• Carbon letters
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• v.6 no.2
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• pp.106-110
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• 2005

In this work, the effects of atmospheric oxygen plasma treatment of carbon fibers on mechanical interfacial properties of carbon fibers-reinforced epoxy matrix composites was studied. The surface properties of the carbon fibers were determined by acid/base values, Fourier-transform infrared spectrometer (FT-IR), and X-ray photoelectron spectroscopy (XPS) analyses. Also, the crack resistance properties of the composites were investigated in critical stress intensity factor ($K_{IC}$), and critical strain energy release rate mode II ($G_{IIC}$) measurements. As experimental results, FT-IR of the carbon fibers showed that the carboxyl/ester groups (C=O) at 1632 $cm^{-1}$ and hydroxyl group (O-H) at 3450 $cm^{-1}$ were observed for the plasma treated carbon fibers, and the treated carbon fibers had the higher O-H peak intensity than that of the untreated ones. The XPS results also indicated that the $O_{1S}/C_{1S}$ ratio of the carbon fiber surfaces treated by the oxygen plasma led to development of oxygen-containing functional groups. The mechanical interfacial properties of the composites, including $K_{IC}$ (critical stress intensity factor) and $G_{IIC}$ (critical strain energy release rate mode II), were also improved for the oxygen plasma-treated carbon fibersreinforced composites. These results could be explained that the oxygen plasma treatment played an important role to increase interfacial adhesions between carbon fibers and epoxy matrix resins in our composite system.

• Steel and Composite Structures
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• v.25 no.6
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• pp.639-648
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• 2017

Fracture energy values KV have been measured on cast steel, used in the container manufacture, by instrumented Charpy impact testing. This material has a large ductility on the upper transition region at $+20^{\circ}C$ and a ductile tearing with an expended plasticity before a brittle fracture on the lower transition region at $-20^{\circ}C$. To assess the fracture toughness of this material we use, the $K_{IC}$-KV correlations to measure the critical stress intensity factor $K_{IC}$ on the lower transition region and the dynamic force - displacement curves to measure the critical fracture toughness $J{\rho}_C$, the essential work of fracture ${\Gamma}_e$ on the upper transition region. It is found, using the $K_{IC}$-KV correlations, that the critical stress intensity factor $K_{IC}$ remains significant, on the lower transition region, which indicating that our testing material preserves his ductility at low temperature and it is apt to be used as a container's material. It is, also, found that the $J_{\rho}-{\rho}$ energetic criterion, used on the upper transition region, gives a good evaluation of the fracture toughness closest to those found in the literature. Finally, we show, by using the ${\Gamma}_e-K_{IC}$ relation, on the lower transition region, that the essential work of fracture is not suitable for the toughness measurement because the strong scatter of the experimental data. To complete this study by a numerical approach we used the ANSYS code to determine the critical fracture toughness $J_{ANSYS}$ on the upper transition region.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2003.04a
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• pp.180-183
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• 2003

In this work. a potential inexpensive epoxy resin. epoxidized soybean oil (ESO) was synthesized and applied as a toughening agent for 4.4'-tetradiglycidyl diaminodiphenyl methane (TGDDM). The chemical structure of ESO was characterized by FT-IR, $^1H NMR, and ^{13}C NMR$ spectroscopy. The curing behaviors. thermal stabilities. fracture toughness. and flexural strength of TGDDM/ESO blend systems were investigated by using the dynamic DSC. thermogravimetric analysis (TGA). and flexural tests. The thermal stabilities of TGDDM/ESO blend systems were decreased with increasing ESO contents. whereas the critical stress intensity factor ($K_{IC}$) and flexural strength ($\sigma_f$) were increased with ESO contents up to 10 wt% ESO.

• Polymer(Korea)
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• v.26 no.3
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• pp.344-352
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• 2002

In this work, two thermal cationic latent catalysts, i.e., triphenyl benzyl phosphonium hexafluoroantimonate (TBPH) and benzyl 2-methylpyrazinium hexafluoroantimonate (BMPH) were newly synthesized. And the thermal and mechanical properties of difunctional epoxy (diglycidylether of bisphenol h, DGEBA) resins initiated by 1 phr of either TBPH or BMPH catalyst were investigated. As experimental results, the epoxy/TBPH system showed higher curing temperature and critical stress intensity factor ($K_{IC}$) than those of epoxy/BMPH. This could be interpreted in terms of slow thermal diffusion rate and bulk structure of four phenyl groups in TBPH. However, the decomposed activation energy determined from Coats-Redfern method was lower in the case of epoxy/TBPH. This result was probably due to the fact that broken short chain structure was developed by steric hindrance of TBPH.

• International Journal of Concrete Structures and Materials
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• v.5 no.1
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• pp.29-33
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• 2011

This article employs Least Square Support Vector Machine (LSSVM) for determination of fracture parameters of concrete: critical stress intensity factor ($K_{Ic}^s$) and the critical crack tip opening displacement ($CTOD_c$). LSSVM that is firmly based on the theory of statistical learning theory uses regression technique. The results are compared with a widely used Artificial Neural Network (ANN) Models of LSSVM have been developed for prediction of $K_{Ic}^s$ and $CTOD_c$, and then a sensitivity analysis has been performed to investigate the importance of the input parameters. Equations have been also developed for determination of $K_{Ic}^s$ and $CTOD_c$. The developed LSSVM also gives error bar. The results show that the developed model of LSSVM is very predictable in order to determine fracture parameters of concrete.

