• Title/Summary/Keyword: differential distribution

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A Study on the Agglomeration of BaTiO3 Nanoparticles with Differential Synthesis Route (나노입자 합성방법에 따른 타이타늄산바륨 나노입자뭉침 현상 연구)

  • Han, W.-J.;Yoo, B.-Y.;Park, H.-H.
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.2
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    • pp.33-39
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    • 2015
  • $BaTiO_3$ is typical ferromagnetic materials with dielectric constant of above 200. $BaTiO_3$ nanoparticles applications are available for multiple purposes such as nanocapacitors, ferroelectric random access memories, and so on. Applications are is diverse from the dispersion of nanoparticles depending on the route of synthesis. In this study, $BaTiO_3$ nanoparticles were synthesized by two different methods such as oxalate method and sol-gel process (ambient condition sol method). Particle size and dispersion condition were studied according to the preparation method and capping agent. Poly vinyl pyrrolidone (PVP) was used as a capping agent in oxalate method and tetrabutylammonium hydroxide (TBAH) used as a capping agent in sol-gel process each. Cubic crystal structure of $BaTiO_3$ phase could be confirmed by X-ray diffraction analysis. Fourier transform-infrared spectroscopy was employed for the confirmation of the capping agent and $BaTiO_3$ nanoparticles. The particle size and distribution analysis was also performed by particles size analyzer and scanning electron microscope.

A Study on Maximum Responses of Rotational Shells Subjected to Uneven Settlements by Stochastic Method (부등침하를 받는 회전 쉘의 최대응답 추정에 관한 연구)

  • 정명채
    • Computational Structural Engineering
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    • v.10 no.3
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    • pp.175-184
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    • 1997
  • The objective of this paper is to study arelationship between maximum response and its standard deviation of rotational shells that are subjected to uneven settlements. For this, the ratio, .eta, of the maximum response to standard deviation and it's approximate, .eta./sub apr/, are investigated by stochastic methods. Also, an equation for .eta./sub apr/, that is a function of predominant harmonic number is suggested. The settlements are represented by the Fourier series. Each term in the series contains two coefficients; the amplitude and the phase angle. It is assumed that phase angles are random variables and amplitudes are deterministic. To investigate the characteristics of .eta. and .eta./sub apr/, 100 phase angles for two types of artificial amplitudes spectra are used in the analysis. .eta. and .eta./sub apr/, are almost constant regardless of amplitude type, position of a shell or type of responses; they fall into from 2.0 to 2.5. .eta./sub apr/ is always close to .eta., but tends to be somewhat greater. It may be concluded that a maximum responses of rotational shells subjected to uneven settlements are .eta./sub apr/ (about 2.5) times of its standard deviation. It is considered that this result is used when we design rotational shell structures subjected to differential settlements.

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ACN9 Regulates the Inflammatory Responses in Human Bronchial Epithelial Cells

  • Jeong, Jae Hoon;Kim, Jeeyoung;Kim, Jeongwoon;Heo, Hye-Ryeon;Jeong, Jin Seon;Ryu, Young-Joon;Hong, Yoonki;Han, Seon-Sook;Hong, Seok-Ho;Lee, Seung-Joon;Kim, Woo Jin
    • Tuberculosis and Respiratory Diseases
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    • v.80 no.3
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    • pp.247-254
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    • 2017
  • Background: Airway epithelial cells are the first line of defense, against pathogens and environmental pollutants, in the lungs. Cellular stress by cadmium (Cd), resulting in airway inflammation, is assumed to be directly involved in tissue injury, linked to the development of lung cancer, and chronic obstructive pulmonary disease (COPD). We had earlier shown that ACN9 (chromosome 7q21), is a potential candidate gene for COPD, and identified significant interaction with smoking, based on genetic studies. However, the role of ACN9 in the inflammatory response, in the airway cells, has not yet been reported. Methods: We first checked the anatomical distribution of ACN9 in lung tissues, using mRNA in situ hybridization, and immunohistochemistry. Gene expression profiling in bronchial epithelial cells (BEAS-2B), was performed, after silencing ACN9. We further tested the roles of ACN9, in the intracellular mechanism, leading to Cd-induced production, of proinflammatory cytokines in BEAS-2B. Results: ACN9 was localized in lymphoid, and epithelial cells, of human lung tissues. ACN9 silencing, led to differential expression of 216 genes. Pathways of sensory perception to chemical stimuli, and cell surface receptor-linked signal transduction, were significantly enriched. ACN9 silencing, further increased the expression of proinflammatory cytokines, in BEAS-2B after Cd exposure. Conclusion: Our findings suggest, that ACN9 may have a role, in the inflammatory response in the airway.

