• Title/Summary/Keyword: defect engineering

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Preparation of Disulfonated Poly(arylene ether sulfone) Random Copolymer Thin Film Composite Membranes Using a Benign Solvent (친환경용매 기반의 술폰화 폴리아릴렌 에테르 술폰 랜덤 공중합체 Thin Film Composite 제조)

  • Lee, Chang Hyun;McGrath, James E.;Freeman, Benny
    • Membrane Journal
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    • v.24 no.4
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    • pp.292-300
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    • 2014
  • Chlorine-resistant sulfonated poly(arylene ether sulfone) random copolymer (SPAES)-thin film composite (TFC) membranes for desalination are prepared using monoglyme as a selective solvent, which dissolves SPAES, but should be inert to porous polysulfone layer (e.g., Udel$^{(R)}$). Different from formic acid and diethylene glycol used as other selective solvents, monoglyme is environmentally friendly and has much lower boiling temperature. After a pretreatment of Udel$^{(R)}$ support film in isopropyl alcohol-glycerine mixture to minimize pore penetration leading to fairly reduced water flux, coating of SPAES solution in monoglyme onto the support and stepwise drying processes are conducted for defect-free TFC formation. The transport behavior through SPAES-TFC membranes is observed, correlating with the effects of sulfonation level, protonation, and physical and chemical crosslinking of SPAES selective layers.

Optical Characteristics of CdSe/ZnS Quantum Dot with Precursor Flow Rate Synthesized by using Microreactor (마이크로리액터를 이용한 전구체 유속에 따른 CdSe/ZnS 양자점의 광학특성)

  • Park, Ji Young;Jeong, Da-Woon;Ju, Won;Seo, Han Wook;Cho, Yong-Ho;Kim, Bum Sung
    • Journal of Powder Materials
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    • v.23 no.2
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    • pp.91-94
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    • 2016
  • High-quality colloidal CdSe/ZnS (core/shell) is synthesized using a continuous microreactor. The particle size of the synthesized quantum dots (QDs) is a function of the precursor flow rate; as the precursor flow rate increases, the size of the QDs decreases and the band gap energy increases. The photoluminescence properties are found to depend strongly on the flow rate of the CdSe precursor owing to the change in the core size. In addition, a gradual shift in the maximum luminescent wave (${\lambda}_{max}$) to shorter wavelengths (blue shift) is found owing to the decrease in the QD size in accordance with the quantum confinement effect. The ZnS shell decreases the surface defect concentration of CdSe. It also lowers the thermal energy dissipation by increasing the concentration of recombination. Thus, a relatively high emission and quantum yield occur because of an increase in the optical energy emitted at equal concentration. In addition, the maximum quantum yield is derived for process conditions of 0.35 ml/min and is related to the optimum thickness of the shell material.

Two Cases of Auricular Salvage after Wide Excision of Malignant Tumor at Periauricular Area (이개 주변 악성종양의 광범위절제술 후 이개의 보존 2례)

  • Kim, Kyul-Hee;Chung, Chul-Hoon;Chang, Yong-Joon;Lee, Jong-Wook;Rho, Young-Soo;Kim, Chang-Woo
    • Korean Journal of Head & Neck Oncology
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    • v.25 no.1
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    • pp.39-42
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    • 2009
  • Wide excision for curative treatment of malignant tumor on periauricular area often leads to loss of the external ear. But the auricle has rich vascular supply, Conservation of auricular contour is possible through salvage and engineering of remained auricular tissue. We experienced two cases of auricular salvage after wide excision of malignant tumor. In the first case, we performed two-staged technique. In first step, we covered soft tissue defect on periauricualr area with the anterolateral thigh free flap and remained auricle was floating over the flap after split-thickness skin graft was applied on it's posterior raw surface because it's survival was not confirmed. Second step was reposition of remained auricule on the anterolateral thigh flap. In the second case, we packed in periauricular dead space and external auditory canal with temoporalis muscle and temporoparietal fascial flap and then covered the flap with split thickness skin graft. In these two cases, there were no recurrence of tumors and we obtained cosmetically & functionally satisfactory results.

