• 제목/요약/키워드: deviation ratio

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Quantitative Analysis and Qualification of Amitrole Using LC/ESI-MS (LC/ESI-MS를 이용한 아미트롤의 정성확인 및 정량분석)

  • Park, Chan-Koo;Eo, Soo-Mi;Kim, Min-Young;Sohn, Jong-Ryeul;Mo, Sae-Young
    • Analytical Science and Technology
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    • v.17 no.2
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    • pp.117-129
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    • 2004
  • Amitrole in environment, difficult to be analyzed by GC or GC/MS due to high polarity and low volatility, was analyzed by LC/ESI/MS in the study. Maximum peak intensity of amitrole in LC/MS/ESI mass spectrum is m/z 85 of protonated molecular ion $(M+H)^+$ with 30V of cone voltage at SIR mode. It was confirmed that ratios between main ion of amitrole, 85 of protonated molecular ion, and m/z 58 fragmented ion of amitrole, had increased corresponding with the increment of cone voltage from 20V to 70V. The isotope molecular weight of amitrole was $86([M+H])^+$ at LC/MS analysis and the mass spectrum ratio between 85 mass and 86 mass was not different by the change of concentration but similar to theoretical ratio(less than 10% standard deviation).The linearity of standard calibration curve under same condition with sample treatment method had $y=1.09354e^6X+26947.2$ and $r^2=0.99$. Recovery rates in water and soil samples were 77.64~83.44% and 71.11~79.44%, respectively. Reliability of the analysis was performed with 5 repeated measurements at each level of standard concentration and the result showed that relative standard deviation was less than 10%; therefore, the extraction and analysis method in the study suggested that it would be reliable to measure amitrole in water and soil media.

Roles of the Specialized Education Recognized by Professional Panels (전문가 패널들이 인식하는 공업계고등학교의 전문교육 역할)

  • Oh, Seung-gyun
    • 대한공업교육학회지
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    • v.33 no.1
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    • pp.1-22
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    • 2008
  • The purpose of this research is to clarify the elements of the function of the role of industrial high schools that its experts perceived. The content of this research is verify the function element required for the performance of the role of specialized education through content validity ratio(CVR). This research adopted the method of literature research and Delphi method, which is to collect and come to an agreement of the opinions of the 26 research panels. The first round is constructed by the semi-constructed questionnaire for the analysis of the opinions of the panels by inductive method. The second round is to categorize the result of the first one into 7 domains, and asked each category by Likert's 5 scale checklists, and statistically analyzed mean, medium, standard deviation, and quartile. The third round is to statistically analyze Mean, standard deviation, medium, and validity ratio(CVR) to reassure the opinions of the panels on the basis of the result of the first one. The categorized contents of the function required for the performance of the specialized education in this research is 'in-service visit and in-service training', 'licence acquiring education', 'employment counseling and job employment information', 'custom-made education connected with industry', 'career education' and 'enhancement of basic career competency'. The panels are divided into professors, teachers, professionals, and policy administrators, and they verified the validity rate of the function role and priority of emphasis. The result showed that the tendency of the education is converting from physical function-centered education to education of emotional attitude and competence of thought.

A Study on Supportive State for Disabled Students of University Libraries in Seoul and Kyonggi (서울.경기 소재 대학도서관의 장애학생 지원 실태 조사)

  • Park, Hyun-Young;Nam, Tae-Woo
    • Journal of Information Management
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    • v.39 no.1
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    • pp.83-108
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    • 2008
  • This thesis investigated disabled students' actual status of applying for university libraries. This thesis investigated how many times the university disabled students utilized the libraries, if facilities, apparatuses, materials, and regular employees were operated properly, and if they were established actually on the target at thirty private university libraries located at Seoul and Gyeonggi regions in operation of specially screening the objective students for special education in 2008. The investigation found that the general operation level of university libraries for disabled students were less than "medium"(average 2.38). As for utilization ratio, the most university students responded that "they didn't utilize libraries so many times(60%)". As for the response ratio of university library facilities and services, the most university students responded, "very insufficient", 99 items(32.27%), and the least university students responded, "very excellent", 28 items(7.0%). On the other hand, as for the analysis of each field, building facilities, in all of the items, were established more than "medium"(average 3.26), but material preparation level(average 1.8 point), employee education for softly supporting disabled students, and library utilization education on the target at disabled students(average 1.87) were less than "insufficient". Especially, the field of service was "insufficient level"(average 2.48), and standard deviation was more than 1.4. Manpower stationing and material delivery services have the biggest standard deviation between universities. So, this investigation found that university libraries reformed access to facilities a lot, but that its level of fundamental policy for library, such as materials, manpower, and the education on utilization, were in insufficient level.

