/$AlPO_4$ on the surface of LMNO, followed by annealing process. The amount of $AlPO_4$ has been varied from 0.5 wt % to 1.0 wt %, while the amount of rGO is maintained at 1.0 wt %. The samples have been characterized by X-ray diffraction, scanning electron microscopy, and high-resolution transmission electron microscopy. The rGO/$AlPO_4$-coated LMNO electrodes exhibit better cyclic performance compared to that of pristine LMNO electrode. Specifically, rGO(1%)/$AlPO_4$(0.5%)- and rGO(1%)/$AlPO_4$(1%)-coated electrodes deliver a discharge capacity of, respectively, $123mAhg^{-1}$ and $122mAhg^{-1}$ at C/6 rate, with a capacity retention of, respectively, 96% and 98% at 100 cycles. Furthermore, the surface-modified LMNO electrodes demonstrate higher-rate capability. The rGO(1%)/$AlPO_4$(0.5%)-coated LMNO electrode shows the highest rate performance demonstrating a capacity retention of 91% at 10 C rate. The enhanced electrochemical performance can be attributed to (1) the suppression of the direct contact of electrode surface with the electrolyte, resulting in side reactions with the electrolyte due to the high cut-off voltage, and (2) smaller surface resistance and charge transfer resistance, which is confirmed by total polarization resistance and electrochemical impedance spectroscopy.

• Journal of Advanced Marine Engineering and Technology
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• v.37 no.8
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• pp.946-952
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• 2013

Large scale fire tests were conducted to develop water mist nozzles as a component of fixed water- based fire fighting systems for Ro-Ro spaces and special category spaces. Fire scenarios for this system consist of two cases which are for cargo fire in a simulated truck and for passenger vehicle fire, and each case has 3 different tests according to the position between fixed water mist nozzles and fire source. Every experiment proceeded for 30 minutes and acceptance criteria were based on gas temperature, fuel package's damage and ignition of targets. This study primarily dealt with the experimental results of cargo fire and focused on fire suppression capability in accordance with discharge pressure, flow rate and flow characteristics like swirl and penetration of the developed water mist nozzles. It appeared that low pressure water mist nozzles with about 40 L/min were able to control fire occurred in Ro-Ro spaces.

• Fire Science and Engineering
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• v.26 no.5
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• pp.73-78
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• 2012

This research is to evaluate the fire extinguishing performance of Compressed Air Foam System and this test was conducted using Foam Head System. Compressed Air Foam System adopt the methods of causing the foam by mixing compressed air in foam-aqueous solution, In Overseas, CAFS (Compressed Air Foam System) is generally used because long distance discharge is possible and the water damage can be minimized by reducing the water usage. In this study, Comparative analysis on fire extinguishing effect is done through test to compare the performance between Foam System applied existing air mixture method and Compressed Air Foam System applied AFFF 3 %, foam-extinguishing-agent based on UL162 standard. In Compressed Air Foam System, the volume proportion of air mixture to foam-aqueous solution is 1 to 1 and discharging flow rate is 140 L/min, 160 L/min, 180 L/min, 200 L/min each. As a result of the test, in terms of fire extinguishing performance, fire suppression time for Compressed Air Foam Systems is shorter than for General Air Mixture System in all flow conditions.

• Fire Science and Engineering
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• v.28 no.4
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• pp.1-7
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• 2014

Several complex devices and equipments are installed in the car's engine room, including various kind of oils or other flammable materials. So re-ignition is very likely to take place in it. In addition, it is restrictive for the driver or the occupant to open the bonnet and to spray the fire extinguisher in the engine room due to the high possibility of explosion. Therefore, a fire extinguishing system, which can detect a fire and inject the fire extinguishing agent to extinguish it, and fire extinguishing agents including HFC-227ea, which can stand the high temperature within the engine room and hold the viscosity sufficient to keep it in the kind of foam, were developed and tested. And the suffocation effect and the cooling effect come from the fire extinguishing principle of the foam fire extinguishing agent and the inhibiter catalyst effect come from the one of HFC-227ea was led simultaneously, and fire extinguishing agents without the secondary damage caused by residuals after the fire extinguishment like a case of the powder fire extinguishing agent, were developed. And experiments using a vehicle collision after the discharge is complete, foreign material can be removed without extinguishing the advantage that experimental results obtained.

