• Title/Summary/Keyword: diffusion mechanism

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Clustering and traveling waves in the Monte Carlo criticality simulation of decoupled and confined media

  • Dumonteil, Eric;Bruna, Giovanni;Malvagi, Fausto;Onillon, Anthony;Richet, Yann
    • Nuclear Engineering and Technology
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    • v.49 no.6
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    • pp.1157-1164
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    • 2017
  • The Monte Carlo criticality simulation of decoupled systems, as for instance in large reactor cores, has been a challenging issue for a long time. In particular, due to limited computer time resources, the number of neutrons simulated per generation is still many order of magnitudes below realistic statistics, even during the start-up phases of reactors. This limited number of neutrons triggers a strong clustering effect of the neutron population that affects Monte Carlo tallies. Below a certain threshold, not only is the variance affected but also the estimation of the eigenvectors. In this paper we will build a time-dependent diffusion equation that takes into account both spatial correlations and population control (fixed number of neutrons along generations). We will show that its solution obeys a traveling wave dynamic, and we will discuss the mechanism that explains this biasing of local tallies whenever leakage boundary conditions are applied to the system.

Formation Mechanism of Cobalt Silicide by Solid Phase Reaction in Co/Ti/Si system (Co/Ti/Si 계에서 고상반응에 의한 Cobalt Silicide 형성기구 고찰)

  • Lee, Seung-Heon;Bae, Jun-Cheol;Sin, Dong-Won;Park, Chan-Gyeong
    • Korean Journal of Materials Research
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    • v.6 no.8
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    • pp.808-816
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    • 1996
  • (100) Si 기판위에 전자 빔 증착법을 이용하여$ 90\AA$두께의 Ti과 $120\AA$두께의 Co를 순차적으로 증착시켰다. 그 후 질소분위기하의 $350-900^{\circ}C$온도구간에서 급속열처리함으로써 (100) Si 기판위의 Co/Ti 이중 박막의 실리사이드화 반응이 일어나게 했으며 이를 XRD, AES, TEM을 이용하여 분석하였다. $500^{\circ}C$이하의 온도에서는 Co원자들이 Ti층쪽으로 빠르게 확산하여 Si와 반응하기 이전에 Ti원자들과 상호 혼합되어 어떠한 실리사이드도 형성되지 않았다. $500^{\circ}C$에서 열처리된 시편의 고분해능전자현미경 영상을 통해 Co-Ti 혼합층과 실리콘 기판과의 계면에서 (100)Si 기판과 정합관계를 가지는 CoSi2가 형성되었음을 확인했다. $600^{\circ}C$열처리에 의해 Co-Ti-Sitka성분 실리사이드가 형성되기 시작하였으며, 형성된 삼성분 실리사이드는 Ti의 out-diffusion에 의해 $900^{\circ}C$ 이상의 온도에서는 불안정하였다. Co/Ti이중 박막에 의해 형성된 CoSi2는 실리콘 기판과 평탄한 계면을 가지며 실리콘 기판에 대해 (100)우선성장방위를 가졌다.

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Fast Handover Provision Mechanism through Reduction of CoA Configuration Time (CoA 설정 시간 단축을 통한 빠른 핸드오버 제공 메카니즘)

  • Jin, Sung-Ho;Choi, Ji-Hyoung;Kim, Dong-Il
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.11 no.11
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    • pp.2027-2031
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    • 2007
  • Recently the diffusion of the advancement of mobile communication technique and mobile terminal increased, The users were demanded seamless services when carrying and moving. It proposed the FMIPv6(Fast Handoff for Mobile IPv6) from the IETF like this meeting this requirement. The handover procedure of the FMIPv6 causes to defecate with movement detection, new CoA configuration and binding update. But, the delay occurs from each process, when the DAD(Duplicate Address Detection) of the CoA executing, the big delay occurs. This paper proposes a scheme of delay reduction, it omits DAD process and stores in the AR(Access Router) relates in the CoA of the mobile terminal information.

