• Title/Summary/Keyword: core particle

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Microstructural property and catalytic activity of nano-sized MnOx-CeO2/TiO2 for NH3-SCR (선택적 촉매 환원법 재료로서 나노 사이즈 MnOx-CeO2/TiO2 촉매에 대한 미세 구조적 특성과 촉매활성 평가)

  • Hwang, Sungchul;Jo, Seung-hyeon;Shin, Min-Chul;Cha, Jinseon;Lee, Inwon;Park, Hyun;Lee, Heesoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.3
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    • pp.115-120
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    • 2016
  • $CeO_2$ is used as a co-catalyst with $TiO_2$ to improve the catalytic activity of $MnO_x$ and characterization of nano-sized powder is identified with de-NOx efficiency. A comparison between $MnO_x-CeO_2/TiO_2$ and single $CeO_2$ was conducted in terms of microstructural analysis to observe the behavior of $CeO_2$ in the ternary catalyst. The $MnO_x-CeO_2/TiO_2$ catalyst was synthesized by sol-gel method and the average particle size of the single $CeO_2$ is about $285{\mu}m$ due to the low thermal stability, whereas the particle size $MnO_x-CeO_2/TiO_2$ is about 130 nm. The strong interaction between Ce and Ti was identified through the EDS mapping by transmission electron microscopy (TEM). The improvement about 20 % of $de-NO_x$ efficiency is observed in the low-temperature ($150^{\circ}C{\sim}250^{\circ}C$) and vigorous oxygen exchange by well-dispersed $CeO_2$ is the reason of catalytic activity improvement.

Beach Resort Formation and Development Processes by Fabric Construction in an Island Environment (구조물 축조에 의한 도서지역 해수욕장의 발달과정에 관한 연구 -완도군 보길면 지역을 사례로-)

  • 박의준;황철수
    • Journal of the Korean Geographical Society
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    • v.36 no.4
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    • pp.474-482
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    • 2001
  • The purpose of this study is to investigate the formation and development processes of beach resort by fabric construction in a island environment. The results are as follows. (1) The research area(Tong-ri beach, Bokil-myon, Chollanam-do)has been transformed to belch by sedimentary environmental change since latter half of 1800's. (2) The mean slope of beach face is 0.96°, and the difference of attitude between beach and mud flat face is 75cm. (3) The mean particle size of beach surface sediment is 3.53$\Phi$. This value is very finer than that of any other beach in Korea peninsula. But its value is coarser than that of mud flat surface sediment. (4) The particle size distribution of core sediment is become changed to fine particle in 70cm depth. This value is corresponded to difference of altitude between beach face and mud flat face. (5) The analysis of aerial photographs after 1970 indicates that sedimentation process was not brisked since 1970's. Consequently, the research ares has been developed by sedimentary environmental change for sea-level rise effect and wave height energy rise effect.

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The Aspects and Meaning of "Wind" Accepted in Sijo (고시조(古時調)에 수용된 '바람'의 양상과 역할)

  • Byun Seung-goo
    • Journal of the Daesoon Academy of Sciences
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    • v.49
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    • pp.401-432
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    • 2024
  • This article examines the types of "wind (바람)" accepted in sijo (three-verse poems), focusing on the accepted pattern, and investigating its role and meaning. The summary is as follows: first of all, the works of "wind" were accepted in the sijo, and the total number of works was 620. There were 459 short sijo, and 161 long sijo. On the other hand, 148 authors wrote on "The Wind," and in the Late Joseon Dynasty, 90 authors composed 265 poems, the most. In the Early Joseon Dynasty, 50 poets composed 111 poems. Most of them were civil officials, and 170 poems were identified. Next, the aspect of jang (章) was confirmed to occur 684 times in total, with 632 instances of being single uses and 52 instances of duplication. Meanwhile, the core of the sijo, the first sentence of the last chapter, contains 'wind (바람)' 34 times in 25 words. And in terms of the aspect of the particle combined with 'wind,' the nominative particle appeared the most at 113 instances, and the auxiliary particle 'eun/neun (은/는)' was the most numerous at 58 instances. As for the types of wind contained in sijo, there are 6 major categories: 106 medium categories, with the total frequency is 688. 'Singular' appears 133 times in 6 words, and 'combination' appears 121 times in terms of total frequency. The combination with terrestrial objects was the most frequent at 79 times, and the combination with 'heavenly' objects was 75 times with 3 words, and 'mixture' indicated a mixture of several objects, with 7 words occurring 42 times. Second the literary acceptance and role of 'wind' in Sijo was examined. First, 'acceptance' and the role as a medium for conveying ideas, acceptance and the role as the development of ideas, and acceptance and role of literary expression. Through this, it can be seen that 'wind' in Sijo was accepted in literature and played a major role. Lastly, the role and meaning of wind in Sijo can be seen in the fact that it remains differentiated from other form of ancient literature or other genres. It serves as a literary device that effectively expresses the theme, and the scope of the material accepted in Sijo was expanded through wind.

