• Title/Summary/Keyword: corrosion phenomenon

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Abnormal Coating Buildup on Si Bearing Steels in Zn Pot During Line Stop

  • Weimin Zhong;Rob Dziuba;Phil Klages;Errol Hilado
    • Corrosion Science and Technology
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    • v.23 no.2
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    • pp.83-92
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    • 2024
  • A hot-dip simulator was utilized to replicate abnormal coating buildup observed during line stops at galvanize lines, assessing the influence of processing conditions on buildup (up to 14 mm/side). Steel samples from 19 coils (comprising IF, BH, LCAK, HSLA, DP600-DP1180, Si: 0.006 - 0.8 wt%, P: 0.009 - 0.045 wt%) were examined to explore the phenomenon of heavy coating growth. It was discovered that heavy coating buildup (~3 mm/h) and rapid strip dissolution (~0.17 mm/h) in a GA or GI pot can manifest with specific combinations of steel chemistry and processing conditions. The results reveal the formation of a unique coating microstructure, characterized by a blend of bulky Zeta crystals and free Zn pockets/networks due to the "Sandlin" growth mechanism. Key variables contributing to abnormal coating growth include steel Si content, anneal temperature, dew point in heating and soaking furnaces, Zn pot temperature, Zn bath Al%, and cold-rolling reduction%. At ArcelorMittal Dofasco galvanize lines, an automatic online warning system for operators and special scheduling for incoming Si-bearing steels have been implemented, effectively preventing further heavy buildup occurrences.

Artificial Intelligence-Based Descriptive, Predictive, and Prescriptive Coating Weight Control Model for Continuous Galvanizing Line

  • Devraj Ranjan;G. R. Dineshkumar;Rajesh Pais;Mrityunjay Kumar Singh;Mohseen Kadarbhai;Biswajit Ghosh;Chaitanya Bhanu
    • Corrosion Science and Technology
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    • v.23 no.3
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    • pp.228-234
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    • 2024
  • Zinc wiping is a phenomenon used to control zinc-coating thickness on steel substrate during hot dip galvanizing by equipment called air knife. Uniformity of zinc coating weight in length and width profile along with surface quality are most critical quality parameters of galvanized steel. Deviation from tolerance level of coating thickness causes issues like overcoating (excess consumption of costly zinc) or undercoating leading to rejections due to non-compliance of customer requirement. Main contributor of deviation from target coating weight is dynamic change in air knives equipment setup when thickness, width, and type of substrate changes. Additionally, cold coating measurement gauge measure coating weight after solidification but are installed down the line from air knife resulting in delayed feedback. This study presents a coating weight control model (Galvantage) predicting critical air knife parameters air pressure, knife distance from strip and line speed for coating control. A reverse engineering approach is adopted to design a predictive, prescriptive, and descriptive model recommending air knife setups that estimate air knife distance and expected coating weight in real time. Implementation of this model eliminates feedback lag experienced due to location of coating gauge and achieving setup without trial-error by operator.

Study on the Durability Characteristics of the PEM Fuel Cells having Gas Diffusion Layer with Different Micro Porous Layer Penetration Thicknesses (기체확산층의 미세다공층 침투 깊이에 따른 고분자 전해질형 연료전지의 내구성능 저하 분석에 관한 연구)

  • Park, Jaeman;Oh, Hwanyeong;Cho, Junhyun;Min, Kyoungdoug;Lee, Eunsook;Jyoung, Jy-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.3
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    • pp.216-222
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    • 2013
  • Durability characteristics of Gas Diffusion Layer(GDL) is one of the important issues for accomplishing commercialization of Proton Exchange Membrane Fuel Cell(PEMFC). It is strongly related to the performances of PEMFC because one of the main functions of GDL is to work as a path of fuel, air and water. When the GDL does not work on their proposed functions due to the degradation of durability, mass transfer in PEMFC is disturbed and it might cause the flooding phenomenon. Thus, investigating the durability of GDL is important and understanding the GDL degradation process is needed. In this study, electrochemical degradation with carbon corrosion is introduced. The carbon corrosion experiment is carried out with GDLs which have different MPL penetration thicknesses. After the experiment, the amount of degradation of GDL is measured with various properties of GDL such as weight, thickness and performance of the PEMFC. The degraded GDL shows loss of their properties.

