• 제목/요약/키워드: degradation test

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Development of Moisture Content Prediction Model for Larix kaempferi Sawdust Using Near Infrared Spectroscopy (근적외선 분광분석법을 이용한 낙엽송 목분의 함수율 예측 모델 개발)

  • Chang, Yoon-Seong;Yang, Sang-Yun;Chung, Hyunwoo;Kang, Kyu-Young;Choi, Joon-Weon;Choi, In-Gyu;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • 제43권3호
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    • pp.304-310
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    • 2015
  • The moisture content of sawdust must be measured accurately and controlled appropriately during storage and transportation because biological degradation could be caused by improper moisture. In this study, to measure the moisture contents of Larix kaempferi sawdust, the near-infrared reflectance spectra (Wavelength 1000-2400 nm) of sawdust were used as detection parameter. After acquiring the NIR reflection spectrum of specimens which were humidified at each relative humidity condition ($25^{\circ}C$, RH 30~99%), moisture content prediction model was developed using mathematical preprocessings (e.g. smoothing, standard normal variate) and partial least squares (PLS) analysis with the acquired spectrum data. High reliability of the MC regression model with NIR spectroscopy was verified by cross validation test ($R^2$ = 0.94, RMSEP = 1.544). The results of this study show that NIR spectroscopy could be used as a convenient and accurate method for the nondestructive determination of moisture content of sawdust, which could lead to optimize wood utilization.

A Study on the Disintegration of Sewage Sludge using Batch Ultrasonic Pretreatment (회분식 초음파 전처리를 이용한 하수슬러지의 분해에 관한 연구)

  • Ko, Hyun-Woong;Jung, Byung-Gil;Jung, Yon-Hwa;Kim, Hyeung-Seok;Jang, Seong-Ho;Sung, Nak-Chang
    • Journal of the Korea Organic Resources Recycling Association
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    • 제12권4호
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    • pp.121-129
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    • 2004
  • Anaerobic digestion is the most common process for sewage sludge stabilization and has benefits of VS reduction and biogas production. Many pretreatment methods have been studied to improve hydrolysis rate because the rate of sewage sludge degradation is slow in anaerobic digestion. This study mainly focused upon the effects on disintegration of sewage sludge by ultrasonic pretreatment according to the variation of acoustic density and duration of sonication time. In this study, acoustic density has been changed as follows : 33W/L, 70W/L, 88W/L, 139W/L in case of 40 kHz with the test time changes of 10min, 20min, 25min, 30min and 40min. In the comparison of $SCOD_{Cr}/TCOD_{Cr}$ variation for excess sludge and mixed sludge disintegration, the rates of $SCOD_{Cr}/TCOD_{Cr}$ have been increased in the condition of denser acoustic density and longer sonication time with acoustic frequency of 40kHz. The pH of the excess sewage sludge and mixed sewage sludge has been decreased in the condition of denser acoustic density and longer sonication time with acoustic frequency of 40kHz.

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Optimization Design in Time Domain on Impulse GPIR System (임펄스 GPIR시스템의 시간영역 최적화 설계)

  • Kim, Kwan-Ho;Park, Young-Jin;Yoon, Young-Joong
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • 제46권3호
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    • pp.32-39
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    • 2009
  • In this paper, system optimization design technique of an impulse ground penetrating image radar (GPIR) in time domain is proposed to improve depth resolution of the system. For the purpose, time domain analysis method of key components such as impulse generator and UWB antenna is explained and by simulation, parameters of each component are determined. In particular, by standardizing the impulse signal, spectrum efficiency of a radiated impulse signal is improved and a U-shaped planar dipole antenna for a UWB antenna is developed. By equipping a parabolic metal reflector with the proposed antenna, external noise is prevented and the ability of radiating an input impulse into ground is improved. In addition, to remove ringing effect of the propose antenna which causes serious degradation of the system performance, resistors are loaded at the edge of the antenna and then Tx and Rx UWB antennas are optimized by simulation in time domain. For images of targets buried under the ground migration technique is applied and influence of tough ground surface on distortion of received impulse signals is reduced using technique of noise and signal distortion reduction in time domain and its time resolution is enhanced. To verify the design optimization procedure, a prototype of an GPIR and an artificial test field are made. Measurement results show that the resolution of the system designed is as good as that of a theoretical model.

