• Title/Summary/Keyword: contaminated soils

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Development of Hybrid Remediation Method for Contaminated Soils with Zinc or Arsenic and Diesel (아연 또는 비소와 경유로 오염된 토양의 복합정화공법 개발)

  • Kim, Hye-Young;Park, Jeong-Hun
    • Journal of Soil and Groundwater Environment
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    • v.15 no.4
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    • pp.13-20
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    • 2010
  • The purpose of this study was to develope the remediation method of contaminated soils with metals and petroleum. The diesel degrading strain was isolated and identified from the soil contaminated by petroleum at industrial sites. Diesel biodegradation experiment was performed by diesel degrading bacteria in both solution and soil slurry. Contaminated soils by Zn or As and diesel were treated consecutively by steam-vapor extraction, biodegradation, and acid washing. The strain was identified as Pseudomonas aeruginosa, and named as Pseudomonas aeruginosa TPH1. The optimal culture conditions of TPH1 were $20^{\circ}C$ and pH 7.0, 3% of diesel concentration. Biodegradation of diesel was performed using the separated strain in liquid medium, and 63% of diesel was degraded in 72 hours. And 52% of diesel was removed in the tested soils. In the treatment of contaminated soils with diesel and Zn or As, 29% ~ 44% of diesel was reduced by steamvapor extraction, 60% ~ 71% of diesel was removed after biodegradation. 47% of Zn and 96% of As were removed after acid(mixture of sulfuric and oxalic acids) washing. It is recommended that consecutive treatment method of steam-vapor extraction, biodegradation and acid washing is effective for remediation of complex contaminated soils with metals and petroleum.

Electrical Resistivity Variations of Contaminated Soils (오염토양의 전기 비저항치 변화 연구)

  • 윤길림;이용길
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.05a
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    • pp.84-89
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    • 2000
  • Parametric studies based on laboratory pilot tests were performed to investigate the relationships between electrical resistivity and contaminated soil properties. Three kinds of sandy soils sampled and leachates from a industrial waste landfill were mixed to model the contaminated soils. Electrical resistivity of soils were measured by using a simulated resistivity cone penetrometer probe. In the experiments, the electrical resistivity were observed with changing the water content, void ratio, unit weight, degree of saturation, and concentration of the leachate. The test results show that the electrical resistivity of soils depends largely on the water content and the electrical property of pore water rather than unit weight and types of soils.

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Chemical Speciation and Potential Mobility of Heavy Metals in Tailings and Contaminated Soils (광미 및 오염된 토양에서 중금속의 존재형태 및 잠재적인 이동도)

  • 이평구;강민주;최상훈;신성천
    • Economic and Environmental Geology
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    • v.37 no.1
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    • pp.87-98
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    • 2004
  • Tailings and contaminated soils from Cheongyang mine and Seobo mine have been analysed by ICP-AES from 5-step sequential extraction method of multielement determination on extraction solutions at each step. As and Co within tailings and contaminated soils from Cheongyang mine and Seobo mine are mainly in the residual phase. In case of Cd, Cu and Zn, the most dominant fraction for tailings of Cheongyang mine is the oxidizable phase, while tailings of Seobo mine is dominated by the residual phase. In contaminated soils from Seobo mine, the predominant fraction for Cd, Cu and Zn is the Fe-Mn oxide phase. The exchangeable fraction of Pb in tailings from Cheongyang mine and Seobo mine is relatively high compared with those of other metals; whereas Pb fraction in contaminated soils from Seobo mine is largely associated with the residual fraction.

Effect of Heavy Metal Species on the Removal of Cu, Pb, and Cd Contaminated Soils Using Electrokinetic Process (Cu, Pb, 및 Cd로 오염된 토양의 동전기적 방법에 의한 제거에 있어 중금속 종이 미치는 영향)

  • Sin, Hyeon Mu;Yun, Sam Seok
    • Journal of Environmental Science International
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    • v.13 no.1
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    • pp.61-68
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    • 2004
  • Three kinds of toxic heavy metals, such as lead, copper, and cadmium, existing abundantly in contaminated soils were selected to investigate pH change, electroosmotic flow, and the removal rate in the application of electrokinetic process. In the change of pHs, they reached to about 12 and 2 at each cathodic and anodic region, respectively, and maintained for reaction being proceeded. Electroosmotic flow rates were not influenced by the kind of metal species but by electropotential gradient. On the soils contaminated by each metal, the removal rate of Cd was the fastest among three as in the order of Cd>Pb>Cu. While on the soils contaminated by mixed metal species, Cu was the fastest. Metal species transported by electrokinetic processes were distributed in between 0.9 and 1.0 of normalized region. In the case of soils contaminated by one kind of metal. the relative concentrations of Pb and Cd estimated in between normalized region 0.9 and 1.0 were 5.2 and 5.7, respectively.

