• 제목/요약/키워드: direct decomposition

검색결과 204건 처리시간 0.022초

연료전지 UAV의 친환경 추진 시스템을 위한 통합형 수소 공급 시스템 연구 (The study of integrated hydrogen supply system for environment friendly propulsion systems of fuel-cell UAV)

  • 이충준;김태규
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2012년도 제38회 춘계학술대회논문집
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    • pp.149-152
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    • 2012
  • 본 논문은 연료전지 UAV의 친환경 추진 시스템을 위한 통합형 수소 공급 시스템 연구에 대해 기술하고 있다. 고체 상태 $NaBH_4$를 직접 분해하기 위해 희석된 염산을 사용하였다. 안정적인 수소 공급을 위해 자체 수소 가압형 반응기와 압력 레귤레이터를 적용하였다. 컨셉 실증과 성능 검증을 위해 고체 상태 $NaBH_4$를 직접 분해하는 통합형 수소 공급 시스템의 시제품을 설계하였다.

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DIRECT COMPARISON STUDY OF THE CAHN-HILLIARD EQUATION WITH REAL EXPERIMENTAL DATA

  • DARAE, JEONG;SEOKJUN, HAM;JUNSEOK, KIM
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제26권4호
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    • pp.333-342
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    • 2022
  • In this paper, we perform a direct comparison study of real experimental data for domain rearrangement and the Cahn-Hilliard (CH) equation on the dynamics of morphological evolution. To validate a mathematical model for physical phenomena, we take initial conditions from experimental images by using an image segmentation technique. The image segmentation algorithm is based on the Mumford-Shah functional and the Allen-Cahn (AC) equation. The segmented phase-field profile is similar to the solution of the CH equation, that is, it has hyperbolic tangent profile across interfacial transition region. We use unconditionally stable schemes to solve the governing equations. As a test problem, we take domain rearrangement of lipid bilayers. Numerical results demonstrate that comparison of the evolutions with experimental data is a good benchmark test for validating a mathematical model.

Preparation and Characterization of MWCNT-g-Poly (Aniline-co-DABSA)/Nafion® Nanocomposite Membranes for Direct Methanol Fuel Cells

  • Abu Sayeed, Md.;Kim, Young Ho;Kim, Chorong;Park, Younjin;Gopalan, A.I.;Lee, Kwang-Pill;Choi, Sang-June
    • Bulletin of the Korean Chemical Society
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    • 제34권9호
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    • pp.2657-2662
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    • 2013
  • Multiwalled carbon nanotube (MWCNT)-g-poly (aniline-co-2,5-diaminobenzenesulfonic acid) (DABSA) reinforced Nafion$^{(R)}$ nanocomposite membranes were prepared and characterized for direct methanol fuel cells (DMFCs). The nanocomposite membranes with approximately $90{\mu}m$ thickness were prepared by the water assisted solution casting method. To evaluate the properties of nanocomposite membranes for DMFC applications, the nanocomposite membranes were characterized by methanol and water uptake, thermal stability, and ion exchange capacity (IEC). Furthermore, oxidative stability measurements in terms of the hydrogen peroxide decomposition rate that represent the oxidative stability of the membranes were examined. The methanol uptake values of the nanocomposite membranes were dramatically decreased compared to the cast Nafion$^{(R)}$ membranes. The IEC values of the nanocomposite membranes were increased about 30% compared to the cast Nafion$^{(R)}$ membrane.

직접 용액 코팅법에 의해 제조한 CuInSe2 에 잔존하는 탄소 불순물층 형성에 관한 연구 (On Formation of Residual Carbon Layer in CuInSe2 Thin Films Formed via direct Solution Coating Process)

  • 안세진;;어영주;곽지혜;윤경훈;조아라
    • Current Photovoltaic Research
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    • 제2권1호
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    • pp.36-39
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    • 2014
  • Formation mechanism of residual carbon layer, frequently observed in the $CuInSe_2$ (CIS) thin film prepared by direct solution coating routes, was investigated in order to find a way to eliminate it. As a model system, a methanol solution with dissolved Cu and In salts, whose viscosity was adjusted by adding ethylcellulose (EC), was chosen. It was found that a double layer, a top metal ion-derived film and bottom EC-derived layer, formed during an air drying step presumably due to different solubility between metal salts and EC in methanol. Consequently, the top metal ion-derived film acts as a barrier layer inhibiting further thermal decomposition of underlying EC, resulting a formation of bottom carbon residue layer.