The Effect of Functional Group Position of the Piperidine Derivatives on the CO2 Absorption Characteristics in the (H2O-Piperidine-CO2) System ((H2O-Piperidine-CO2) system에서 piperidine 유도체의 작용기 위치에 따른 이산화탄소 흡수특성 연구)

  • Choi, Jeong Ho;Yun, Soung Hee;Kim, Yeong Eun;Yoon, Yeo Il;Nam, Sung Chan
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.57-63
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    • 2015
  • Absorption characteristics of 2-methylpiperidine (2MPD), 3-methylpiperidine (3MPD) and 4-methylpiperidine (4MPD) absorbents were studied by a vapor-liquid equilibrium (VLE) apparatus and a differential reaction calorimeter (DRC). Using a VLE apparatus, the $CO_2$ loading capacity of each absorbent was estimated. After reaching the absorption equilibrium, nuclear magnetic resonance spectroscopy (NMR) had been conducted to characterize the species distribution of the ($H_2O$-piperidine-$CO_2$) system. Using a DRC, the reaction of heat was confirmed in accordance with the absorption capacity. The unique characteristics of 2MPD, 3MPD and 4MPD absorbents appeared by the position of methyl group. The 2MPD possessing the methyl group at the ortho position showed its hindrance effect during the absorption process; however, piperidine derivatives possessing the meta position and para position did not show its characteristics in $H_2O$-piperidine-$CO_2$ system.

A Study on the Vent Path Through the Pressurizer Manway and Steam Generator Manway under Loss of Residual Heat Removal System During Mid-loop Operation in PWR (가압경수로의 부분충수 운전중 잔열제거계통 기능 상실사고시 가압기와 증기발생기 Manway 유출유로를 이용한 사고완화에 관한 연구)

  • Y. J. Chung;Kim, W. S.;K. S. Ha;W. P. Chang;K. J. Yoo
    • Nuclear Engineering and Technology
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    • v.28 no.2
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    • pp.137-149
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    • 1996
  • The present study is to analyze an integral test, BETHSY test 6.9c, which represent loss of RURS accident under mid-loop operation. Both the pressurizer manway and the steam generator outlet plenum manway are opened as vent paths in order to prevent the system from pressurization by removing the steam generated in the core. The main purposes are to gain insights into the physical phenomena and identify sensitive parameters. Assessment of capability of CATHARE2 prediction can be established the effective recovery procedures using the code in an actual plant. Most of important physical phenomena in the experiment could be predicted by the CATHARE2 code. The peak pressure in the upper plenum is predicted higher than experimental value by 7 kPa since the differential pressure between the pressurizer and the surge line is overestimated. The timing of core uncovery is delayed by 500 seconds mainly due to discrepancy in the core void distribution. It is demonstrated that openings of the pressurizer manwey and the steam generator manway can prevent the core uncovery using only gravity feed injection. Although some disagreements are found in the detailed phenomena, the code prediction is considered reasonable for the overall system behaviors.

