• Title/Summary/Keyword: curing temperature and times

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A Study on Vulcanization of EPDM by Far-infrared (원적외선에 의한 EPDM의 가교 특성 연구)

  • Bae, J.W.;Kim, J.S.;Lee, J.H.;Jung, W.S.;Park, H.C.;Kang, D.P.
    • Elastomers and Composites
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    • v.43 no.1
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    • pp.1-7
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    • 2008
  • Far-infrared vulcanization of ethylene-propylene-diene terpolymer(EPDM) compounds has been studied in comparison with hot air vulcanization. Vulcanization characteristics of EPDM compounds were measured by degree of curing and temperature of specimens in vulcanization process. As a result, degree of curing by far-infrared of EPDM compounds was shown to be higher value than that by hot air at the same vulcanization temperature. Especially, degree of curing by far-infrared on 3 mm thickness of EPDM compounds was increased by two times compared to that by hot air. While the increase of thermal conductivity of EPDM compounds highly improved degree of curing by far-infrared, that hardly improved degree of curing by hot air.

Experimental Study of Leaching Phenomena of Cs-137 From a Cement Matrix Generated at PWR Plant (가압 경수로에서 생성된 시멘트 고화체로부터 Cs-137의 용출 현상의 실험적 연구)

  • Doh, Jeong-Yeul;Lee, Kun-Jai
    • Journal of Radiation Protection and Research
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    • v.11 no.2
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    • pp.91-103
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    • 1986
  • Experimental study for the leaching behavior of Cs-137 was carried out using the simulated evaporator bottom product of PWR plant. The method of leach test proposed by the IAEA was partially modified using ANS method. The effect of various factors, i.e., sampling method, curing temperature, curing time, leachant temperature, vermiculite addition and volume-to-surface ratio, was considered in this experiment. Diffusion model in semi-infinite slab was in a good agreement with the data obtained from 4-weeks cured specimens. The effective diffusion coefficient of the specimens which were cured at the temperature of $24^{\circ}C$ for 4 weeks was found to be $1.20{\sim}1.47{\times}10^{-11}cm^2/sec$. With the experimentally obtained diffusion coefficient ($1.47{\times}10^{-11}cm^2/sec$), long-term prediction for the leaching of Cs-137 was carried out using finite-slab approximation. The estimated fraction of Cs-137 which remains in the environment is found to be less than 0.25 percent of initial amount after 100 years. About 25 years after the beginning of leaching, its fractional amount in the environment reachs the maximum value, 0.66 percent of initial amount.

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A Study on the Development of Non-PC High-Early-Strength Concrete Without Steam Curing (증기양생이 불필요한 PC부재용 조강형 콘크리트 개발에 관한 연구)

  • Jun, Woo-Chul;Lee, Ji-Hwan;Park, Hee-Gon;Lee, Jae-Sam;Kim, Kyung-Min;Cho, In-Sung
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.2
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    • pp.156-162
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    • 2014
  • This study aims to develop a rapidly hardening type of concrete to achieve the removal of form intensity (more than 10MPa) using the method of curing at room temperature in order to solve some economic environmental problems by omitting the steam curing process involved in producing PC (Precast Concrete). Therefore, this study evaluated a rapidly hardening cement containing a high amunt of C3S, which is very responsive in expressing early intensity, and a rapidly hardening type of concrete which uses some hardening accelerator to increase thehydration reaction of $C_3S$. The results of the experiment on concrete using some hardening accelerator are asfollows. In the slump flow experiment for identifying the liquidity and the air test, the desired values were met. The compression strength showed rapid expression response by 12 hours, and met the desired value within 6~9 hours. Its drying shrinkage value and Autogenous shrinkage value were measured as below ($-754.5{\times}10^{-6}$),and satisfied the requirements. In addition, in the Semi-Adiabatic Temperature Test, it was found that the concrete rose to its peak temperature within 24 hours and then its temperature dropped.

A Study on the Determination of the Removal Times of Form in Concrete Using Fly Ash Cement (플라이애시 시멘트를 사용한 콘크리트의 거푸집 존치기간 결정에 관한 연구)

  • Shin Byung-Cheol;Han Min-Cehol
    • Journal of Environmental Science International
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    • v.15 no.2
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    • pp.185-191
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    • 2006
  • In this paper, removal time of side form from concrete using OPC(ordinary Portland cement) and FAC(fly ash cement) are proposed by appling logistic model, which evaluates the strength development of concrete with maturity. W/B, types of cement and curing temperatures are adapted as test parameters. The estimation of strength development by logistic model has a good agreement between calculated values and measured ones. As for the removal times of form works suggested in this paper, as W/8 increases, curing temperature decreases and fly ash is used, removal time of side form is prolonged. Removal time of form from concrete using OPC suggested in this paper is shorter $2.5\~3.5$ days than those of KASS-5 (Korean Architectural Standard Specifications-5) in the range of over $20^{\circ}C$. And in the range of $10\~20^{\circ}C$ removal time of form is shorter than that of KASS-5 by as much as $4\~4.5$ days. The use of FAC results in an increase in removal time of form compared to that of OPC by about 1 day.

