• Title/Summary/Keyword: corrosion current

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Corrosion Rate of Buried Pipeline by Induced Alternating Current (교류가 유도되는 매설배관에서의 교류 부식속도 측정에 관한 연구)

  • Song H. S.;Kim Y. G.;Lee S. M.;Kho Y. T.;Park Y. S.
    • Journal of the Korean Institute of Gas
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    • v.5 no.3 s.15
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    • pp.63-72
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    • 2001
  • An alternating current (AC) corrosion using coupon and electric resistance (ER) probe has been studied. Coupon coupled with ER probe were applied in terms of AC voltage from high value to low value through the survey of AC voltages on buried gas transmission pipeline over the country. Parameters such as AC current density of coupon, AC voltage, cathodic protection potential, soil resistivity and frequency were monitored continually. Corrosion induced by AC was observed even under cathodically protected condition that met cathodic protection criterion (below -850mv vs. CSE). Corrosion rate was affected mainly not by AC voltage but by both of frequency and AC current density. An experimental corrosion rate relationship could be obtained statistically, In which AC corrosion rate increased linearly with effective AC current density and its slope was 0.619 in case of coupon and 0.885 in case of ER probe.

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Electrochemical Analysis on Flow-Accelerated Corrosion Behavior of SA106 Gr.C Steel in Alkaline Solution

  • Kim, Jun Hwan;Kim, In Sup;Chung, Han Sub
    • Corrosion Science and Technology
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    • v.2 no.1
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    • pp.41-46
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    • 2003
  • Flow-Accelerated Corrosion behavior concerning both activation and mass transfer process of SA106 Gr.C steel was studied using rotating cylinder electrode in room temperature alkaline solution by DC and AC electrochemical techniques. Passive film was tanned from pH 9.8 by step oxidation of ferrous product into hydroxyl compound. Corrosion potential shifted slightly upward with rotating velocity through the diffusion of cathodic species. Corrosion current density increased with rotating velocity in pH 6.98, while it soon saturated from 1000 rpm at above pH 9.8. On the other hand the limiting current increased with rotating speed regardless of pH values. It seems that activation process, which represents formation of passive film on the bare metal surface, controls the entire corrosion kinetics

Anti-Corrosion Characteristics of WC-based Alloy Coatings Fabricated by HVOF Process - Polarization Characteristics in Alkaline Solution - (HVOF 용사법에 의해 제조된 WC계 합금 코팅층의 방식특성(II) - 알칼리 용액에서의 분극특성 -)

  • Kim, Tae-Yong;Kim, Yeong-Sik;Kim, Jae-Dong
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.40-44
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    • 2014
  • The purpose of this paper is to investigate polarization characteristics of WC-based alloy coatings in alkaline solution. The coatings were fabricated with WC-CrC-Ni, WC-Co-Cr and WC-Co composite powders by HVOF process. Corrosion tests of coatings and substrate were carried out using potentiostat/galvanostat at solution with pH 8 and pH 13. Corrosion potential(Ecorr) and corrosion current density(Icorr) could be studied from polarization curve, and corrosion behavior was analyzed by SEM and EDS. WC-Co-Cr coating and WC-CrC-Ni coating showed more favorable anti-corrosion characteristics than WC-Co coating and substrate at solution with pH 8 and pH 13.

Effect of Impressed Current System for Corrosion Protection of Rebars in Concrete (콘크리트 중의 철근 부식 억제를 위한 외부전원법의 효과)

  • Moon, Han-Young;Kim, Seong-Soo;Kim, Hong-Sam
    • Magazine of the Korea Concrete Institute
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    • v.11 no.2
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    • pp.221-230
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    • 1999
  • Corrosion of rebars can occur if there are cracks, moisture and availability of oxygen or carbonation proceeds, chloride penetrates and diffuses in concrete. Once rebars in concrete corrodes, subsequently accompanied with scaling, spalling in concrete cover. As a result of them, the RC structure is seriously deteriorated. In this study, theoretical review and experiments for cathodic protection(CP) have been performed to control corrosion of rebars in concrete contained chlorides and pre-crack. For CP the impressed current system was applied, the protection effect was investigated when rebars was directly contacted with salt water due to crack and open to much chlorides in concrete. In order to investigate the effect of protection, when CP was energized for 1 year, half-cell potential, potential-decay with current density, corrosion ratio, etc. were measured. With the cathodic protection by impressed current system, the depolarized values of all specimen were met NACE Standard, the effect of 34~84% of the ratio of corrosion area and 84~86% of cross-section reduction were calculated.

