DOI QR코드

DOI QR Code

Study on the Durability Characteristics of the PEM Fuel Cells having Gas Diffusion Layer with Different Micro Porous Layer Penetration Thicknesses

기체확산층의 미세다공층 침투 깊이에 따른 고분자 전해질형 연료전지의 내구성능 저하 분석에 관한 연구

  • Received : 2013.06.18
  • Accepted : 2013.06.30
  • Published : 2013.06.30

Abstract

Durability characteristics of Gas Diffusion Layer(GDL) is one of the important issues for accomplishing commercialization of Proton Exchange Membrane Fuel Cell(PEMFC). It is strongly related to the performances of PEMFC because one of the main functions of GDL is to work as a path of fuel, air and water. When the GDL does not work on their proposed functions due to the degradation of durability, mass transfer in PEMFC is disturbed and it might cause the flooding phenomenon. Thus, investigating the durability of GDL is important and understanding the GDL degradation process is needed. In this study, electrochemical degradation with carbon corrosion is introduced. The carbon corrosion experiment is carried out with GDLs which have different MPL penetration thicknesses. After the experiment, the amount of degradation of GDL is measured with various properties of GDL such as weight, thickness and performance of the PEMFC. The degraded GDL shows loss of their properties.

Keywords

References

  1. V. A. Sethuraman, J. W. Weidner, A. T. Haug, L. V. Protsailo, "Durability of perfluorosulfonic acid and hydrocarbon membranes: effect of humidity and temperature", J. Electrochem., Vol. 155, No. 2, 2008, pp. B119-124. https://doi.org/10.1149/1.2806798
  2. Y. H. Tang, J. L. Zhang, C. J. Song, J. J. Zhang, "Single PEMFC design and validation for hightemperature MEA testing and diagosis up to $300^{circ}C$", Electrochem. Solid-State Lett., Vol. 10, No. 9, 2007, pp. B142-146. https://doi.org/10.1149/1.2750440
  3. S. R. Samms, S. Wasmus, R. F. Savinell, "Thermal stability of Nafion in simulated fuel cell environments", J. Electrochem. SOC., Vol. 143, No. 5, 1996, pp.1498-1504. https://doi.org/10.1149/1.1836669
  4. N. Ramaswamy, N. Hakim, S. Mukerjee, "Degradation mechanism study of perfluorinated proton exchange membrane under fuel cell operating conditions", Electrochim. Acta., Vol. 53, No. 8, 2008, pp. 3279-3295. https://doi.org/10.1016/j.electacta.2007.11.010
  5. T. Ha, J. Cho, J. Park, K. Min, H. Kim, E. Lee, J. Jyoung, "Experimental study of the effect of dissolution on the gas diffusion layer in polymer electrolyte membrane fuel cell", Int. J. Hydrogen Energy, Vol. 36, No. 19, 2011, pp. 12427-12435. https://doi.org/10.1016/j.ijhydene.2011.06.096
  6. T. Ha, J. Cho, J. Park, K. Min, H. Kim, E. Lee, J. Jyoung, "Experimental study on carbon corrosion of the gas diffusion layer in polymer electrolyte membrane fuel cells", Int. J. Hydrogen Energy, Vol. 36, No. 19, 2011, pp. 12436-12443. https://doi.org/10.1016/j.ijhydene.2011.06.098
  7. J. Cho, T. Ha, J. Park, K. Min, H. Kim, E. Lee, J. Jyoung, "Analysis of transient response of a unit proton-exchange membrane fuel cell with a degraded gas diffusion layer", Int. J. Hydrogen Energy, Vol. 36, No. 10, 2011, pp. 6090-6098. https://doi.org/10.1016/j.ijhydene.2011.02.060
  8. J. H. Chun, K. T. Park, D. H. Jo, J. Y. Lee, S. G. Kim, S. H. Park, E. S. Lee, J. Jyoung, S. H. Kim, "Development of a novel hydrophobic/hydrophilic double micro porous layer for use in a cathode gas diffusion layer in PEMFC", Int. J. Hydrogen Energy, Vol. 36, No. 14, 2011, pp. 8422-8428. https://doi.org/10.1016/j.ijhydene.2011.04.038
  9. J. Cho, J. Park, H. Oh, K. Min, E. Lee, J. Jyoung, "Analysis of the transient response and durability characteristics of a proton exchange membrane fuel cell with different micro-porous layer penetration thickness", Appl. Energy, Vol. 111, 2013, pp. 300-309. https://doi.org/10.1016/j.apenergy.2013.05.022
  10. G. Chen, H. Zhang, H. Ma, H. Zhong, "Electrochemical durability of gas diffusion layer under simulated proton exchange membrane fuel cell conditions", Int. J. Hydrogen Energy, Vol. 34, No. 19, 2009, pp. 8185-8192. https://doi.org/10.1016/j.ijhydene.2009.07.085

Cited by

  1. Characterization of Milled Carbon Fibers-filled Pitch-based Carbon Paper for Gas Diffusion Layer vol.29, pp.5, 2016, https://doi.org/10.7234/composres.2016.29.5.262