A Study on the Correlation between Electrical Resistivity and Properties of Contaminated Soils (오염지반의 전기비저항치와 토성과의 상관성 연구)

  • 윤길림;이영남
    • Geotechnical Engineering
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    • v.14 no.2
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    • pp.79-92
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    • 1998
  • Parametric studies based on laboratory pilot tests were performed to investigate the relationships between electrical resistivity and properties of contaminated soils. Three kinds of sandy soils sampled and leachate from an industrial waste landfill were mired to model the contaminated soils. Electrical resistivity of soils was measured by using a simulated resistivity cone penetrometer probe. In the experiments. the electrical resistivity was observed by changing the water content, void ratio, unit weight, degree of saturation, and concentration of the leachate. The test results show that the electrical resistivity of soils depends largely on the water content and the electrical property of pore water rather than unit weight and types of soils.

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Effect of Rice Straw Compost on Arsenic Uptake and Accumulation in Rice (Oryza sativa L.) (벼의 비소흡수와 축적에 미치는 볏짚퇴비의 효과)

  • Jung, Ha-il;Kim, Myung-Sook;Jeon, Sangho;Lee, Tae-Gu;Chae, Mi-Jin
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.42 no.2
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    • pp.108-113
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    • 2022
  • Arsenic (As) uptake and accumulation from agricultural soil to rice vary depending on the soil environmental conditions such as soil pH, redox potential, clay content, and organic matter (OM) content. Therefore, these factors are important in predicting changes in the uptake and accumulation of As in rice plants. Here, we studied the chemical properties of As-contaminated and/or rice straw compost (RSC)-treated soils, the growth responses of RSC-applied rice plants under As-contaminated soils, the changes in As content of soil, and the relationship between As uptake and accumulation from the RSC-treated soils to the rice organs under As-contaminated soils. Rice plants were cultivated in 30 mg kg-1 As-contaminated soils under three RSC treatments: 0 (control), 12, and 24 Mg ha-1. No significant differences were indicated in the chemical properties of pre-experimental (before transplanting rice seedling) soils, with the exception of EC, OM, and available P2O5. As the treatment of RSC under 30 mg kg-1 As-contaminated soils increased, EC, OM, and available P2O5 increased proportionally in soil. Increased soil RSC under As-contaminated soils increased shoot dry weight of rice plants at harvesting stage. As content in roots increased proportionally with RSC content, whereas As content in shoots decreased under As-contaminated soil at all stages of rice plants. Nevertheless, As accumulation were significantly decreased in both roots and shoots of RSC-treated rice plants than those in the plants treated without RSC. These results indicate that the use of RSC can mitigate As phytotoxicity and reduce As accumulation in rice plants under As-contaminated soils. Therefore, RSC can potentially be applied to As-contaminated soil for safe crop and forage rice production.

Removal Characteristics of TPHs and Heavy Metals in Contaminated Soil with Ultrasonic Washing (초음파세척을 이용한 오염토양 내 TPHs 및 중금속 제거특성)

  • Jung, Byung-Gil;Ro, Gi-Hyun;Sung, Nak-Chang
    • Journal of Environmental Science International
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    • v.18 no.4
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    • pp.473-478
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    • 2009
  • The removal characteristics of total petroleum hydrocarbons (TPHs) and heavy metals in contaminated soils with ultrasonic washing have been studied. The ultrasonic washing was evaluated on a laboratory scale. In this investigation, the effects of factors such as ultrasonic frequency, power intensity, duration of irradiation, contents of the TPHs and heavy metals and mixing ratios between the contaminated soils and water, were considered. Experimental results suggested that the rates for contaminant extraction of the TPHs and heavy metals in the contaminated soil increased considerably with the ultrasonic washing. Therefore, the ultrasonic washing has previously been to be an effective method to remediate the contaminated soils with the TPHs and heavy metals.

