• 제목/요약/키워드: degraded Material

검색결과 368건 처리시간 0.028초

결정입계 처리에 따른 다결정 실리콘 태양전지의 효율 향상 (Efficiency Improvement of Polycrystalline Silicon Solar Cells using a Grain boundary treatment)

  • 김상수;김재문;임동건;김광호;원충연;이준신
    • E2M - 전기 전자와 첨단 소재
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    • 제10권10호
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    • pp.1034-1040
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    • 1997
  • A solar cell conversion effiency was degraded by grain boundary effect in polycrystalline silicon. Grain boundaries acted as potential barriers as well as recombination centers for the photo-generated carriers. To reduce these effects of the grain boundaries we investigated various influencing factors such as emitter thickness thermal treatment preferential chemical etching of grain boundaries grid design contact metal and top metallization along boundaries. Pretreatment in $N_2$atmosphere and gettering by POCl$_3$and Al were performed to obtain multicrystalline silicon of the reduced defect density. Structural electrical and optical properties of slar cells were characterized before and after each fabrication process. Improved conversion efficiencies of solar cell were obtained by a combination of pretreatment above 90$0^{\circ}C$ emitter layer of 0.43${\mu}{\textrm}{m}$ Al diffusion in to grain boundaries on rear side fine grid finger top Yb metal and buried contact metallization along grain boundaries.

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Effect of Room Temperature Ionic Liquids Adsorption on Electromechanical Behavior of Cellulose Electro-Active Paper

  • Mahadeva, Suresha K.;Yi, Chen;Kim, Jae-Hwan
    • Macromolecular Research
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    • 제17권2호
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    • pp.116-120
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    • 2009
  • The cellulose smart material called electro-active paper (EAPap) is made by regenerating cellulose. However, the actuator performance is degraded at low humidity levels. To solve this drawback, EAPap bending actuators were made by activating wet cellulose films in three different room-temperature ionic liquids: l-butyl-3-methylimidazolium hexaflurophosphate ($BMIPF_6$), 1-butyl-3-methylimidazolium chloride (BMICL) and 1-butyl-3-methylimidazolium tetrafluroborate ($BMIBF_4$). In the results, the actuator performance was dependent on the type of anions in the ionic liquids, in the order of $BF_4$>Cl>$PF_6$. The BMIBF 4-activated actuator showed the maximum displacement of 3.8 mm with low electrical power consumption at relatively low humidity. However, the BMICL-activated actuator showed a slight degradation of actuator performance. Further performance and durability improvement will be possible once various ionic liquids are blended with cellulose.

Structural Control Aiming for High-performance SiC Polycrystalline Fiber

  • Ishikawa, Toshihiro;Oda, Hiroshi
    • 한국세라믹학회지
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    • 제53권6호
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    • pp.615-621
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    • 2016
  • SiC-polycrystalline fiber (Tyranno SA, Ube Industries, Ltd.) shows very high heat-resistance and excellent mechanical properties up to very high temperatures. However, further increase in the strength is required. Up to now, we have already clarified the relationship between the strength and the defect-size of the SiC-polycrystalline fiber. The defects are formed during the conversion process from the raw material (amorphous Si-Al-C-O fiber) into SiC-polycrystalline fiber. In this conversion process, a degradation of the Si-Al-C-O fiber and a subsequent sintering of the degraded fiber proceed as well, accompanied by a release of CO gas and compositional changes, to obtain the dense SiC-polycrystalline fiber. Since these changes proceed in each filament, the strict control should be needed to minimize residual defects on the surface and in the inside of each filament for achieving the higher strength. In this paper, the controlling factors of the fiber strength and the fine structure will appear.

용융탄산엽형 연로전지에 있어서 새로운 형태의매니폴드케이싱에 의한 전해질 펌핑 방지에 관한 연구 (Prevention of the Electrolyte Pumping in the Molten Carbonate Fuel Cell by Means of the Improved Manifoldcasing)

  • 박상길;노창주
    • 대한전기학회논문지
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    • 제41권1호
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    • pp.95-106
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    • 1992
  • For commercial application of the MCFC, the life time of the MCFC should exceed 40,000 hours, But the life time of the state-of-the-art MCFC was limited to 15,000 hours. The main reasons of the life time limit can be classified as the deficiency of the electrolyte and cathode dissolution. It has been found that the electrolyte deficiency is caused by the continuous evaporation of the electrolyte. However a recent reaserch shows that an electrolyte pumping phenomenon, which implies, the migration of the electrolyte through the gasket material of the external gas manifold, is also the reason of the electrolyte deficiency. Due to the electrolyte pumping phenomenon, positive end cell of the stack suffers the electrolyte deficiency and negative end cell of stack is flooded with electrolyte. Therefore, the cell performance is degraded. The author invented a new manifoldcasing, which prevents the contact between the wet seal and the gasket of the manifold, and gives a complete elimination of an electrolyte pumping effect.

BLT 박막의 CMP 공정시 압력에 따른 Surface Morphology 및 Defects 특성 (Characteristics of Surface Morphology and Defects by Polishing Pressure in CMP of BLT Films)

  • 정판검;이우선
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.101-102
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    • 2006
  • PZT thin films, which are the representative ferroelectric materials in ferroelectric random access memory (FRAM), have some serious problem such as the imprint, retention and fatigue which ferroelectric properties are degraded by repetitive polarization. BL T thin film capacitors were fabricated by plasma etching, however, the plasma etching of BLT thin film was known to be very difficult. In our previous study, the ferroelectric materials such as PZT and BLT were patterned by chemical mechanical polishing (CMP) using damascene process to top electrode/ferroelectric material/bottom electrode. It is also possible to pattern the BLT thin film capacitors by CMP, however, the CMP damage was not considered in the experiments. The properties of BLT thin films were changed by the change of polishing pressure although the removal rate was directly proportional to the polishing pressure in CMP process.

