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An Electrochemical Evaluation on the Crevice Corrosion of 430 Stainless Steel with Variation of Crevice Wide by Micro Capillary Tubing Method (Micro Capillary Tube 방법을 이용한 430 스테인레스강 틈의 폭변화에 따른 틈부식의 전기화학적 평가)

  • Na, Eun-Young
    • Journal of the Korean Electrochemical Society
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    • v.6 no.4
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    • pp.250-254
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    • 2003
  • In this study, the IR drop theory was adopted to explain the initiation of crevice corrosion in the framework of IR drop in crevice electrolyte. Furthermore, the electrochemical polarization was measured to study the mechanism of crevice corrosion for type STS430 stainless steel. lest method adopts under condition that the size of specimen is $10\times20\times5mm,\;in\;1N\;H_2SO_4+0.1N\;NaCl$ solution, and the artificial crevice gap sizes are three kinds, the Micro capillary tube size is inner diameter 0.04 mm, outer diameter 0.08 mm. Crevice corrosion is measured under the applied voltage of passivation potential -200mV/SCE, resulted from anodic potentio-dynamic polarization to the external surface along the crevice. The potential difference was measured by depth profile by Micro capillary tube which inserted in the crevice. The obtained results of this study showed that 1) As artificial crevice gap size became narrow, the current density was increased, whereas no crevice corrosion was found in the crevice gap size $3\times0.5\times16mm\;in\;1N\;H_2SO_4+0.1N\;NaCl\;solution\;at\;20^{\circ}C$ 2) potential of the crevice was about from -220 to -358mV which is lower than that of external surface potential of -200mV The results so far confirmes that the potential drop(so-called IR drop) in the crevice is one of the major mechanisms the process of crevice corrosion for 430 stainless steel.

A Time Variable Modeling Study of Vertical Temperature Profiles in the Okjung Lake (옥정호의 연직 수온분포에 관한 시변화 모델 연구)

  • Park, Ok-Ran;Park, Seok-Soon
    • Korean Journal of Ecology and Environment
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    • v.35 no.2 s.98
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    • pp.79-91
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    • 2002
  • A time variable modeling study was performed for seasonal variations of vertical temperature profiles in the Okjung Lake located in upstream of the Sumjin River. Based on the model structure of the US Army Corps of Engineer's CE-QUAL-W2, the lake was divided into 3 branches, 50 longitudinal segments and 49 vertical layers and vertical profiles of water temperature and current velocity were simulated over one year. The model results were calibrated and verified against vertical profiles of water temperature measured every month from March 1998 to February 1999 at 5 different locations. The model results showed a good agreement with the field measurements. The hydrologic balance during this period was validated by comparing the simulated values of surface elevation level with the measured data. There was some discrepancy in July data between the model results and the fleld measurements. This could be attributed partially to the inadequacy of the model to the highly hydrodynamic nature of water body and partially to the lack of accuracy in local atmospheric temperature data during summer monsoon period. The model results have shown that there was no seasonal over-turn in most part of the Okjung Lake, where water temperature maintained above $4^{\circ}C$ over one year. In the upstream shal-low area (depth<20 meter), however, temperature at surface layer fell below $4^{\circ}C$ and water was frozen such that slight over-turn would occur during winter period. From this study, we concluded that the Okjung Lake is oligomictic. This conclusionis significantly different from the general pattern that the lakes located from $20^{\circ}C$ to $40^{\circ}C$ latitude would be warm monomictic. From the examination of simulated current velocity distribution, it was found that the upstream inflows would infiltrate into mesolimnion of the lake during hydrodynamic summer monsoon periods due to the thermal density of water.

Periodontopathogen LPSs Regulate MicroRNA Expression in Human Gingival Epithelial Cells

