• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.118-125
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• 2007

The firtst-order conditional moment closure (CMC) model is applied to CH4/air swirl diffusion flame in a gas turbine model combustor. The flow and mixing fields are calculated by fast chemistry assumption with SLFM library and a beta function pdf for mixture fraction. RNG k-e model is used to consider the swirl flame in a confined wall. Reacting scalar fields are calculated by elliptic CMC formulation with chemical kinetic mechanism, GRI Mech 3.0. Validation is done against measurement data for mean flow and scalar fields in the model combustor [1]. Results show reasonable agreement with the mean mixture fraction and its variance, while temperature is overpredicted as the level of local extinction increases. The second-order CMC model is needed to consider local extinction with considerable conditional fluctuations near the nozzle.

• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.7-12
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• 2007

To reveal the newly found liftoff height behavior of hydrogen jet, we have experimentally studied the stabilization mechanism of turbulent, lifted jet flames in a non-premixed condition. The objectives of the present research are to report the phenomenon of a liftoff height decreasing as increasing fuel velocity, to analyse the flame structure and behavior of the lifted jet, and to explain the mechanisms of flame stability in hydrogen turbulent non-premixed jet flames. The velocity of hydrogen was varied from 100 to 300m/s and a coaxial air velocity was fixed at 16m/s with a coflow air less than 0.1m/s. For the simultaneous measurement of velocity field and reaction zone. PIV and OH PLIF technique was used with two Nd:Yag lasers and CCD cameras. As results, it has been found that the stabilization of lifted hydrogen diffusion flames is related with a turbulent intensity, which means that combustion occurs where the local flow velocity is valanced with the turbulent flame propagation velocity.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05c
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• pp.409-414
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• 1996

Radionuclides such as Cs and Sr were removed from dilute aqueous solutions by means of inorganic adsorbents, 13X and chabazite. The physical adsorption obeyed the DA equation and non-equilibrium dynamic adsorption model, which describes surface diffusion mechanism with the DA equation, simulated the adsorption behavior of cesium and strontium on zeolite in fixed bed adsorbers. The dynamic model simulated the adsorption behavior of cesium and strontium.

• Journal of the Korean Chemical Society
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• v.27 no.1
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• pp.24-30
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• 1983

The polarographic behavior of 1-(2-pyridylazo)-2-naphthol (PAN) in acetonitrile as an aprotic solvent has been investigated. The reduction of PAN in $10^{-2}$ molarity of tetraethyl-ammonium perchlorate acetonitrile solution proceeds along two one-electron steps to give the corresponding hydrazo compound. Every reduction wave was diffusion controlled and considerably reversible. The reduction mechanism of PAN in acetonitrile is estimated as follows;

• Journal of Hydrogen and New Energy
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• v.15 no.1
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• pp.12-22
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• 2004

In order to evaluate the potential of partial hydrocarbon substitution to improve the safety of hydrogen use in general and the performance of internal combustion engines in particular, the outward propagation and development of surface cellular instability of spark-ignited spherical premixed flames of mixtures of hydrogen, hydrocarbon, and air were experimentally studied at NTP (normal temperature and pressure) condition in a constant-pressure combustion chamber. With propane being the substituent, the laminar burning velocities, the Markstein lengths, and the propensity of cell formation were experimentally determined, while the laminar burning velocities and the associated flame thicknesses were computed using a recent kinetic mechanism. Results show substantial reduction of laminar burning velocities with propane substitution, and support the potential of propane as a suppressant of both diffusional-thermal and hydrodynamic cellular instabilities in hydrogen-air flames.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.719-722
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• 2005

The watertightness of concrete is judged by the depth of penetration of water forced in under pressure with the mechanism of flow of seepage water examined theoretically and experimentally. As a result, it is found that in the case of low water pressure approximately 0.15Mpa or less, the flow is Darcy seepage flow, the same as flow in an ordinary sand stratum, whereas in the case of high water pressure, the flow is diffused seepage flow accompanied by internal deformation of concrete. It is suggested that the watertightness of concrete be evaluated by seepage coefficient in the case of the former and diffusion coefficient in the case of the latter.

• Journal of the Korean Ceramic Society
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• v.18 no.1
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• pp.35-40
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• 1981

The kinetics of the dehydration of Ha-dong kaolin was studied isothermally at various temperatures. Dehydration rate was measured by thermogravimetry method in the temperature range of 440~50$0^{\circ}C$ and the particle size range of 170~325mesh. The general equation f($\alpha$)=kt, where $\alpha$ is the fraction reacted in the time and the function f($\alpha$) depends on the reaction mechanism, was applied to this reaction. The function, f($\alpha$) was obtained by application of reduced-time plot and plot of lnln (1-$\alpha$) vs. ln (time), and expressed as (1-$\alpha$) ln (1-$\alpha$)+$\alpha$=kt. The dehydration followed the diffusion-controlled reaction model and gave activation energy of 30Kcal/mole.

• International Journal of Concrete Structures and Materials
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• v.9 no.4
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• pp.453-462
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• 2015

A critical review on existing creep theories in calcium-silicate-hydrate (C-S-H) is presented with an emphasis on several fundamental questions (e.g. the roles of water, relative humidity, temperature, atomic ordering of C-S-H). A consensus on the rearrangement of nanostructures of C-S-H as a main consequence of creep, has almost been achieved. However, main disagreement still exists on two basic aspects regarding creep mechanisms: (1) at which site the creep occurs, like at interlayer, intergranular, or regions where C-S-H has a relatively higher solubility; (2) how the structural rearrangement evolutes, like in a manner of interlayer sliding, intra-transfer of water at various scales, recrystallization of gelled-like particles, or dissolution-diffusion-reprecipitation at inter-particle boundary. The further understanding of creep behavior of C-S-H relies heavily on the appropriate characterization of its nanostructure.

• Journal of Electrochemical Science and Technology
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• v.4 no.3
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• pp.93-101
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• 2013

The electrodeposition of indium onto a copper electrode from an aqueous sulfate solution containing $In^{3+}$ was studied by means of cyclic voltammetry and chronoamperometry. Reduction and oxidation of indium on copper were investigated by using cyclic voltammograms at different negative limiting potentials and at different scan rates in cumulative cycles. Cyclic voltammograms indicated that reduction and oxidation processes of indium could involve various reactions. Chronoamperometry was carried out to analyze the nucleation mechanism of indium in the early stage of indium electrodeposition. The non-dimensional plot of the current transients at different potentials showed that the shape of the plot depended on the applied potential. The nucleation of indium at potential step of -0.6~-0.8 V was close to progressive nucleation limited by diffusion. However the non-dimensional plot of current transients for the indium nucleation showed different behaviors from theoretical curves at the potential step lower than -0.8 V.

• Proceedings of the Korean Society of Broadcast Engineers Conference
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• 2008.02a
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• pp.25-28
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• 2008

Shirai 등은 FSE'04에서 DSM 설계 원리를 적용하여 증명 가능한 Feistal 구조를 제안하였다. 제안된 구조는 임의의 라운드 수에 대하여 능동 S-box의 최소 개수를 증명할 수 있다. 그러나 제안된 구조에 제약된 조건을 만족하는 행렬이 존재함을 증명하지 못하였다. 본 논문에서는 DSM 설계 원리에 최대 branch number를 갖는 $m{\times}m$ 이진 행렬을 적용하였을 경우 동일한 최대 branch number를 가지지 못함을 증명 한다$(m{\leq}34)$. 이는 이진 행렬을 이용하여 Shirai 등이 제안한 구조를 설계할 수 없음을 의미한다.