• 한국환경과학회지
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• 제23권11호
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• pp.1881-1888
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• 2014

Greenhouse gas (GHG) emissions from dye wastewater treatment processes were estimated by analysing their mass and energy balances, which were then used as baseline information for environmental assessment. The total GHG emissions from dye wastewater treatment plants were divided into direct emissions from the treatment processes and indirect ones from electricity usage. The amounts of $CO_2$, $CH_4$ and $N_2O$ emissions were calculated according to the Intergovernmental Panel on Clime Change (IPCC) guideline for the GHG target management system. For 3 years between 2011 and 2013, direct and indirect emissions were on average 8,742.7 and 7,892.0 Ton.$CO_2eq/year$, respectively, with the former exhibiting 52.6 %. Also, compared to 2012, in 2013, the eco-efficiency indicator by the GHG emissions was found to be more than 1, suggesting that environmental quality was effectively improved.

• 대한화학회지
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• 제11권1호
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• pp.12-16
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• 1967

?織物上의 Chlorantine Fast Red 5B(C.I. Direct Red 81)의 照光으로 因한 褪色을 檢討하여 同染料의 CF曲線의 기울기는 異例的으로 負의 기울기를 나타내는 反面 CFG 曲線의 기울기는 正의 기울기를 나타낸다는 것을 밝혀내고, 同染料의 CF曲線의 기울기가 負로 나타남에도 不拘하고 CFG曲線의 기울기는 正으로 나타나게 되는 理由를, Weber-Fechner의 法則이 染色物의 視覺에 依한 褪色判定에 作用하는 때문인 것으로 보고, 視覺判定에 依할 때의 染料의 褪色量($F_v$)은 $F_v=[logC_0-log(C_0-C_0F_t/100)]{\times}100/(logC_0+b)$ 但 $F_t$; t時間 照光後의 染料의 褪色量, $C_0$; 染料의 初濃度, b; 定數으로 表示할 수 있다는 것을 明白히 하였다. 아울러 染料濃度 增加에 따르는 日光堅牢度 上昇의 原因으로서 染料의 集合效果外에, 染料濃度가 視覺判定에 依한 褪色判定結果에 미치는 影響도 考慮해야 할것임을 明白히 하였다.

• 한국의류학회지
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• 제46권3호
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• pp.375-389
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• 2022

3D printing has been considered a key technology, leading the fourth industrial revolution. However, 3D printed textile still has a lot of limitations to overcome before it can be adopted as a clothing material in terms of design, flexibility and dyeability. This study aims to provide modeling design for imparting the flexibility and post-dyeing process for 3D printed textiles. The modeling types were designed to test the flexibility of 3D printed textiles. The post-dyeing process was evaluated through dye absorption depending on the resin and modeling types, respectively. The results were as follows: two types of modeling (Modeling A and B) were designed with a ring structure to test the flexibility of the 3D printed textiles. The 3D printed textiles with ring-based structure Modeling A had flexibility regardless of the hardness of resin types. In the dyeability test, softening resin (S-Resin) and hardening resin (H-Resin) were found to have good dyeability with acid dye and direct dye, respectively. The condition of S-Resin with acid dye and H-Resin with direct dye was controlled by dye absorption rate.

• Fibers and Polymers
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• 제3권4호
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• pp.147-152
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• 2002

Copper (II) salts are used as metallizing agents in the synthesis of new non-genotoxic direct dyes for cotton. Specifically, cotton fabric is dyed with non-genotoxic disazo direct dyes and then treated with copper salts. The complexes are characterized by neutron activation analysis, absorption spectrometry and standard Salmonella mammalian mutagenicity assay, and the after-treated fabrics are evaluated for lightfastness and washfastness. Direct dyes possessing ortho-propoxy and ortho'-hydroxy substituted systems formed the corresponding nonmutagenic 1:2 dye:metal complex and undergo significant improvement in lightfastness following metallization.

• 한국염색가공학회지
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• 제6권3호
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• pp.1-7
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• 1994

Cotton fiber and NaOH-mercerized cotton fiber had been treated by liquid ammonia and were dyed with two direct dyes, C.I. Direct Red 2 and Blue 1. The effect of the treatment on the rate of dyeing, dye adsorption isotherm, and affinity were studied. The rate of dyeing was increased in the order of NaOH-mercerized> NaOH/liquid ammonia-treated > liquid ammonia-treated>Untreated cotton irrespective of kind of dyes. The rate of dyeing for NaOH-treated fiber considerably increased, whereas liquid ammonia-treated or NaOH/liquid ammonia-treated did not because the structural transformation was not enough for the dyes to penetrate easily into the liquied ammonia-treated cottons. The time of half-dyeing was considerably reduced by mercerizing with NaOH, but lengthened by liquid ammonia treatment because of increased equilibrium dye exhaustion especially in dyeing with C.I. Dierect Red 2. In spite of a short time of the ammonia treatment for 4 seconds, the equilibrium exhaustions of both of direct dyes, C.I. Direct Red 2 and C.I. Direct Blue 1, were increased in proportion to internal volume of treated cotton under a condition of fixed affinity.

