• Title/Summary/Keyword: crystalline temperature

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Study on the Influence of Cubic Liquid Crystalline Phases of Monoolein on the Stability and Transdermal Delivery of Retinylpalmitate (Monoolein액정상이 Retinylpalmitate의 안정성과 경피전달에 미치는 효과에 관한 연구)

  • Lee, Kyoung-Gum;Kang, Myung-Joo;Choi, Young-Wook;Lee, Jae-Hwi
    • Journal of Pharmaceutical Investigation
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    • v.37 no.4
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    • pp.243-247
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    • 2007
  • Retinoids have many important and diverse functions and particularly, have been widely used as anti-aging agent and for the treatment of acne and psoriasis in cosmetics. However, retinoids have low stability against the air, light, water, oxygen and heat, thus, to stabilize the retinoids in formulations is very critical procedure. In this study, cubic liquid crystalline phase of monoolein was applied to stabilize the retinylpalmitate (RP) and to enhance the transdermal permeation. Cubic liquid crystalline phase significantly enhanced the stability of RP. After 15 days, the content of RP in the cubic formulation was 94.7% while the content of RP in ethanol solution was below 0.5% at room temperature. Although BHT containing crystalline phase showed the slightly increased stability of RP, there were no significant differences in RP stability between with or without antioxidants (ascorbic acid, ${\alpha}$-tocopherol, BHT, BHA) at $40^{\circ}C$. The skin retention of RP in crystalline formulations was approximately $5.3{\sim}6.4$ times greater than that of o/w cream formulation. Incorporation of RP into cubic liquid crystalline phase of monoolein effectively stabilized the RP and worked as excellent topical vehicle for RP. Liquid crystalline phase is considered to be suitable formulation for RP for topical delivery system as a stabilizer and permeation enhancing agent.

A Study of Nucleation and Growth in Zinc Crystal Glaze by Firing Conditions (아연결정유의 제조에 있어서 소성조건에 따른 결정생성과 성장에 관한 연구)

  • Lee, Chi-Youn;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.253-262
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    • 2009
  • The purpose of this study is to find out optimum conditions for zinc crystalline glaze under variables of firing: maximum firing temperature, crystal growth temperature, temperature increasing speed, annealing speed, holding time at maximum temperature and holding time at crystal growth temperature. Ferro Frit3110, ZnO and Quartz were used as starting materials and tested by three component system. The best result of test was selected and extended to its vicinity as five glaze formulas. And then the specimens were experimented by variable firing conditions and analyzed by crystal appearance observation, XRD, FT-IR and Raman spectroscopy. In result, main crystal was willemite in the zinc glazes. Some gahnite was detected in specimens which were fired at $1230^{\circ}C$, $1250^{\circ}C$ and $1270^{\circ}C$, however gahnite was not identified at $1300^{\circ}C$. Optimum zinc crystalline glaze was gained by following firing condition: temperature increasing speed $5^{\circ}C$/min, holding 1 h at $1270^{\circ}C$, annealing speed $3^{\circ}C$/min till $1170^{\circ}C$, holding 2 h at $1170^{\circ}C$ then naturally annealed.

Structural and Electrical Characteristics of IGZO Thin Films Deposited at Different Substrate Temperature and Hydrogen Flow Rate (증착 온도 및 수소 유량에 따른 IGZO 박막의 구조적 및 전기적 특성)

  • Park, Su Jin;Lee, Kyu Mann
    • Journal of the Semiconductor & Display Technology
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    • v.15 no.4
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    • pp.46-50
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    • 2016
  • In this study, we have investigated the effect of the substrate temperature and hydrogen flow rate on the characteristics of IGZO thin films for the TCO(transparent conducting oxide). For this purpose, IGZO thin films were deposited by RF magnetron sputtering at room temperature and $300^{\circ}C$ with various $H_2$ flow rate. In order to investigate the influences of the hydrogen, the flow rate of hydrogen in argon mixing gas has been changed from 0.1sccm to 1.0sccm. IGZO thin films deposited at room temperature show amorphous structure, whereas IGZO thin films deposited at $300^{\circ}C$ show crystalline structure having an (222) preferential orientation. The electrical resistivity of the amorphous-IGZO films deposited at R.T. was lower than that of the crystalline-IGZO thin films deposited at $300^{\circ}C$. The increase of electrical resistivity with increasing substrate temperature was interpreted in terms of the decrease of the charge carrier mobility. The transmittance of the IGZO films deposited at $300^{\circ}C$ was decreased deposited with hydrogen gas.