Thermal cracking assessment for nuclear containment buildings using high-strength concrete

  • Yang, Keun-Hyeok;Mun, Jae-Sung;Kim, Do-Gyeum;Chang, Chun-Ho;Mun, Ju-Hyun
    • Computers and Concrete
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    • v.26 no.5
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    • pp.429-438
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    • 2020
  • To shorten the construction times of nuclear facility structures, three high-strength concrete mixtures were developed with specific consideration given to their curing temperatures, their economic efficiency, and the practicality of their quality control. This study was conducted to examine the temperature rise profiles of these three concrete mixtures and the potential for early-age thermal cracking in the primary containment vessel of a nuclear reactor with a wall thickness of 1200 mm. The one-layer placement height of the concrete for the primary containment vessel was increased from the conventional 3 m to 3.5 m. A nonlinear finite element analysis (FEA) was conducted using the thermal properties of concrete determined from the isothermal hydration and adiabatic hydration tests, and tuned through comparisons made with temperature rise profiles obtained for 1200-mm-thick mock-up wall specimens cured at temperatures of 5, 20, and 35℃. The hydration heat performance of the three concrete mixtures and their potential to produce thermal cracking in nuclear facilities indicate that the mixtures have considerable potential for practical application to the primary containment vessel of a nuclear reactor at various curing temperatures, fulfilling the minimum requirements of the ACI 301 and minimizing the likelihood of the occurrence of thermal cracks.

Evaluation of Adhesion Property with Pot Life and Curing Humidity of GFRC and Epoxy Adhesive (유리섬유강화 복합재료와 에폭시 접착제의 가사시간과 경화습도에 따른 접착 강도 평가)

  • Yoo, Ji-Hoon;Shin, Pyeong-Su;Kim, Jong-Hyun;Lee, Sang-Il;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.21 no.2
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    • pp.65-70
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    • 2020
  • Epoxy adhesive was mainly used to combine different composite materials. Epoxy adhesive was a typical thermosetting resin that can be bonded by changing from a linear structure to a three-dimensional network structure by curing reaction of epoxy and hardener. The curing conditions of epoxy adhesive were different with different types of hardener such as mixing ratio, curing time, and temperature. These curing conditions affected to the adhesive property of epoxy adhesive. In industry, it was difficult to proceed the applying epoxy adhesive and combining two parts immediately. The adhesive property decreased by humidity and pre-curing of epoxy adhesive in waiting time between two processes. In this paper, the glass fiber reinforced composite (GFRC) was combined with epoxy adhesive and adhesion property between epoxy adhesive and GFRCs was evaluated using single lap shear test. The different waiting times and humidity conditions were applied to epoxy adhesive in room temperature and adhesive property decreased as the waiting time increased. In small amount of humidity, the adhesive property increased because a small amount of moisture in the surroundings accelerated the curing reaction. In certain amount of humidity, however, the adhesion property decreased.

Laboratory investigation for engineering properties of sodium alginate treated clay

  • Cheng, Zhanbo;Geng, Xueyu
    • Structural Engineering and Mechanics
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    • v.84 no.4
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    • pp.465-477
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    • 2022
  • The formation of biopolymer-soil matrices mainly depends on biopolymer type and concentration, soil type, pore fluid and phase transfer to influence its strengthening efficiency. In this study, the physical and mechanical properties of sodium alginate (SA) treated kaolinite are investigated through compaction test, thread rolling teat, fall cone test and unconfined compression test with considering biopolymer concentration, curing time, initial water content, mixing method. The results show that the liquid limit slightly decreases from 69.9% to 68.3% at 0.2% SA and then gradually increases to 98.3% at 5% SA. At hydrated condition, the unconfined compressive strength (UCS) of SA treated clay at 0.5%, 1%, 2% and 3% concentrations is 2.57, 4.5, 7.1 and 5.48 times of untreated clay (15.7 kPa) at the same initial water content. In addition, the optimum biopolymer concentration, curing time, mixing method and initial water content can be regarded as 2%, 28 days, room temperature water-dry mixing (RD), 50%-55% to achieve the maximum unconfined compressive strength, which corresponds to the UCS increment of 593%, compared to the maximum UCS of untreated clay (780 kPa).