  • Lee, Hwa-Sun;Na, Hee-Sam;Jeong, So-Yeon;Jeong, Sung-Hee;Park, Hae-Ryoun;Chung, Jin
    • International Journal of Oral Biology
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    • v.36 no.3
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    • pp.109-116
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    • 2011
  • Periodontitis results from the activation of host immune and inflammatory defense responses to subgingival plaque bacteria, most of which are gram-negative rods with lipopoly-saccharides (LPSs) in their cell walls. LPSs have been known to induce proinflammatory responses and recently it was reported also that they induce the expression of microRNAs (miRNAs) in host cells. In our current study therefore, we aimed to examine and compare the miRNA expression patterns induced by the LPSs of major periodontopathogens in the human gingival epithelial cell line, Ca9-22. The cells were treated with 1 ${\mu}g$/ml of E. coli (Ec) LPS or 5 ${\mu}g$/ml of an LPS preparations from four periodontopathogens Porphyromonas gingivalis (Pg), Prevotella intermedia (Pi), Aggregatibacter actinomycetemcomitans (Aa), and Fusobacterium nucleatum (Fn) for 24 h. After small RNA extraction from the treated cells, miRNA microarray analysis was carried out and characteristic expression profiles were observed. Fn LPS most actively induced miRNAs related to inflammation, followed by Aa LPS, Pi LPS, and Ec LPS. In contrast, Pg LPS only weakly activated miRNAs related to inflammation. Among the miRNAs induced by each LPS, miR-875-3p, miR-449b, and miR-520d-3p were found to be commonly up-regulated by all five LPS preparations, although at different levels. When we further compared the miRNA expression patterns induced by each LPS, Ec LPS and Pi LPS were the most similar although Fn LPS and Aa LPS also induced a similar miRNA expression pattern. In contrast, the miRNA profile induced by Pg LPS was quite distinctive compared with the other bacteria. In conclusion, miR-875-3p, miR-449b, and miR-520d-3p miRNAs are potential targets for the diagnosis and treatment of periodontal inflammation induced by subgingival plaque biofilms. Furthermore, the observations in our current study provide new insights into the inflammatory miRNA response to periodontitis.

Water Quality in Hwawon Coastal Sea of Korea for Rainy and Dry Season (건기와 우기시 화원면 주변 해역의 수질 비교)

  • Kim, Do-Hee
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.10 no.4
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    • pp.193-200
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    • 2007
  • The purpose of this study is investigate to water quality, pH, turbidity, salinity, nutrients, SS, DO, COD, ${NH_4}^+$-N, ${NO_2}^-+{NO_3}^-$-N, TN, TP, ${PO_4}^{3-}$-P in ditches and seawater of the Hwawon, southwestern coastal area of Korea. Two stations of the ditch, one station at outfall from reservoir of the coastal development and 15 stations of seawater were measured in August just after a 96.5 mm rainfall and in dry season of November 2006. The sampling time were divided into a rainy and dry season based on turbidity, SS, salinity and nutrients difference of distributions that was evidence as a inflow of pollutants from the developing coastal land area. The pH, turbidity, salinity and SS were high and showed different from between surface and bottom in near the developing of coastal land than the other stations after a strong rainfall over 90 mm while it were not varied in vertical and horizontal concentration profile in dry season. The other nutrients were showed the same concentrations gradient patterns. In opposition to expectations, the SS in dry season was higher than in the rainy season due to upwelling by the wind and strong current. It appears that the researched coastal seawater qualities were mainly effected by the inflow of freshwater from the ditches and drain from the reservoir of the developing land area during strong rainfall while the seawater qualities were mainly effected by the wind and strong current in dry season.

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The fabrication and evaluation of CdS sensor for diagnostic x-ray detector application (진단 X선 검출기 적용을 위한 CdS 센서 제작 및 성능 평가)

  • Park, Ji-Koon;Lee, Mi-Hyun;Choi, Young-Zoon;Jung, Bong-Zae;Choi, Il-Hong;Kang, Sang-Sik
    • Journal of the Korean Society of Radiology
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    • v.4 no.2
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    • pp.21-25
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    • 2010
  • Recently, various semiconductor compounds as radiation detection material have been researched for a diagnostic x-ray detector application. In this paper, we have fabricated the CdS detecton sensor that has good photosensitivity and high x-ray absorption efficiency among other semiconductor compounds, and evaluated the application feasibility by investigating the detection properties about energy range of diagnostic x-ray generator. We have fabricated the line voltage selector(LCV) for a signal acquisition and quantities of CdS sensor, and designed the voltage detection circuit and rectifying circuit. Also, we have used a relative relation algorithm according to x-ray exposure condition, and fabricated the interface board with DAC controller. Performance evaluation was investigated by data processing using ANOVA program from voltage profile characteristics according to resistive change obtained by a tube voltage, tube current, and exposure time that is a exposure condition of x-ray generator. From experimental results, an error rates were reduced according to increasing of a tube voltage and tube current, and a good properties of 6%(at 90 kVp) and 0.4%(at 320 mA) ere showed. and coefficient of determination was 0.98 with relative relation of 1:1. The error rate according to x-ray exposure time showed exponential reduction because of delayed response velocity of CdS material, and the error rate has 2.3% at 320 msec. Finally, the error rate according to x-ray dose is below 10%, and a high relative relation was showed with coefficient of determination of 0.9898.