Layout of Long-pass-edge Filter Correspond with the Optical Transmission in Crystalline (수정체 광투과에 대응하는 LPE Filter 설계)

  • Kim, YongGeun
    • Journal of Korean Ophthalmic Optics Society
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    • v.4 no.2
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    • pp.57-63
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    • 1999
  • The optical absorption and transmittance of cow' crystalline were measured by spectrophotometer in the 200~800nm wavelength regions. The optical absorptions of crystalline composed of a high absorption band in the UV-A, UV-B, and appeared the light transmittance edge in the 400nm wavelength region, and completely transmitted without the absorption in the high wavelength regions than 400nm. Also, the optical absorption and transmittance had no temperature dependence. The optical transmittance spectrum of crystalline concord with the thin film structure of $n_0/(0.5H)L(LH)^6(0.5H)/n_s$ and $n_0{\mid}(0.5LH0.5L)^kL/1.25{\mid}4.0$ of long-pass edge filter form. In the artificial crystalline and inter lens layout, long-pass edge filter layout can UV cut off.

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Synthesis and Optoelectronic Characteristics of Single-crystalline Si Nanowires

  • Kim, Kyung-Hwan;Keem, Ki-Hyun;Kang, Jeong-Min;Yoon, Chang-Joon;Jeong, Dong-Young;Min, Byung-Don;Cho, Kyoung-Ah;Kim, Hyun-Suk;Kim, Sang-Sig
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.5
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    • pp.198-201
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    • 2005
  • Photocurrent of a single-crystalline Si nanowire is investigated in this paper. Single-crystalline Si nanowires with amorphous $SiO_2$ shells were first synthesized from ball-milled SiO powders by thermal chemical vapor deposition, and then the amorphous $SiO_2$ shells were etched out from the as-synthesized Si nanowires. For a single-crystalline Si nanowire, photocurrent-voltage curves taken in air at room temperature were non-linear, and rapid photoresponses were observed when the light was switched on and off. The photocurrent was not changed in intensity under the illumination. Photocurrent mechanism in the single-crystalline Si nanowire is discussed in this paper.

Synthesis and photoresponse characteristics of single-crystalline Si nanowires (단일 Si 나노선 합성 및 광특성 연구)

  • Kim, Kyung-Hwan;Keem, Ki-Hyun;Kang, Jeong-Min;Yoon, Chang-Joon;Jeong, Dong-Young;Min, Byung-Don;Cho, Kyoung-Ah;Kim, Hyun-Suk;Kim, Sang-Sig
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.81-83
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    • 2005
  • Photocurrent of a single-crystalline Si nanowire is investigated in this paper. Single-crystalline Si nanowires with amorphous $SiO_2$ shells were first synthesized from ball-milled SiO powders by thermal chemical vapor deposition, and then the amorphous $SiO_2$ shellswere etched out from the as-synthesized Si nanowires. For a single-crystalline Si nanowire, photocurrent-voltage curves taken in air at room temperature were non-linear, and rapid photoresponses were observed when the light was switched on and off. The photocurrent was not changed in intensity under the illumination. Photocurrent mechanism in the single-crystalline Si nanowire is discussed in this paper.

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Controlling Size, Shape and Polymorph of TiO2 Nanoparticles by Temperature-Controlled Hydrothermal Treatment

  • Kwon, Do Hun;Jung, Young Hee;Kim, Yeong Il
    • Journal of the Korean Chemical Society
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    • v.59 no.3
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    • pp.238-245
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    • 2015
  • The crystallization and morphology change of amorphous titanias by hydrothermal treatment have been investigated. The amorphous titanias were prepared by pure water hydrolysis of two different precursors, titanium tetraisopropoxide (TTIP) and TTIP modified with acetic acid (HOAc) and characterized prior to hydrothermal treatment. In order to avoid complicate situation, the hydrothermal treatment was performed in a single solvent water with and without strong acids at various temperatures. The effects of strong acid, temperature and time were systematically investigated on the transformation of amorphous titania to crystalline TiO2 under simple hydrothermal condition. Without strong acid the titanias were transformed into only anatase phase nanoparticle regardless of precursor type, temperature and time herein used (up to 250 ℃ and 48 hours). The treatment temperature and time effected only on the crystalline size, not on the crystal phase et al. However, it was clearly revealed that the strong acids such as HNO3 and HCl catalyzed the formation of rutile phase depending on temperature. HCl was slightly better than HNO3 in this catalytic activity. The morphology of rutile TiO2 formed was also a little affected by the type of acid. The precursor modifier, HOAc slightly reduced the catalytic activity of the strong acids in rutile phase formation.

