• 콘크리트학회논문집
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• 제12권5호
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• pp.25-34
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• 2000

When concrete is placed underwater, it is diluted with separating cementitious material and as a result the quality of concrete becomes poor. To solve this problem, antiwashout underwater concrete is increasingly used for the construction and repair of the concrete structure underwater. The objective of this study is to investigate the characteristics of antiwashout underwater concrete as to the mix proportion, casting and curing water through experimental researches. The unit weight of water and cement, water-cement ratio, fine aggregate ratio, unit weight of antiwashout underwater agent and superplasticizer, and casting and curing water were chosen to measure the suspended solids, pH, air contents, slump flow, unit weight of hardened concrete, and compressive strength. From this study, the incremental modulus at mix proportion design and unit weight of antiwashout underwater agent were increased more than fresh water, and it is a optimum mix proportion that the unit weight of water(and cement) is 230kg/$\textrm{m}^3$(460kg/$\textrm{m}^3$), waterOcement ratio is 50%, fine aggregate ratio is 40%, unit weight of antiwashout underwater agent is 1.2% of water contents per unit weight of concrete, and unit weight of supeplasticizer is 2.5% of cement contents per unit weight of concrete when the antiwashout underwater concrete is used for the underwater work of ocean.

• 한국응용과학기술학회지
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• 제18권2호
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• pp.153-159
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• 2001

Due to its low density, good mechanical properties and chemical inertness, glassy carbon(GC) has been studied for appications in several fields. A raw thermosetting resin of furanic resin was polymerized with a curing agent of p-toluenesulfonic acid monohydrate. The maximum yield of GC was obtained at the curing agent content of 1.0 wt% in furanic resin. In order to make thick GC, the affect of graphite filler addition to the furanic resin was investigated. The density and electrical resitivity of GC after graphitization were 1.45 $g/cm^{3}$ and 47 ${\times}10^{-4}$ ${\Omega}$ ${\cdot}$ cm respectively and the amorphous structure of GC was confirmed by XRD profiles with very broad peaks comparable to those of graphite at $206^{\circ}$ and $45^{\circ}$.

• 접착 및 계면
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• 제11권2호
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• pp.63-69
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• 2010

본 연구는 2-EHA (2-ethyl hexyl acrylate), 2-EHMA (2-ethyl hexyl methacrylate), 2-HEA (2-Hydroxy ethyl acrylate), acrylic acid 모노머를 이용하여 hydroxy기를 가진 아크릴 수지 점착제를 합성한 후 MOI (Methacryloyloxyethyl isocyanate) 또는 2-isocyanatoethyl methacrylate의 투입량 조절을 통한 경화특성을 향상시킬 수 있는 adduct 반응을 시킨 이소시아네이트 변성 아크릴 수지 점착제를 제조하였다. 시험 결과 초기 점착력과 박리 접착강도는 MOI와 가교제인 isocyanate의 양이 증가할수록 감소하였다. UV 조사후, MOI와 가교제인 isocyanate의 양이 증가할수록 높은 경화특성 때문에 박리접착 강도는 좀 더 낮아지는 결과를 가져왔다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2004년도 학술.기술논문발표회
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• pp.1-4
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• 2004

In this paper. applicability of high early strength type AE water reducing agent(HESAEWA) developed by the authors is discussed by applying Mock-up test. For fresh concrete properties, concrete using existing AE water reducing agent(EAEWRA) and HESAEW A meets the target slump and air content at jobsite. Setting time of concrete using HESAEWA is shorter than that using EAEWRA. Remarkable variance of bleeding and settlement is not observed with type of AE water reducing agent. For hardened concrete properties, use of HESAEW A results in higher strength development compared with that of EAEWRA at standard curing and in field curing condition. Reaching time to accomplish 5MPa of compressive strength. which is possible to remove side form. is taken using HESAEWA earlier than that of EAEWRA by 1day. Therefore, it is confirmed that use of HESAEWA can meet the requirements of general quality of concrete and achieve high early strength development as well as has a desirable field applicability.

• 한국염색가공학회지
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• 제30권3호
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• pp.180-189
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• 2018

To study the effect of stereoisomeric structures of curing agents on curing behaviors, thermal and mechanical properties of epoxy resins, DGEBA(diglycidyl ether of bisphenol A) epoxy resin and 3,3'- and 4,4'-DDS(diaminodiphenyl sulfone) curing agents were selected. The curing initiation temperature and activation energy of DGEBA/3,3'-DDS was lower than DGEBA/4,4'-DDS. DGEBA/3,3'-DDS has a faster curing rate and higher degree of cure than DGEBA/4,4'-DDS, suggesting that 3,3'-DDS has higher reactivity than 4,4'-DDS. Tensile strength and fracture toughness of DGEBA/3,3'-DDS was lower than those of DGEBA/4,4'-DDS, indicating that mechanical properties of the epoxy resin can be different only by the stereoisomeric difference in chemical structure of the curing agent.

