• Title/Summary/Keyword: contaminated water

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The Fuel Characteristics of Diesel by Water Contamination (수분오염에 따른 경유의 연료적 특성)

  • Lim, Young-Kwan;Won, Ki-Yoe;Kang, Byung-Seok;Park, So-Hwi;Park, Jang-Min;Kang, Dea-Hyuk
    • Tribology and Lubricants
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    • v.36 no.6
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    • pp.385-390
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    • 2020
  • It rains heavily, such as long rain and typhoons, during a typical rainy season in Korea. In this season, several fuel contamination accidents by water and vehicular problems caused by water contaminated fuel occur. Many research groups have studied the effects of water contaminated fuel on vehicles and environment. However the characteristics of water contaminated fuel have not been studied. In this study, we prepared diesel samples with a constant ratio of water (0~30 volume %) using an emulsifier. Then, we analyzed these diesel samples for their representative fuel properties. In the analytical results, diesel with 30% water showed an increase in fuel properties such as density (823→883 kg/㎥), kinematic viscosity (2.601→6.345 ㎟/s), flash point (47→56℃), pour point (-22→2℃), CFPP (cold filter plugging point) (-17→20℃) and copper corrosion number (1a→2a). The low temperature characteristics, such as low pour point and CFPP, blocks the fuel filter in the cold season. In addition, water contaminated diesel decreases lubricity (190→410 ㎛) under high frequency reciprocating rig (HFRR) and derived cetane number (54.81→34.25). The low lubricity of fuel causes vehicle problem such as pump and injector damage owing to severe friction. In addition, the low cetane diesel fuel increases exhaust gases such as NOx and particulate matters (PM) owing to incomplete combustion. This study can be used to identify the problems caused by water contamination to vehicle and fuel facilities.

Microwave Remediation of Soils Contaminated by Volatile Organic Chemicals (마이크로파에 의한 휘발성 유기토양오염물질 제거에 관한 연구)

  • 문경환;김우현;이병철;김덕찬
    • Journal of Environmental Health Sciences
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    • v.22 no.3
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    • pp.116-122
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    • 1996
  • This study has been focused on the applicability of microwave treatment of soil contaminated by volitile organic chemicals. Substrates studied were sand and sandy soil. These substrates were impregnated with toluene, tetrachloroethylene, o-xylene and p-dichlorobenzene. The microwave treatment was conducted in a modified domestic microwave oven: 2450 MHz, 700 W. The sandy soil temperature added water went up rapidly to about 130$\circ$C for 4 minutes. And then, the temperature appeared to plateau out. A series of tests were performed to depict the effectiveness of microwave treatment technique to organic contaminants from soils. Removal efficiencies in sandy soil and sand were increased with increasing water content and exposure time. Microwave radiation penetrates the soil and heats water throughout the matrix. Therefore, addition of a certain amount of water to the contaminated soil can efficiently enhance the ability of the soil to absorb microwave energy and promote the evaporation of the volitile contaminants. And the vapour pressure of impregnated organic contaminants becomes lower. the removal efficiency becomes poor.

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Adsorptive and kinetic studies of toxic metal ions from contaminated water by functionalized silica

  • Kumar, Rajesh;Verma, Sunita;Harwani, Geeta;Patidar, Deepesh;Mishra, Sanjit
    • Membrane and Water Treatment
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    • v.13 no.5
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    • pp.227-233
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    • 2022
  • The objective of the study, to develop adsorbent based purifier for removal of radiological and nuclear contaminants from contaminated water. In this regard, 3-aminopropyl silica functionalized with ethylenediamine tetraacetic acid (APS-EDTA) adsorbent prepared and characterized by Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD). Prepared APS-EDTA used for adsorptive studies of Cs(I), Co(II), Sr(II), Ni(II) and Cd(II) from contaminated water. The effect on adsorption of various parameters viz. contact time, initial concentration of metal ions and pH were also analyzed. The batch method has been employed using metal ions in solution from 1000-10000 ㎍/L, contact time 5-60 min., pH 4-10 and material quantities 50-200 mg at room temperature. The obtained adsorption data were used for drawing Freundlich and Langmuir isotherms model and both models were found suitable for explaining the metal ions adsorption on APS-EDTA. The adsorption data were followed pseudo second order reaction kinetics. The maximum adsorption capacity obtained 1.3037-1.4974 mg/g for above said metal ions. The results show that APS-EDTA have great potential to remove Cd(II), Co(II), Cs(I), Ni(II) and Sr(II) from aqueous solutions through chemisorption and physio-sorption.