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화력발전설비 진단기술 및 전문가 시스템개발에 관한 연구 (A study on the developing the diagnosis technology and expert system in fossil power plant)

  • 백영민;정희돈;신은주
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2008년도 동계학술발표대회 논문집
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    • pp.642-648
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    • 2008
  • In order to analyze the causes of fossil power plant facilities due to a degradation and corrosion, artificial degraded materials composed of the facilities were manufactured. Various experiment were performed based on mechanical test, microstructure observation, hardness test, electrochemical potentiokinetic reactivation test(EPR) and corrosion scale thickness measurement test. The master curves were write out using Larson-Miller parameter to evaluate the degree of degradation with the above diagnosis methods. These data were applied to materials database of fossil power plant diagnosis. Finally expert system on the fossil power plant diagnosis was developed using the master curves and diagnosis algorithms.

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알루미늄 호일의 친수코팅 성능 개선에 관한 실험적 연구 (Experimental study on the hydrophilic performance of pre-coated aluminum foil)

  • 김영생;길용현;박환영;윤백;김자수소;김병열
    • 설비공학논문집
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    • 제11권6호
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    • pp.725-732
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    • 1999
  • It is usual to use hydrophilic-coated aluminum foil for evaporator fin of air-conditioners to reduce air flow resistance caused by the water droplets condensed on the fin surface. The major effect of a hydrophilic coating is to reduce the contact angle of the condensate and prevent bridging of the condensate between the adjacent fins. The performance of hydrophilic coating generally tends to be degraded as it is used since the coating material is washed down by the condensate. In the present work, several types of hydrophilic coatings were evaluated in terms of durability of hydrophilicity, corrosion resistance and heat resistance. Results showed that an improved hydrophilic coating of resin type presented superb qualify in terms of durability and corrosion resistance while having almost the same level of qualify in heat resistance compared with the others.

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A Stress Analysis Method for the Rotor Design of an IPMSM Considering Radial Force

  • Kim, Won-Ho
    • Journal of Electrical Engineering and Technology
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    • 제9권3호
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    • pp.888-892
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    • 2014
  • In the design of the rotor of an interior permanent magnet synchronous motor (IPMSM), the bridge between the permanent magnets helps prevent the scattering of permanent magnets and pole pieces during high-speed operation. In the design of a motor, if the bridge is too thick, its performance will be largely degraded because of flux leakage. Additionally, if the bridge is too thin, its mechanical safety cannot be guaranteed. Thus, an accurate analysis method is required to determine the thickness of the bridge. Conventional stress analysis methods determine the thickness of the bridge by only considering the centrifugal force of the rotors. In this study, however, a method that additionally considers the radial force generated by the air-gap flux density based on the conventional methods is proposed and reflected in the design of a traction motor for electric vehicles. Finally, the validity of this study is verified through a reliability test related to high-speed operation.

Cause Analysis for a Lining Damage in Sea Water System Piping Installed in a Korean Industrial Plant

  • Hwang, K.M.;Park, S.K.
    • Corrosion Science and Technology
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    • 제20권1호
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    • pp.1-6
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    • 2021
  • Many Korean industrial plants including nuclear and fossil power plants use seawater as the ultimate heat sink to cool the heat generated by various facilities. Owing to the high corrosivity of seawater, facilities and piping made of metal material in contact with seawater are coated or lined with polymeric materials to avoid direct contact with seawater. However, polymeric materials used as coating and lining have some level of permeability to water and are degraded over time. Korean industrial plants have also experienced a gradual increase in the frequency of damage to pipes in seawater systems due to prolonged operating periods. In the event of a cavitation-like phenomenon, coating or lining inside the piping is likely to be damaged faster than expected. In this paper, the cause of water leakage due to base metal damage caused by the failure of the polyester lining in seawater system piping was assessed and the experience with establishing countermeasures to prevent such damage was described.

이종금속 용접부의 경도변화에 대한 장시간 인공열화의 영향 (Effects of Long-term Artificial-Aging on the Hardness Variation of Dissimilar Metal Weldments)

  • 김정석
    • 한국기계가공학회지
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    • 제18권1호
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    • pp.31-37
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    • 2019
  • This study investigates the effects of long-term artificial-aging on hardness variation in the dissimilar metal weldments for nuclear power plant facilities. These dissimilar welds are inevitably required to join the components in nozzle parts of pressurized vessels, such as austenitic stainless steels and ferritic steels. A artificial thermal aging was conducted in an electrical furnace to simulate material degradation at high temperatures. The test materials were held at the temperature of $600^{\circ}C$ for 10000 hours and interrupted at various levels of degraded specimens. The degradation of hardness is a well-known phenomenon resulting from long-term aging or high-temperature degradation of structural materials. In this study, the variation of hardness at each position was different, and complicated in relation to microstructures such as twins, grains, precipitates, phase transformations, and residual stresses in dissimilar weldments. We discussed the variation of hardness in terms of microstructural changes during long-term aging.