Determination of Polarization Resistance by Harmonic Current Measurements (조화 전류 측정에 의한 분극 저항 평가)

  • Kim, Jong Jip;Yu, Mi Young
    • Corrosion Science and Technology
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    • v.11 no.6
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    • pp.247-256
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    • 2012
  • Harmonic current was measured for a dummy cell with various values of resistance, and the procedure developed through the measurements was applied to the investigation of effects of the amplitude of applied frequency and applied potential on the harmonic current of a stainless steel and a carbon steel in chloride containing solutions. From the measurements of harmonic current in the dummy cell, the optimum values of applied frequency and applied potential in harmonic current measurements were found to be 1 mHz and 20 mV (or lower), respectively. Increase in harmonic current with applied frequency was observed in the case where the level of harmonic current is low as in a stainless steel. Decrease in polarization resistance was also noted in this corrosion system with either increasing applied frequency or decreasing applied potential. However, no obvious effects of applied frequency was observed on harmonic current and polarization resistance in a carbon steel in which the level of harmonic current is high.

ACSR Inner Corrosion Detection by Eddy Current Sensor (와전류센서를 이용한 ACSR 전선의 내부부식 검출)

  • 강연욱;강지원;양병모;정재기
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.12 no.1
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    • pp.12-19
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    • 1998
  • This paper deals with ACSR(Aluminum Conductor Steel Reinforced) inner corrosion detection using a detector which automatically runs on an ACSR distribution line and inspects the inner corrosion of the conductor by utilization of the nondestructive eddy current test. According to corrosion appearance and development of ACSR, the impedance change of the eddy current coils is theoretically verified. And then specifications and performances of the detector are described. Experimental procedures and desirable test results are reported. In conclusion, this detector can realize the nondestructive detecting of an ACSR inner corrosion. Upgrading the maintenance efficiency and improving the reliability of distribution line, whether is covered with insulating materials or not, would be expected by this nondestructive test method.method.

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The Effect of Shot Peening on Corrosive Behavior of SAE 5155 in $3.5\%$ NaCl Solution ($3.5\%$ NaCl수용액에서 SAE 5155의 부식거동에 미치는 쇼트피닝의 영향)

  • An Jae-Pil;Park Keyung-Dong
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.6
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    • pp.692-700
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    • 2005
  • In this study. investigated the effect of shot peening on the corrosion of SAE 5155 steel immersed in $3.5\%$ NaCl solution and corrosion characteristics by the heat treatment during shot peening process. The immersion test was Performed on the four kinds of specimens. Corrosion Potential, polarization curve, residual stress etc. were investigated from experimental results. From these test results, the effect of shot peening on the corrosion was evaluated The important results of the experimental study on the effects of shot peened SAE 5155 on the corrosion are as follows; Shot peened specimens show the low of corrosion current as compared with un peened specimens. In the case of corrosion potential, shot Peened specimen shows more negative Potential as compared with that of parent metal Surface of specimen, which is treated with shot peening Process. is Placed as more activated state against inner parent metal. Corrosion rate is shown that shot Peened specimens have less corrode than un peened specimens. But non heat treated shot peened specimens show the biggest weight loss owing to variable compressive residual stress layer by shot ball.

Evaluation of Corrosion Characteristics of Underwater Hardening Paint (수중 경화형도료의 부식특성에 관한 전기화학적 고찰)