Trend and Shift Analysis for Hydrologic and Climate Series (수문 및 기후 자료에 대한 선형 경향성 및 평균이동 분석)

  • Oh, Je Seung;Kim, Hung Soo;Seo, Byung Ha
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4B
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    • pp.355-362
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    • 2006
  • Several techniques of MK test, Spearman's Rho test, Linear Regression test, CUSUM test, Cumulative Deviation, Worsley Likelihood Ratio test, Rank Sum test, and Students' t test were applied to detect the trends of slope and shift which exist in hydrologic and climate time series. The time series of annual rainfall, inflow, tree ring index, and southern oscillation index (SOI) were used and the trends of these series were compared in the study. From the results, it can be found that the data could be classified into two categories such as linear trend and shift. 4 series data of 8 rainfall series which reveal the trend show the shift and 8 series data of 18 tree ring index and March and April series of monthly SOI data show shift. Moreover, ADF test and BDS test were used to test stationarity and non-linearity of the data. In conclusion, through the study, various trend analysis techniques were compared and 6 kinds of characteristics which can exist in hydrologic time series were identified.

A Study on The Success Factors of Youth Enterprises (청년창업 성공요인에 관한 연구: 창업전문가를 대상으로)

  • Shim, Hyeon Min;Seol, Byung Moon
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.17 no.2
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    • pp.1-13
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    • 2022
  • This study derived the success factors of youth enterprises by applying the Delphi Method to start-up experts. Through this, it aims to improve understanding of youth enterprises in entrepreneurship education and start-up support projects and contribute to the development of education and support programs suitable for youth enterprises. Also The purpose of this study is to help youth entrepreneurs solve their curiosity about the success factors of youth enterprises, identify the factors that youth entrepreneurs should first secure or perform among the factors they need to consider during start-ups, and use limited resources efficiently and effectively to succeed. In this study, the Delphi Survey was conducted twice in total. The first Delphi Survey utilized the Modified Delphi Method using structured closed-ended questions, and a pilot test was conducted on youth entrepreneurs and start-up experts to compensate for the problem of the Modified Delphi Method. In the first Delphi Survey, IBM SPSS Statistics 22 and Microsoft Office Excel 2016 were used to calculate the mean, standard deviation, median, interquartile range, and content validity ratio. In the Delphi 2nd survey, the same statistical values in the 1st survey and additionally cronbach's alpha were calculated. As a result of the Delphi Survey, four factors, such as the entrepreneurial characteristics, entrepreneurial preparation, entrepreneurial strategy, and entrepreneurial environment, and 22 sub-factors were derived as success factors for youth enterprises.

Comparison of the Performance of Machine Learning Models for TOC Prediction Based on Input Variable Composition (입력변수 구성에 따른 총유기탄소(TOC) 예측 머신러닝 모형의 성능 비교)

  • Sohyun Lee;Jungsu Park
    • Journal of the Korea Organic Resources Recycling Association
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    • v.32 no.3
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    • pp.19-29
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    • 2024
  • Total organic carbon (TOC) represents the total amount of organic carbon contained in water and is a key water quality parameter used, along with biochemical oxygen demand (BOD) and chemical oxygen demand (COD), to quantify the amount of organic matter in water. In this study, a model to predict TOC was developed using XGBoost (XGB), a representative ensemble machine learning algorithm. Independent variables for model construction included water temperature, pH, electrical conductivity, dissolved oxygen concentration, BOD, COD, suspended solids, total nitrogen, total phosphorus, and discharge. To quantitatively analyze the impact of various water quality parameters used in model construction, the feature importance of input variables was calculated. Based on the results of feature importance analysis, items with low importance were sequentially excluded to observe changes in model performance. When built by sequentially excluding items with low importance, the performance of the model showed a root mean squared error-observation standard deviation ratio (RSR) range of 0.53 to 0.55. The model that applied all input variables showed the best performance with an RSR value of 0.53. To enhance the model's field applicability, models using relatively easily measurable parameters were also built, and the performance changes were analyzed. The results showed that a model constructed using only the relatively easily measurable parameters of water temperature, electrical conductivity, pH, dissolved oxygen concentration, and suspended solids had an RSR of 0.72. This indicates that stable performance can be achieved using relatively easily measurable field water quality parameters.