Study on the Application for Hydrogen Storage Tank of MmNi4.5Mn0.5Zrx(x=0, 0.025, 0.05, 0.1) Alloys Containing Excess Zr (과잉 Zr을 첨가한 MmNi4.5Mn0.5Zrx(x=0, 0.025, 0.05, 0.1) 합금의 수소용기 적용에 관한 연구)

  • Kang, Kil-Ku;Park, Sung-Gap;Kang, Sei-Sun;Kwon, Ho-Young
    • Korean Journal of Materials Research
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    • 제12권8호
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    • pp.624-633
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    • 2002
  • In order to improve the hydrogen storage capacity and the activation properties of the hydrogen storage alloys, the rare-earth metal alloy series, MmN $i_{4.5}$M $n_{0.5}$Z $r_{x}$(x=0, 0.025, 0.05, 0.1), are prepared by adding excess Zr in MmN $i_{4.5}$M $n_{0.5}$ alloy. The various parts in hydrogen storage vessel consisted of copper pipes reached the setting temperature within 4~5 minutes after heat addition, which indicated that storage vessel had a good heat conductivity required in application. The performance test on storage vessel filled with rare-earth metal alloys of 1000 gr was also conducted after hydrogen charging for 10 min at $18^{\circ}C$ under 10 atm. It showed that the average capacity of discharged hydrogen volume was found to be for $MmNi_{4.5}$ $Mn_{0.5}$ and $MmNi_{4.5}$ $Mn_{x}$ 0.5/$Zr_{samples}$ indicated that the released amount of hydrogen for this $AB_{5}$ type alloys was more than 92 % of theoretic value, and also it was found that the optimum discharging temperature for obtaining an appropriate pressure of 3 atm was determined to be $V^{\circ}C$ for $MmNi_{4.5}$ $Mn_{0.5}$$Zr_{x}$(x=0, 0.025, 0.05, 0.1) hydrogen storage alloys. The released amount of these hydrogen storage samples was 125 $\ell$ , 122.4 $\ell$ and 108.15 $\ell$/kg for $MmNi_{4.5}$ $Mn_{0.5}$ $Zr_{0.025}$ $MmNi_{4.5}$M $n_{0.5}$Z $r_{0.05}$, and MmN $i_{4.5}$ Mn_0.5$Zr_{0}$, at $70^{\circ}C$ respectively. Amount of the 2nd phases increase with increase on Zr contents in $MmNi_{4.5}$$Mn_{0.5}$ $Zr_{ 0.1}$/ alloy. This phenomenon indicates that$ ZrNi_3$ in $MmNi_{4.5}$ $Mn_{0.5}$ $Zr_{x}$ / phase, which shows the maximum storage capacity and the strong resistance to intrinsic degradation, is considered as a proper alloy for hydrogen storage. As the Zr contents increase, the activation time and the plateau pressure decreases and sloping of the plateau pressure increases.creases.eases.s.

Comparison of Behavior of Connections between Modular Units according to Shape of Connector Plates (연결 강판 형상에 따른 모듈러 유닛 간 접합부의 거동 비교)

  • Lee, Sang Sup;Bae, Kyu Woong;Park, Keum Sung
    • Journal of Korean Society of Steel Construction
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    • 제28권6호
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    • pp.467-476
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    • 2016
  • For the connections between modular units in modular buildings, the bolted joints with connector plates are used commonly. The strength of structure is determined by the weakest part of structure and the connections may be weaker than the members being joined. Therefore, to check the safety of modular building, the structural performance of connections between modular units as well as that of beam-to-column connections should be evaluated. In this study, the behavior of module to module connection with straight and cross shaped connector plates is investigated by lateral cyclic tests according to KBC2009 0722.2.4 which shall be conducted by controlling the story drift angle in the width and the longitudinal direction respectively. All of test results generally show the stable ductile behavior up to 0.04rad drift levels and the tests in longitudinal direction show a superior energy dissipation per cycle in each of the load steps. However, the straight shaped connector plates have the degradation of stiffness with cyclic loading and the larger drift angle of column than the cross shaped connector plates.

