• 열처리공학회지
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• 제10권1호
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• pp.63-70
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• 1997

A study was performed to examine the aging behaviors of Al-2.1Li-2.9Cu alloy by differential scanning calorimetry and transmission electron microscopy. DSC measurements were conducted over the temperature range of $25{\sim}550^{\circ}C$ at a heating rate of $5^{\circ}C$/min. for the specimens aged at 130, 160, $190^{\circ}C$ and $220^{\circ}C$ for various times after solution treatment at $540^{\circ}C$ for 30 minutes. The peaks due to the formation of G.P.zone were not detected in the specimens aged at 130 and $160^{\circ}C$, but those at 190 and $220^{\circ}C$ appeared in DSC curves. The heat absorption due to the dissolution of ${\delta}^{\prime}$ phase was increased with increasing aging time at $130^{\circ}C$ aging. In contrast, those values for the specimens aged at 160 and $190^{\circ}C$ were initially increased and inversely decreased at the transition time of 72 and 1 hour, respectively. The heat evolution due to the formation of $T_1$ phase was nearly unchanged at $130^{\circ}C$ aging, but at $160^{\circ}C$ and $190^{\circ}C$ aging, drastically decreased after the transition time. It can be considered that the increase of $T_1$ phase results in the decrease of ${\delta}^{\prime}$ phase when aging time is longer than the transition time. The hardness of the specimen aged at $190^{\circ}C$ is initially higher compared with that at $160^{\circ}C$, however, the peak hardness shows the lower value than that at $160^{\circ}C$.

• 한국가스학회지
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• 제26권5호
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• pp.41-48
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• 2022

2-Chloro-N-(Cyano-2-thienyl methyl) acetamide(CCTA)는 농약을 합성하는데 사용하는 중간체로써 상온 및 상압에서는 안정하지만 열축적 시 분해될 수 있다. 본 연구에서는 열중량분석기(TGA) 실험을 통해 온도에 따른 질량 변화 측정으로 분해거동을 확인하고, 시차주사열량계(DSC)를 이용하여 열분해특성을 평가하였다. CCTA는 약 91℃에서 발열 분해반응이 급격하게 발생하였으며, Kissinger method, Kissinger-Akahira- Sunose(KAS) method, Flynn-Wall-Ozawa(FWO) method를 이용한 활성화 에너지 계산 결과, 각각 162 kJ/mol, 140 kJ/mol, 139 kJ/mol 으로 나타났다. 활성화에너지를 이용하여 계산된 24시간 이내 최대발열속도에 도달하는 온도인 T_D24는 52~55 ℃로 평가되었다.

• 대한기계학회논문집B
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• 제23권8호
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• pp.945-956
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• 1999

This work reports a set of approximate analytical solutions describing the initial transient process of close-contact melting between a rectangular parallelepiped solid and a flat plate on which either constant temperature or constant heat flux is imposed. Not only relative motion of the solid block tangential to the heating plate, but also the density difference between the solid and liquid phase is incorporated in the model. The thin film approximation reduces the force balance between the solid weight and liquid pressure, and the energy balance at the melting front into a simultaneous ordinary differential equation system. The normalized model equations admit compactly expressed analytical solutions which include the already approved two-dimensional solutions as a subset. In particular, the normalized liquid film thickness is independent of all pertinent parameters, thereby facilitating to define the transition period of close-contact melting. A unique behavior of the solid descending velocity due to the density difference is also resolved by the present solution. A new geometric function which alone represents the three-dimensional effect is introduced, and its properties are clarified. One of the representative results is that heat transfer is at least enhanced at the expense of the increase in friction as the cross-sectional shape deviates from the square under the same contact area.

• International Journal of Aeronautical and Space Sciences
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• 제4권2호
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• pp.17-25
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• 2003

Simple methods are developed to predict temperatures of a satellite box during launch stage. The box is mounted on outer surface of satellite and directly exposed to space thermal environment for the time period from fairing jettison to separation. These simple methods are to solve a 1st order ordinary differential equation (ODE) which is simplified from the governing equation after applying several assumptions. The existence of analytical solution for the 1st order ODE is determined depending on treatment of time-dependent molecular heating term. Even for the case that the analytical solution is not available due to the time dependent term, the 1st order ODE can be solved by relatively simple numerical techniques. The temperature difference between two different approaches (analytical and numerical solutions) is relatively small (Jess than $1^{\circ}C$ along the time line) when they are applied to STSAT-I launch scenario. The present methods can be generally used as tools to quickly check whether a satellite box is safe against space environment during the launch stage for the case that the detailed thermal analysis is not available.

• 폴리머
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• 제25권6호
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• pp.876-883
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• 2001

에톡시히드로퀴논과 브로모 테레프탈산을 사용하여 용액 중합법으로 네마틱 액정 상을 가지는 열방성 액정 고분자를 합성하였다. 합성된 헥사데실-몬모릴로나이트 (C$_{16}$-MMT)를 액정고분자의 용융 전이온도 이상에서 매트릭스 고분자에 대해 여러 wt%로 조성을 변화시키면서 나노복합재료를 만들었다. $C_{16}$-MMT가 액정 고분자에 대해 2 wt%만 첨가되어도 열적 성질이 크게 증가하였으며 이후로 $C_{16}$-MMT가 증가함에 따라 일정하게 증가하였다. 유기화 점토가 2에서 6 wt%까지 증가되어도 액정 상은 파괴되지 않고 그대로 유지되었다. X-ray 회절도의 결과, 첨가된 $C_{16}$-MMT의 일부는 TLCP에 잘 분산되었으나, 일부는 뭉쳐진 형태로 존재하였으며 첨가된 $C_{16}$-MMT의 상이 증가할수록 뭉침이 증가되었다. 합성된 나노복합재료의 열적 성질과 몰폴로지는 시차주사 열분석기(DSC), 열중량 분석기(TGA), 편광 현미경, 그리고 전자 현미경(SEM, TEM) 등을 이용하여 분석하였다.다.