Development of Low-Temperature Storage Method of Sweet Persimmons (단감의 저온저장방법(低溫貯藏方法) 개발(開發)에 관(關)한 연구(硏究))

  • Chung, J.H.;Suh, S.R.
    • Journal of Biosystems Engineering
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    • v.19 no.3
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    • pp.232-246
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    • 1994
  • This study was conducted to develop the long-tenn storage method to minimize the black spot occurred on the surface of persimmons stored in the films at low temperature. The storage experiments were done with different films and persimmon varieties at $0^{\circ}C$ storage condition for 5 months, and then the physical and chemical characteristics of persimmons were tested monthly. The results were as follows : 1. The film 160 made from zeolites showed highest performance in well storings sweet persimmons for 5 months, compared with other films by eyesight. The initial moisture condensation inside the films seemed to cause the black spots on persimmons, and the effect of the film holes was never significant to prevent the black spots. 2. The sugar content was ranged from $14^{\circ}Brix$ to $15^{\circ}Brix$ regardless of film types and persimmom varieties, and it changed little for storage of 5 months. 3. The decrease rate of persimmom weight in the film 160 and 180 was 0.3% for storage of 5 months, while those in other films reached to 2%. The decrease rate of persimmon weight was least in the film 160 and 180. 4. The hardness of Fuyu least decreased in the films 160 and 380. It was changed from 36 kg/cnf to 8-27 $kg/cm^2$, and that of Charyang was from 31 $kg/cm^2$ to 8-10 $kg/cm^2$ for storage of 5 months. The hardness of Charyang rapidly decreased as storage period increased. 5. The average rate of black spot(defect rate) of Fuyu measured by a computer image processing system was least in the film 160 by 0.5%, but those in other films was ranged from about 5% to 20% for storage of 5 months. The rate of black spot of Charyang was less than that of Fuyu among most of films. 6. The intensity, hue, and saturation in persimmon color changed according to storage period. Especially, the intensity of persimmon colors decreased as storage period increased, but it was least in the film 160. 7. An integrated long-term storage method of sweet persimmons was suggested in the basis of the experiments and literature reviews.

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Growth and Effect of Thermal Annealing for ZnIn2S4 Single Crystal Thin Film by Hot Wall Epitaxy (Hot Wall Epitaxy (HWE)법에 의한 ZnIn2S4 단결정 박막 성장과 열처리 효과)

  • Park, Chang-Sun;Hong, Kwang-Joon
    • Korean Journal of Materials Research
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    • v.18 no.6
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    • pp.318-325
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    • 2008
  • Single crystal $ZnIn_2S_4$ layers were grown on thoroughly etched semi-insulating GaAs(100) substrate at $450^{\circ}C$ with hot wall epitaxy (HWE) system by evaporating $ZnIn_2S_4$ source at $610^{\circ}C$. The crystalline structure of the single crystal thin films was investigated by the photoluminescence (PL) and double crystal X-ray rocking curve (DCRC). The temperature dependence of the energy band gap of the $ZnIn_2S_4$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)=2.9514\;eV-(7.24{\times}10^{-4}\;eV/K)T^2/(T+489\;K)$. After the as-grown $ZnIn_2S_4$ single crystal thin films were annealed in Zn-, S-, and In-atmospheres, the origin of point defects of $ZnIn_2S_4$ single crystal thin films has been investigated by the photoluminescence (PL) at 10 K. The native defects of $V_{Zn}$, $V_S$, $Zn_{int}$, and $S_{int}$ obtained by PL measurements were classified as a donors or acceptors type. And we concluded that the heat-treatment in the S-atmosphere converted $ZnIn_2S_4$ single crystal thin films to an optical p-type. Also, we confirmed that In in $ZnIn_2S_4$/GaAs did not form the native defects because In in $ZnIn_2S_4$ single crystal thin films existed in the form of stable bonds.

Analysis on Dynamic Software Defects for Increasing Weapon System Reliability (국방 무기체계 소프트웨어 신뢰성 향상을 위한 소프트웨어 동적 결함 분석)

  • Park, Jihyun;Choi, Byoungju
    • KIPS Transactions on Software and Data Engineering
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    • v.7 no.7
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    • pp.249-258
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    • 2018
  • The importance of software in military weapon systems is increasing, and the software structure is becoming more complicated. We therefore must thoroughly verify its reliability. In particular, the defects from the interaction of the software components that make up the weapon system are difficult to prevent only with static testing and code coverage level dynamic testing. In this paper, we classify dynamic software defect types and analyze the issues reported in the Open Source Software (OSS) used in the US department of defense weapon systems. The dynamic defects classified in this paper usually occur after integration, and it is difficult to reproduce and identify the cause. Based on this analysis, we come to the point that the software integration test must be enhanced in order to verify the reliability of the weapon system.