Studies on the Synthesis of Diphenyl-2-Ethanolamidophosphate (DPEOAP) and Flame Retardancy Effect of DPEOAP on polyester Fabrics (Diphenyl-2-ethanolamidophosphate의 합성과 폴리에스테르 직물에 대한 방염성에 관한 연구)

  • Lee, Kwang-woo;Kim, Young-Man
    • Fashion & Textile Research Journal
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    • v.2 no.2
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    • pp.123-131
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    • 2000
  • Diphenyl-2-ethanolamidophosphate (DPEOAP) was synthesized to treat polyester fabrics in order to improve its flame retardancy. The flame retardancy and physical properties of DPEOAP-treated polyester fabrics were investigated. The results were as follows: 1) polyester fabrics can be treated with DPEOAP by means of Pad-Dry-Cure method, because DPEOAP was easily soluble in benzene. 2) The most economic conditions of treatment were determined as 10% of DPEOAP cocentration, $140^{\circ}C$ of curing temperature, and 2 minutes of curing time. 3) Though the washablity of DPEOAP is low in comparison with the other products which are purchasable in a market, it has an excellent flame retardment effect 3 times more than in number of flame contact just with 0.66% add-on. 4) The physical properties of DPEOAP treated polyester fabrics were little changed as compared with non-treated fabric.

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A STUDY ON THE TENSILE BOND STRENGTH TO TOOTH STRUCTURE OF TOOTH COLORED MATERIALS ACCORDING TO FILLING METHODS AND LIGHT CURING UNITS (심미수복재의 수복방법과 광조사기기에 따른 치질과의 인장결합강도에 관한 연구)

  • Hwang, Ho-Keel;Kim, Young-Kwan;Oh, Haeng-Jin
    • Restorative Dentistry and Endodontics
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    • v.21 no.2
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    • pp.652-663
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    • 1996
  • The purpose of this study was to evaluate the tensile bond strength to tooth structure of composite resin and glass ionomer cement according to filling methods and light curing units. In this study, two class V cavities were prepared on the buccal surface of each tooth of 140 extracted human molars, and they were randomly assigned into 3 experimental groups with 40 teeth and control group with 20 teeth. And then, each experimental groups subdivided into 2 groups(A,B) according to light curing units. The cavities of each group were filled with the CLEARFIL FII self curing resin(Control Group), Z-100 light curing resin(Group 1), Vitremer$^{TM}$ light curing glass ionomer cement(Group 2) and Z-100 light curing resin over the Vitrebond$^{TM}$ liner(Group 3). And subdivided A Group used Argon Laser(SPECTRUM$^{TM}$, U.S.A.), B Group used XL 1,000 curing light (3M, U.S.A.). The specimens underwent temperature changed from $5^{\circ}C$ to $55^{\circ}C$ five hundred times. After thermocycling, specimens were stored in 100% relative humidity at $37^{\circ}C$ for 24 hours. And then, the tensile bond strength of specimens were calculated with Universal Testing Machine(AGS-100A, Japan). The results were as follows : 1. Among the experimental groups, the group 2-B showed the highest tensile bond strength ($18.89{\pm}7.80$) and the group 1-A showed the lowest tensile bond strength ($11.68{\pm}2.28$). There was significant difference between group 2-B and group 1-A(p<0.01). 2. Between the light curing units, the XL 1,000 unit showed higher tensile bond strength ($16.63{\pm}3.20$) than that of the Argon Laser unit ($13.73{\pm}2.30$). There was significant difference between XL 1,000 and Argon Laser(p<0.01). 3. About filling methods and materials, the group 2 showed the highest tensile bond strength ($17.56{\pm}1.89$) and the group 1 showed the lowest tensile bond strength($13.03{\pm}1.90$). There was significant difference between group 2 and group 1,3(p<0.01). In conclusion, the results showed that the glass-ionomer cement that cured by XL 1,000 light curing unit demonstrated significantly higher tensile bond strength than other curing unit and filling methods.

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Electrical Properties and Preparation of 6FDA/4-4'DDE Polyimide Thin Films by Vapor Deposition Polymerization Method (진공증착중합법을 이용한 6FDA/4-4'DDE 폴리이미드 박막의 제조와 전기적 특성)

  • Hwang, S.Y.;Lee, B.J.;Kim, H.G.;Kim, Y.B.;Park, K.S.;Lim, H.C.;Kang, D.H.;Park, K.H.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1487-1489
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    • 1998
  • In this paper, thin films of PI were fabricated VDPM of dry processes which are easy to control the film's thickness and hard to pollute due to volatile solvents. From FT-lR, PAA thin films fabricated by VDP were changed to PI thin films by thermal curing. From SEM, AFM and Ellipsometer experimental, as the higher curing temperatures the films thickness decreases and reflectance increases. Therefore, Pl could be fabricated stable by increasing curing temperature. The relative permitivity and dissipation loss factor were 3.7 and 0.008. Also, the resistivity was about $1.05{\times}10^{15}{\Omega}cm$ at $30^{\circ}C$.

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