• 멤브레인
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• 제5권4호
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• pp.129-136
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• 1995

본 연구는 에멀젼 액막을 이용한 염색 폐수 내의 염료 이온 제거에 관한 연구이다. Aliquat 336을 함유한 액막과 D2EHPA를 함유한 액막으로 각각 음이온성 염료와 양이온성 염료 제거에 관한 최적 조건을 확립하였으며, 이 조건하에서 실제의 염색 폐수 처리 실험을 행하였다. 직접 염료인 Sirius Red, 반응성 염료인 Reactofix Supra Blue 및 염기성 염료인 Apollo Blue를 대상으로 하여 막상의 계면활성제(Span 80)와 담체(Aliquat 336 or D2EHPA)의 농도, 내수상의 counter ion($Na_2SO_4$) 농도, 그리고 에멀젼 투여량 등을 변화시키며 염료 제거 실험을 행하였다. 반응 5분 후에 추출 평형에 도달하였으며, 각 염료에 대하여 색소 성분의 95% 이상을 제거할 수 있었다. 제막 조건에 가장 큰 영향을 미치는 인자는 담체의 농도로서 일정량 이상의 담체는 막의 물질 전달 저항을 증가시켜 색도 제거 효과를 감소시킴을 알 수 있었다. 또한, 막상의 계면활성제의 양, 내수상의 counter ion의 양 및 투여 에멀젼의 양은 평형 도달 후의 최종 색도보다는 추출 속도에 더 큰 영향을 미침을 알 수 있었다. 실제 염색 폐수를 에멀젼 액막으로 2단계 처리한 결과 550nm에서의 흡광도를 초기 0.53에서 10분 후 0.03까지 낮출 수 있었다.

• 한국염색가공학회지
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• 제22권2호
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• pp.145-154
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• 2010

An alkalophilic microorganism capable of degrading dyes was developed for the treatment of alkaline dye solution. This strain was identified as Pseudomonas species. Using this microorganism, biological treatment of dye was studied in Erlenmeyer flasks. The characteristics of this microorganism were observed under various incubating-condition such as temperature, pH, nitrogen source, and macronutrients concentration. The removal effciencies of Disperse Red 60 from synthetic wastewater were 33.5 ~ 36.9% at the range of $30{\sim}40^{\circ}C$, and they were 31.1 ~ 36.7% at the range of initial pH 8 ~ pH 10, respectively. The optimal culture medium was found to be 0.25%(w/v) yeast extract, 0.25%(w/v) polypeptone, 0.1%(w/v) $KH_2PO_4$, 0.2%(w/v) $MgSO_4{\cdot}7H_2O$, and 1.0%(w/v) $Na_2CO_3$. In treatment of various dyes using Erlenmeyer flasks, the removal effciencies of Disperse Blue 87, Disperse Yellow 64, Disperse Red 60, Acid Blue 193, Acid Red 138, and Direct Yellow 23 were found to be 76%, 71%, 58%, 93%, 94%, and 90% respectively after 24hrs reaction of alkalophilic strain Pseudomonas sp. YBE-12.

• 한국염색가공학회지
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• 제8권1호
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• pp.15-25
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• 1996

Wool fabric and merino wool top were dyed with two dyes, C.I. Acid Red 13 and C.I. Direct Blue 1 in presence of hydrogen peroxide/glyoxal redox system at various conditions such as dyeing time, temperature and redox concentration. The pH of dye bath was 4.5 in buffer solution of $KH_{2}PO_{4}$ (0.1mol/1)/$Na_{2}HPO_{4}$ (0.1mol/1). Also dyeing of cotton fabric was carried out with C.I. Direct Blue 1 in absence or presence of redox system. The color depth(K/S) increased with redox concentration and dyeing temperature. The increases in dyeing rate and equilibrium dye exhaustion of Acid Acid 13 and Direct Blue 1 on wool fiber and fabric in the present of hydrogen peroxide/glyoxal have been caused by decreasing in pH value during dyeing process which due to the decomposition of hydrogen ion in glyoxal with the assistance of hydrogen peroxide. But the decreases in exhaustion of Direct Blue 1 on cotton may be attributed to repulsive interac ion between salt and salt.

• 한국의류학회지
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• 제35권10호
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• pp.1228-1241
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• 2011

This research compares the change in berberine content in liquid dye and the color and dye uptake of amur cork tree dyed silk upon thermal degradation treatment. Thermal degradation of amur cork tree extract and liquid dye of standard berberine was carried out at room temperature, $4^{\circ}C$ refrigeration, and $100^{\circ}C$ oven conditions for 0-192 hours. Amur cork tree dyed silk was treated in a $100^{\circ}C$ oven for 0-240 hours. The berberine content in liquid dye was measured by the relative abundance of the berberine peak in the HPLC-MS chromatograms. The color and dye uptake of dyed silk was measured using K/S value and colorimetric data. The berberine content in standard berberine dye was 2.4 times that of the amur cork tree extract. A similar result was observed between the K/S value of standard berberine dyed silk and that of amur cork tree dyed silk. The berberine dyed silk showed the highest dye uptake after 120 hours in a $100^{\circ}C$ oven. This result was similar to the change in a berberine content in liquid dye in a $100^{\circ}C$ oven treatment. The change of the K/S value of amur cork tree dyed silk and berberine content of amur cork tree extract was similar up to 24 hours. The result suggests that there is a direct relationship between the color change of amur cork tree dyed silk and the berberine content in amur cork tree dye.

• 대한화학회지
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• 제6권2호
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• pp.104-107
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• 1962

It is thought that the adsorption isotherms in dyeing of cellulose by the direct cotton dyes are consisted of combined type of Langmuir and Freundlich as the opinion of Fujino, et al;$[D]_F=ab[D]_S/(1+b[D]_S)+k[D]_S$where a,b,k; constants, $[D]_F$; dye adsorption on the fiber, $[D]_S$; dye concentration in the bath. This means that the dyes adsorbed in cellulose present in the state of partly mono molecular and partly aggregate; the characteristic fading order curve will be expressed as the combined system of uniform particle size distribution and assumed that the slope of the theoretical models of Baxter, et al., and assumed that the slope of curve will be changed near the point of a, the saturation value of Langmuir isotherms in the above equation. Firstly, the theoretical fading rate curve was treated with small colour difference as the one step of experimental of above consideration.