Comparison Study on CNR and SNR of Thoracic Spine Lateral Radiography (흉추 측면검사 영상의 CNR과 SNR 측정의 비교 연구)

  • Kim, Ki-Won;Min, Jung-Whan;Lyu, Kwang-Yeul;Kim, Jung-Min;Jeong, Hoi-Woun;Lee, Joo-Ah;Jung, Jae-Hong;Sung, Dong-Chan;Park, Soon-Cheol
    • Journal of radiological science and technology
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    • v.36 no.4
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    • pp.273-280
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    • 2013
  • This study was proven for the T-spine breathing technique in lateral projection, using computer radiography (CR), charge coupled device (CCD), indirect digital radiography (IDR) and direct digital radiography (DDR). All images were evaluated and compared with CNR and SNR measured with the mean pixels and the standard deviation as setting ROI of spinous process, pedicle, vertebral body, intervertebral foramen and intervertebral disk using Image J. In experiment results of 4 type detectors, T-spine breathing technique was indicated as excellent in ROI of spinous process, pedicle, vertebral body, intervertebral foramen and intervertebral disk. As T-spine breathing technique indicated excellent images compared to the existing T-spine lateral radiography, this method would be useful for elderly patients who have difficulty in deep exhalation. This study was indicated the application possibility of T-spine breathing technique by presenting contrast to noise ratio (CNR) and signal to noise ratio (SNR) with quantitative value in 4 type detectors.

Evaluation of Shrinkage Strain of Alkali-Activated Slag Concrete (알칼리활성 슬래그 콘크리트의 건조수축 변형률 평가)

  • Yang, Keun-Hyeok;Seo, Eun-A
    • Journal of the Korea Concrete Institute
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    • v.25 no.6
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    • pp.593-599
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    • 2013
  • The unrestrained shrinkage strain of alkali-activated (AA) slag concrete was examined and compared with design equations specified in code provisions and empirical equations proposed by Yang et al. The main parameters investigated were the water-to-binder ratio (W/B), unit water content and fine aggregate-to-total aggregate ratio (S/a). Test results revealed that shrinkage strain of AA slag concrete is nearly proportional to the W/B ratio, whereas its time function is independent of the W/B ratio. The shrinkage strain of AA slag concrete increased significantly when the unit water content is above $185kg/m^3$, whereas it is marginally affected by the S/a ratio. The design equation of ACI 209 considerably overestimates the shrinkage behavior of AA slag concrete, whereas CEB-FIP equation tends to underestimate the shrinkage at the age more than 28 days. The empirical equation of Yang et al. is in better agreement with test results, showing that values of mean and standard deviation of error coefficients obtained from each specimen are 016 and 0.07, respectively.

Characteristics of the Lidar Ratio Determined from Lidar and Sky Radiometer Measurements in Seoul (라이다와 스카이 라디오미터 관측 자료를 이용한 서울지역 라이다 비의 특성 분석)

  • Kim, M.H.;Kim, S.W.;Yoon, S.C.;Sugimoto, Nobuo;Sohn, B.J.
    • Atmosphere
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    • v.21 no.1
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    • pp.57-67
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    • 2011
  • Aerosol lidar ratio (extinction-to-backscatter ratio) at 532 nm was determined using 4-year measurements of elastic-backscatter lidar and sky radiometer at Seoul National University of Seoul, Korea. The mean lidar ratio (with standard deviation) based on 4 years of measurements is found to be $61.7{\pm}16.5$ sr, and weak seasonal variations are noted with a maximum in JJA ($68.1{\pm}16.8$ sr) and a minimum in DJF ($57.2{\pm}17.9$ sr). The lidar ratios for clean, dust, and polluted conditions are estimated to be $45.0{\pm}9.5$ sr, $51.7{\pm}13.7$ sr, and $62.2{\pm}13.2$ sr, respectively. While the lidar ratio for the polluted condition is appears to be consistent with previous studies, clean and dust conditions tend to have larger ratios, compared to previous estimates. This discrepancy is thought to be mainly due to the anthropogenic aerosols existing throughout the year around Seoul, which may cause increased lidar ratios even for clean and dust conditions.

Design Approach for Boundary Element of Flexure-Governed RC Slender Shear Walls Based on Displacement Ductility Ratio (휨 항복형 철근콘크리트 전단벽의 경계요소설계를 위한 변위연성비 모델제시)

  • Mun, Ju-Hyun;Yang, Keun-Hyeok
    • Journal of the Korea Concrete Institute
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    • v.26 no.6
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    • pp.687-694
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    • 2014
  • This study established a displacement ductility ratio model for ductile design for the boundary element of shear walls. To determine the curvature distribution along the member length and displacement at the free end of the member, the distributions of strains and internal forces along the shear wall section depth were idealized based on the Bernoulli's principle, strain compatibility condition, and equilibrium condition of forces. The confinement effect at the boundary element, provided by transverse reinforcement, was calculated using the stress-strain relationship of confined concrete proposed by Razvi and Saatcioglu. The curvatures corresponding to the initial yielding moment and 80% of the ultimate state after the peak strength were then conversed into displacement values based on the concept of equivalent hinge length. The derived displacement ductility ratio model was simplified by the regression approach using the comprehensive analytical data obtained from the parametric study. The proposed model is in good agreement with test results, indicating that the mean and standard deviation of the ratios between predictions and experiments are 1.05 and 0.19, respectively. Overall, the proposed model is expected to be available for determining the transverse reinforcement ratio at the boundary element for a targeted displacement ductility ratio.