Changes in Toxicity of Porphyra tenera Precontaminated with Fluoranthene During Processing (Fluoranthene으로 오염시킨 김의 가공처리중 독성변화)

  • Kim, Jong-Sang;Park, Kwan-Ha;Hwang, In-Young
    • Environmental Analysis Health and Toxicology
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    • v.14 no.3
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    • pp.75-79
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    • 1999
  • Due to increasing marine pollution there is a great possibility that seaweed is contaminated with polycyclic aromatic hydrocarbons (PAHs). To investigate the effect of processing on PAM removal from Porphyra tenera (laver) contaminated PAH, laver was contaminated with fluoranthene known to have a strong photoinduced toxicity, followed by washings and drying, which are usual processes for dried laver preparation. Sample at each step was collected and its toxicity was evaluated using cultured animal cells as well as analyzing PAH contents. Fluoranthene level in laver was significantly lowered by sequential washings with sea water and distilled water, but not by drying. Fluoranthene content in raw laver right after contamination was 221 ppm and decreased to 130 ppm by washings with seawater plus distilled water while its level was not lurker lowered by drying process. Cytotoxicity and photoinduced cytotoxicity in mammalian cells were significantly elevated in laver extracts containing fluoranthene. Cellular arylhydrocarbon hydroxylase (AHH), one of the biomarkers for cellular accumulation of PAH, was greatly induced by laver extract contaminated with fluoranthene. These results suggest that photoinduced toxicity and AHH activity can be used to monitor contamination of seafood by PAHs. Fluoranthene accumulated in laver was efficiently removed by sequential washings with seawater and tap water for 24 hrs and 12 hrs, respectively.

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Advanced separation techniques for treatment of soil contaminated with heavy metals (중금속 오염 토양의 고도 선별 정화(복원)기술)

  • Lee, Hyo-Suk;Chae, Yeong-Bae
    • Journal of the Korean Professional Engineers Association
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    • v.41 no.3
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    • pp.24-29
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    • 2008
  • Recently, the serious problems have been occurred due to the contaminated sites with heavy metals are increasing. There are several remediation technologies of the metal contaminated soil such as physical separation, washing with water or acid, biologically, electrically. Pytoremediation, ultrasonic etc. Among these technologies the physical separation can be put in a good option to solve the metal contaminated soil economically and environmental friendly. Because this technology has been already commercially certificated in the mineral processing field for a long time.

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Study on Subcritical Water Degradation of RDX Contaminated Soil in Batch and Dynamic Mode (배치형과 연속흐름형에 의한 토양 중 RDX의 아임계 분해특성 비교연구)

