• 제목/요약/키워드: degraded material

검색결과 368건 처리시간 0.026초

Pt/LiNbO3/AlN/Si(100) 구조를 이용한 MFIS 커패시터의 전기적 특성 (Electric Properties of MFIS Capacitors using Pt/LiNbO3/AlN/Si(100) Structure)

  • 정순원;김광호
    • 한국전기전자재료학회논문지
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    • 제17권12호
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    • pp.1283-1288
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    • 2004
  • Metal-ferroelectric-insulator-semiconductor(WFIS) capacitors using rapid thermal annealed LiNbO$_3$/AlN/Si(100) structure were fabricated and demonstrated nonvolatile memory operations. The capacitors on highly doped Si wafer showed hysteresis behavior like a butterfly shape due to the ferroelectric nature of the LiNbO$_3$ films. The typical dielectric constant value of LiNbO$_3$ film in the MFIS device was about 27, The gate leakage current density of the MFIS capacitor was 10$^{-9}$ A/cm$^2$ order at the electric field of 500 kV/cm. The typical measured remnant polarization(2P$_{r}$) and coercive filed(Ec) values were about 1.2 $\mu$C/cm$^2$ and 120 kV/cm, respectively The ferroelectric capacitors showed no polarization degradation up to 10$^{11}$ switching cycles when subjected to symmetric bipolar voltage pulses of 1 MHz. The switching charges degraded only by 10 % of their initial values after 4 days at room temperature.e.

Microstructure, Mechanical and Wear Properties of Hot-pressed $Si_3N_4-TiC$ Composites

  • Hyun Jin Kim;Soo Whon Lee;Tadachika Nakayama;Koichi Niihara
    • The Korean Journal of Ceramics
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    • 제5권4호
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    • pp.317-323
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    • 1999
  • Si3N4-TiC composites have been known as electrically conductive ceramics. $Si_3N_4-TiC$ composites with 2 wt% $Al_2O_3$ and 4 wt% $Y_2O_3$ were hot pressed in $N_2$ environment. The mechanical properties including hardness, fracture toughness, and flexural strength and tribological properties were investigated as a function of TiC content. $Si_3N_4-40$ vol% TiC composite was hot pressed at $1,750^{\circ}C$, $1,800^{\circ}C$, and $1,850^{\circ}C$ for 1, 3 and 5 hours in $N_2$ gas. Mechanical and tribolgical properties depended on microstructures, which were controlled by hte TiC content, hot press temperature, and hot press holding time. However, mechanical properties and tribological behaviors were degraded by the chemical reaction between TiC and N. The chemically reacted products such as TiCN, SiC, and $SiO_2$ were detered by the X-ray diffraction analysis.

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부스닥트용 내열성 에폭시 분체도료의 절연 및 열화 특성 연구 (A Study on the Insulation and Electrical Degradation Properties of Heat Resistance Epoxy Powder for Busduct)

  • 강철화;박지군;박종규;주현돈;김현희
    • 한국전기전자재료학회논문지
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    • 제26권9호
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    • pp.662-668
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    • 2013
  • Reported here are results of the mechanical and electrical properties of both of intact and thermally degraded epoxy-coated copper busducts that are made by fluidized bed process. To elucidate and compare the properties mentioned above, electrical breakdown by thermal and water aging, v-t characteristic, bending test, impact test and cross cut test are carried out. Although the performance of electrical and mechanical properties are gradually decreased in increasing the severe conditions such as temperature, aging time, and so forth, sample C has a better performance in both mechanical and electrical properties.