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Syntaxonomy of the Forest Vegetation and Surrounding Taegu, Korea (대구 인접지역에 대한 삼림식생의 군락분류)

  • Choung, Heung-Lak;Lee, Ho-Joon;Lee, Jae-Seok
    • The Korean Journal of Ecology
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    • v.23 no.5
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    • pp.407-421
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    • 2000
  • The forest vegetation surrounding Taegu area was investigated by the methodology of the ZM school of phytosociology, from September, 1994 to August, 1997. The forest vegetation was classified into 7 communities, 8 subcommunities and 5 afforestations as follows : Quercus mongolica community (Typical subcommunity, Carex siderosticta subcommunity), Quercus variabilis community, Quercus acutissima community, Quercus dentate community, Carpinus cordata-Acer mono community (Typical subcommunity, Quercus serrata subcommunity, Cornus controversa subcommunity), Pinus densiflora community (Typical subcommunity, Sanguisorba officinalis subcommunity, Rhododendron schlippenbachii subcommunity), Lespedeza maximowiczii-Rhododendron mucronulatum community , Robinia pseudo-acacia afforestation, Pinus rigida afforestation, Larix leptolepis afforestation, Pinus thunbergii afforestation, Pinus koraiensis afforestation. The differential species of the Quercus mongolica community were Quercus mongolica, Athyrium yokoscense, Rhododendron schlippenbachii, Fraxinus sieboldiana, Acer pseudo-sieboldianum, Symplocos chinensis for. pilosa, Astilbe chinensis var. davidii, Weigela subsessilis, and Melampyrum roseum, those of the Carpinus cordata-Acer mono community were Acer mono, Carpinus cordata, Carpinus laxiflora, and Staphylea bumalda, those of the Pinus densiflora community were Pinus densiflora, Quercus serrata, Cocculus trilobus, and Juniperus rigida. Constance degree of the Quercus serrate was especially high in shrub and herb layers of the Pinus densiflora community. The results of factor analysis by DCA showed that distribution pattern of the communities were similar to that by Z-M method and that communities were arranged according to soil moisture gradient. Rhododendron schlippenbachii subcommunity of the P. densiflora community and the Typical subcommunity of the Q. mongolica community were distributed in similar environments.

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Allele and Genotype Frequencies of the Polymorphic Methylenetetrahydrofolate Reductase and Colorectal Cancer among Jordanian Population

  • Yousef, Al-Motassem;Shomaf, Maha;Berger, Sondra;Ababneh, Nidaa;Bobali, Yahya;Ali, Dema;Al-Hasan, Sara;Diab, Ola;Ismail, Said
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.8
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    • pp.4559-4565
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    • 2013
  • Background: Methylenetetrahydrofolate reductase (MTHFR) is involved in DNA synthesis and repair. We here aimed to investigate two common polymorphisms, C677T and A1298C, with genotype and haplotype frequencies in colorectal cancer (CRC) cases among Jordanian. Materials and Methods: 131 CRC cases were studied for MTHFR C677T and A1298C polymorphisms, compared to 117 controls taken from the general population, employing the PCR-RFLP technique. Results: We found the frequency of the three different genotypes of MTHFR C677T among Jordanians to be CC: 61.7%, CT: 35.2%, and TT 3.1% among CRC cases and 50.9%, 38.8% and 10.3% among controls. Carriers of the TT genotype were less likely to have CRC (OR=0.25; 95%CI: 0.076-0.811; p=0.021) as compared to those with the CC genotype. Genotype analysis of MTHFR A12987C revealed AA: 38.9%, AC: 45%, and CC 16% among CRC cases and 37.4%, 50.4% and 12.2% among controls. There was no significant association between genetic polymorphism at this site and CRC. Haplotype analysis of MTHFR polymorphism at the two loci showed differential distribution of the TA haplotype (677T-1298A) between cases and controls. The TA haplotype was associated with a decreased risk for colorectal cancer (OR=0.6; 95% CI: 0.4-0.9, p=0.03). Conclusions: The genetic polymorphism of MTHFR at 677 and the TA haplotype may modulate the risk for CRC development among the Jordanian population. Our findings may reflect an importance of genes involved in folate metabolism in cancer risk.