An NMR Study on Molecular Motions of $\alpha$,2,6-Trichlorotoluene in Solution State

  • Ahn, Sang-Doo;Lee, Jo-Woong
    • Bulletin of the Korean Chemical Society
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    • v.15 no.7
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    • pp.553-559
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    • 1994
  • Dynamics of $CH_2CI$ group in ${\alpha},2,6$-trichlorotoluene dissolved in $CDCl_3$ was studied by observing various relaxation modes for $^{13}C$ under proton undecoupled condition. Partially relaxed $^{13}C$ spectra were obtained at $34^{\circ}C$ as a function of evolution time after applying various designed pulse sequences to this $AX_2$ spin system. It was found that nonlinear regression analysis of the relaxation data for these magnetization modes could provide the information about dipolar and spin-rotational auto-correlation and cross-correlation spectral densities for fluctuation of the $^{13}C-^1H$ internuclear vector in $CH_2Cl$ group. The results show that the effect of cross-correlation is comparable in magnitude to that of auto-correlation and the relaxation in this spin system is dominated by dipolar mechanism rather than spin-rotational one. From the resulting spectral density data we could calculate the bond angle ${\angle}HCH\;(105.1$^{\circ}$) and elements of the rotational diffusion tensor for $CH_2Cl$ group.

Characteristics of the Ionospheric Mid-Latitude Trough Measured by Topside Sounders in 1960-70s

  • Hong, Junseok;Kim, Yong Ha;Lee, Young-Sook
    • Journal of Astronomy and Space Sciences
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    • v.36 no.3
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    • pp.121-131
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    • 2019
  • The ionospheric mid-latitude trough (IMT) is the electron density depletion phenomenon in the F region during nighttime. It has been suggested that the IMT is the result of complex plasma processes coupled to the magnetosphere. In order to statistically investigate the characteristics of the IMT, we analyze topside sounding data from Alouette and ISIS satellites in 1960s and 1970s. The IMT position is almost constant for seasons and solar activities whereas the IMT depth ratio and the IMT feature are stronger and clearer in the winter hemisphere under solar minimum condition. We also calculated transition heights at which the densities of oxygen ions and hydrogen/helium ions are equal. Transition heights are generally higher in daytime and lower in nighttime, but the opposite aspects are seen in the IMT region. Utilizing the Incoherent Scatter Radar (ISR) electron temperature measurements, we find that the electron temperature in the IMT region is enhanced at night during winter. The increase of electron temperature may cause fast transport of the ionospheric plasma to the magnetosphere via ambipolar diffusion, resulting in the IMT depletion. This mechanism of the IMT may work in addition to the simply prolonged recombination of ions proposed by the traditional stagnation model.

An advanced core design for a soluble-boron-free small modular reactor ATOM with centrally-shielded burnable absorber

  • Nguyen, Xuan Ha;Kim, ChiHyung;Kim, Yonghee
    • Nuclear Engineering and Technology
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    • v.51 no.2
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    • pp.369-376
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    • 2019
  • A complete solution for a soluble-boron-free (SBF) small modular reactor (SMR) is pursued with a new burnable absorber concept, namely centrally-shielded burnable absorber (CSBA). Neutronic flexibility of the CSBA design has been discussed with fuel assembly (FA) analyses. Major design parameters and goals of the SBF SMR are discussed in view of the reactor core design and three CSBA designs are introduced to achieve both a very low burnup reactivity swing (BRS) and minimal residual reactivity of the CSBA. It is demonstrated that the core achieves a long cycle length (~37 months) and high burnup (~30 GWd/tU), while the BRS is only about 1100 pcm and the radial power distribution is rather flat. This research also introduces a supplementary reactivity control mechanism using stainless steel as mechanical shim (MS) rod to obtain the criticality during normal operation. A further analysis is performed to investigate the local power peaking of the CSBA-loaded FA at MS-rodded condition. Moreover, a simple $B_4C$-based control rod arrangement is proposed to assure a sufficient shutdown margin even at the cold-zero-power condition. All calculations in this neutronic-thermal hydraulic coupled investigation of the 3D SBF SMR core are completed by a two-step Monte Carlo-diffusion hybrid methodology.