Optimizing the Electricity Price Revenue of Wind Power Generation Captures in the South Korean Electricity Market (남한 전력시장에서 풍력발전점유의 전력가격수익 최적화)

  • Eamon, Byrne;Kim, Hyun-Goo;Kang, Yong-Heack;Yun, Chang-Yeol
    • Journal of the Korean Solar Energy Society
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    • v.36 no.1
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    • pp.63-73
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    • 2016
  • How effectively a wind farm captures high market prices can greatly influence a wind farm's viability. This research identifies and creates an understanding of the effects that result in various capture prices (average revenue earned per unit of generation) that can be seen among different wind farms, in the current and future competitive SMP (System Marginal Price) market in South Korea. Through the use of a neural network to simulate changes in SMP caused by increased renewables, based on the Korea Institute of Energy Research's extensive wind resource database for South Korea, the variances in current and future capture prices are modelled and analyzed for both onshore and offshore wind power generation. Simulation results shows a spread in capture price of 5.5% for the year 2035 that depends on both a locations wind characteristics and the generations' correlation with other wind power generation. Wind characteristics include the generations' correlation with SMP price, diurnal profile shape, and capacity factor. The wind revenue cannibalization effect reduces the capture price obtained by wind power generation that is located close to a substantial amount of other wind power generation. In onshore locations wind characteristics can differ significantly/ Hence it is recommended that possible wind development sites have suitable diurnal profiles that effectively capture high SMP prices. Also, as increasing wind power capacity becomes installed in South Korea, it is recommended that wind power generation be located in regions far from the expected wind power generation 'hotspots' in the future. Hence, a suitable site along the east mountain ridges of South Korea is predicted to be extremely effective in attaining high SMP capture prices. Attention to these factors will increase the revenues obtained by wind power generation in a competitive electricity market.

Analysis of Electric Vehicle's Environmental Benefits from the Perspective of Energy Transition in Korea (에너지 전환정책에 따른 전기자동차의 환경편익 추정연구)

  • Jeon, Hocheol
    • Environmental and Resource Economics Review
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    • v.28 no.2
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    • pp.307-326
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    • 2019
  • The electric vehicle is a representative measure to reduce greenhouse gas and local air pollutants in the transportation sector. Most countries provide purchase subsidies and tax reductions to promote electric vehicle sales. The electric vehicles have been considered as zero-emission vehicles(ZEV) in light of the fact that there has been no pollutant emission during driving. However, recent studies have pointed out that the pollutant emitted from the process of generating electricity used for charging the electric vehicles need to be treated as emissions of the electric vehicles. Furthermore, the environmental benefits of electric vehicle replacing the internal combustion vehicle vary with the power mix. In line with the recent studies, this study analyzes the impact of electric vehicles based on the current power mix and future energy transition scenarios in Korea. To estimate the precise air pollutants emission profile, this study uses hourly electricity generation and TMS emission data for each power plant from 2015 to 2016. The estimation results show that the electric vehicles under the current power mix generate the environmental benefits of only -0.41~10.83 won/km. Also, we find that the environmental benefit of electric vehicle will significantly increase only when the ratio of the coal-fired power plant is reduced to a considerable extent.

Spatial Distribution of Pigment Concentration Around the East Korean Warm Current Region Derived from Satellite Data - Satellite Observation in May 1980 - (위성원격탐사에 의한 동한난류 주변 해역의 색소농도 공간적 분포 -1980년 5월 관측을 중심으로 -)

  • Kim Sang Woo;Saitoh Sei-ich;Kim Dong Sun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.3
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    • pp.265-272
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    • 2002
  • Spatial distribution of Phytoplankton Pigment Concentration (PPC) and Sea Surface Temperature (SST) around the East Korean Warm Current (EKWC) was described, using both Coastal Zone Color Scanner (CZCS) images and Advanced Very High Resolution Radiometer (AVHRR) images in May, 1980. Water mass in this region can be classified into five categories in the horizontal profile of PPC and SST, nLw (normalized water-leaving radiance) images: (1) coastal cold water region associated with concentrations of dissolved organic material or yellow colored substances and suspended sediments, (2) cold water region of thermal frontal occurred by a combination of phytoplankton absorption and suspended materials, (3) warm water overlay region by the phytoplankton absorption than the suspended materials; (4) warm water region occurred by the low phytoplankton absorption, and (5) offshore region occurred by the high phytoplankton absorption. In particular, the highest PPC (>2.0 mg/m^3) area appeared in the CZCS and AVHRR images with a band shaped distribution of the thermal front and ocean color front region, which is located the coastal cold waters alonB western thermal front of the warm streamer of the EKWC. In this region, the highest PPC occurred by a combination of the high absorption of the phytoplankton (443 nm) and highest reflectance of suspended materials (550 nm). Another high PPC ($\simeq$$6\;mg/m^3$) appeared in the warm water overlay region inside warm streamer. High phytoplankton pigment concentration of this region was corresponding to the short wavelength of 443 nm, which represented phytoplankton absorption of the CZCS image.

