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Conduction Mechanism for PAP and Comparison of Physical Properties of PAP with other Polyaniline-based Conducting Polymers

  • Choi, Kyung-Moon;Lee, Eun-Ju;Kim, Keu-Hong
    • Bulletin of the Korean Chemical Society
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    • v.11 no.5
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    • pp.371-376
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    • 1990
  • Polyaniline perchlorate (PAP) was synthesized by the chemical oxidation of aniline using ferric perchlorate as a strong oxidant. The electrical conductivity of PAP was measured at temperatures from - 170 to 25$^{\circ}C$. It is suggested from the conductivity measurements that the conduction mechanism for PAP is a polaron hopping conduction. From the dependence of resistivity on the reciprocal temperature, the activation energy was computed to be 0.072 eV. From the comparison of the ESR parameterks and conductivity at 25$^{\circ}C$ for the polyaniline-based conducting polymers, the conductivities of PAP, PATFB and PATS increase with increasing ${\Delta}H_{pp}$, decreasing A/B ratio and decreasing g-value, respectively. It is shown by TGA results for PAP, PATFB and PATS that the maximum weight loss rates (Pr) are 0.185 (at 269$^{\circ}C$ ), 0.366 (at 324$^{\circ}C$) and 0.23 mg/min (at 338$^{\circ}C$), respectively.

Interdiffusion at Interfaces of polymers with Similar Physical Properties

  • Kim, Un Cheon;Lee, Chang Jun;Sim, Hun Gu;Park, Hyeong Suk
    • Bulletin of the Korean Chemical Society
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    • v.21 no.6
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    • pp.577-582
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    • 2000
  • Interdiffusion process at interfaces of chemically identical polymers (e.g., deuterated-nondeuterated pairs) with different molecular weights or polymers with similar physical properties, is studied here by varying the diffusion time. Considering the vacancy flux ($J_v$) and adopting the Cahn-Hilliard interracial energy in describing this system, we can see that the variation of the interfacial composition profile with time is asymetric and the interface moves towards the polymer with the lower molecular weight as interdiffusion progresses. Furthermore, interface shift $\Delta\chi$, which characterizes the interdiffusion between polymers, agrees well with the behaviors of the existing experimental data. We can also obtain the interface shift factor C, which can be converted into values of $D_s$ (self-diffusion coefficient of the smaller molecules), from the slopes of the linear fits to the data of the interface shift.

EVOLUTION AND MONOTONICITY FOR A CLASS OF QUANTITIES ALONG THE RICCI-BOURGUIGNON FLOW

  • Daneshvar, Farzad;Razavi, Asadollah
    • Journal of the Korean Mathematical Society
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    • v.56 no.6
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    • pp.1441-1461
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    • 2019
  • In this paper we consider the monotonicity of the lowest constant ${\lambda}_a^b(g)$ under the Ricci-Bourguignon flow and the normalized Ricci-Bourguignon flow such that the equation $$-{\Delta}u+au\;{\log}\;u+bRu={\lambda}_a^b(g)u$$ with ${\int}_{M}u^2dV=1$, has positive solutions, where a and b are two real constants. We also construct various monotonic quantities under the Ricci-Bourguignon flow and the normalized Ricci-Bourguignon flow. Moreover, we prove that a compact steady breather which evolves under the Ricci-Bourguignon flow should be Ricci-flat.

Effects of Heat Treatment on Surface Properties of Aluminum 6061 Alloy After Anodization (알루미늄 6061 합금 양극산화 후 열처리에 따른 표면 특성 관찰)

  • Seungmin, Lee;Chanyoung, Jeong
    • Corrosion Science and Technology
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    • v.21 no.6
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    • pp.495-502
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    • 2022
  • Anodization is a representative electrochemical surface treatment method that can improve both heat resistance and corrosion resistance by forming an anodization film on the surface of the aluminum. However, these properties can be changed after an additional heat treatment process. In this study, Al 6061 was subjected to an anodization process at 60 V for 1 hour, 5 hours, or 9 hours. An additional heat treatment process was performed at 500 ℃ for 30 minutes. Field emission scanning electron microscopy (FE-SEM) analysis revealed that the thickness of the anodized film was increased in proportion to the anodization time. Both pore size and pore diameter of the anodized film was also increased after anodization. After an additional heat treatment process, there were no significant changes in the thickness, pore size, or pore diameter of the anodized film. Heat resistance was confirmed through thermal analysis and chemical resistance was evaluated with a potentiodynamic polarization test.

Above bandgap optical properties of ZnS grown by hot-wall epitaxy

  • Lee, M.S.;Koo, M.S.;Kim, T.J.;Kim, Y.D.;Yoo, Y.M.;O, B.;Choi, Y.D.
    • Journal of Korean Vacuum Science & Technology
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    • v.3 no.2
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    • pp.112-115
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    • 1999
  • The real ($\varepsilon$1) and imaginary ($\varepsilon$2) parts of the dielectric function of ZnS have been measured by spectroscopic ellipsometry (SE) in the 3.7-6.0 eV photon-energy range at room temperature. The obtained dielectric function spectra reveal distinct structures at energies E0/(E0+$\Delta$0) and E1 critical points. The spectrum after chemical treatment to remove surface oxide overlayer showed that these data seem to be the best representation of the dielectric function of ZnS, having the largest $\varepsilon$2 value at E1 peak region reported so far by SE. Dielectric-related optical constants of ZnS, such as the complex refractive indices (n+n=ik), absorption coefficient, and reflectance, are also presented.

