• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.02a
• /
• pp.433-433
• /
• 2011

Since the concept of graphene was established, it has been intensively investigated by researchers. The unique characteristics of graphene have been reported, the graphene attracted a lot of attention for material overcomes the limitations of existing semiconductor materials. Because of these trends, economical fabrication technique is becoming more and more important topic. Especially, the epitaxial growth method by sublimating the silicon atoms on Silicon carbide (SiC) substrate have been reported on the mass production of high quality graphene sheets. Although SiC exists in a variety of polytypes, the 3C-SiC polytypes is the only polytype that grows directly on Si substrate. To practical use of graphene for electronic devices, the technique, forming the graphene on 3C-SiC(111)/Si structure, is much helpful technique. In this paper, we report on the growth of graphene on 3C-SiC(111) surface. To investigate the morphology of formed graphene on the 3C-SiC(111) surface, the radial distribution function (RDF) was calculated using molecular dynamics (MD) simulation. Through the comparison between the kinetic energies and the diffusion energy barrier of surface carbon atoms, we successfully determined that the graphitization strongly depends on temperature. This graphitization occurs above the annealing temperature of 1500K, and is also closely related to the behavior of carbon atoms on SiC surface. By analyzing the results, we found that the diffusion energy barrier is the key parameter of graphene growth on SiC surface.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.3 no.2
• /
• pp.146-156
• /
• 1995

Growing international concern about environmental issues in recent years has led to new proposals for strengthening exhaust emission standards and fuel economy requirements throughout the world. The low emission vehicle(LEV) standards drawn up by the California Air Resources Board(CARB) in the U.S.A are noticeably stringent To cope with this regulation, a reduction of HC emission is the most important challenge for the automotive industry because HC emission levels are severer than any other components emission levels. In this paper, the apparatus for visulalizing the wall film flow in a intake manifold and the spark plug with optical fiber for detecting the signal from diffusion flame are developed to mal,e the HC formation mechanism clear. High speed camera system is also used to elucidate the correlation wall film flow and the diffusion flame. Using these methods, the effect of fuel injection systems such as injection direction, spray angle, atomised injection on HC emission levels is investigated. Consequently, the optimal fuel injection conditions for minimizing the wall film flow and reducing the HC emission are found through this research.

• Journal of Sensor Science and Technology
• /
• v.16 no.6
• /
• pp.434-440
• /
• 2007

Two kinds of new NOx sensing mechanism was proposed and examined. One of those was potentiomtric sensor based on the measurement of decomposed oxygen from NO using YSZ porous diffusion barrier and Pd catalytic electrode. The sensor based on decomposed oxygen measurement responded to the range of 300 - 1000 ppm NO in $N_{2}$ environment and the sensitivities were coincident with theoretical values at 700 and $800^{\circ}C$ but the decomposition rate depended on gas flow rate. The other sensor was equilibrium potentiometric type using $Gd_{2}O_{3}$-nitrates solid solution as sensing material. The sensor using $Gd_{2}O_{3}$-nitrates solid solution was suitable for NOxxsensing at $700^{\circ}C$ in 5 % oxygen and the sensitivity was 19.3 mV/decade. However, long term stability of the sensing material at high temperature was not sufficient.

• Membrane Journal
• /
• v.9 no.1
• /
• pp.51-62
• /
• 1999

The recovery of trace volatile organic components from water by pervaporation was investigated. Permeation experiments through homogeneous polydimethylsiloxane(PDMS) membrane was carried out and the effect of feed concentrations and membrane thicknesses on the permeation characteristics were investigated. A solution-diffusion model is used to describe the pervaporation transport mechanism. In homogeneous PDMS membrane it appeared that the selectivities of MEK and toluene are constant, and that organic flux has a linear relationship with feed concentration. These results indicate that the coupling effects between organics were negligible. The selectivity of PDMS membranes is invariant with respect to the membrane thickness. The intrinsic membrane permeability of organic components determined by using a solution-diffusion model. Comparing with various composite type membrane, the membrane using PEG treated nonwoven fabric as sublayer showed the best performance in VOC recovery by pervaporation.

• Asian Journal of Business Environment
• /
• v.3 no.2
• /
• pp.17-22
• /
• 2013

Purpose - This dissertation is based on previous research, and analyzes processing trade, which constitutes a major section of foreign trade in Shandong Province. Research design, data, and methodology - The study uses the survey data on polarization, which is a vital index reflecting the unbalanced growth of regional economic development. The article introduces the processing trade polarization index, and the processing trade polarization fluctuation rate, to predict the geographical polarization posture and development trends in Shandong Province. Results -The development of processing trade in Shandong Province shows the level of gradient from east to west. The first-line growth pole has been formed and developed, and the initial formation of the diffusion mechanism has taken place. However, coordination problems in accompanying regional development have become increasingly prominent. Conclusions - This study focuses on the development of processing trade strategy and suggests overall coordination of development objectives, using non-balanced development goals. According to regional characteristics and development objectives of the processing trade in Shandong Province, the region around the city is divided into innovation diffusion region, enhanced growth areas, areas expected to undertake development, and areas to upgrade in four levels, given the different policy proposals.