  • Moon, Kyung-Man;Oh, Min-Seok;Lee, Myung-Hoon;Lee, Syung-Yul;Kim, Yun-Hae
    • Journal of Ocean Engineering and Technology
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    • v.25 no.2
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    • pp.85-91
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    • 2011
  • Many protection methods such as surface coating, electric protection, or other methods have been applied to the numerous steel structures widely used in continental and marine areas to control their corrosion, which is done from an economic point of view. Most of these steel structures are primarily protected by coating methods. However, some steel piles under seawater are protected by the electric protection method, that is, either using an impressed current or a sacrificial anode method. Furthermore, environmental contamination may cause a severely corrosive environment, which, in turn, causes the accelerated corrosion of steel structures. Subsequently, coated steel structures could deteriorate more rapidly than the designed lifetime because of the acid rain caused by air pollution, etc. Therefore, a coating of marine paint exposed to seawater, that is, underwater hardening painting, is increasingly required to be fast drying as well as highly corrosion resistant. In this study, five types of underwater hardening paints were prepared with different resin series and additives. Their corrosion and water resistances were investigated using electrochemical methods such as corrosion potential, polarization curves, impedance and cyclic voltammogram measurements, etc. Even though it is generally accepted that the corrosion resistance of bare steel tends to increase with a shift of the corrosion potential in the noble direction, the corrosion resistance of a sample with a coating exhibited a relatively better tendency when it had a lower corrosion potential in this study. The corrosion current density was also decreased with a decrease in the diffusion limiting current density, which may mean that there is some relationship between corrosion and water resistance. The S sample of the ceramic resin series showed the relatively best corrosion and water resistance among those of samples, while the worst corrosion and water resistance were observed for the R sample of the epoxy resin series. The corrosion and water resistance of those samples tended to deteriorate with an increase in the immersion days, and their corrosion and water resistances were considered to be apparently improved by the types of resin and additives.

Study on the Influence of Stray current Between Sacrificial Anode Cathodic Protection and Impressed Current Cathodic Protection in Marine Environment

  • Jeong, Jin-A;Kim, Ki-Joon
    • Corrosion Science and Technology
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    • v.11 no.3
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    • pp.77-81
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    • 2012
  • Cathodic protection(CP) is widely used as a means of protecting corrosion for not only marine structures like ship hulls and offshore drilling facilities, but also underground structures like buried pipelines and oil storage tanks. The principle of CP is that the anodic dissolution of metal can be protected by supplying electrons to the cathode metal. When unprotected structures are nearby to CP systems, interference problems between unprotected and protected structures may be happened. The stray current interference can accelerate the corrosion of nearby structures. So far many efforts have been made to reduce the interference in the electric railway systems adjacent to the underground metal structures like buried pipelines and gas/oil tanks. During recent few decades the protection technologies against stray current induced corrosion have been significantly improved and a number of techniques have been developed. However, there is very limited information an marine environments. Some complex harbor structures are protected by two cathodic protection systems, i.e. sacrificial anode cathodic protection(SACP) and impressed current cathodic protection(ICCP). In this case, when the protection current from sacrificial anodes returns to the cathode through electrolyte, it passes through nearby other low resistance metal structures. In many cases the stray current of ICCP systems influences the function of SACP. In this study, the risk of stray current from the SACP system to adjacent reinforced concrete structures has been verified through laboratory experiments. Concrete and steel pile structures modeled a part of bridge have been investigated in terms of CP potential and current between the two. The variation of stray current according to the magnitude of ICCP/SACP has been studied to mitigate it and to suggest the proper protection criteria.

Effects of Alloying Elements on the Surface Characteristics of Fe-38Al Intermetallic Compounds (Fe-38 at.% Al계 금속간화합물의 표면특성에 미치는 합금원소의 영향)

  • 최한철
    • Journal of the Korean institute of surface engineering
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    • v.37 no.2
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    • pp.128-136
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    • 2004
  • Effects of alloying elements on the surface characteristics of Fe-38Al intermetallic compounds were investigated using potentiostat. The specimens were casted by the vacuum arc melting. The subsequent homogenization and the stabilization led to the homogeneous DO$_3$ structure of the specimen. After the corrosion tests, the surface of the tested specimen was observed by the optical microscopy and scanning electron microscopy(SEM). For Fe-38 at.% Al intermetallic compound, the addition of Cr and Mo proved to be beneficial in decreasing the grain boundary attack by decreasing the active current density. Addition of Band Nb resulted in a higher active current density and also a higher passive current density. These results indicated the role of Cr and Mo in improving the pitting corrosion resistance of Fe-38 at.%Al intermetallic compound. Band Nb addition to Fe-38 at.%Al accelerated the granular corrosion. Fe-38 at.%Al containing Cr and Mo showed remarkably improved pitting corrosion resistance in comparison with Band Nb addition to Fe-38 at. %Al.