Thermal Stability of $\textrm{RuO}_2$ Thin Film Annealed at High Temperature in Oxygen Atmosphere ($\textrm{RuO}_2$ 박막의 산소 분위기 열처리시 열적 안정성에 관한 연구)

  • O, Sang-Ho;Park, Chan-Gyeong;Baek, Hong-Gu
    • Korean Journal of Materials Research
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    • v.8 no.12
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    • pp.1090-1098
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    • 1998
  • $RuO_2$ thin films were deposited on Si and Ru/Si substrates by rf magnetron reactive sputtering and annealed in oxygen atmosphere(1atm) to investigate their thermal stability and diffusion barrier property. $RuO_2$ thin films were thermally stable up to 700\ulcorner for 10min. in oxygen atmosphere and showed excellent barrier property against the interdiffusion of silicon and oxygen. After annealing at $750^{\circ}C$ , however, volatilization to higher oxide occurred at the surface and inside of $RuO_2$ thin film and diffusion barrier property was also deteriorated. When annealed at $800^{\circ}C$, $RuO_2$thin film showed a different microstructure from that of $RuO_2$ thin film annealed at 75$0^{\circ}C$. It is likely that surface defect structure of $RuO_2$, $RuO_3$, and excess oxygen had an influence on the mode of volatilization with increasing annealing temperature.

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Influence of Electron Beam Irradiation on the Electrical Properties of Zn-Sn-O Thin Film Transistor (Zn-Sn-O 박막 트랜지스터의 전기적 특성에 대한 전자빔 조사의 영향)

  • Cho1, In-Hwan;Jo, Kyoung-Il;Choi, Jun Hyuk;Park, Hai-Woong;Kim, Chan-Joong;Jun, Byung-Hyuk
    • Korean Journal of Materials Research
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    • v.27 no.4
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    • pp.216-220
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    • 2017
  • The effect of electron beam (EB) irradiation on the electrical properties of Zn-Sn-O (ZTO) thin films fabricated using a sol-gel process was investigated. As the EB dose increased, the saturation mobility of ZTO thin film transistors (TFTs) was found to slightly decrease, and the subthreshold swing and on/off ratio degenerated. X-ray photoelectron spectroscopy analysis of the O 1s core level showed that the relative area of oxygen vacancies ($V_O$) increased from 10.35 to 12.56 % as the EB dose increased from 0 to $7.5{\times}10^{16}electrons/cm^2$. Also, spectroscopic ellipsometry analysis showed that the optical band gap varied from 3.53 to 3.96 eV with increasing EB dose. From the results of the electrical property and XPS analyses of the ZTO TFTs, it was found that the electrical characteristic of the ZTO thin films changed from semiconductor to conductor with increasing EB dose. It is thought that the electrical property change is due to the formation of defect sites like oxygen vacancies.

The Effects of Chitin Derivative and Hydroxyapatite Compound in Canine Bone (키틴 유도체와 하이드록시아페타이트 복합체가 개의 뼈에 미치는 영향)

  • Lee, Hae-Beom;Shin, Seung-Ho;Kim, Min-Su;Lee, Ki-Chang;Chung, Yong-Sik;Kim, Nam-Soo
    • Journal of Veterinary Clinics
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    • v.25 no.5
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    • pp.370-378
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    • 2008
  • The aim of this study was to investigate bioactivities of 50% Chitin - hydroxyapatite (Chitin-H) compound and 50% Chitosan - hydroxyapatite (Chitosan-H) compound in canine bone. Ten healthy mongrel dogs (1-5 years old, 1.7 - 6.9 kg) were used in this study. These compounds had been transplanted into bilateral femur separately, and then the changes of femur were observed through the examinations of hemato-biochemical profiles, radiology, and histological profiles for 42 days. After 3 weeks, expanded radiolucent changes were observed in both areas transplanted the compounds. After 6 weeks, the area transplanted the Chitin-H compound did not observe any changes of bony tissue, while the area inserted the Chitosan-H compound was observed changes of increasing bone formation. In histological examination, infiltrations of inflammatory cells and bone absorptions were observed at both transplanted sites. However an increasing of active osteogenesis was observed at the transplanted site with Chitosan-H compound. In conclusion, Chitosan-H compound had an function of active osteogenesis as compared with Chitin-H compound. From this study, it is indicated that Chitosan-H compound would be used in dogs with severe bone defect.

A Suggestion for Merging Quality Management into Software Project Schedule Management (소프트웨어개발 일정관리와 품질관리의 통합 방안)

  • Paek, Seon-Uck;Han, Yong-Soo;Hong, Sug-Won
    • Information Systems Review
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    • v.6 no.2
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    • pp.195-208
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    • 2004
  • In this paper we propose a new software project development management model incorporating quality management to schedule management. Though many efficient techniques such as code review and inspection are used to remove defects, the effect of defect removal time on project schedule hasn't been studied much. However, poor quality management has an important effect upon overall schedule and sometimes software projects fails due to it. Thus, quality management and schedule management should be considered together and we need to reflect the time to maintain software quality into the schedule management. For the proposed model we introduced "Quality Value" representing the needed time to remove software defects. We assume PSP/TSP to gather the needed data for quality value. The proposed model can be used to predict the effect of software defects on schedule in advance and to prevent schedule lag.