• Title/Summary/Keyword: converter slag

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A Study on the Reuse of Modified and Quenched Converter Slag as Cement Additives (개질.수쇄한 전로슬래그의 시멘트 혼화재로 활용에 관한 연구)

  • Ko In-Yong;Jin Byung-Sub;Kim Young-Whan
    • Resources Recycling
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    • v.12 no.5
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    • pp.23-28
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    • 2003
  • Converter slag was reduced and modified with the addition of 5~10 weight percent of $SiO_2$, $Al_2O_3$ and $SiO_2+Al_2O_3$. which was water quenched and used as a cement additives. Additive was mixed from 10 to 30 weight percent with ordinary portland cement and made 9 kinds of mixed cement. Compressive strength of mixed cement mortar was tested md compared with com pressive strength of ordinary portland cement mortar. Effect of hydration reaction on the compressive strength of cement mortar was investigated by means of x-ray diffraction and scanning electron microscopy.

Considerations of Permeability of Converter Slag by Laboratory and In-situ Tests (실내 및 현장시험에 의한 제강 슬래그의 투수성 고찰)

  • 이문수;이광찬
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.43 no.5
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    • pp.93-105
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    • 2001
  • The permeability of converter slag, replacing material of sand mat on improving soft clay foundation, was evaluated in the laboratory as well as in situ test. Effects of grain size, flow water time and aging were investigated using sea and fresh water Converter slag which has a grain size less than 10mm were submerged with fresh water and sea water. In fresh water, the coefficients of permeability in samples A and B were measured as 4.50${\times}$10$^{-2}$ cm per second and 1.20${\times}$10$^{-1}$ cm per second, respectively while as 1.88$\times$10$^{-2}$ cm per second and 3.86$\times$10$^{-1}$ cm per second in sea water. The condition of turbulent flow may exit and was experimentally certified based on the relationship of hydraulic gradient and seepage velocity. After 180 days in using sea water, the coefficients of permeability of samples A and B decreased ten times smaller than those initial values, and after that time continually decreased as for till 360 days. Finally, filling with voids in high-calcium quicklime(CaO) may result in the reduction of coefficient of permeability. In-situ coefficient of permeability however was Practically satisfactory.

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Properties of Extruding Cement Panel Using Ca-extracted Slag as Silicious Source (Ca 추출 슬래그를 실리카 원료로 사용한 압출성형시멘트 패널의 특성)

  • Choi, Hong-Beom;Kim, Jin-Man;Yu, Jae-Seong;Hyun, Ji-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.117-118
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    • 2016
  • This paper evalutes properties of extruding cement panel using Ca-extracted convert slag and air-cooled blast furnace slag. Flexural strength of extruding cement panel has measured in air dry and autoclave curing as basic study for use as silicious source. As a result, when Ca-extracted converter slag replaces 25% in autoclave curing, flexural strength measures 13.1MPa better than panel control mix. In result of using air-cooled blast furnace slag, Ca-extracted air-cooled blast furnace slag dose not show increase of flexural strength.

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Dynamic modeling of LD converter processes

  • Yun, Sang Yeop;Jung, Ho Chul;Lee, In-Beum;Chang, Kun Soo
    • 제어로봇시스템학회:학술대회논문집
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    • 1991.10b
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    • pp.1639-1645
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    • 1991
  • Because of the important role LD converters play in the production of high quality steel, various dynamic models have been attempted in the past by many researchers not only to understand the complex chemical reactions that take place in the converter process but also to assist the converter operation itself using computers. And yet no single dynamic model was found to be completely satisfactory because of the complexity involved with the process. The process indeed involves dynamic energy and mass balances at high temperatures accompanied by complex chemical reactions and transport phenomena in the molten state. In the present study, a mathematical model describing the dynamic behavior of LD converter process has been developed. The dynamic model describes the time behavior of the temperature and the concentrations of chemical species in the hot metal bath and slag. The analysis was greatly facilitated by dividing the entire process into three zones according to the physical boundaries and reaction mechanisms. These three zones were hot metal (zone 1), slag (zone 2) and emulsion (zone 3) zones. The removal rate of Si, C, Mn and P and the rate of Fe oxidation in the hot metal bath, and the change of composition in the slag were obtained as functions of time, operating conditions and kinetic parameters. The temperature behavior in the metal bath and the slag was also obtained by considering the heat transfer between the mixing and the slag zones and the heat generated from chemical reactions involving oxygen blowing. To identify the unknown parameters in the equations and simulate the dynamic model, Hooke and Jeeves parttern search and Runge-Kutta integration algorithm were used. By testing and fitting the model with the data obtained from the operation of POSCO #2 steelmaking plant, the dynamic model was able to predict the characteristics of the main components in the LD converter. It was possible to predict the optimum CO gas recovery by computer simulation

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A Study on the Mechanical Properties of Mortar Using Steen Slag Fine Aggregate (제강슬래그 잔골재 사용 모르타르의 역학적 특성에 대한 고찰)

