• Title/Summary/Keyword: defect engineering

Search Result 2,235, Processing Time 0.035 seconds

Defects and Electrical Properties of ZnO-Bi2O3-Mn3O4-Co3O4 Varistor (ZnO-Bi2O3-Mn3O4-Co3O4 바리스터의 결함과 전기적 특성)

  • Hong, Youn-Woo;Lee, Young-Jin;Kim, Sei-Ki;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.25 no.12
    • /
    • pp.961-968
    • /
    • 2012
  • In this study, we have investigated the effects of Mn and Co co-doping on defects, J-E curves and grain boundary characteristics of ZnO-$Bi_2O_3$ (ZB) varistor. Admittance spectra and dielectric functions show two bulk defects of $Zn_i^{{\cdot}{\cdot}}$ (0.17~0.18 eV) and $V_o^{\cdot}$ (0.30~0.33 eV). From J-E characteristics the nonlinear coefficient (${\alpha}$) and resistivity (${\rho}_{gb}$) of pre-breakdown region decreased as 30 to 24 and 5.1 to 0.08 $G{\Omega}cm$ with sintering temperature, respectively. The double Schottky barrier of grain boundaries in ZB(MCo) ($ZnO-Bi_2O_3-Mn_3O_4-Co_3O_4$) could be electrochemically single type. However, its thermal stability was slightly disturbed by ambient oxygen because the apparent activation energy of grain boundaries was changed from 0.64 eV at lower temperature to 1.06 eV at higher temperature. It was revealed that a co-doping of Mn and Co in ZB reduced the heterogeneity of the barrier in grain boundaries and stabilized the barrier against an ambient temperature (${\alpha}$-factor= 0.136).

Synthesis of Li4/3Mn5/3O4 by Sol-Gel Process and its Electrochemical Properties (졸-겔법에 의한 Li4/3Mn5/3O4의 합성 및 전기화학적 특성)

  • Lee, Jin-Sik;Lee, Chul-Tae
    • Applied Chemistry for Engineering
    • /
    • v.10 no.1
    • /
    • pp.80-84
    • /
    • 1999
  • $Li_{4/3}Mn_{5/3}O_4$ having a defect structure was prepared by sol-gel process using lithium acetate and manganese acetate as starting materials, and their electrode characteristics in the lithium secondary battery was investigated. The reaction mole ratio was determined as $AA/Mn(OAc)_2$ of 0.2 and $NH_4OH/Mn(OAc)_2$ to $H_2O/Mn(OAc)_2$ of 0.4. The product was obtained through heat treatment at $350^{\circ}C$ for 12hrs after 1'st heat treatment at $150^{\circ}C$ of xerogel under oxygen atmosphere. When the charge and discharge cycles were performed between 2.0 V and 3.2 V, $Li/Li_{4/3}Mn_{5/3}O_4$ cell showed the dicharge capacity of 84.23 mAh/g and the good cycleability was obtained in the plateau region.

  • PDF

The Study on Improving Accuracy of Land Cover Classification using Spectral Library of Hyperspectral Image (초분광영상의 분광라이브러리를 이용한 토지피복분류의 정확도 향상에 관한 연구)

  • Park, Jung-Seo;Seo, Jin-Jae;Go, Je-Woong;Cho, Gi-Sung
    • Journal of Cadastre & Land InformatiX
    • /
    • v.46 no.2
    • /
    • pp.239-251
    • /
    • 2016
  • Hyperspectral image is widely used for land cover classification because it has a number of narrow bands and allow each pixel to include much more information in comparison with previous multi-spectral image. However, Higher spectral resolution of hyperspectral image results in an increase in data volumes and a decrease in noise efficiency. SAM(Spectral Angle Mapping), a method based on vector inner product to compare spectrum distribution, is a highly valuable and popular way to analyze continuous spectrum of hyperspectral image. SAM is shown to be less accurate when it is used to analyze hyperspectral image for land cover classification using spectral library. this inaccuracy is due to the effects of atmosphere. We suggest a decision tree based method to compensate the defect and show that the method improved accuracy of land cover classification.

