• Progress in Superconductivity and Cryogenics
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• v.3 no.1
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• pp.69-73
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• 2001

For developing the cryogenic air separation unit, it requires some technology such as basic process design. equipment design and manufacturing based on the cryogenic physical properties and separation theory. In this study, we developed a process and equipment for producing high purity nitrogen which has the production capacity of 1600N㎥/h under 1 ppm $O_2$ and $H_2O$. Also we found that the number of theoretical plate(NTP) of distillation column was 44 and maximum nitrogen recovery ration of this process was 42% from the process simulation. The performance test was also carried out for the nitrogen recovery ratio and equipment efficiency. The results showed that the optimum nitrogen recovery was 41% and the maximum equipment efficiency was attained.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2001.02a
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• pp.132-135
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• 2001

Cryogenic air separation unit(ASU) was developed about 100 year ago in Europe. However, because there is not any ability of process design or manufacturing of ASU in Korea, many ASUs come from advanced countries every year. The purpose of this study is the development of cryogenic air separation unit by our own ability, especially cold box for nitrogen production. On this study, we developed the computer program for physical properties of gases and process simulation. We also did process design and manufactured of cold box, including air separation column, liquid air heat exchanger and condenser. The result of cold box test was successful.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.3
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• pp.322-327
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• 2020

In this work, a study for the reduction of the electric power consumption has been estimated in main air compressors in the air separation unit through cryogenic distillation columns with PRO/II with PROVISION V10.2 at AVEVA company. Both required LNG mass flow rate and cold heat contained in 1 ton of LNG were also predicted using Peng-Robinson equation of state with Twu's new alpha function. Through this work, we concluded that 32.33-48.69% of electric power could be saved by using LNG cold heat.

• Progress in Superconductivity and Cryogenics
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• v.4 no.1
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• pp.145-150
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• 2002

The distillation column is one of large energy consumable units in the cryogenic air separation process and the accurate energy analysis of this unit is necessary for choice of energy saving process. In this work, the energy method was adopted for energy analysis of a cryogenic nitrogen distillation column. In order to designing the energy saving distillation column, the exergy distribution of feed air, exergy efficiency and exergy loss for process condition was investigated and the optimal process condition to minimize the exergy loss was found. The result from this work can be used as a guideline for the choice of the process design conditions and efficiency improvement of cryogenic distillation column.

• 한국가스학회:학술대회논문집
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• 1997.09a
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• pp.223-228
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• 1997

• 한국가스학회:학술대회논문집
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• 1998.09a
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• pp.3-8
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• 1998

• 한국가스학회:학술대회논문집
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• 2000.09a
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• pp.157-162
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• 2000

• Membrane Journal
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• v.6 no.3
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• pp.117-126
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• 1996

Membrane-based gas separation systems are now widely accepted and employed as unit operation in industrial gas, chemical, and allied industries. Following their successful commercialization in the late seventies to recover hydrogen from ammonia purge gas streams, membrane-based systems have gained acceptance in a wide variety of applications. Numerous systems are in operation today to: recover hydrogen from other purge gas and hydrocarbon streams; adjust the $H_{2}/CO$ ratio in syngas; remove $CO_{2}$ from natural gas; recover helium; dry gas streams; and separate air. Lower cost, ease of operation, operational flexibility and portability are a few of the reasons membrane-based systems are chosen over absorption and cryogenic-based separations in certain applications.

• Journal of the Korean Institute of Gas
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• v.1 no.1
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• pp.41-48
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• 1997

The equation of state is widely utilized as a simple model for the prediction of gas properties. There are several equations of state and they often make diverse and hard to believe output of gas properties. In this study, We show a reliability of equation of state for nitrogen, oxygen and argon in pressure range from 1 bar to 30 bar and temperature range from liquefaction to room temperature. We use three equations of state such as Soave-Redlich-Kwong, Peng-Robinson and BWR-LS' equation of state which provided in the Aspen plus. The results were compared with literatures and virial equation. Finally, We report the differences of process calculation of distillation column and expansion turbine in cryogenic air separation plant with change of equation of state.

• Korean Chemical Engineering Research
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• v.56 no.5
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• pp.647-654
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• 2018

In order to solve the global warming and reduce greenhouse gas emissions, it has been developed the $CO_2$ capture technology by oxy-fuel combustion. But there is a problem that the economic efficiency is low because the oxygen production cost is high. ASU (Air Separation Unit) is known to be most suitable method for producing large capacity of oxygen (>2,000 tpd). But most of them are optimized for high purity (>99.5%) oxygen production. If the ASU process is optimized for low purity(90~97%) oxygen producing, it is possible to reduce the production cost of oxygen by improving the process efficiency. In this study, the process analysis and comparative evaluation was conducted for developing large capacity ASU for oxy-fuel combustion. The process efficiency was evaluated by calculating the recovery rate and power consumption according to the oxygen purity using the AspenHysys. As a result, it confirmed that the optimal purity of oxygen for oxyfuel combustion is 95%, and the power consumption can be reduced by process optimization to 12~18%.