Spherical Indentation Testing에 의한 1Cr-1Mo-0.25V 강의 기계적 물성 평가 (Spherical Indentation Testing to Evaluate Mechanical Properties In 1Cr-1Mo-0.25V Steel)

  • 이종민;남영현;남승훈;이승석;이억섭
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집A
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    • pp.266-271
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    • 2001
  • Spherical indentation technique was developed to evaluate the flow properties of metallic materials in carbon steel, stainless steel and alloys, etc. Through the spherical indentation test, differently degraded 1Cr-1Mo-0.25V steel's mechanical properties were observed and compared with conventional standard test data. The flow properties of 1Cr-1Mo-0.25V steels were estimated by analyzing the indentation load-depth curve. To characterize the flow property, we used material yield slope and constraint factor index rather than strain-hardening exponent because the variation of strain-hardening exponent was very little and the data showed irregularly. And the constraint factor's effect was small when the material yield slope was taken into account.

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슈퍼 오스테나이트 스테인리스강의 열화손상에 대한 비파괴적 평가 (An Nondestructive Evaluation of Degraded Damage for Superaustenitic Stainless Steel)

  • 권일현;백승세;;유효선
    • 대한기계학회논문집A
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    • 제26권7호
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    • pp.1332-1339
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    • 2002
  • This research was undertaken to clarify effects of thermal aging on electrochemical and mechanical properties of superaustenitic stainless steel and to detect the material degradation nondestructively. The steel was artificially aged at $300{\sim}650^{\circ}C$ for $240{\sim}10,000h$ and the mechanical properties were investigated at $-196{\sim}650^{\circ}C$ using small punch(SP) test. Also, the change in electrochemical properties caused by effects of thermal aging on superaustenitic stainless steel was investigated using electrochemical anodic polarization test in a KOH electrolyte. Carbides and ${\eta}-phase(Fe_2Mo)$ precipitated in the grain boundaries seem to deteriorate the mechanical properties by decreasing cohesive strength in the grain boundaries and to promote the current density observed in electrochemical polarization curves, The electrochemical and mechanical properties of superaustenitic stainless steel decreased significantly in the specimen aged at $650^{\circ}C$ corresponding to the sensitization temperature for conventional austenitic stainless steels.

실리콘을 이용한 수트리 열화된 전력 케이블의 절연 보강 (Insulation Reinforcement of the Electrical Power Cable Degradated by the Water Tree Using Silicon)

  • 강형곤;박준채;고석철;임성훈;이종화;한윤봉;한병성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
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    • pp.468-471
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    • 2003
  • Fault of under ground power cable occurs usually from the water tree such as the vented tree, the bow tree and the water-rich halo. The water tree penetrates to the polyethylene cable insulations. Sometimes, the water tree also diffuses to mother cable in the substation. In this paper, instead of replacement of the faulty cable, we tried to cure an electrical power cable degraded by the water trees with silicon injection method. And measured the results with the isothermal relaxation current analysis method. After cable cure, Chonil line was improved from 2.27 to 1.96 in a phase, from 2.148 to 2.020 in b phase, and from badness to 2.192 in c phase. And Keumam line was also improved from 2.419 to 1.920 in a phase, from 2.301 to 2.000 in b phase, and from badness to 1.957 in c phase.

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수용액에 용출된 에폭시수지 화합물의 TiO$_2$ 광분해효과와 생물독성에 미치는 영향 (Effects of TiO$_2$ Photodegradation on Leaching from Epoxy Resin Chemical in Water and Biological Toxicity)

  • 여민경;조은정
    • Environmental Analysis Health and Toxicology
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    • 제19권3호
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    • pp.271-278
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    • 2004
  • Epoxy resins are mostly used as a molding material for drinking water tank. Bisphenol A is used at a constituent material for epoxy resins and is widely suspected to act as an endocrine disrupter. In this study, we investigated embryo hatching in zebrafish reared in water undergone leaching process of expoxy resin, and found a decreased survival rate. Bisphenol A eluted from epoxy resin in drinking water tank was completely degraded by TiO$_2$ photocatalysis. We detected 7.8 ng/ml of bisphenol A in epoxy resin tank, and observed that the concentration was undetectable after 48h photocatalysis over TiO$_2$. There was no toxicity in hatching rates in zebrafish and morphogenesis after photocatalysis. The effect of TiO$_2$ photocatalytic reactions on the catalase activities in the f]y stage of zebrafish was also examined. At 1 week post hatching, cataiase activities were higher both in the group of epoxy resin with 48 h TiO$_2$ photocatalysis and in the TiO$_2$ photocatalysis for 48 hours were higher than control group. However catalase activities of the treatment group of epoxy resin by TiO$_2$ photocatalysis for 48 hours were similar to control in 5 weeks post hatching fries. In conclusion, the toxicity of TiO$_2$ photocatalysis was not observed in this zebrafish.