A Study on Reliability Analysis and Quantitative Risk Analysis for Liquefied Petroleum Gas Station (LPG 충전시설에 대한 신뢰도 분석과 정량적 위험성 분석에 관한 연구)

  • Kim In-Won;Jin Sang-Hwa;Kim Tea-Woo;Kim In-Tae;Yeo Yeong-Koo
    • Journal of the Korean Institute of Gas
    • /
    • v.5 no.4 s.16
    • /
    • pp.40-48
    • /
    • 2001
  • For a Liquified Petroleum Gas(LPG) station, the reliability analysis, such as Fussell-Vesely importance, risk decrease factor and risk increase factor, was carried out and the risk ranks of events were determined. In order to confirm the degree of the risks identified in the reliability analysis, the quantitative risk analysis was done for the equipments which had the large values of risk ranks. As a result of the importance analysis for the LPG station, the external event was identified as the most riskful event. The defect of construction structure and the pipe corrosion were riskful as well. The result of quantitative risk analysis showed that the length of 46.3 meters were estimated to damage the process equipments by the thermal flux from the catastrophic rupture of storage tank in Boiling Liquid Expanding Vapor Explosion.

  • PDF

Synthesis of BaTiO3 Thin Film on Ti Electrode by the Current Pulse Waveform (펄스전류파형을 이용한 Ti 전극위에서 BaTiO3박막의 합성)

  • Kang, Jinwook;Tak, Yongsug
    • Applied Chemistry for Engineering
    • /
    • v.9 no.7
    • /
    • pp.998-1003
    • /
    • 1998
  • $BaTiO_3$ thin film was electrochemically deposited on Ti electrode in a 0.4 M $Ba(OH)_2$ solution of $85^{\circ}C$ using a current pulse waveform. Both $BaTiO_3$ crystallinity and faradaic efficiency for the film formation were enhanced with the increase of cathodic current density and pulse time. Based on the surface analysis and electrochemical studies, it was suggested that, during cathodic pulsed, the surface pH increase due to the reduction of $H_2O$ accelerates the structural changes of Ti oxides which were formed during anodic cycle. Prior to experiments, Ti oxides were intentionally grown in 0.1 M $H_2SO_4$ solution and the effect of initial oxide film thickness on the $BaTiO_3$ film formation was investigated. The migration of $Ti^{+4}$ ions through the oxide film was retarded with the increase of film thickness and it was observed that the crystallization of $BaTiO_3$ was only limited to the defect area of surface oxides.

  • PDF

Identification of Novel Mitochondrial Membrane Protein (Cdf 3) from Arabidopsis thaliana and its Functional Analysis in a Yeast System

  • Kim, Kyung-Min;Jun, Do-Youn;Kim, Sang-Kook;Kim, Chang-Kil;Kim, Byung-Oh;Kim, Young-Ho;Park, Wan;Sohn, Jae-Keun;Hirata, Aiko;Kawai-Yamada, Maki;Uchimiya, Hirofumi;Kim, Dai-Hee;Sul, Ill-Whan
    • Journal of Microbiology and Biotechnology
    • /
    • v.17 no.6
    • /
    • pp.891-896
    • /
    • 2007
  • We screened the Arabidopsis cDNA library to identify functional suppressors of AtBI-1, a gene that suppresses cell death induced by Bax gene expression in yeast. Cdf 3 encodes a 118-amino-acid protein with a molecular mass of 25 kDa. This protein has two uncharacterized domains at amino acids residues 5-64 and 74-117. In the present study, CDF3 was found to induce growth defects in yeast and arrested yeast growth, although the cell-growth defect was somewhat less than that of Bax. Its localization in the inner mitochondria was essential for suppression of yeast-cell proliferation. The morphological abnormality of the intracellular network, which is a hallmark of AtBI-1, was attenuated by Cdf3 expression.

Effect of Dry-Electropolishing on the High Cycle Fatigue Properties of Ti-6Al-4V Alloy Manufactured by Selective Laser Melting (선택적 레이저 용융법으로 제조된 Ti-6Al-4V 합금의 고 주기 피로 특성에 미치는 건식 전해 연마의 영향)

  • Yang, Dong-Hoon;Kim, Young-Kyun;Hwang, Yujin;Kim, Myoung-Se;Lee, Kee-Ahn
    • Journal of Powder Materials
    • /
    • v.26 no.6
    • /
    • pp.471-476
    • /
    • 2019
  • Additively manufactured metallic components contain high surface roughness values, which lead to unsatisfactory high cycle fatigue resistance. In this study, high cycle fatigue properties of selective laser melted Ti-6Al-4V alloy are investigated and the effect of dry-electropolishing, which does not cause weight loss, on the fatigue resistance is also examined. To reduce the internal defect in the as-built Ti-6Al-4V, first, hot isostatic pressing (HIP) is conducted. Then, to improve the mechanical properties, solution treatment and aging are also implemented. Selective laser melting (SLM)-built Ti64 shows a primary α and secondary α+β lamellar structure. The sizes of secondary α and β are approximately 2 ㎛ and 100 nm, respectively. On the other hand, surface roughness Ra values of before and after dry-electropolishing are 6.21 ㎛ and 3.15 ㎛, respectively. This means that dry-electropolishing is effective in decreasing the surface roughness of selective laser melted Ti-6Al-4V alloy. The comparison of high cycle fatigue properties between before and after dry-electropolished samples shows that reduced surface roughness improves the fatigue limit from 150 MPa to 170 MPa. Correlations between surface roughness and high cycle fatigue properties are also discussed based on these findings.