• Korean Journal of Computational Design and Engineering
• /
• v.18 no.6
• /
• pp.399-406
• /
• 2013

This paper describes a new simulation technique for advection-diffusion phenomena over the sea surface using the lattice Boltzmann method (LBM), capable of predicting oil dispersion from tankers. The LBM is used to solve the pollutant transport problem within the framework of the ocean environment. The sea space is represented by the lattices, where each lattice has the information on oil transportation. Since dispersed oils (i.e., oil droplets) at sea are transported by convection due to waves, buoyancy, and turbulent diffusion, the conservation of mass and many physical oil transport rules were used in the prediction model. Since the LBM is modeled using the uniform lattices and simple rules, it can be easily accelerated by the parallel mechanism, for example, GPU-accelerated method. The proposed model using the LBM is used to simulate a simple pollution event with the oil pollutants of 10,000 kL. The simulation results indicate that the LBM method accelerated with the GPU is 6 times faster than that without the GPU.

• Journal of Hydrogen and New Energy
• /
• v.23 no.3
• /
• pp.256-263
• /
• 2012

We studied the degradation phenomenon of Pt catalyst in PEMFC. We used the electron microscope analysis technique including the ultra-microtome pretreatment method, FEG-SEM and TEM analysis methods for analysis of Pt nanoparticles. The Pt catalyst degradation is observed not only in electrode site but also in membrane site. We investigated these various degradation phenomena. The cathode electrode layer thickness is reduced. The size of the catalyst is increased much larger than initial size in membrane site. The catalyst moved from electrode layer to the electrolyte membrane. The rounded shape of catalyst was changed to the polygon. As a result, we found that the catalyst degradation processes of migration and coarsening occurred by the followings mechanisms; (1) dissolution of Pt ; (2) diffusion of Pt ion ; (3) Pt ion chemical reduction in membrane; (4) Coarsening of Pt particles (Ostwald ripening) ; (5) polygon shape change of Pt by {111} plane growth.

• Korean Journal of Food Science and Technology
• /
• v.11 no.2
• /
• pp.118-121
• /
• 1979

Under the experimental conditions of varying the thickness(2L cm) of ginseng disc and the bulk, concentration $(C_b.{\;}%)$, the experimental results were well coincided with those of the model which was set up by using the inter disc diffusion with constant diffusivity. It was therefore convinced that the extraction rate is controlled by the diffusion rate of ginseng components through the disc. The relationship between the diffusivity$(D{\;}cm^2/min)$ and the mean concentration (C %) of soluble ginseng components in the disc is as follows, $ln{\frac{C-C_{b0}}{C_i-C_{b0}}}=ln{\frac{8}{{\pi}^2}-{\frac{{\pi}^2D}{4L^2}{\theta}$ where $C_i(%)$ is the initial concentration of soluble ginseng components and $\theta$ (min.) is the extraction time.

• Journal of the Korean Ceramic Society
• /
• v.53 no.5
• /
• pp.511-520
• /
• 2016

Electrolyte-supported symmetric Ni-YSZ cermet electrodes of ca. $23{\mu}m$ were prepared by screenprinting and the impedance was measured as a function of humidity from 2% to 90% balanced in $H_2$ at a total flow rate of 50 sccm. The Ni felt current collector of 1 mm thickness exhibited a Gerischer-like gas concentration impedance in the low frequency range, which was similarly observed in the cermet-supported solid oxide cells, while the Pt paste collector exhibited only electrochemical polarization. The electrochemical polarization of both samples was modeled by a non-ideal diffusion-reaction transmission line model including CPEs with ${\alpha}$= 0.5. In the case of the Pt paste collector, all the Bisquert parameters exhibited humidity dependence to the -1/2 power, supporting a non-faradaic chemical reaction mechanism at three phase boundaries. Consequently, the surface diffusivity and reaction rate increased linearly with humidity. Less pronounced humidity dependence and somewhat lower utilization length with an Ni felt collector can be attributed to the diffusion-limited gas flow through the collector.

• Journal of the Korean Society of Safety
• /
• v.29 no.4
• /
• pp.23-27
• /
• 2014

The use of electromagnetic energy and non-equilibrium plasma for enhancing ignition and combustion stability is receiving increased attention recently. The conventional technologies have adapted the electrical devices to make the electromagnetic field, which resulted in various safety issues such as high-maintenance, additional high-cost system, electric shock and explosion. Therefore, an electrodeless microwave technology has an advantage for economic and reliability compared with conventional one because of no oxidation. However, the application of microwave has been still limited because of lack of interaction mechanism between flame and microwave. In this study, an experiment was performed with jet diffusion flames induced by microwaves to clarify the effect of microwave on the combustion stability and pollutant emissions. The results show that microwave induced flames enhanced the flame stability and blowout limit because of abundance of radical pool. However, NOx emission was increased monotonically with microwave intensity except 0.2 kW, and soot emission was reduced at the post flame region.