Stabilization of oily contaminated clay soils using new materials: Micro and macro structural investigation

  • Ghiyas, Seyed Mohsen Roshan;Bagheripour, Mohammad Hosein
    • Geomechanics and Engineering
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    • v.20 no.3
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    • pp.207-220
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    • 2020
  • Clay soils have a big potential to become contaminated with the oil derivatives because they cover a vast area of the earth. The oil derivatives diffusion in the soil lead to soil contamination and changes the physical and mechanical properties of the soil specially clay soils. Soil stabilization by using new material is very important for geotechnical engineers in order to improve the engineering properties of the soil. The main subjects of this research are a- to investigate the effect of the cement and epoxy resin mixtures on the stabilization and on the mechanical parameters as well as the microstructural properties of clay soils contaminated with gasoline and kerosene, b- study on the phenomenon of clay concrete development. Practical engineering indexes such as Unconfined Compressive Strength (UCS), elastic modulus, toughness, elastic and plastic strains are all obtained during the course of experiments and are used to determine the optimum amount of additives (cement and epoxy resin) to reach a practical stabilization method. Microstructural tests were also conducted on the specimens to study the changes in the nature and texture of the soil. Results obtained indicated that by adding epoxy resin to the contaminated soil specimens, the strength and deformational properties are increased from 100 to 1500 times as that of original soils. Further, the UCS of some stabilized specimens reached 40 MPa which exceeded the strength of normal concrete. It is interesting to note that, in contrast to the normal concrete, the strength and deformational properties of such stabilized specimens (including UCS, toughness and strain at failure) are simultaneously increased which further indicate on suitability and applicability of the current stabilization method. It was also observed that increasing cement additive to the soil has negligible effect on the contaminated soils stabilized by epoxy resin. In addition, the epoxy resin showed a very good and satisfactory workability for the weakest and the most sensitive soils contaminated with oil derivatives.

Remediation of Diesel Contaminated Soil Using Flowing Subcritical Water (흐름식 아임계수에 의한 경유오염토양의 정화)

  • Li, Guang-Chun;Jung, Sun-Kook;Chung, Seon-Yong;Jo, Young-Tae;Park, Jeong-Hun
    • Journal of Soil and Groundwater Environment
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    • v.16 no.3
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    • pp.10-16
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    • 2011
  • The experimental studies for remediation of diesel contaminated soils were performed using subcritical water in laboratory scale. Contaminated soils from industrial area and artificially contaminated soils were utilized for soil remediation. Experimental system was composed for subcritical water to flow upward through the soil packed column for extracting contaminants. 10 g of contaminated soil was packed into the column and water flow rate was 2 mL/min. To evaluate the effects of temperature, pressure and treatment time on the removal efficiency, temperature was changed from 100$^{\circ}C$ to 350$^{\circ}C$, pressure from 50 bar to 220 bar and treatment time at the predetermined temperature from 0 min to 120 min. The purification efficiency increased as temperature increased. However, the effect of pressure and treatment time was low. Temperature 250$^{\circ}C$, pressure 50 bar and treatment time 30 min were selected for optimal operating condition for this study.

A Leaching Characteristics on Lime Stabilization of Heavy Metal Contaminated Soil in a Waste Mine Area (폐 광산 지역 중금속 오염 토양의 석회안정화 적용 시 용출특성)

  • Oa, Seong-Wook
    • Journal of Korean Society on Water Environment
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    • v.27 no.6
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    • pp.862-867
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    • 2011
  • Pozzolanic-based stabilization/solidification (S/S) is an effective and economic remediation technology to immobilize heavy metals in contaminated soils. In this study, quick lime (CaO) was used to immobilize cadmium and zinc present in waste mine contaminated clayey sand soils. Addition of 5% quicklime to the contaminated soils effectively reduced heavy metal leachability after 2 bed volume operation below the drinking water regulatory limits. Lime addition was revealed to increase the immobilization for all heavy metals in tested pH ranges, so it could be an optimal choice for short-term remediation of heavy metal contaminated soil. The mass balances for these column tests show metal reduction of 92% for Cd and 87% for Zn of total resolved mass in case of 5% lime application.