Variation of Inflow Density Currents with Different Flood Magnitude in Daecheong Reservoir (홍수 규모별 대청호에 유입하는 하천 밀도류의 특성 변화)

  • Yoon, Sung-Wan;Chung, Se-Woong;Choi, Jung-Kyu
    • Journal of Korea Water Resources Association
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    • v.41 no.12
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    • pp.1219-1230
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    • 2008
  • Stream inflows induced by flood runoffs have a higher density than the ambient reservoir water because of a lower water temperature and elevated suspended sediment(SS) concentration. As the propagation of density currents that formed by density difference between inflow and ambient water affects reservoir water quality and ecosystem, an understanding of reservoir density current is essential for an optimization of filed monitoring, analysis and forecast of SS and nutrient transport, and their proper management and control. This study was aimed to quantify the characteristics of inflow density current including plunge depth($d_p$) and distance($X_p$), separation depth($d_s$), interflow thickness($h_i$), arrival time to dam($t_a$), reduction ratio(${\beta}$) of SS contained stream inflow for different flood magnitude in Daecheong Reservoir with a validated two-dimensional(2D) numerical model. 10 different flood scenarios corresponding to inflow densimetric Froude number($Fr_i$) range from 0.920 to 9.205 were set up based on the hydrograph obtained from June 13 to July 3, 2004. A fully developed stratification condition was assumed as an initial water temperature profile. Higher $Fr_i$(inertia-to-buoyancy ratio) resulted in a greater $d_p,\;X_p,\;d_s,\;h_i$, and faster propagation of interflow, while the effect of reservoir geometry on these characteristics was significant. The Hebbert equation that estimates $d_p$ assuming steady-state flow condition with triangular cross section substantially over-estimated the $d_p$ because it does not consider the spatial variation of reservoir geometry and water surface changes during flood events. The ${\beta}$ values between inflow and dam sites were decreased as $Fr_i$ increased, but reversed after $Fr_i$>9.0 because of turbulent mixing effect. The results provides a practical and effective prediction measures for reservoir operators to first capture the behavior of turbidity inflow.

The Simulation of Pore Size Distribution from Unsaturated Hydraulic Conductivity Data Using the Hydraulic Functions (토양 수리학적 함수를 이용한 불포화 수리전도도로부터 공극크기분포의 모사)

  • Yoon, Young-Man;Kim, Jeong-Gyu;Shin, Kook-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.4
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    • pp.407-414
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    • 2010
  • Until now, the pore size distribution, PSD, of soil profile has been calculated from soil moisture characteristic data by water release method or mercury porosimetry using the capillary rise equation. But the current methods are often difficult to use and time consuming. Thus, in this work, theoretical framework for an easy and fast technique was suggested to estimate the PSD from unsaturated hydraulic conductivity data in an undisturbed field soil profile. In this study, unsaturated hydraulic conductivity data were collected and simulated by the variation of soil parameters in the given boundary conditions (Brooks and Corey soil parameters, ${\alpha}_{BC}=1-5L^{-1}$, b = 1 - 10; van Genuchten soil parameters, ${\alpha}_{VG}=0.001-1.0L^{-1}$, m = 0.1 - 0.9). Then, $K_s$ (1.0 cm $h^{-1})$ was used as the fixed input parameter for the simulation of each models. The PSDs were estimated from the collected K(h) data by model simulation. In the simulation of Brooks-Corey parameter, the saturated hydraulic conductivity, $K_s$, played a role of scaling factor for unsaturated hydraulic conductivity, K(h) Changes of parameter b explained the shape of PSD curve of soil intimately, and a ${\alpha}_{BC}$ affected on the sensitivity of PSD curve. In the case of van Genuchten model, $K_s$ and ${\alpha}_{VG}$ played the role of scaling factor for a vertical axis and a horizontal axis, respectively. Parameter m described the shape of PSD curve and K(h) systematically. This study suggests that the new theoretical technique can be applied to the in situ prediction of PSD in undisturbed field soil.