• Computers and Concrete
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• v.9 no.3
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• pp.215-226
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• 2012

This article employs Support Vector Machine (SVM) for determination of fracture parameters critical stress intensity factor ($K^s_{Ic}$) and the critical crack tip opening displacement ($CTOD_c$) of concrete. SVM that is firmly based on the theory of statistical learning theory, uses regression technique by introducing ${\varepsilon}$-insensitive loss function has been adopted. The results are compared with a widely used Artificial Neural Network (ANN) model. Equations have been also developed for prediction of $K^s_{Ic}$ and $CTOD_c$. A sensitivity analysis has been also performed to investigate the importance of the input parameters. The results of this study show that the developed SVM is a robust model for determination of $K^s_{Ic}$ and $CTOD_c$ of concrete.

• Polymer(Korea)
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• v.37 no.1
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• pp.61-65
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• 2013

In this work, the anodic oxidation of carbon fibers was carried out to enhance the mechanical interfacial properties of carbon fibers-reinforced epoxy matrix composites. The surface characteristics of the carbon fibers were studied by FTIR, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). Also, the mechanical interfacial properties of the composites were studied with interlaminar shear strength (ILSS), critical stress intensity factor ($K_{IC}$), and critical strain energy release rate ($G_{IC}$). The anodic oxidation led to a significant change in the surface characteristics of the carbon fibers. The anodic oxidation of carbon fiber improved the mechanical interfacial properties, such as ILSS, $K_{IC}$, and $G_{IC}$ of the composites. The mechanical interfacial properties of the composites anodized at 20% sulfuric/nitric (3/1) were the highest values among the anodized carbon fibers. These results were attributed to the increase of the degree of adhesion at interfaces between the carbon fibers and the matrix resins in the composite systems.

• Korean Chemical Engineering Research
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• v.43 no.5
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• pp.632-636
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• 2005

In this work, the effect of chemical treatments on surface properties of SiC was investigated in thermal and mechanical interfacial behaviors of SiC/PMMA nanocomposites. The acid/base value, contact angles, and FT-IR analysis were performed for the study of surface characteristics of the SiC studied. The thermal stabilities of the SiC/PMMA nanocomposites were investigated by thermogravimetric analysis (TGA). Also the mechanical interfacial properties of the composites were studied in critical stress intensity factor ($K_{IC}$) and critical strain energy release rate ($G_{IC}$) measurements. As a result, the acidically treated SiC (A-SiC) had higher acid value than that of untreated SiC (V-SiC) or basically treated SiC (B-SiC). The acidic solution treatment led to an increase in surface free energy of the SiC, mainly due to the increase of its specific component. Thermal and mechanical interfacial properties of the SiC/PMMA nanocomposites, including initial decomposition temperature (IDT), $K_{IC}$, and $G_{IC}$ had been improved in the acidic treatment on SiC. This was due to the improvement in the interfacial bonding strength, resulting from the acid-base interfacial interactions between the fillers and polymeric matrix.

• Polymer(Korea)
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• v.25 no.4
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• pp.587-593
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• 2001

In this work, red mud (RM) was chemically modified by 0.1, 1, and 5 M H3PO4 solution to prepare epoxy/RM nanocomposites. The effect of chemical treatment on pH, acid-base values, specific surface area, and porosity of RM surface was analyzed. To estimate the mechanical interfacial properties of epoxy/RM nanocomposites, the critical stress intensity factor (K$_{IC}$) was measured. From the experimental results, it was clearly revealed that the porosity, specific surface area, and acid values of RM surface were developed as the increase of the treatment concentration due to the increase of acidic functional group, including hydroxyl group on RM surface. The mechanical interfacial properties of epoxy/treated-RM nanocomposites were higher than those of epoxy/RM as-received due to an improvement of interfacial bonding between basic matrix and RM surface.

• Journal of the Korean Chemical Society
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• v.47 no.5
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• pp.472-478
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• 2003

In this work, the zeolite/diglycidylether of bisphenol A(DGEBA) systems were investigated in terms of the cure kinetics and mechanical interfacial properties of the composites. The 4, 4-diamino diphenyl methane(DDM) was used as a curing agent for epoxy. Two types of zeolite(PZ) were prepared with 15 and 35 wt% KOH treatments(15-BZ and 35-BZ, respectively) for 24 h, and their surface characteristics were studied by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction(XRD). Cure kinetics of the composites were examined in the context of differential scanning calorimetry(DSC), and mechanical interfacial properties were investigated in critical stress intensity factor($K_{IC}$) and critical strain energy release rate($G_{IC}$). In the results of XPS and XRD, sodium ion(Na) of zeolite was exchanged for potassium ion(K), resulting from the treatment of KOH. Also, $Si_{2p}/Al{2p}$ composition ratios of the treated zeolite were increased, which could be attributed to the weakening of Al-O bond in framework. Cure activation energy($E_a$) of 15-BZ composites was decreased, whereas KIC and $G_{IC}$ were increased, compared with those of the pure zeolite/DGEBA composites. It was probably accounted that the acidity of zeolite was increased by surface treatments and the cure reaction between zeolite and epoxy was influenced on the increased acidity of zeolite.