Synthesis of Isopropyldichlorosilane by Direct Process

  • Lim, Weon-Cheol;Cho, Joo-Hyun;Han, Joon-Soo;Yoo, Bok-Ryul
    • Bulletin of the Korean Chemical Society
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    • 제28권10호
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    • pp.1661-1664
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    • 2007
  • Direct reaction of elemental silicon with a gaseous mixture of isopropyl chloride (1) and hydrogen chloride in the presence of copper catalyst using a stirred bed reactor equipped with a spiral band agitator gave isopropyldichlorosilane having a Si-H bond (2a) as a major product and isopropyltrichlorosilane (2b) along with chlorosilanes, trichlorosilane and tetrachlorosilane. A process for production of 2a was maximized using the 1:0.5 mole ratio of 1 to HCl and smaller size of elemental silicon at a reaction temperature of 220 °C. When a reaction was carried out by feeding a gaseous mixture of 1 [12.9 g/h (0.164 mol/h)] and HCl [2.98 g/h (0.082 mol/h)] to a contact mixture of elemental silicon (360 g) and copper (40 g) under the optimum condition for 45 h, 2a among volatile products kept up about 82 mol % until 35 h and then slowly decreased down 68 mol % in 45 h reaction. Finally 2a was obtained in 38% isolated yield (based on 1 used) with an 85% consumption of elemental silicon in a 45 h reaction. In addition to 2a, 2b was obtained as minor product along with chlorosilanes, trichlorosilane, and tetrachlorosilane. The decomposition of 1 was suppressed and the production of 2a improved by adding HCl to 1.

집속 아르곤 이온 레이저 빔을 이용한 레이저 유도 직접 구리 패터닝 (Laser-Induced Direct Copper Patterning Using Focused $Ar^+$ Laser Beam)

  • 이홍규;이경철;안민영;이천
    • 한국전기전자재료학회논문지
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    • 제13권11호
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    • pp.969-975
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    • 2000
  • Laser direct writing of micro-patterned copper lines has been achieved by pyrolytic decomposition of copper formate films (Cu(HCOO)$_2$.4$H_2O$), as a metallo-organic precursor, using a focused CW Ar$^{+}$ laser beam (λ=514nm) on PCB boards and glass substrates. The linewidth and thickness of the lines wee investigated as a functin of laser power and scan speed. The profiles of the lines were measured by scanning electron microscope (SEM), surface profiler ($\alpha$-step) and atomic force measured by scanning electron microscope (SEM), surface profiler ($\alpha$-step) and atomic force microscopy (AFM). The electrical resistivities of the patterned lines were also investigated as a function of laser parameters using probe station and semiconductor analyzer. We compared resistivities of the patterned copper lines with these of the Cu bulk. Resistivities decreased due to changes in morphology and porosity of the deposit, which were about 3.8 $\mu$$\Omega$cm and 12$\mu$$\Omega$cm on PCB and glass substrates after annealing at 30$0^{\circ}C$ for 5 minutes.s.

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The Effect of Foreign Direct Investment Inflow on Exports: Evidence from Vietnam

  • DO, Duc Anh;SONG, Yinghua;DO, Huu Tung;TRAN, Thi Thu Hien;NGUYEN, Thanh Thuy
    • The Journal of Asian Finance, Economics and Business
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    • 제9권2호
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    • pp.325-333
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    • 2022
  • Foreign direct investment (FDI) and export are now often regarded as two of the most important drivers of economic growth on a worldwide scale. The impact of foreign direct investment on Vietnam's exports is investigated in this study. The data for the time period 1985-2020 was obtained from the World Bank and the Vietnam General Statistics Office. The years 1985 to 2020 were chosen to evaluate the evolution of macroeconomic parameters since 1986. The impact of the Covid-19 epidemic on renovation reform. The Johansen co-integration test proved that FDI and domestic investment (DI) had a long-term positive impact on Vietnam's export growth. The Granger causality test revealed that there is a one-way relationship between FDI and export in the near term, but no such relationship exists between DI and export. The result of the variance decomposition study demonstrates that the FDI sector has a bigger impact on Vietnam's export growth than the DI sector. Furthermore, export activities are vulnerable to FDI sector shocks. As a result, in recent years, FDI has been regarded as the most important factor of export growth in Vietnam.

