• Title/Summary/Keyword: corrosion potential and current

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An Experimental Study on Relationship Between Half-Cell Potential and Corrosion Current Density of Chloride-Induced Corroded Steel in Concrete (염해에 따라 콘크리트 속에서 부식된 철근의 반전지전위와 부식전류밀도의 상관관계에 관한 실험적 연구)

  • Jo, Sang-Hyeon;Kim, Dong-Won;Kee, Seong-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.1-13
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    • 2022
  • This study aims to investigate the feasibility of the half-cell potential (HCP) measurements on the concrete surface for evaluation of corrosion rate (or corrosion levels) of reinforcing steel in concrete. A series of experimental study is performed to measure HCP (or corrosion potential, Ecorr) and corrosion current density (icorr) of reinforcing steel in concrete cube specimens, with a side length of 200 mm. Various corrosion levels in a range of 0% to 20% of the test specimens are accelerated by impressing current to the reinforcing steel in concrete immersed in 3.0 % NaCl solution. HCP is measured in accordance with ASTM C876-15, and corrosion current density is determined by using the Stern-Geary equation and measured polarization resistance measured by electrochemical impedance spectroscopy (EIS). As a result, a numerical formula that relates HCP and icorr in the test specimen is established by a regression analysis of the measured data in this study. It is observed that HCP is linearly correlated with log(icorr) with a R2 greater than 0.87, which is less affected by the experimental variables such as concrete mixture proportion, diameter of reinforcing steel and the amount of applied current in this study. These results exhibit that HCP measurements could be effective for evaluation of corrosion rate (or corrosion levels) of reinforcing steel in concrete in the case of exposed to a certain consistent environment.

The Performance of Cathodic Protection with ICCP

  • Oh, Jin-Seok
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.8
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    • pp.1286-1290
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    • 2004
  • This paper describes the anti-corrosion system on underwater structures of ships. Metals and alloys have several positions in the series such as immunity, corrosion and passivity. The iron potential has to change from the corrosion position to the anodic protection or cathodic protection for preventing corrosion by providing corrosion protection system such as ICCP(Impressed Current Cathodic Protection). The purpose of ICCP system is to eliminate the rusting or corrosion, which occurs on metal immersed in water. The system includes a power supply unit, which consists of a transformer, a converter. a controller, etc. This paper presents the protection performance of ICCP under dynamic condition such as velocity. The variation of potential and current density with time and environment factors are also described Finally, the experimental results will be explained and analysed.

An Electrochemical Evaluation on the Corrosion of Weld Zone in Cold Arc Welding of the Cast Iron

  • Moon, Kyung Man;Kim, Jin Gyeong;Lee, Myung Hoon;Kim, Ki Joon
    • Corrosion Science and Technology
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    • v.7 no.2
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    • pp.134-137
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    • 2008
  • Cold arc welding of cast iron has been widely used with repair welding of metal structures. However its welding is often resulted in the galvanic corrosion between weld metal zone and heat affected zone(HAZ) due to increasing of hardness. In this study, corrosion properties such as hardness, corrosion potential, surface microstructures, and variation of corrosion current density of welding zone with parameters of used electrodes for cast iron welding were investigated with an electrochemical evaluation. Hardness of HAZ showed the highest value compared to other welding zone regardless of kinds of used electrodes for cast iron welding. And its corrosion potential was also shifted to more negative direction than other welding zone. In addition, corrosion current density of WM in polarization curves was qualitatively smaller than that of HAZ. Therefore galvanic corrosion may be apparently observed at HAZ. However galvanic corrosion may be somewhat controlled by using an optimum welding electrode.

Corrosion Rate of Buried Pipeline by Alternating Current

  • Song, H.S.;Kim, Y.G.;Lee, S.M.;Kho, Y.T.;Park, Y.S.
    • Corrosion Science and Technology
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    • v.4 no.1
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    • pp.1-7
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    • 2005
  • An alternating current (AC) corrosion on buried pipeline has been studied using coupon and ER probe. Coupons and ER probes were applied to the sites from high value of AC voltage to low value based on the survey of AC voltages on buried gas transmission pipeline over the country. Parameters such as AC current density of coupon, AC voltage, cathodic protection potential, soil resistivity and frequency were monitored continually. Corrosion induced by AC was observed even under cathodically protected condition that met cathodic protection criterion (; below -850 mV vs. CSE). Corrosion rate was affected mainly not by AC voltage but by both of frequency and AC current density. An experimental corrosion rate relation could be obtained according to effective AC current density, in which AC corrosion rate increased linearly with effective AC current density, and its slope was 0.619 in coupon method and 0.885 in ER probes.

The Study on the Wear-Corrosion Behavior of Ductile Cast Iron in the Acidic Environment (산성환경 중에서 구상흑연주철재의 마멸-부식거동에 관한 연구)

  • 임우조;박동기
    • Tribology and Lubricants
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    • v.18 no.4
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    • pp.299-304
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    • 2002
  • This paper reports the studies on the wear-corrosion behavior of ductile cast iron in the acidic environment. In atmosphere and variety of pH solution, specific wear rate and wear-corrosion characteristics of GCD 60 with various sliding speed and distance were investigated. And electrochemical polarization test of GCD 60 was examined in the environment of various pH values. The main results are as following : As the contact pressure increases, the critical velocity of specific wear rate becomes transient at low sliding speed. As pH value becomes low, wear-corrosion loss increases in the aqueous solution. As the corrosion environment is acidified, corrosion potential of GCD 60 becomes noble and corrosion current density increases.

