• Journal of Magnetics
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• 제18권4호
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• pp.417-421
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• 2013

The dominant magnetization reversal behavior of electrodeposited CoPt samples with various thicknesses deposited at different current densities was the domain wall motion by means of wall pinning. The magnetic interaction mechanism was dipolar interaction for all samples. The dipolar interaction strength was significantly affected by the sample thickness rather than by the current density, while the magnetic properties were closely related to the current density.

• Bulletin of the Korean Chemical Society
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• 제14권1호
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• pp.91-95
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• 1993

In this work we have studied the spin-lattice relaxation of $^{19}$F spins in benzotrifluoride in our quest for a reliable method of discriminating the contribution due to dipolar relaxation mechanism from that due to spin-rotational mechanism for nuclear spins located on methyl or substituted methyl group in organic molecules. Over the temperature range of 248-268 K the decay of normalized longitudinal magnetization was found to be well described by a two parameter equation of the form R(t) = exp(-st){$\frac{5}{6}$exp(-s$_1$)+$\frac{1}{6}$} which was derived under the assumption that interactions in the A3 spin system are modulated randomly and predominantly by internal rotational motions of -CF_3$ top, and it was shown that the separation of contribution due to dipolar interactions from that due to spin-rotation interaction could be successfully achieved by least-square fitting of observed data to this equation. The results indicate that the spin-rotational contribution is overwhelmingly larger than that of dipolar origin over the given temperature range and becomes more deminating at higher temperature.

• 한국자기학회지
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• 제21권5호
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• pp.151-156
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• 2011

전기도금법으로 제작한 CoPt 자성막의 두께가 자기상호작용과 자기적 성질에 미치는 영향을 잔류자기화 곡선과 자기이력 곡선을 측정 분석하여 규명하였다. CoPt 자성막의 두께가 증가함에 따라 수직 보자력과 포화자화가 증가하였으나 각형비는 급격히 감소하였다. 잔류자화 곡선의 분석결과로부터 모든 시료의 주된 자기상호작용 기구는 쌍극자 상호작용이며, 시료의 두께가 증가함에 따라 상호작용의 세기가 증가함을 알 수 있었다.

• 한국자기학회지
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• 제23권6호
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• pp.188-192
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• 2013

수직 자기기록 매체로 알려진 CoPt 자성막을 전기도금법으로 제작하여 자기상호작용이 활성화 부피와 면적에 미치는 영향을 조사하였다. 모든 시료의 상호작용 기구는 쌍극자 상호작용이었으며, 낮은 전류밀도에서 제작한 시료일수록 두께가 두꺼울수록 상호작용 세기가 증가하였다. 한편 활성화 부피는 낮은 전류밀도에서 제작한 시료가 더 컸으나 두께에 따른 증감현상은 뚜렷하지 않았다. 그러나 활성화 면적은 상호작용의 세기가 강할수록 전류밀도가 낮을수록 감소하는 경향을 보였다.

• Bulletin of the Korean Chemical Society
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• 제20권10호
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• pp.1205-1208
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• 1999

27Al NMR chemical shielding, quadrupolar coupling, and dipolar coupling interactions for corundum (α-Al2O3) are determined from the single-crystal 27 Al NMR spectra according to the rotation about three orthogonal axis. 27 Al NMR parameters obtained in this work with high accuracy are as follows: δiso = 7.4(4) ppm, QCC = 2.30(4) MHz, h = 0.08(3), and R = 2.0(3) kHz. This work appears to be the first NMR measurement of an aluminum-aluminum dipolar coupling interaction in α-Al2O3 crystals.

• Journal of the Optical Society of Korea
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• 제15권4호
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• pp.407-414
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• 2011

We analyze the cooperative spontaneous emission of optically excited nanocrystals into surface plasmon polaritons propagating on the surface of a cylindrical metallic nanowire. The spontaneous emission probability of the nanocrystals is obtained by perturbative expansions with and without dipole-dipole interaction among nanocrystals in order to see the cooperative effects. The spontaneous emission probability depends on the radial and axial distributions, as well as on the dipolar orientation of nanocrystals. It is shown that the spontaneous emission probability is strongly influenced by dipole-dipole interaction, axial distribution, and dipolar orientation of nanocrystals for closely spaced nanocrystals.