펜톤시약에 의한 이온교환수지의 직접산화분해 (The Direct Decomposition of Ion-Exchange Resins by Fenton's Reagent)

  • 김길정;손종식;류우석
    • 방사성폐기물학회지
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    • 제5권3호
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    • pp.221-227
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    • 2007
  • 음이온교환수지인 IRN-78및 IRN-77과의 혼합 수지를 액체 상태로 직접 분해 처리하기 위하여 Fenton 시약을 이용하였다. 개선된 분해방법의 특징은 수지를 먼저 건조시키고 $FeSO_4$ 용액을 수지에 완전히 흡수시킨 후 일정량의 $H_2O_2$를 첨가하여 분해반응을 유도하는 방법을 적용하였다. 촉매로서 $CuSO_4,\;Cu(NO_3)_2$ 및 IRN-77 수지의 분해시 사용한 $FeSO_4$를 각각 사용하여 각 이온교환수지의 단독 및 혼합수지의 분해에 필요한 적절한 촉매와 그의 농도 및 $H_2O_2$의 소요량을 측정하였다. IRN-78 수지에 대해 $CuSO_4$ 촉매를 사용한 경우, 초기 분해반응을 유도하기 위해 $40^{\circ}C$까지 가열이 필요하였으며, 반응유도시간은 촉매의 적정온도에서 약 20분 이내 개시되는 것으로 나타났다. 동 수지에 $FeSO_4$를 사용한 경우에는 가열 없이 즉시 분해반응이 진행되었으며 분해율도 수% 높게 나타났다. 결론적으로 IRN-78 및 IRN-77과의 혼합수지의 분해를 위한 최적 촉매는 $FeSO_4$로 나타났으며 가열하지 않고 상온에서 반응유도시간 없이 각 수지를 단독으로 분해한 경우보다 적은 양의 $H_2O_2$로 완전히 액상으로 분해시킬 수 있는 좋은 결과를 얻었다. 또한 이들 각각의 수지 및 혼합수지에 대한 적절한 촉매 및 적정 농도와 완전분해에 필요한 $H_2O_2$의 양을 제시하였다.

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Maximum Canopy Height Estimation Using ICESat GLAS Laser Altimetry

  • Park, Tae-Jin;Lee, Woo-Kyun;Lee, Jong-Yeol;Hayashi, Masato;Tang, Yanhong;Kwak, Doo-Ahn;Kwak, Han-Bin;Kim, Moon-Il;Cui, Guishan;Nam, Ki-Jun
    • 대한원격탐사학회지
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    • 제28권3호
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    • pp.307-318
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    • 2012
  • To understand forest structures, the Geoscience Laser Altimeter System (GLAS) instrument have been employed to measure and monitor forest canopy with feasibility of acquiring three dimensional canopy structure information. This study tried to examine the potential of GLAS dataset in measuring forest canopy structures, particularly maximum canopy height estimation. To estimate maximum canopy height using feasible GLAS dataset, we simply used difference between signal start and ground peak derived from Gaussian decomposition method. After estimation procedure, maximum canopy height was derived from airborne Light Detection and Ranging (LiDAR) data and it was applied to evaluate the accuracy of that of GLAS estimation. In addition, several influences, such as topographical and biophysical factors, were analyzed and discussed to explain error sources of direct maximum canopy height estimation using GLAS data. In the result of estimation using direct method, a root mean square error (RMSE) was estimated at 8.15 m. The estimation tended to be overestimated when comparing to derivations of airborne LiDAR. According to the result of error occurrences analysis, we need to consider these error sources, particularly terrain slope within GLAS footprint, and to apply statistical regression approach based on various parameters from a Gaussian decomposition for accurate and reliable maximum canopy height estimation.

Platinum Nano-Dispersion via In Situ Processing - Preparation and catalytic Property of Porous $CaZrO_3/MgO/Pt$ Nanocomposite

  • Yoshikazu;Hwang, Hae-Jin;Naoki Kondo;Tatsuki Ohji
    • 한국분말재료학회지
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    • 제8권3호
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    • pp.163-167
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    • 2001
  • A bulk porous $CaZrO_3/MgO$ composite with plantinum nano-dispersion was synthesized in air atmosphere through the combination of several in situ reactions, including the pyrolysis of $PtO_2$. A mixture of $CaMg(CO_3)_2$(dolomite), $ZrO_2$, $PtO_2$ and LiF (0.5 wt%, as an additive) was cold isostatically pressed at 200 MPa and sintered at $1100^{\circ}C$ for 2 h. The porous $CaZrO_3/MgO/Pt$ composite ($CaZrO_3/MgO$ : Pt=99 : 1 in volume) had a uniformly open-porous structure (porosity: 56%) with three-dimensional (3-D) network and a narrow pore-size distribution, similarly to the porous $CaZrO_3/MgO$ composites reported before. Catalytic Properties (viz., NO direct decomposition and NO reduction by $C_2H_4$) of the $CaZrO_3/MgO/Pt$ composite were investigated up to $900^{\circ}C$. In the absence of oxygen, the NO conversion rate reached ~52% for the direct decomposition and ~100% for the reduction by $C_2H_4$, respectively. The results suggest the possibility of the porous composite as a multifunctional filter, i.e., simultaneous hot gas-filtering and $de-NO_x$ in one component.

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