Ab-initio Study of Hydrogen Permeation though Palladium Membrane (팔라듐 얇은 막의 수소 투과에 대한 제일 원리 계산)

  • Cha, Pil-Ryung;Kim, Jin-You;Seok, Hyun-Kwang;Kim, Yu Chan
    • Korean Journal of Metals and Materials
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    • v.46 no.5
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    • pp.296-303
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    • 2008
  • Hydrogen permeation through dense palladium-based membranes has attracted the attention of many scientists largely due to their unmatched potential as hydrogen-selective membranes for membrane reactor applications. Although it is well known that the permeation mechanism of hydrogen through Pd involves various processes such as dissociative adsorption, transitions to and from the bulk Pd, diffusion within Pd, and recombinative desorption, it is still unclear which process mainly limits hydrogen permeation at a given temperature and hydrogen partial pressure. In this study, we report an all-electron density-functional theory study of hydrogen permeation through Pd membrane (using VASP code). Especially, we focus on the variation of the energy barrier of the penetration process from the surface to the bulk with hydrogen coverage, which means the large reduction of the fracture stress in the brittle crack propagation considering Griffith's criterion. It is also found that the penetration energy barrier from the surface to the bulk largely decreases so that it almost vanishes at the coverage 1.25, which means that the penetration process cannot be the rate determining process.

Pore structure evolution characteristics of sandstone uranium ore during acid leaching

  • Zeng, Sheng;Shen, Yuan;Sun, Bing;Zhang, Ni;Zhang, Shuwen;Feng, Song
    • Nuclear Engineering and Technology
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    • v.53 no.12
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    • pp.4033-4041
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    • 2021
  • To better understand the permeability of uranium sandstone, improve the leaching rate of uranium, and explore the change law of pore structure characteristics and blocking mechanism during leaching, we systematically analyzed the microstructure of acid-leaching uranium sandstone. We investigated the variable rules of pore structure characteristics based on nuclear magnetic resonance (NMR). The results showed the following: (1) The uranium concentration change followed the exponential law during uranium deposits acid leaching. After 24 h, the uranium leaching rate reached 50%. The uranium leaching slowed gradually over the next 4 days. (2) Combined with the regularity of porosity variation, Stages I and II included chemical plugging controlled by surface reaction. Stage I was the major completion phase of uranium displacement with saturation precipitation of calcium sulfate. Stage II mainly precipitated iron (III) oxide-hydroxide and aluminum hydroxide. Stage III involved physical clogging controlled by diffusion. (3) In the three stages of leaching, the permeability of the leaching solution changed with the pore structure, which first decreased, then increased, and then decreased.

Computer simulation study for the effect of potential energy on the behavior of grain boundary using Molecular dynamics

  • Choi, Dong-Youl;Kim, Hyun-Soo;Kim, Young-Suk;Tomita, Yoshihiro
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.03b
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    • pp.173-178
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    • 1999
  • In this study MD simulations have been performed to observe the behavior of a grain boundary in an a-Fe plate under 2-dimensional loading. In MD simulation the acceleration of every molecule can be achieved from the potential energy and the force interacting between each molecule and the integration of the motion equation by using Verlet method gives the displacement of each molecule. Initially four a-Fe rectangular plates having different misorientation angles of grain boundary were modeled by using the Johnson potential and Morse potential We compared the potential energy of the grain boundary system with that of the perfect structure model. Also we could obtain the width of the grain boundary by investigating the local potential energy distribution. The tensile loading for each grain boundary models was applied and the behavior of grin boundary was studied. From this study it was clarified that in the case using Johnson potential the obvious fracture mechanism occurs along the grain boundary in the case of Morse potential the diffusion of the grain boundary appears instead of the grain boundary fracture.

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Zeolite Based Pervaporation Membrane: A Review (제올라이트 기반 투과증발 분리막: 총설)

  • JooYeop, Lee;Rajkumar, Patel
    • Membrane Journal
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    • v.32 no.6
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    • pp.383-389
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    • 2022
  • Membrane separation process is an important technique utilized for various applications. This separation process proceeds due to a driving force such as concentration gradient, pressure or electrical potential gradient etc. Pervaporation is one of the separation process based on solution-diffusion mechanism. The pressure of the permeate side is reduced by creating vacuum and separation is driven due to pressure difference. Purity of the fuel or chemical like ethanol or isopropyl alcohol are improved by dehydration process through porous zeolite membrane. These membranes have high thermal, chemical, mechanical stability. This review is classified mainly into two different sections: Ethanol and bio-oil dehydration by zeolite membrane.