• 한국추진공학회지
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• 제20권1호
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• pp.37-42
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• 2016

본 연구에서는 HTPB를 적용한 고체추진제의 공정간 검사를 위해 경화제를 넣기 전과 넣은 후의 미 경화 추진제의 연소속도를 검토하였다. 그리고 경화제를 넣기 전 미 경화 추진제의 연소속도는 압력 1000 psi에서 약 9.7 mm/s 정도이며, 시간에 따른 연소속도 변화는 없었다. 경화제가 들어간 미 경화 추진제의 연소속도는 약 8.1 mm/s로 시간에 따라 느려지는 경향을 보였다. 경화반응 속도가 느린 미 경화 추진제는 시간에 따라 연소속도가 서서히 느려졌으며, 경화반응 속도가 빠른 미 경화 추진제는 연소속도가 빠르게 느려지는 것을 확인할 수 있었다. 그리고 완전히 경화된 추진제의 연소속도는 약 6.8 mm/s 정도로 가장 느린 것으로 나타났다.

• 접착 및 계면
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• 제18권4호
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• pp.166-170
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• 2017

본 연구에서는 2-ethylhexyl acrylate, styrene, butadien, 2-hydroxyethyl acrylate, acrylic acid 등의 단량체 조성과 개시제 함량을 조절하여 아크릴고무 점착제를 합성하였다. 제조된 점착제를 이용하여 점착부여제와 경화제를 변화시켜 초기점착력, 점착력, 유지력, 그리고 내열성을 측정함으로써 그 영향을 조사하였다. 실험 결과 개시제의 함량이 증가하면 분자량이 감소하여 초기점착력과 점착력이 증가하였으나, 유지력과 내열성은 감소하는 것을 확인 할 수 있었다. 점착부여제에 따른 물성 변화는 점착부여제의 함량을 높일수록 일정 수준까지는 점착력이 높아 졌으나, 초기점착력과, 유지력, 내열성에서는 함량변화에 따른 물성변화가 크지 않았다. 경화제 함량에 따른 물성 변화는 경화제의 함량을 높일수록 경화밀도가 증가하여, 초기점착력과 점착력은 감소하였고 반면에 유지력과 내열성은 높아지는 경향을 나타내었다.

• 품질경영학회지
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• 제16권1호
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• pp.43-48
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• 1988

Most of silicone used for water repellent finish is MHP (methyl hydrodiene polysiloxane), which is formed by hydrolysis and condensation polymerization of MHD (methyl hydrodiene dichlorosilane: Me H Si $Cl_2$). The cross-linking theory explains the water repellent mechanism of MHP. The silicone finish on fiber could improve in handle, softness, abrasion resistance, soil repellency, tear strength and crease resistance, as well as water repellency. According to using method silicone-water repellent finishing agents, could be devided into air dry type and curing type. MHP is the typical curing type of water repellent finishing agent, and this type requires the curing temperature above $150^{\circ}C$ at least. High curing temperature is the very drawback of this curing type. For this reason, there has been global interest in the lowering of its temperature. The objective of this study is to investigate merits of alkali treatment for silicone finishing by ANOVA and LSD (least significant difference).

• 대한토목학회논문집
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• 제35권2호
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• pp.465-470
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• 2015

에폭시 아스팔트 혼합물은 에폭시 수지와 경화제의 화학반응이 진행되어 양생시간을 거쳐 성능 발현이 이루어진다. 에폭시 아스팔트의 양생수준은 후속공정의 진행과 교통개방 및 공정계획의 수립에 절대적인 영향을 미치므로 정확한 예측모델의 개발이 중요하다. 본 연구에서는 기존 예측식에 사용되는 인자들의 화학적 의미 분석을 통하여 에폭시 수지의 농도와 경화특성을 반영하여 기존식보다 확대된 적용 범위를 갖는 양생수준 예측식을 제시하였다. 실외양생 실험과 비교 결과 상관계수가 0.971 이상으로 나타나 조성이 다른 에폭시 아스팔트 혼합물의 온도와 시간에 따른 양생수준을 예측할 수 있는 것으로 나타났다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2020년도 가을 학술논문 발표대회
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• pp.127-128
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• 2020

This research is part of the research for unifying the mass concrete and utilizing the rate of super retarding agent. We analyzed the performance of super retarding agent 20℃ conditions. It was found that there was no deterioration in fluidity and air quality due to the change in the super retarding agent mixing rate. It was found that when super retarding agent was mixed up to 0.5 %, it was delayed for 22.3 hours at 20℃. Therefore in order to ensure the performance required at the site, the super retarding agent mixing rate must be determined by fully considering the situation at the site. In addition it will be analyzed that super retarding agent performance analysis at high temperature will be required in subsequent studies.