• Korean Journal of Environmental Biology
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• v.17 no.4
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• pp.407-414
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• 1999

Distribution of biota and removal efficiency of organic matter in natural wetland systems were examined from June to October 1998. The aquatic macrophyte communities were consisted of 13 families and 22 species. The composition of occurrence species were as follows: Phragmites communis Trinius are 35%, Persicaria thunbergii Nakai are 19%, Typha angustifolia L. are 17%, Bidens tripartita L. are 16%, Echinochloa crus-galli (L.) Beauv. are 12% and others are l％. The fauna collected from 5 sites consisted of total 6 classes of macroinvertebrates. The composition of occurrence classes were as follows: Insecta are 76%, O1igochaeta are 19%, Gastrapoda are 4％ and others are 1%. These included 18 families, 7 orders of Insects. The larve and mosquito and midges were found in wetlands. Preventive strategies are needed for the suppression of mosquito at the stage of wetland planning and design. In wetland, removal efficiency of dissolved organic carbon is low because of primary production and the background level of DOC in the wetland discharge seems to be 5 mgC/1, but those of BOD was ca. 50%. Wetlands receiving water of low concentration can not work as purification field.

• Fire Science and Engineering
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• v.26 no.2
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• pp.1-10
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• 2012

While a performance based sprinkler design method has been widely used in UK and USA according to fire hazards of occupancies, Korean fire safety industry could not yet accept it due to nonstandardization on risk level of various occupancy. Even only two or three spray pattern sprinkler was produced in Korea fire safety industry, therefore, various spray pattern sprinklers have not yet introduced to major occupancies. Spray pattern sprinklers with one of two K value have been used in all occupancies in Korea Market. UK and USA's Fire industry should produced the spray sprinklers with various K-factors and protection area due to performance based sprinkler design requirement. Therefore the fire load density for main occupancies has been investigated in order to compare with installation standard in advanced countries. Eventually a lot of variations in orifice and K factors of standard heads were set up including special heads needed for high hazard areas such as large drop type, enlarged orifice type and early suppression fast response.

• Korean Journal of Materials Research
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• v.17 no.8
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• pp.447-451
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• 2007

We investigated the dependence of the various annealing conditions and thickness ($6\sim45nm$) of the Ti-doped $Al_2O_3$ coating on the electrochemical properties and the capacity fading of Ti-doped $Al_2O_3$ coated $LiCoO_2$ films. The Ti-doped-$Al_2O_3$-coating layer and the cathode films were deposited on $Al_2O_3$ plate substrates by RF-magnetron sputter. Microstructural and electrochemical properties of Ti-doped-$Al_2O_3$-coated $LiCoO_2$ films were investigated by transmission electron microscopy (TEM) and a dc four-point probe method, respectively. The cycling performance of Ti-doped $Al_2O_3$ coated $LiCoO_2$ film was improved at higher cut-off voltage. But it has different electrochemical properties with various annealing conditions. They were related on the microstructure, surface morphology and the interface condition. Suppression of Li-ion migration is dominant at the coating thickness >24.nm during charge/discharge processes. It is due to the electrochemically passive nature of the Ti-doped $Al_2O_3$ films. The sample be made up of Ti-doped $Al_2O_3$ coated on annealed $LiCoO_2$ film with additional annealing at $400^{\circ}C$ had good adhesion between coating layer and cathode films. This sample showed the best capacity retention of $\sim92%$ with a charge cut off of 4.5 V after 50 cycles. The Ti-doped $Al_2O_3$ film was an amorphous phase and it has a higher electrical conductivity than that of the $Al_2O_3$ film. Therefore, the Ti-doped $Al_2O_3$ coated improved the cycle performance and the capacity retention at high voltage (4.5 V) of $LiCoO_2$ films.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.3
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• pp.317-324
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• 2020

Plastic wastes generated from domestic waste are separated by mixed discharge with foreign substances, and the cost of the separation and screening process increases, so recycling is relatively low. In this study, as a fundamental study for recycling mixed plastic wastes generated from domestic waste into concrete aggregates, changes in concrete properties according to the plastic waste types and the substitution rate were evaluated experimentally. The mixed plastic waste aggregate(MPWA) was found to have a lower density and a higher absorption rate compared to the coarse aggregate with good particle size distribution. On the other hand, the single plastic waste aggregate(SPWA) was composed of particles of uniform size, and both the density and the absorption rate were lower than that of the fin e aggregate. It was found that the MPWA substitution concrete did not cause a material separation phenomenon due to a relatively good particle size distribution even with the largest amount of plastic waste substitution, and the amount of air flow increased little. The compressive strength and flexural strength of the PWA substitution concrete decreased as the amount of substitution of the PWA increased due to the low strength of the PWA, the suppression of the cement hydration reaction due to hydrophobicity, and the low adhesion between the PWA and the cement paste. It was found that the degree of deterioration in compressive strength and flexural strength of concrete substituted with MPWA having good particle size distribution was relatively small.