• 한국자기공명학회논문지
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• 제22권4호
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• pp.76-81
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• 2018

Investigation of the protein-protein interaction mode at atomic resolution is essential for understanding on the underlying functional mechanisms of proteins as well as for discovering druggable compounds blocking deleteriou interprotein interactions. Solution NMR spectroscopy provides accurate and precise information on intermolecular interactions even for weak and transient interactions, and it is also markedly useful for examining the change in the conformation and dynamics of target proteins upon binding events. In this mini-review, we comprehensively describe three unique and powerful methods of solution NMR spectroscopy, paramagnetic relaxation enhancement (PRE), pseudo-contact shift (PCS), and residual dipolar coupling (RDC), for the study on protein-protein interactions.

• Bulletin of the Korean Chemical Society
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• 제7권3호
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• pp.170-178
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• 1986

The NMR chemical shift arising from 4d electron angular momentum and 4d electron angular momentum and 4d electron spin dipolar-nuclear spin angular momentum interactions for a $4d^1$ system in a strong crystal field environment of trigonal symmetry, when the threefold axis is chosen to be the axis of quantization axis, has been examined. A general expression using the nonmultipole expansion method (exact method) is derived for the NMR chemical shift. From this expression all the multipolar terms are determined. We observe that along the (100), (010), (110), and (111) axes the NMR chemical shifts are positive while along the (001) axis, it is negative. We observe that the dipolar term (1/R3) is the dominant contribution to the NMR chemical shift except for along the (111) axis. A comparison of the multipolar terms with the exact values shows also that the multipolar results are exactly in agreement with the exact values around $R{\geqslant}0.2$ nm. The temperature dependence analysis on the NMR chemical shifts may imply that along the (111) axis the contribution to the NMR chemical shift is dominantly pseudo contact interaction. Separation of the contributions of the Fermi and the pseudo contact interactions would correctly imply that the dipolar interaction is the dominant contribution to the NMR chemical shifts along the (100), (010), (001), and (110) axes, but along the (111) axis the Fermi contact interaction is incorrectly the dominant contribution to the NMR chemical shift.

• Bulletin of the Korean Chemical Society
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• 제27권11호
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• pp.1752-1756
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• 2006

This study explores and interprets in a new way the complex solvent and the temperature dependence of the NMR shifts for the N-$CH_2$ protons in tris(N,N-diethyldithiocarbamato) iron(III) in acetone, benzene, carbon disulfide, chloroform, dimethylformamide and pyridine. The NMR shifts are interpreted in terms of the Fermi contact interaction and the dipolar term from the multipole expansion of the interaction of the electron orbital angular momentum and the electron spin dipolar-nuclear spin angular momentum. This analysis yields a direct measure of the effect of the solvent system on the environment of the transition metal ion. The results are analysed in terms of the crystal field environment of the transition metal ion with contributions from (a) the dithiocarbamate ligand (b) the solvent molecules and (c) the interaction of the effective dipole moment of the polar solvent molecule with the transition metal ion complex.

• 한국자기학회지
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• 제27권1호
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• pp.23-29
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• 2017

시료 크기별 자화 역전과 자기 상호작용이 보자력에 미치는 영향을 조사한 결과, 자구생성보다 자벽고착에 의한 자화 역전 현상이 지배적인 시료일수록 보자력과 각형비가 컸다. 이와 같은 현상은 자벽이 낟알 경계면이나 시료 내부에 존재하는 고착점에 강하게 포획되기 때문인 것으로 판단된다. 한편 자기 상호작용을 분석한 결과, 시료의 크기에 무관하게 모든 시료는 쌍극자 상호작용이 지배적인 상호작용 기구이며, 쌍극자 상호작용이 강한 시료일수록 보자력이 작았다. 따라서 보자력은 자화 역전 현상, 자기 상호작용 기구와 세기에도 깊이 관련됨을 알 수 있다.