Determination of Betaine in Fructus Lycii Using Hydrophilic Interaction Liquid Chromatography with Evaporative Light Scattering Detection

  • Shin, Hyun-Du;Suh, Joon-Hyuk;Kim, Jung-Hyun;Lee, Hye-Yeon;Eom, Han-Young;Kim, Un-Yong;Yang, Dong-Hyug;Han, Sang-Beom;Youm, Jeong-Rok
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.553-558
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    • 2012
  • A simple new method was developed for the determination of betaine in Fructus Lycii using hydrophilic interaction liquid chromatography with evaporative light scattering detection (HILIC-ELSD). Good chromatographic separation and reasonable betaine retention was achieved on a Kinetex HILIC column ($2.1{\times}100mm$, $2.6{\mu}m$) packed with fused-core particle. The mobile phase consisted of (A) acetonitrile and (B) 10 mM ammonium formate (pH 3.0)/acetonitrile (90/10, v/v). It was used with gradient elution at a flow rate of 0.7 mL/min. The column temperature was set at $27.5^{\circ}C$ and the injection volume was $10{\mu}L$. The ELSD drift tube temperature was $50^{\circ}C$ and the nebulizing gas (nitrogen) pressure was 3.0 bar. Stachydrine, a zwitterionic compound, was used as an internal standard. Calibration curve over $10-250{\mu}g/mL$ showed good linearity ($R^2$ > 0.9992) and betaine in the 70% methanol extract of Fructus Lycii was well separated from other peaks. Intraand inter-day precision ranged from 1.1 to 3.0% and from 2.4 to 5.3%, respectively, while intra- and inter-day accuracy ranged from 100.0 to 107.0% and from 94.3 to 103.9%, respectively. The limit of quantification (LOQ) was $10{\mu}g/mL$ and the recoveries were in the range of 98.2-102.7%. The developed HILIC-ELSD method was successfully applied to quantitatively determine the amount of betaine in fourteen Fructus Lycii samples from different locations, demonstrating that this method is simple, rapid, and suitable for the quality control of Fructus Lycii.

Geochemical and Geophysical Characteristics of Shallow Gases in the Deep Sea Sediments, Southwestern Ulleung Basin (울릉분지 남서부 심해저 퇴적층에 분포하는 천부 가스의 지화학 및 지구물리 특성)

  • 김일수;이영주;유동근;류병재
    • Economic and Environmental Geology
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    • v.36 no.3
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    • pp.149-157
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    • 2003
  • Deep sea core samples were taken in the southwestern part of the Ulleung Basin in order to characterize the properties of shallow gases in the sediment. Amount of shallow gases in the sediments were calculated by head space techniques, and chemical and isotopic compositions of hydrocarbon gases were analyzed. Geochemical analyses were carried out on the gas bearing sediments to find out relationship between natural gas contents and organic characteristics of the sediments. Seismic characteristics of shallow gases in the sediments were also examined in this study. The amount of the hydrocarbon gases in the sediments range from 0.01% to 11.25%. Calculation of volume of gas per volume of wet sediment varies from 0.1 to 82.0 ml HC/L wet sediment. Methane consists 98% of the total hydrocarbon gases except for two samples. Based on the methane content and isotopic composition$(\delta^{13}c)$: -94.31$\textperthousand$~-55.5$\textperthousand$), the hydrocarbon gases from the sediments are generated from bacterial activities of methanogenic microbes. Contents of hydrocarbon gases are variable from site to site. Volume of shallow gases in the sediments shows no apparent trends vs. either characteristics of organic matter or particle sizes of the sediments. Gas concentration is high in the area of seismic anomalies such as blanking zone or chimney structures in the section. Physicochemically the pore water and the formation water systems are saturated with gases in these areas. Concentration of hydrocarbon gases in the sediments in these area shows favorable condition for generation of gas hydrate, as far as the other conditions are satisfied.