Effect of Vinyl Ethylene Carbonate on Electrochemical Characteristics for Activated Carbon/Li4Ti5O12 Capacitors (활성탄/리튬티탄산화물 커패시터의 전기화학적 특성에 미치는 비닐에틸렌카보네이트의 영향)

  • Kwon, Yong-Kab;Choi, Ho-Suk;Lee, Joong-Kee
    • Journal of the Korean Electrochemical Society
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    • 제15권3호
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    • pp.190-197
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    • 2012
  • We employed the vinyl ethylene carbonate (VEC) as an electrolyte additive and investigated the effect of the electrolyte additive on the electrochemical performance in hybrid capacitor. The activated carbon was adopted as cathode material, and the $Li_4Ti_5O_{12}$ oxide was used as anode material. The electrolyte was prepared with the $LiPF_6$ salt in the mixed solvent of ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate(EMC). We evaluated the electrochemical performance of the hybrid capacitor with increasing the amount of the VEC electrolyte additive, which is known as the remover of oxygen functional group and the stabilizer of the electrode by reducing the surface of electrode, and obtained the superior performance data especially at the addition of the VEC electrolyte additive of around 0.7 vol%. On the contrary, the addition of the VEC more than 0.7 vol% in the electrolyte leads to the degradation in electrochemical performance of hybrid capacitor, suggesting the increase of the side reaction from the excessive VEC additive. X-ray photoelectron spectroscopy (XPS) revealed that the addition of the VEC suppressed the formation of LiF component, which is known as the insulator, on the surface of electrode. The optimized addition of VEC exhibited the improved capacity retention around 82.7% whereas the bare capacitors without VEC additive showed the 43.2% of capacity retention after 2500 cycling test.

Seismic Performance of Circular RC Bridge Columns with Longitudinal Steel Connection Details (축방향철근 연결상세에 따른 철근콘크리트 원형교각의 내진성능)

  • Lee Jae-Hoon;Son Hyeok-Soo;Ko Seong-Hyun
    • Journal of the Korea Concrete Institute
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    • 제16권2호
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    • pp.249-260
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    • 2004
  • The longitudinal steel connection of reinforced concrete bridge column is sometimes practically unavoidable, however the current Korean bridge design specifications have no special provisions about lap-splices of longitudinal steel. This paper reports experimental results of a research program investigating the seismic performance of circular RC bridge columns with respect to longitudinal steel connection detailing. Twenty-one circular column specimens were tested under quasi-static test. The columns with the entire longitudinal steel lap-spliced within plastic hinge region show relatively sudden strength degradation and low ductility than the columns with continuous longitudinal steel and the columns with half of longitudinal steel lap-spliced. However, the seismic performance of the column with mechanically connected longitudinal steel is similar to that of the column with continuous longitudinal steel. The final objectives of this study are to suggest appropriate longitudinal reinforcement connection details for the limited ductility design concept and to provide quantitative reference data and tendency for performance or damage assessment based on the performance levels such as cracking, yielding, collapse, etc. Ultimate displacement/drift ratio, displacement ductility, response modification factor, equivalent viscous damping ratio, residual deformation index, and effective stiffness are investigated and discussed in this paper.