  • 문한영;유정훈;박영훈;강정용;정문철;송준혁
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.322-325
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    • 2003
  • Recently, as quality river aggregates like sands and gravels become scarce, use of crushed stones and sands, seashore sands, and seashore gravels is increasing abruptly. And, aggregates recycled from slags and waste concretes are used. However, since the converter slag easily expands and breaks due to free lime, differently from the blast-furnace slag, it is not suitable for use as concrete aggregates. Since the atomized steel slag aggregate has slippery surface and spherical shape, the mortar flowing characteristics improved as the atomized steel slag content increases, without regard to the aggregates coarseness and water/cement ratio. The flow characteristics loss rate of the mortar manufactured from steel slag aggregates was similar to that of the mortar manufactured from washed sand only. The compact strength of the mortar manufactured from coarse PS Ball were larger than that manufactured from washing sand only.

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Feasibility Study on the Multi-functional Ceramics using Industrial By-product for Treatment of Acid Mine Drainage (산성광산배수 처리를 위한 산업부산물 소재 다기능성 세라믹의 적용 가능성 연구)

  • Lee, Yeong-Nam;Yim, Soo-Bin
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.12
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    • pp.25-36
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    • 2017
  • This research was conducted to investigate the removal characteristics of heavy metals and sulfate ion from acid mine drainage (AMD) by multi-functional zeolite-slag ceramics (ZS ceramics), in which natural zeolite and converter slag were mixed and calcined at high temperature. The batch test showed that the removal efficiency of heavy metals by pellet-type ZS ceramics increased as the mixing weight ratio of converter slag to natural zeolite increased. The optimal mixing ratio of natural zeolite to converter slag for the removal of heavy metals and sulfate ion from AMD was observed to be 1:2~1:3. The adequate calcination temperature and time of ZS ceramics for the treatment of AMD were found to be $600{\sim}800^{\circ}C$ and 2 hours, respectively. The removal test of heavy metals and sulfate ion from AMD by the ZS ceramics prepared in optimal condition exhibited very high removal efficiencies close to 100% for all heavy metals (Al, As, Cd, Cu, Fe, Mn, Pb, Zn) and 77.1% for sulfate ion. The experimental results in this study revealed that the ZS ceramics could function as an effective agent for the treatment of AMD.

Phosphate removal by the continuous flow pilot plant with converter slag (연속흐름 모형실험장치를 이용한 전로슬래그에 의한 인산염 제거)

  • Lee, Sang Ho;Hwang, Jeong Jae
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.4
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    • pp.453-459
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    • 2014
  • The excessive concentration of phosphorus in the river and reservoir is a deteriorating factor for the eutrophication. The converter slag was used to remove the phosphate from the synthetic wastewater. Influencing factors were studied to remove soluble orthophosphate with the different particle sizes through the batch and the column experiments by continuous flow. Freundlich and Langmuir adsorption isotherm constants were obtained from batch experiments with $PS_A$ and $PS_B$. Freundlich isotherm was fitted better than Langmuir isotherm. Regression coefficient of Freundlich isotherm was 0.95 for $PS_A$ and 0.92 for $PS_B$, respectively. The adsorption kinetics from the batch experiment were revealed that bigger size of convert slag, $PS_A$ can be applied for the higher than 3.5 mg/L of phosphate concentration. The pilot plant of continuous flow was applied in order to evaluate the pH variation, breakthrough points and breakthrough adsorption capacity of phosphate. The variation of pH was decreased through the experimental hours. The breakthrough time was 1,432 and 312 hours to 10 mg/L and 50 mg/L for the influent concentration, respectively. The breakthrough adsorption capacity was 3.54 g/kg for 10 mg/L, and 1.72 g/kg for 50 mg/L as influent phosphate concentration.

시멘트/슬래그/Fe(II) 시스템에 의한 NAPL TCE의 분해 특성

  • 박정현;강완협;황인성;박주양
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.218-222
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    • 2004
  • Batch slurry experiments were conducted to develop cement/slag/Fe(II) system that could treat hazardous liquid wastes containing halogenated organic solvents. Portland cement in combination with Fe(II) was reported to reductively dechlorinate chlorinated organics in a modified solidification/stabilization process. TCE (trichloroethylene) was used a model halogenated organic solvent. The objectives of this study were to assess the feasibility of using cement and steel converter slag amended with Fe(II) as a low cost abiotic reductive dechlorination and to investigate the kinetics of TCE dechlorination over a wide range of TCE concentration. From the result of screening experiments, cement/slag/Fe(II) system was identified as a potentially effective system to treat halogenated organic solvent. Kinetic studies were carried out to further investigate degradation reaction of TCE NAPL (Non Aqueous Phase Liquids) in cement/slag/Fe(II) systems by using batch slurry reactors. Degradation rate of TCE solution in this system can be explained by pseudo-first-order rate law because the prediction with the rate law is in good agreement with the observed data.

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