Hand Held the distance measurement of platform on GPS (GPS기반 Hand Held Type 거리 측정기)

  • 박지훈;김영길
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2003.10a
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    • pp.864-867
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    • 2003
  • GPS (Global Positioning System) made by the Department of Defense in U.S.A is positioning system to use satellite and initially it has been used only for the military forces but open to civilian in about 1987. This system has widely been used for not only surveying land, but also car navigation on the street and means to build up the data of the GIS. With GPS, recently our country is accelerating to make imbeded system and also the study on imbeded system is well under way. For example, Car navigation and the construction of the Seokang bridge between Willson Arch at Han river by using DGPS were evaluated as successful model to lead accurate location with the precision of the cm. The examples of the project performance with GPS has gradually been extended to the each department organization of the local and central government. for the example, It is true that BIS(Bus Information System) is widely spreading out. In addition, the study on the Distribution Maintenance System is expected to be well in progress to take advantage of GPS based on the data base of the NGIS(National Geography Institute System) of the NGI(National Geography Institute). This paper shows that we embodied not only the large imbeded system for car and finding the location in Korean Land Corporation but also the protype of the kinematics Wrist Held which is easily portable to pedestrian, climber and marathon runner.

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Emulsion Polymerization of Vinyl acetate-Butyl acrylate Copolymer (유화 중합에 의한 비닐 아세테이트-부틸 아크릴레이트 공중합체의 합성 연구)

  • 설수덕;임종민
    • Polymer(Korea)
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    • v.28 no.2
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    • pp.135-142
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    • 2004
  • Poly(vinyl acetate) (PVAc) prepared by emulsion polymerization has broad applications for additives such as paint binder, adhesive for wood and paper due to its low glass transition temperature which help to plasticize substrate resins. Since emulsion polymerization has a disadvantage that surfactant and ionic initiator degrade properties of the product polymer, poly(vinyl acetate-co-butyl acrylate) (VVc-BA) was synthesized using potassium persulfate as catalyst and poly(vinyl alcohol) (PVA) as protective colloid to prevent the degradation. The copolymer latex product was internally plasticized and has enhanced colloid stability, adhesion, tensile strength and elongation. During VAc-BA emulsion polymerization, no coagulation and complete conversion occur with the reactant mixture of 0.7wt% potassium persulfate, 15wt% poly(vinyl alcohol) (PVA-217), and the balanced monomer that the weight ratio of vinyl acetate to butyl acrylate is 19. As the concentrations of PVA increase, the copolymerization becomes faster and polymer particles are more stable, resulting in enhanced mechanical stability of the VAc-BA copolymer. However, the size of the polymer particles decreases with increasing PVA contents. Properties of the VAc-BA copolymer, such as minimum film formation temperature, glass transition temperature, surface morphology, molecular weight and molecular weight distribution, tensile strength and elongation, were characterized using differential scanning calorimeter, transmission electron microscope and other instruments.

The Synthesis and Properties of Nonlinear Optical Polyquinonediimine Containing Mono-Azobenzene Group in the Side Chain (곁사슬에 모노-아조벤젠기를 갖는 비선형 광학 폴리퀴논디이민의 합성과 성질에 관한 연구)

  • 이상배;양정성;박동규
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.737-743
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    • 2000
  • Polyquinonediimines (PQDI) which have stable structure on heat and contains mono-azobenzene in the side chain were synthesized by means of condensation polymerization under TiCl$_4$. The synthesized monomers and polymers were identified by FT-IR, $^1$H-NMR, and elementary analysis. Especially, PQDI was comfirmed by the double-bonding peak of >C=N appeared near 1625 $cm^{-1}$ / by means of FT-IR spectrum. PQDI containing mono-azobenzene group in both side chains wat not soluble in non-polar solvents at all but partially soluble in the polar solvents having small dielectric constant, and dissolved in the strong acid such as sulfuric acid and $CH_3$SO$_3$H. Molecular weight distribution of PQDI measured by GPC showed 1.74. It was confirmed through X-ray diffraction analysis that the polymer was partially crystalline at the low angle region, but amorphous after heat treatment at 1$25^{\circ}C$. The glass transition temperature (T$_{g}$ ) of synthesized polymer was measured as 1$25^{\circ}C$ by differential scanning calorimetry. The SHG value for $\chi$$^{(2)}$ after poling at 1$25^{\circ}C$ was 8.6 pm/V (λ=1.542 ${\mu}{\textrm}{m}$). The SHG value slowly decreased with time from the start but appeared temporal stability after 100 hours.

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