Cultivation and Electron Microscopy of Bovine Leukemia Virus from Peripheral Blood Lymphocytes of Holstein-Friesian Dairy Cattle (젖소 말초혈액 림프구로부터 소백혈병 바이러스 배양 및 전자현미경적 관찰)

  • Yoon, Soon-Seek;Park, Jung-Won;Byun, Jae-Won;Kang, Mun-Il;Yoo, Han-Sang;Han, Hong-Ryul
    • Applied Microscopy
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    • v.35 no.1
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    • pp.23-30
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    • 2005
  • Many studies have been performed on the bovine leukemia virus (BLV) since bovine leukosis had been reported in 1968 in Korea. However, there was no report on the ultrastructural examination of BLV. An attempt to detect C-type viral particles in the cultured peripheral blood lymphocytes of Holstein-Friesian dairy cattle, was made to determine whether in vitro viral expression might be used as a reliable method to identify the cow which is likely to transmit BLV. In transmission electron microscopic (TEM) examination, the virus particles were found predominantly outside of the lymphocytes even though a few particles were also observed within the membrane bound cytoplasmic vacuoles. All of them were C-type particles consisting of a central, electron-dense core separated by a clear area from a limiting envelope with a unit membrane structure. Virus particles were easily detected in the lymphocyte which was cultured with medium supplemented with either T-lymphocyte mitogen (conconavalin A) or B-lymphocyte mitogen (lipopolysaccharide). Identical viral particles, although fewer, were also consistently present in the lymphocytes cultured with medium which was containing foetal bovine serum (FBS) only and which was containing neither FBS or mitogen. By contrast, no virus particle was detected in extensive examination of lymphocytes before culture. In conclusion, the BLV cultivation and detection methods established in this study could be used as a tool to identify and eliminate the cattle which can transmit the BLV.

Evaluating Various Nitrogen Sources for Divot Recovery on Creeping bentgrass (Creeping bentgrass의 생육과 디봇피해 회복을 위한 질소의 유형별 효과)

  • Lee, Sang-Kook
    • Asian Journal of Turfgrass Science
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    • v.26 no.2
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    • pp.135-139
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    • 2012
  • Creeping bentgrass (Agrostis stolonifera) is one of the most popular turfgrasses for high-quality playing surface such as putting green on golf courses and athletic fields. Continues damage such as divot injury on creeping bentgrass is major issue to maintain golf course properly. Although plentiful researches to maximize divot resistance have been reported, minimal research has focused on relation between nitrogen (N) sources and divot resistance. The study was conducted to determine the effect of N source for turfgrass divot recovery and overall tee performance. Eleven fertilizer treatments as N sources were applied to creeping bentgrass 'Penncross'. Before the first application, divot injuries were simulated by removing a core of soil and turfgrass from established plots and backfilling with native soil. Data collection included turfgrass color and quality. N release speed did not influenced divot recovery. Frequency of urea application had no effects on divot recovery. Urea with split application had no difference with no treatment for divot recovery. Polyon product especially polyon mini (41-0-0) had the best performance for divot recovery and for maintaining better turfgrass quality. Overall, small particle size of slow-release N form would influence creeping bentgrasss to recover divot damage.

Reconstruction of Changes in Eolian Particle Deposition Across the Mid-Pleistocene Transition in the Central Part of the North Pacific (중기 플라이스토세 전이기 전후 북태평양 중앙 해역 퇴적물에 기록된 풍성 퇴적물 입자 퇴적 양상 변화 복원)