  • Choi, Jae-Heon;Lee, Hwan;Lee, Cheol-Hyo;Kim, Ju-Yup;Park, Jeong-Hun;Jo, Young-Tae
    • Journal of Soil and Groundwater Environment
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    • v.20 no.6
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    • pp.95-102
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    • 2015
  • The purpose of this study is to compare the degradation characteristics by subcritical water of RDX contaminated soil using batch mode and dynamic mode devices. First, upon application of RDX contaminated soil, RDX treatment efficiency was increased with increasing the temperature in both modes. At 150℃, the treatment efficiency was 99.9%. RDX degradation efficiency got higher with lower ratio of solid to liquid. However, the treatment efficiency in the dynamic mode tended to be decreased at a certain ratio of solid to liquid or lower. The treatment efficiency was increased when it took longer time for the reactions in both modes. As the results of analysis on concentration of treated water after subcritical water degradation, the RDX recovery rate of dynamic and batch modes at 150℃ was 10.5% and 1.5%, respectively. However, both modes showed very similar recovery rates at 175℃ or higher. RDX degradation products were analyzed in treated water after it was treated with subcritical water. According to the results, RDX degradation mechanism was mostly oxidation reaction and reduction reaction was partially involved. Therefore, it suggested that most of RDX in soil was degraded by oxidation of subcritical water upon extraction. According to this result, it was found that both batch and dynamic modes were very effectively applied in the treatment of explosive contaminated soil.

An Investigation on the Effect of Stabilization Methods and Leaching characteristics of Heavy Metals in Paddy Soils contaminated by Heavy Metal under Submerged Condition (담수조건에 따른 토양 내 중금속 용출특성과 안정화공법의 효과 검토)

  • Yu, Chan;Yun, Sung-Wook;Kang, Sin-Il;Jin, Hae-Geun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09a
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    • pp.1201-1212
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    • 2010
  • In order to investigate on the effect of stabilization methods for rice paddies contaminated by heavy metals, a series of lab-scale model test was carried out by applying the characteristics of submerged Paddy soil. To perform the lab-scale model test, columns were made by acrylic with the dimension of diameter=10cm, thickness=0.5cm and were filled with soils which was contaminated were mixed with stabilization agents(lime stone 5% and steel refining slag 5% respectively). To manipulate the reduction condition, soils in the columns were submerged with distilled water. And then soil water and subsurface water in each column were sampled in the regular term and analysed the various physical and chemical properties.

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The Removal of Arsenic from Contaminated Water using a Hybrid Membrane Process.

  • Legault, A.S.;Trembaly, A.Y.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.06a
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    • pp.93-104
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    • 1997
  • The objective of this study is to develop a method to reduce arsenic concentrations in contaminated water. This work is also aimed at increasing the specificity of membrane separation processes. Arsenic in contaminated waters is often present in the form of negatively charged oxyanions. These are relatively small molecules which cannot be separated directly by ultrafiltration. Oxyanions can be captured by polyelectrolytes and separated by ultrafiltration. Results will be presented on the use of two polyelectrolytes; polyethylenimine (PEI) and poly-diallyl dimethyl ammonium chloride (DADMAC) at various feed concentrations. A semi-continuous process utilizing PEI in a circulation loop was tested. The restfits indicate that better than 99.6 % recovery (permeate concentration < 0.001 $\mu$g/L) can be achieved based on an initial arsenic concentration of 300 $\mu$g/L. The results indicate that this treatment method is suitable as a main treatment process for drinking water or a polishing step after arsenic precipitation.

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Experimental Study on Freezing Soil Barrier Wall for Contaminant Transfer Interception (오염물질 이동 차단을 위한 동결차수벽 형성에 관한 실험적 연구)

  • Shin, Eun-Chul;Kim, Jin-Soo
    • Journal of the Korean Geosynthetics Society
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    • v.10 no.2
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    • pp.29-34
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    • 2011
  • The purpose of this study was to prevent spreading of contaminants from movement of underground water by creating a barrier using artificial freezing method on a soil contaminated by oils and various DNAPLs. Specimens with 80% and 90% degrees of saturation were prepared to form freezing barrier using artificial freezing method. As the results of freezing specimen within soil bin with artificial ground freezing system, artificial contaminated soil cut off wall formed the thinnest wall after 12 hours. It is judged that this cut off wall will control the second soil pollution by intercepting expansion and movement of pollutants and DNAPLs within artificial contaminated soil cut off wall by underground water, intercepting inflow or outflow of underground water. Cut off walls formed by artificial ground freezing system had each other freezing speed according to degree of saturation.