Study on the Crevice Corrosion of Mild Steel in Fluid Environment (유체환경 중에서 연강재의 간극부식에 관한 연구)

  • Lim, Uh Job;Yun, Byoung Du
    • 유체기계공업학회:학술대회논문집
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    • 2000.12a
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    • pp.373-378
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    • 2000
  • The crevice corrosion of local corrosion occur when the gap exist on metal surface. This crevice corrosion happen to region such as flange of pipe, contact part of casing, under gasket and packing, between valve disk and seat of pump etc. Especially The crevice corrosion of mild steel(SS 400) get serious. This paper was studied on the crevice corrosion of SS 400 in fluid environment. In $0\%,\;2\%,\;3.5\%,\;5\% NaCl$ solution, the aspect of the crevice corrosion and polarization behavior under the crevice corrosion was investigated. And Weight loss rate of SS 400 with crevice and non-crevice was measured according to the NaCl concentration. The main results obtained are as follows : 1) Under crevice corrosion, the corrosion potential become less noble as the concentration of NaCl solution increased. 2) The current density under open circuit potential was high drained as concentration of NaCl solution increased by $3.5\%$ but the concentration increased over $3.5\%$, the current density was low drained. 3) The weight loss rate of SS 400 was increased as concentration of NaCl solution Increased by $3.5\%$, but the concentration increased over $3.5\%$, that of SS 400 was decreased. 4) Effect of oxygen for crevice corrosion in the concentration of $3.5\%$ NaCl solution become sensitive than that $0\%$ NaCl solution.

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Effect of the Specific Resistance of Water on Corrosion Characteristics of STS 304 for Gas Boiler (가스보일러용 STS 304의 부식특성에 미치는 용수의 비저항의 영향)

  • Lim, Uh-Joh;Kim, Hwan-Sik;Yun, Byoung-Du
    • Journal of Fisheries and Marine Sciences Education
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    • v.19 no.3
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    • pp.323-328
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    • 2007
  • This paper was studied on the effect of the specific resistance of water on corrosion characteristics of STS 304 for gas boiler. The electrochemical polarization test of STS 304 for gas boiler was carried out. And the polarization resistance, uniform corrosion, corrosion behavior by impressed potential and corrosion sensitivity of STS 304 with specific resistance were considered. The main results are as following: 1) With being low the specific resistance of water, the polarization resistance and corrosion potential of STS 304 decreases, while corrosion current density increases. 2) Under constant impressed potential, the corrosion sensitivity of STS 304 is large with being low the specific resistance due to synergy effect of Cl ion.

The Effect of Acidic Environments on the Corrosion-Wear of Cr Plating (크롬도금의 부식-마멸에 미치는 산성환경의 영향)

  • 곽남인;임우조
    • Tribology and Lubricants
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    • v.19 no.4
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    • pp.211-216
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    • 2003
  • This paper was studied on the corrosion and corrosion-wear behavior of chromium (Cr) plating in the acidic environments. In the various pH of acidic solutions, the electrochemical polarization test and wear-corrosion test of Cr plating were carried out. And thus potential, corrosion current density and corrosion-wear loss behaviour of Cr plating are investigated.

Study on the Crevice Corrosion Behavior of 55400 in Marine Environment (해양환경 중에서 SS 400 강제의 간극부식거동에 관한 연구)

  • 임우조;윤병두
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.6
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    • pp.1336-1340
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    • 2001
  • Due to increase of air pollution substance, such as $SO_2$,$SO_3$, H2S ,CO, HCI, $Cl_2$ and so on, the operating environment of mechanical equipment and facilities like generating plants, ships, metal structure etc., are acidified and corroded. In these environments, the crevice corrosion of marine facilities frequently occurs at crevice like jointed bolt, gasket or sealant, riveted plates, contact of metal with non-metallic solids etc. Therefore, this paper was studied on the crevice corrosion behavior of mild steel(SS 400) in marine environment. In a variety of NaCl solutions, the aspect of he .crevice corrosion and polarization behavior under the crevice corrosion was investigated. The main results obtained are as follows: 1) Under crevice corrosion, the open circuit potential become less treble as the concentration of NaCl solution increased. 2) The corrosion current density of mild steel was high drained as the concentration of NaCl solution increased by 3.5%, but in the concentration increased over 3.5%, the corrosion current density was low drained. 3) The crevice corrosion is more sensitive to the synergy effect of dissolved oxygen and NaCl.

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Anti-Corrosion Characteristics of WC-based Alloy Coatings Fabricated by HVOF Process - Polarization Characteristics in Alkaline Solution - (HVOF 용사법에 의해 제조된 WC계 합금 코팅층의 방식특성(II) - 알칼리 용액에서의 분극특성 -)

  • Kim, Tae-Yong;Kim, Yeong-Sik;Kim, Jae-Dong
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.40-44
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    • 2014
  • The purpose of this paper is to investigate polarization characteristics of WC-based alloy coatings in alkaline solution. The coatings were fabricated with WC-CrC-Ni, WC-Co-Cr and WC-Co composite powders by HVOF process. Corrosion tests of coatings and substrate were carried out using potentiostat/galvanostat at solution with pH 8 and pH 13. Corrosion potential(Ecorr) and corrosion current density(Icorr) could be studied from polarization curve, and corrosion behavior was analyzed by SEM and EDS. WC-Co-Cr coating and WC-CrC-Ni coating showed more favorable anti-corrosion characteristics than WC-Co coating and substrate at solution with pH 8 and pH 13.