Cyclic Lond Testing for Strong Axis Joints Connected with SRC Column and RC Beams (SRC기둥-RC보 강축 접합부 상세의 구조성능 평가)

  • Moon, Jeong-Ho;Lee, Kang-Min;Lim, Jae-Hyung;Oh, Kyung-Hwan;Kim, Sung-Ho
    • Journal of the Korea Concrete Institute
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    • 제19권4호
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    • pp.401-409
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    • 2007
  • The objective of this research is to provide better knowledge on the behavior of strong axis SRC column-RC beam joint, supported by experimental results, that can be broadly applicable to many structures. For this purpose, firstly literature reviews and field survey were made to classify the most commonly used for these types of joints. Then, experimental program was designed and performed including 6 SRC column-RC beam joint specimens designed with various joint details. Using the experimental results obtained from the quasi-static cyclic tests, structural performances of the joints such as hysteretic curves, maximum strength capacities, strength degradation beyond the maximum strength, ductilities, and energy dissipation capacities were investigated. Test results showed that specimens with wide beam shape (RCW-P, RCW-W, RCW-F) and T beam shape (RCT-W) showed better structural performances than the bracket type specimens (HBR-L, HBR-S). These specimens also revealed to have higher strength capacities than the nominal design strength. However, H beam bracket type specimens (HBR-L, HBR-S) need further study both analytically and experimentally to verify the reason for unexpected structural performances.

Effect of Pt Particle Size on the Durability of PEMFC (연료전지 촉매의 입자크기가 내구성에 미치는 영향)

  • Min, Kyoung-Won;Kim, Hyun-Jong;Han, M.K.;U, Yu-Tae;Kim, Mok-Soon;Chu, Young-Hwan
    • Journal of the Korean Electrochemical Society
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    • 제11권4호
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    • pp.313-318
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    • 2008
  • The influence of the particle size of platinum(Pt) on the stability and activity was studied. The particle size of platinum was controlled in the range of $3.5{\sim}9\;nm$ by heat treatment of commercial Pt/C and confirmed by XRD and TEM. An accelerated degradation test was performed to evaluate the stability of platinum catalysts. Oxygen reduction reaction was monitored for the measurement of activity. As increasing the Pt particle size, the stability of Pt/C electrode was enhanced and the activity was reduced. It was confirmed that the stability of Pt/C electrode was in inverse proportion to the activity. PtCo/C alloy catalyst was used to improve the activity and stability of large-sized platinum particle. The maximum power density of commercial Pt/C was $507.6\;mV/cm^2$ and PtCo/C alloy catalyst was $585.8\;mV/cm^2$. The decrement of electrochemical surface area showed Pt/C(60%) and PtCo/C alloy catalyst(24%). It was possible to enhance both of stability and activity of catalyst by the combination of particle size control and alloying.

Effect of fuel component on nitrous oxide emission characteristics in diesel engine (디젤엔진에 있어서 연료의 성분이 아산화질소 배출에 미치는 영향)

  • Yoo, Dong-Hoon
    • Journal of Advanced Marine Engineering and Technology
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    • 제38권9호
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    • pp.1045-1050
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    • 2014
  • $N_2O$(Nitrous Oxide) is known as the third major GHG(Green House Gas) following $CO_2$(Carbon Oxide) and $CH_4$(Methane). The GWP(Global Warming Potential) factor of $N_2O$ is 310 times as large as that of $CO_2$ because $N_2O$ in the atmosphere is very stable, and it becomes a source of secondary contamination after photo-degradation in the stratosphere. Investigation on the cause of the $N_2O$ formation have been continuously reported by several researchers on power sources with continuous combustion form, such as a boiler. However, in the diesel engine, research on $N_2O$ generation which has effected from fuel components has not been conducted. Therefore, in this research, author has investigated about $N_2O$ emission rates which was changed by nitrogen and sulfur concentration in fuel on the diesel engine. The test engine was a 4-stroke direct injection diesel engine with maximum output of 12 kW at 2600rpm, and operating condition of that was set up at a 75% load. Nitrogen and sulfur concentrations in fuel were raised by using six additives : nitrogen additives were Pyridine, Indole, Quinoline, Pyrrol and Propionitrile and sulfur additive was Di-tert-butyl-disulfide. In conclusion, diesel fuels containing nitrogen elements less than 0.5% did not affect $N_2O$ emissions in the all concentrations and kinds of the additive agent in the fuel. However, increasing of the sulfur additive in fuel increased $N_2O$ emission in exhaust gas.