열발광 특성을 이용한 저밀도 폴리에틸렌의 방사선 열화 검출 (Radiation Degradation Detection of LDPE Using Thermoluminescence Method)

  • 이청;이강원;박정남;임기조;류부형;박영국;강성화;김기엽
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 연구회
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    • pp.43-46
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    • 2001
  • Polymers are widely used as insulating materials at various part of power industry. However, electrical properties of these polymers are easily degraded with their working environments, especially radiation areas. In this research, radiation degradation of low density polyethylene (LDPE) used as cable insulation was evaluated with thermoluminescence characteristics. LDPE was irradiated with gamma ray up to 1000 kGy at a dose rate of 5 kGy/hr in the presence of air at room temperature. Each of the irradiated samples were carried out thermoluminescence analysis as a function of temperature. Interrelationships between thermoluminescence and dielectric characteristics and volume resistivity are investigated as well. The results of thermoluminescence analysis showed that those would be significant factors for evaluation of radiation degradation.

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Spin coating 공정을 이용한 Polymethyl methacrylate (PMMA) 박막의 polymer gate dielectric layer로써의 특성평가 (Properties of Polymethyl methacrylate (PMMA) for Polymer Gate Dielectric Thin Films Prepared by Spin Coating)

  • 나문경;강동필;안명상;명인혜;강영택
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 춘계학술대회 논문집
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    • pp.29-32
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    • 2005
  • Poly (methyl methacrylate) (PMMA) is one of the promising representive of polymer gate dielectric for its high resistivity and sutible dielectric constant. PMMA (Mw=96700) films were prepared on p-Si by spin coating method. PMMA were coated compactively and flatly as observeed by AFM. MIS(Al/PMMA/p-Si) structure was made and capacitance-voltage (C-V) and current-voltage (I-V) measurements were done with PMMA films for different thermal treatment temperature. PMMA films were showed proper dielectric constant and breakdown voltage. Above the glass transition temperature PMMA films degraded. C-V measured at various frequencies, dielectric constant increased a little. The absence of hysteresis in the C-V characteristics, which eliminate the possibility of mobile charges in the PMMA films. The observed thermal stability, smooth surfaces, dielectric constant, I-V behavior implies PMMA formed by spin coating can be used as an efficient gate dielectric layer in OTFTs.

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Bi-2223/Ag 고온초전도 선재의 전처리에 따른 가공성 및 초전도 특성 (The effect of pre-treatment on superconducting property and deformation of Bi-2223/Ag tapes.)

  • 하홍수;이동훈;최정규;황선역;양주생;김상철;하동우;오상수;권영길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 초전도 자성체 연구회
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    • pp.25-29
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    • 2003
  • Pre-treatment of Bi-2223/Ag tapes has been investigated to improve the superconducting property and grain alignment. However, rolling deformability of Bi-2223/Ag wires was degraded by the breakage of Ag alloy sheath after pre-treatment. Various pre-treatment conditions were tried to prevent the problem of sliver sheath and improve the superconducting property of Bi-2223/Ag tapes. Filament precursor of Bi-2223/Ag tapes was modified to be textured easily during main sintering by the optimum pre-treatment with low oxygen pressure and up to $800^{\circ}C$. Critical current was also increased up to 20% than that of no pre-treated tape.

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