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The Geometry of 𝛿-Ricci-Yamabe Almost Solitons on Paracontact Metric Manifolds

  • Somnath Mondal;Santu Dey;Young Jin Suh;Arindam Bhattacharyya
    • Kyungpook Mathematical Journal
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    • v.63 no.4
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    • pp.623-638
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    • 2023
  • In this article we study a 𝛿-Ricci-Yamabe almost soliton within the framework of paracontact metric manifolds. In particular we study 𝛿-Ricci-Yamabe almost soliton and gradient 𝛿-Ricci-Yamabe almost soliton on K-paracontact and para-Sasakian manifolds. We prove that if a K-paracontact metric g represents a 𝛿-Ricci-Yamabe almost soliton with the non-zero potential vector field V parallel to 𝜉, then g is Einstein with Einstein constant -2n. We also show that there are no para-Sasakian manifolds that admit a gradient 𝛿-Ricci-Yamabe almost soliton. We demonstrate a 𝛿-Ricci-Yamabe almost soliton on a (𝜅, 𝜇)-paracontact manifold.

CONVERGENCE THEOREMS FOR GENERALIZED α-NONEXPANSIVE MAPPINGS IN UNIFORMLY HYPERBOLIC SPACES

  • J. K. Kim;Samir Dashputre;Padmavati;Rashmi Verma
    • Nonlinear Functional Analysis and Applications
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    • v.29 no.1
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    • pp.1-14
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    • 2024
  • In this paper, we establish strong and ∆-convergence theorems for new iteration process namely S-R iteration process for a generalized α-nonexpansive mappings in a uniformly convex hyperbolic space and also we show that our iteration process is faster than other iteration processes appear in the current literature's. Our results extend the corresponding results of Ullah et al. [5], Imdad et al. [16] in the setting of uniformly convex hyperbolic spaces and many more in this direction.

ON FUZZY 𝛽-VOLTERRA SPACES

  • V. CHANDIRAN;S. SOUNDARA RAJAN;G. THANGARAJ
    • Journal of applied mathematics & informatics
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    • v.42 no.1
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    • pp.189-197
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    • 2024
  • The purpose of this paper is to introduce and study the new class of spaces called the fuzzy 𝛽-Volterra spaces with the help of fuzzy β-dense and fuzzy 𝛽-G𝛿 sets. Examples are given to illustrate the concept. Some interesting characterizations of the fuzzy 𝛽-Volterra spaces are established in this paper.

A Study on the Magnetic Properties of YIG Ferrites with Zr-Substitution (Zr치환에 따른 YIG계 페라이트의 자기적 특성 연구)

  • 양승진;윤종남;김정식
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.428-433
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    • 2003
  • In this study, we investigated the variation of microstructural and electromagnetic properties of YIG ferrites for Isolator/Circulator application with the sintering temperature and Zr addition. The composition of the ferrites was Y$_{2.1}$Ca$_{0.9}$Fe$_{4.4-x}$V$_{0.5}$In$_{0.05}$Al$_{0.05}$Zr$_{x}$O$_{12}$ with x=0, 0.05, 0.1 and 0.2. The YIG ferrites were prepared by the conventional ceramic sintering process. The Zr-substituted YIG ferrite, Y$_{2.1}$ Ca$_{0.9}$Fe$_{4.4-x}$V$_{0.5}$In$_{0.05}$Al$_{0.05}$ Zr$_{x}$O$_{12}$ showed the highest saturation magnetization (1097 gauss) at x=0.1. The microwave properties were shown as isolation of 18.60 dB and insertion loss of 0.45 dB at x=0.2. Additionally, Zr-substitution was effective in decreasing ferromagnetic resonance linewidth with Zr content.

VARIABLE STARS IN THE REGION OF CYG OB3 ASSOCIATION CENTERED ON THE OPEN CLUSTER NGC 6871 II (산개성단 NGC 6871을 중심으로 한 Cyg OB3 성협 영역의 변광성 II)

  • Jeon, Young-Beom;Park, Yoon-Ho;Lee, UiRyeol;Kim, DongHyeon;Jang, Hyeeun;Cho, SungYoon
    • Publications of The Korean Astronomical Society
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    • v.28 no.3
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    • pp.83-93
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    • 2013
  • This is the second paper on a systematic search for variable stars in Cyg OB3 region. In this paper we present the observational properties of 46 variable stars found in the region. Among them, 27 are eclipsing binaries and others are semi-long periodic or slow irregular variables. Only 5 are known variables and the rest are newly discovered ones. We have obtained the period and amplitude of 20 eclipsing binaries using the phase fitting method, and present the light curves of 46 variable stars.