• 항공우주기술
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• 제3권2호
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• pp.42-49
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• 2004

발사단계 중 fairing jettison에서 separation에 이르는 과정에서 위성체의 부품박스가 가지는 온도를 worst hot 조건에 대하여 해석적 방법을 이용하여 구하였다. Fairing jettison 이후에 위성체에 가해지는 외부 열환경과 박스 자체 내부에서의 발열, 박스 자체의 온도에 의한 방사열을 고려하여, 하나의 질량으로 가정할 수 있는 박스에 대한 온도 지배방정식을 해석해가 존재하는 1차 상미분 방정식으로 단순할 수 있었다. 특히, 고려하는 박스의 질량의 변화여부에 따라 해석해가 다른 지배방정식이 유도되었고, 각 경우에 대하여도 단순화된 식 내의 상수항의 조건에 따라 서로 다른 해석해가 존재하였다. 또한, 유도된 해석해를 실제 위성체인 STSAT-1의 worst hot 발사 조건에 대하여 적용하여 위성체 상단에 부착한 부품 박스의 온도를 예측하여 보았고, 이를 통하여 해석해의 유용성을 검증하였다.

• 천문학회보
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• 제42권2호
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• pp.61.2-61.2
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• 2017

We report a fine scale transient brightening event near a pore boundary with the Fast Imaging Solar Spectrograph (FISS) of the 1.6m Goode Solar Telescope (GST), the Atmospheric Imaging Assembly (AIA) aboard the Solar Dynamics Observatory (SDO), and Helioseismic and Magnetic Imager (HMI) aboard SDO. The event appears in all AIA extreme ultraviolet bands, also in the two FISS lines, $H{\alpha}$ and Ca II $8542{\AA}$, and lasted for a minute. The brightening occurred at a footpoint of a loop. The conjugate brightening occurred at the other foot point outside the FISS field of view. The brightening near the pore exhibit a redshift of 4.3 km s-1 in the $H{\alpha}$ and about 2.3 km s-1 in Ca II line. Differential emission measure derived from 6 AIA EUV passbands and cloud model fitting of the two FISS lines indicate the temperature increase of between 10,000 and 20 MK at the main event. After the brightening, the upward mass motion appears in the AIA images. We discuss the physical implication of this brightening in the context of magnetic reconnection and coronal heating.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2009년도 하계학술발표대회 논문집
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• pp.899-903
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• 2009

Recently, research and development of the linear compressor are being active. The reason is that the one has not only higher efficiency than reciprocating type, but also lower noise. But because the dicharge valve of linear compressor is operated in high pressure and temperature circumstance, it is important to prevent leakeage. In this paper three other plastic reinforced composite materials were used. Those are TPI, PEEK and PEK which were containing other volume and kind of carbon fibers. First, for assessing mechanical properties, we measured the hardness and the heating property of the trst sepecimen by the microvickers hardness tester and the differential scanning calorimeter respectively. Finally, through FALEX tester, we could know the characteristics of the wear proving the results of before-conducted experiments.

• Macromolecular Research
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• 제15권7호
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• pp.662-670
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• 2007

The crystallization behavior and fine structure of poly(ethylene terephthalate) (PET)/A-zeolite nanocomposites were assessed via differential scanning calorimetry (DSC) and time-resolved small-angle X-ray scattering (TR-SAXS). The Avrami exponent increased from 3.5 to approximately 4.5 with increasing A-zeolite contents, thereby indicating a change in crystal growth formation. The rate constant, k, evidenced an increasing trend with increases in A-zeolite contents. The SAXS data revealed morphological changes occurring during isothermal crystallization. As the zeolite content increased, the long period and amorphous region size also increased. It has been suggested that, since PET molecules passed through the zeolite pores, some of them are rejected into the amorphous region, thereby resulting in increased amorphous region size and increased long period, respectively. In addition, as PET chains piercing into A-zeolite pores cannot precipitate perfect crystal folding, imperfect crystals begin to melt at an earlier temperature, as was revealed by the SAXS profiles obtained during heating. However, the spherulite size was reduced with increasing nanofiller content, because impingement between adjacent spherulites in the nanocomposite occurs earlier than that of homo PET, due to the increase in nucleating sites.

• Elastomers and Composites
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• 제23권4호
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• pp.289-298
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• 1988

The thermal degradation of poly(methyl methacrylate)(PMMA) and poly($\alpha$-methylstyrene-co-acrylonitrile)(SAN) mixtures were carried out using the thermogravimetry(TG) and differential scanning calorimetry(DSC) in the stream of nitrogen and air with 50 ml/min at the various heating rate from 4 to $20^{\circ}C/min$ and temperature from 20 to $500^{\circ}C$. The value of activation energies of thermal degradation determined by TG and DSC in the various PMMA/SAN mixtures were 34-54 kcal/mol in the stream of nitrogen. The value of activation energy of SAN 60% mixture were appeared high in comparison with addition rule. PMMA/SAN mixtures by the analysis of infrared spectrophotometer were decomposed by main chain scission in the stream of nitrogen.