Machine Learning based on Approach for Classification of Abnormal Data in Shop-floor (제조 현장의 비정상 데이터 분류를 위한 기계학습 기반 접근 방안 연구)

  • Shin, Hyun-Juni;Oh, Chang-Heon
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.21 no.11
    • /
    • pp.2037-2042
    • /
    • 2017
  • The manufacturing facility is generally operated by a pre-set program under the existing factory automation system. On the other hand, the manufacturing facility must decide how to operate autonomously in Industry 4.0. Determining the operation mode of the production facility itself means, for example, that it detects the abnormality such as the deterioration of the facility at the shop-floor, prediction of the occurrence of the problem, detection of the defect of the product, In this paper, we propose a manufacturing process modeling using a queue for detection of manufacturing process abnormalities at the shop-floor, and detect abnormalities in the modeling using SVM, one of the machine learning techniques. The queue was used for M / D / 1 and the conveyor belt manufacturing system was modeled based on ${\mu}$, ${\lambda}$, and ${\rho}$. SVM was used to detect anomalous signs through changes in ${\rho}$.

Evaluation of Forward Osmosis (FO) Membrane Performances in a Non-Pressurized Membrane System (비가압식 막 공정을 통한 정삼투막 성능 평가)

  • Kim, Bongchul;Boo, Chanhee;Lee, Sangyoup;Hong, Seungkwan
    • Journal of Korean Society on Water Environment
    • /
    • v.28 no.2
    • /
    • pp.292-299
    • /
    • 2012
  • The objective of this study is to develop a novel method for evaluating forward osmosis (FO) membrane performances using a non-pressurized FO system. Basic membrane performance parameters including water (A) and solute (B) permeability coefficients and unique parameter for FO membrane such as the support layer structural parameter (S) were determined in two FO modes (i.e., active layer faces feed solution (AL-FS) and active layer faces draw solution (AL-DS)). Futhermore, these parameters were compared with those determined in a pressurized reverse osmosis (RO) system. Theoretical water flux was calculated by employing these parameters to a model that accounts for the effects of both internal and external concentration polarization. Water flux from FO experiment was compared to theoretical water fluxes for assessing the reliability of those parameters determined in three different operation modes (i.e., AL-FS FO, AL-DS FO, and RO modes). It is demonstrated that FO membrane performance parameters can be accurately measured in non-pressurized FO mode. Specifically, membrane performance parameters determined in AL-DS FO mode most accurately predict FO water flux. This implies that the evaluation of FO membrane performances should be performed in non-pressurized FO mode, which can prevent membrane compaction and/or defect and more precisely reflect FO operation conditions.

A Study on the Electrical Characteristic Analysis of c-Si Solar Cell Diodes

  • Choi, Pyung-Ho;Kim, Hyo-Jung;Baek, Do-Hyun;Choi, Byoung-Deog
    • JSTS:Journal of Semiconductor Technology and Science
    • /
    • v.12 no.1
    • /
    • pp.59-65
    • /
    • 2012
  • A study on the electrical characteristic analysis of solar cell diodes under experimental conditions of varying temperature and frequency has been conducted. From the current-voltage (I-V) measurements, at the room temperature, we obtained the ideality factor (n) for Space Charge Region (SCR) and Quasi-Neutral Region (QNR) of 3.02 and 1.76, respectively. Characteristics showed that the value of n (at SCR) decreases with rising temperature and n (at QNR) increases with the same conditions. These are due to not only the sharply increased SCR current flow but the activated carrier recombination in the bulk region caused by defects such as contamination, dangling bonds. In addition, from the I-V measurements implemented to confirm the junction uniformity of cells, the average current dispersion was 40.87% and 10.59% at the region of SCR and QNR, respectively. These phenomena were caused by the pyramidal textured junction structure formed to improve the light absorption on the device's front surface, and these affect to the total diode current flow. These defect and textured junction structure will be causes that solar cell diodes have non-ideal electrical characteristics compared with general p-n junction diodes. Also, through the capacitance-voltage (C-V) measurements under the frequency of 180 kHz, we confirmed that the value of built-in potential is 0.63 V.