Effect of Applied Voltage Bias on Electrochemical Migration in Eutectic SnPb Solder Alloy

  • Lee, Shin-Bok;Jung, Ja-Young;Yoo, Young-Ran;Park, Young-Bae;Kim, Young-Sik;Joo, Young-Chang
    • Corrosion Science and Technology
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    • v.6 no.6
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    • pp.282-285
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    • 2007
  • Smaller size and higher integration of electronic systems make narrower interconnect pitch not only in chip-level but also in package-level. Moreover electronic systems are required to operate in harsher conditions, that is, higher current / voltage, elevated temperature / humidity, and complex chemical contaminants. Under these severe circumstances, electronic components respond to applied voltages by electrochemically ionization of metals and conducting filament forms between anode and cathode across a nonmetallic medium. This phenomenon is called as the electrochemical migration. Many kinds of metal (Cu, Ag, SnPb, Sn etc) using in electronic packages are failed by ECM. Eutectic SnPb which is used in various electronic packaging structures, that is, printed circuit boards, plastic-encapsulated packages, organic display panels, and tape chip carriers, chip-on-films etc. And the material for soldering (eutectic SnPb) using in electronic package easily makes insulation failure by ECM. In real PCB system, not only metals but also many chemical species are included. And these chemical species act as resources of contamination. Model test systems were developed to characterize the migration phenomena without contamination effect. The serpentine-shape pattern was developed for analyzing relationship of applied voltage bias and failure lifetime by the temperature / humidity biased(THB) test.

A Study on the Measurement of Foreign Material in Dissimilar Metal Contact Using Pulse Laser and Confocal Fabry-Perot Interferometer (펄스 레이저와 CFPI를 이용한 이종금속 접촉부의 이물질 측정에 관한 연구)

  • Hong, Kyung-Min;Kang, Young-June;Park, Nak-Kyu
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.2
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    • pp.160-164
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    • 2013
  • A laser ultrasonic inspection system is a non-contact inspection device which generates and measures ultrasonics by using laser beam. A laser ultrasonic inspection system provides a high measurement resolution because the ultrasonic signal generated by a pulse laser beam has a wide-band spectrum and the ultrasonic signal is measured from a small focused spot of a measuring laser beam. In this study, galvanic corrosion phenomenon was measured by non-destructive and non-contact method using the laser. The case of mixed foreign material on the part of corrosion was assumed and laser ultrasonic experiment was conducted. Ultrasonic was generated by pulse laser from the back side of the specimen and ultrasonic signal was acquired from the same location of the front side using continuous wave laser and Confocal Fabry-Perot Interferometer(CFPI). The characteristic of the ultrasonic signal of exist foreign material part was analyzed and the location and size of foreign material was measured.

A Study on Fatigue Strength of Austenitic Stainless Steel for Centrifuge (원심분리기용 오스테나이트계 스테인리스강의 피로강도에 관한 연구)

  • Lee, Mee-Hae;Kim, Yong-Soo;Park, Joon-Woo
    • Journal of the Korean Society of Safety
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    • v.23 no.3
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    • pp.12-16
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    • 2008
  • For industrial centrifuges, the state of their welding areas, even with a naked-eye observation, offers potential safety problems such as inconsistent bead formation. STS304, which is used mainly in centrifuges, is made of metal alloys with chrome and nickel as the main ingredients, offering excellent corrosion resistance, thermal resistance, and high strength, and thus allowing it to be used for diverse purposes. This paper conducted tensile and fatigue tests of STS304 to improve the safety of centrifuges. In the findings, for the static behavior of the STS304 material, welded specimens increased their yield and tensile strength compared with the base test specimens, but decreased their elongation ratio. Also, the data dispersion phenomenon of welded specimens remarkably increased.