Effects of the Substrate Temperature on the Properties of Ni-Zn-Cu Ferrite Thin Films Deposited by RF Magnetron Sputtering (RF Magnetron Sputtering에 의해 증착된 Ni-Zn-Cu Ferrite 박막의 물성에 미치는 기판온도의 영향)

  • 공선식;조해석;김형준;김경용
    • Journal of the Korean Ceramic Society
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    • v.29 no.5
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    • pp.383-390
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    • 1992
  • We investigated the effect of substrate on the properties of the Ni-Zn-Cu ferrite thin films deposited on SiO2 (1000∼3000${\AA}$) / Si (100) substrate at various conditions by rf magnetron sputtering. A disktype Ni-Zn-Cu ferrite sintered by conventional ceramic process and argon gas were used as a target and a sputtering gas, repectively. The compositions of the thin films measured by EPMA were similar to target composition (Fe: 65.8 at%, Ni: 12.7 at%, Cu: 6.7 at%, Zn: 14.8 at%) irrespective of substrate temperature. Amorphous thin films were deposited when substrate was not intentionally heated, but the films came to crystallize with increasing substrate temperature, and crystalline thin films were deposited at substrate temperature above 200$^{\circ}C$. Below 250$^{\circ}C$ saturation magnetization (Ms), remanence (Mr) and coercivity (Hc) of the ferrite thin film increased with the substrate temperature due to the increase of grain size and the improvement of crystallinity. And above 250$^{\circ}C$, Ms, Mr increased slightly, but Hc of the amorphous thin films increased due to crystallization, whereas that of the crystalline thin films decreased because of grain growth and stress release.

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A Study on Correlation between Improvement in Efficiency of PV and Green roof of Public Building (공공건물 옥상녹화와 설치태양광(PV)의 효율향상 상관관계 연구)

  • Lee, Eung Jik
    • KIEAE Journal
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    • v.13 no.5
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    • pp.111-118
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    • 2013
  • This study aims to investigate advantages of complex installation of green roof and PV system in a public building, to analyze the impact of green roof on the efficiency of PV power generation, and to consider the correlation between green roof and PV power generation. When the temperature and power generation of the modules installed in the green roof and non-green roof of the public building were measured for 3 days, the average temperature of the green roof was 23.6 degrees, and it was 36.1 degrees in the non-green roof which increased by nearly 53%. Overall, the module temperature in the green roof was lower. On the other hand, in relation to the PV generation depending on temperature reduction during the same period, the mono-crystalline module and the poly-crystalline module in the green roof showed an increase in generation at nearly 222.2W and 341.6W, and the efficiency rose by 5.5% and 6.2%, respectively, compared to the modules in the non-green roof. Therefore, it is analyzed that green roof has a positive influence on PV power generation. Finally shows the efficiency of the installed on the Green Roof PV system (complex Installation) higher than on the concrete roof PV system. Thus, the complex PV systems as well as the usual benefits of green roofs will provide greater synergies.

Roof-attached Crystalline Silicon Photovoltaic Module's Thermal Characteristics (지붕 설치형 결정질 실리콘 태양전지모듈의 온도 특성)

  • Kim, Kyung-Soo;Kang, Gi-Hwan;Yu, Gwon-Jong;Yoon, Soon-Gil
    • Journal of the Korean Solar Energy Society
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    • v.32 no.3
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    • pp.11-18
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    • 2012
  • To expect accurately the maximum power of solar cell module under various installation conditions, it is required to know the performance characteristics like temperature dependence. Today, the PV (photovoltaic) market in Korea has been growing. Also BIPV (building integrated photovoltaic) systems are diversified and become popular. But thermal dependence of PV module is little known to customers and system installers. In IEC 61215,a regulation for testing the crystalline silicon solar cell module, the testing method is specified for modules. However there is limitation for testing the module with diverse application examples. In extreme installation method, there is no air flow between rear side of module and ambient, and it can induce temperature increase. In this paper, we studied the roof type installation of PV module on the surface of one-axis tracker system. We measured temperature on every component of PV module and compared to open-rack structure. As a result, we provide the foundation that explains temperature characteristics and NOCT (nominal operation cell temperature) difference. The detail description will be specified as the following paper.