  • Lee, Sojung;Seo, Inah;Hyeong, Kiseong
    • Ocean and Polar Research
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    • v.41 no.4
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    • pp.275-288
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    • 2019
  • We investigated flux, grain size distribution, Nd-Sr isotope composition, mineral composition, and trace metal composition (REEs and Sc) of inorganic silicate fraction (ISF, mainly Asian dust with an unrestricted amount of volcanic materials) deposited during 600~1000 ka across the Mid-Pleistocene Transition at core NPGP 1401-2A (32°01'N, 178°59'E, 5205m) taken from the central part of the North Pacific. Our results reveal about a 2-fold increase in ISF flux after 800 ka, which is associated with an increase in La/Sc and a decrease in mean grain size. Asian dusts are finer than volcanic materials and La/Sc increases with the enhanced contribution of Asian dusts. Thus, increased flux after 800 ka can be explained by the increased contribution of Asian dusts relative to volcanic materials, likely due to an intensified Westerly Jet (WJ) and the drying of the Asian continent after the MPT. Mean grain size of ISF varies systematically in relation to glacial-interglacial cycles with a decrease during glacial stages, which is consistent with the previous results in the study area. Such a cyclical pattern is also attributed to the increase in the relative contribution of Asian dusts over volcanic components in glacial stages due to intensified WJ and drying of the Asian continent. Thus, it can be concluded that climate changes that had occurred across the MPT were similar to those of interglacial to glacial transitions at least in terms of the dust budget. Different from the Shatsky Rise, however, compositional changes associated with glacial-interglacial mean grain size fluctuations are not observed in Nd-Sr isotope ratios and trace element composition in our study of the Hess Rise. This may be attributed to the location of the study site far (> 4,000 km) from the volcanic sources. The volcanic component at the study site comprises less than 10% and varies within 3% over glacial-interglacial cycles. Such a small variation was not enough to imprint geochemical signals.

Construction of Environmental Friendly Special-Purpose Ship for the Removal of Blue-green Algae (친환경적 녹조 제거용 특수선박 건조)

  • Shin, Jae-Ki;Yi, Hye-Suk;Jeong, Sun-A;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.42 no.3
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    • pp.404-406
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    • 2009
  • This study note wished to introduce special-purpose ship for algae removal that is developed by core technology of our country. The ship is consisted of main frame and adjuvant that can attach and detach as cross (+) shape of a character. The characteristics of ship are super light weight and low draft. That is consisted of four devices as suction, collection, filtration and recovering units. Among these, filtration used screen filter (mesh size 30 ${\mu}m$). Also, can separate and remove water and algae by compression air participle notion. Percentage of moisture content of concentrated algal particle was 85%. Water parted with algae finally is exhausted to water area. Removal efficiency that compare by chlorophyll-$\alpha$ concentration was about 57% (inflow: 83.2 ${\mu}g\;L^{-1}$, outflow: 35.8 $[\mu}g\;L^{-1}$) without physical and chemical pretreatment. Forward, need to achieve effect test in various conditions (algal biomass, flow etc.) for efficiency and technological elevation of exclusion device. We wished to contribute in presuppression system construction of massive algal development that manage blue-green algae occurrence area effectively, and prevents spread as lower part of reservoir.

Ultrastructural Studies of Vitellogenesis According to Germ Cell Development, and Mating Period and Spawning Activity in Female Rapa Whelk, Rapana venosa (Gastropoda: Muricidae) in the Brackish Water Area of Seomjin River, Korea (한국 섬진강 기수역 암컷 피뿔고둥 Rapana venosa (복족류 : 뿔소라과)의 생식세포 발달에 따른 난황형성과정의 미세구조적 연구 및 교미 시기와 산란 활성)

  • SON, Pal-Won;LEE, Il-Ho;KIM, Sung-Han
    • Journal of Fisheries and Marine Sciences Education
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    • v.27 no.4
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    • pp.1031-1040
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    • 2015
  • Ultrstructural studies of germ cell differentiation and vitellogenesis in the oocytes of the female Rapana venosa in the brackish water area of Seomjin River were investigated by transmission electron microscope observations. In the early vitellogenic oocytes, the Golgi complex and mitochondria were involved in the formation of glycogen particle, lipid droplets, and yolk granules. In the late vitellogenic oocytes, the rough endoplasmic reticulum and multivesicular bodies were involved in the formation of proteid yolk granules in the cytoplasm. However, heterosynthetic vitellogenesis in this species were not observed in vitellogenic oocytes during oogenesis. A mature yolk granule was composed of three components: crystalline core, electron lucent cortex and the limiting membrane. As shown in some large gastropods, vitellogenesis in R. venosa occurred by way of endogenous autosynthesis without heterosythetic vitellogenesis (exogeneous endocytosis), which are found in the oocytes in bivalves. The mating period and spawning activity were related with the increases of seawater temperatures and salinities.