기계가공면의 소성 스트레인에 관한 연구

  • 김태영;신형곤;소율영
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1991.11a
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    • pp.54-58
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    • 1991
  • It is well known that metal cutting leaves a plastically deformed layer in the machined surface. This residual phenomenon affects in various forms the physical properties of machined components such as the fatigue strength, the dimensional instability, microcracks, and the stress corrosion cracking. These physical properties, so called surface integrity, are very important for designing highly stressed and critically loaded components. Typical plastic strains in the machined surface are very difficult to measure, since they are located within a very short distance from the surface and they change very rapidly. There is an alternative way to determine the residual strain in plastically deformed materials by measuring the grain size after a subsequent recrystallization process. Although, this technique has been successfully applied by several researchers to find the plastic zone around notches and cracks in various materials and welding beads, few works have been reported using the recrystallization method to determine the residual strains in machined surface. Therefore, the purpose of this investigation Is to explore the effectiveness of the recrystallization technique in machining applications, and in particular, to find the effect of cutting parameters, i.e., depth of cut and rake angle on the plastic strains.

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The medium coupling effect on propagation of guided waves in engineering structures and human bone phantoms

  • Chen, Jiangang;Su, Zhongqing;Cheng, Li
    • Coupled systems mechanics
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    • v.1 no.4
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    • pp.297-309
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    • 2012
  • As a result of the medium coupling, propagation characteristics of ultrasonic waves guided by a multi-phase medium can be different from those in a homogeneous system. This phenomenon becomes prominent for a medium consisting of phases with considerably distinct material and physical properties (e.g., submerged structures or human bones covered with soft tissues). In this study, the coupling effect arising from both fluid and soft tissues on wave propagation in engineering structures and human bone phantoms, respectively, was explored and calibrated quantitatively, with a purpose of enhancing the precision of ultrasonic-wave-based non-destructive evaluation (NDE) and clinical quantitative ultrasound (QUS). Calibration results were used to rectify conventional NDE during evaluation of corrosion in a submerged aluminium plate, and QUS during prediction of simulated healing status of a mimicked bone fracture. The results demonstrated that with the coupling effect being appropriately taken into account, the precision of NDE and QUS could be improved.

Stress and Fracture Analyses of Nuclear Power Plant LP Turbine Rotor Discs

  • Lee, Choon-Yeol;Kwon, Jae-Do;Chai, Young S.;Jang, Ki-Sang
    • Journal of Mechanical Science and Technology
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    • v.14 no.2
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    • pp.207-214
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    • 2000
  • Fracture phenomenon has been reported on blades, rotors, connections and rotor discs of LP turbines of nuclear power plants, which is caused by fatigue, stress corrosion and erosion. In this study, as a tool of reliability evaluation, a number of stress and fracture analyses were performed on the defected area under various operating conditions using the finite element method. Possible defects on key-way and rotor disc were assumed to be two-dimensional cracks and centrifugal force, temperature distribution and shrink-fit effect were included as external loads. From stress analysis results, stress intensity factors were obtained and these values can be utilized to evaluate reliability and predict remaining lifetime of the turbine discs.

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Evaluation of Chloride Ion Binding Capacity of Hardened Portland Cement Paste Containing Hydrotalcite (경화된 하이드로탈사이트 혼입 포틀랜드 시멘트 페이스트의 염소이온 고정능력 평가)

  • Han, Jae-Do;Lee, Yun-Su;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.27-28
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    • 2018
  • Deterioration of reinforced concrete structures due to salt corrosion is a phenomenon that can be easily seen, and the main reason for deterioration is chloride ion. Therefore, researches are actively conducted to control chlorine ion penetration worldwide. The purpose of this study is to evaluate the chloride ion fixation capacity of Portland cement paste containing Hydrotalcite. For this purpose, cement paste containing 0%, 2.5%, and 5% of Hydrotalcite was sealed and cured for 28 days, and the cured cement paste was crushed. Chloride ion solution was prepared at a concentration of 0.5M using NaCl, and the powdered cement paste was reacted for a specific time in aqueous chloride ion solution. After the reaction, the concentration of the chloride ion aqueous solution was measured using a silver nitrate potentiometric titrator, and the reacted cement paste was analyzed using XRD and FT-IR.

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