• Title/Summary/Keyword: contact transition

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Experimental Study for Removing Lacquer Layer on Iron Surface by Nd:YAG Laser System (Nd:YAG 레이저를 이용한 철제 표면 옻칠 제거 실험 연구)

  • Park, Chang Su;Cho, Nam Chul;Hwang, Hyun Sung
    • Journal of Conservation Science
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    • v.32 no.3
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    • pp.377-384
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    • 2016
  • There are physical and chemical method for removement of a lacquered layer existing on the surface when gilding an iron Buddha, these caused environmental pollution by surface degradation and is very noxious for conservation scientist's health. Thus, on this study, we conducted a lacquered layer removement experiments using Nd:YAG Laser which is contactless and eco-friendly. Specimens were made by polishing $5{\times}5$ size of iron(99.9%) specimens surfaces evenly and by differing of number of coating of unrefined lacquer, so there were thickness differences of $10{\mu}m$, $20{\mu}m$, and $30{\mu}m$. The laser machine used in this study was Nd:YAG Laser, and we used two wavelength modes; 1064 nm(160~180 mJ) for infrared light region and 532 nm(50~350 mJ) for ultraviolet light region. The experiment done by investigating the transition of specimens' surfaces with laser wavelength, energy, and numbers of investigation. The remain amount of lacquered layer surfaces before/after laser irradiation was investigated by stereoscopic microscope, observation by SEM, Non-contact Surface Roughness Measurement Device, and FT-IR etc. As a result of each analysis, we could verify the thickness of $10{\mu}m$, $20{\mu}m$ of lacquered layer removed without surface degradation when using 1064 nm wavelength with $1.0J/cm^2$ density. We could find out that Nd:YAG Laser is effective for removing remained lacquered layers when gilding an iron Buddha. In the future, when not only the metal has made various studies also wood lacquered furniture or the like, it seems to be utilized to remove the lacquer without surface damage.

A Study on the Change of Primipara's Mother - Infant Interactional process (모아상호작용과정의 진행양상에 관한 연구)

  • Cho, Mi-Young
    • Women's Health Nursing
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    • v.1 no.1
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    • pp.5-27
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    • 1995
  • One of the important tasks for new parents, especially mothers, is to establish warm, mutually affirming interpersonal relationships with the new baby in the family, with the purpose of promoting the health development of the child and the well-being of the whole family. Nurses assess the quality of the behavioral characteristics of the maternal-infant interaction. The purpose of this longitudinal descriptive correlational study is to investigate the changes of the mother - infant interactions from postpartum 1 day to postpartum 8weeks of the transition to parenthood. The aim was to contribute to the development of theoretical under standing on which to base care toward promoting the quality of maternal - infant interaction. Data were collect ed directly by the investigator and at rained from Jul, 1, 1990 to Jun 8, 1991, Subjects were a random sample of 44 mothers, 44 who had a normal delivery (but with out other perinatal complications) at four general hospitals in Seoul. Instruments used were the Stainton Parent-infant Interaction Scale (1981). The first observations were made in the delivery room, followed by day 1, day 2, day 3 and 2 weeks, 4 weeks, 6 weeks and 8 weeks after, birth, for a total of 8 contacts. Observations in the hospital were made during the hour prior to scheduled feedings. The infant was placed beside the mother. Later contacts were made at home. Data analysis was don by computer using as SPSS program and included, Paired t-test, t-test and Pearson Correlation coefficient ; the results were as follows. 1. The daily maternal-infant interaction score for the initial contact ofter birth to 8 weeks postpartum had the lowest average score 5.21 and the highest 8.02(in a range of 0-10). This subject group of mothers needed Extra nursing supporting to promote their maternal-infant interaction. 2. The daily scores for the maternal-infant interaction tended to rise, showing a gradual improvement over the period of eight weeks. However, there were significantly different increases in maternal-infant interaction only from the first to second day (p=0.000) and from the fourth to sixth weeks ofter birth.(p=0.000) 3. When the seven items of maternal-infant interaction were evaluated items of maternal-infant inter action were evaluated separately, "Care taking for the baby" had the highest average score, 1.60(in a range of 0-2) and "Speaks to baby" the lowest, 0.8. All items, suggested the subjects' need of nursing intervention to promote maternal-infant interaction 4. There were positive correlations between certain general characteristics, namely, both a higher economic status (p=0.027) and breast feeding (p=0.021) and maternal-infant interaction.

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Occurrence and Applied-mineralogical Characterization of Diatomite from the Pohang-Gampo Area (포항-감포 지역산 규조토의 산출상태와 응용광물학적 특성)

  • Noh, Jin-Hwan
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.311-324
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    • 2006
  • In the Pohang-Gampo area, several diatomite beds occurred in mostly thinner than 1 m are embedded in the Pohang Formation of marine environment and the pyroclastic Eoil Formation. The diatomite from the Eoil Formation is constituting the high-grade ore altered slightly by diagenesis. In contrast, the diatomite intercalated within the upper horizon of the Yeonil Group is comparatively low-grade and highly altered in places. During diagenesis, an increasing of crystallinity of opal, i.e., the original mineral component of diatom, results in ultimately the mineral transition to quartz with accompanying a drastic change in morphology and texture of the altered diatomite. The diagenetic alteration appears to have undergone by way of the chemical diagenesis, which is largely controlled by degree of fluid contact, rather than burial diagenesis. For the diatomite from the Pohang-Gampo area, careful SEM observations, XRD, chemical analyses, and determination of specific surface area were done to identify the fossil species, mineral and chemical composition, and other physical properties in the view of assesment of grade and quality. The domestic diatomite ores are evaluated to be not good in grade and quality, compared to those of famous foreign localities. However, some diatomite deposits of marin,: origin from the Pohang Formation is constituting a peculiar clay-rich type, i.e., moler applicable to the special usage such as a manufacturing of lightweight brick. Because such a diatomite is frequently intercalated relatively as a thicker bed in the upper part of the Yeonil Group, a systematic and careful investigation should be done for the exploitation and development of an economic diatomite deposit of the moler type.

Dynamic Behavior Study in Systems Containing Nonpolar Hydrocarbon Oil and C12E5 Nonionic Surfactant (C12E5 비이온 계면활성제 수용액과 비극성 탄화수소 오일 사이의 동적 거동 관찰)

  • Bae, Min Jung;Lim, Jong Choo
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.46-53
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    • 2009
  • Phase equilibrium and dynamic behavior studies were performed in systems containing $C_{12}E_5$ nonionic surfactant solution and nonpolar hydrocarbon oil. The phase behavior result showed an oil-in-water(O/W) microemulsion(${\mu}E$) in equilibrium with excess oil phase at low temperatures and a water-in-oil(W/O) ${\mu}E$ in equilibrium with excess water phase at high temperatures. For intermediate temperatures a 3 phase region containing excess water, excess oil, and a middle-phase microemulsion was observed and the transition temperature was found to increase with an increase in the chain length of a hydrocarbon oil. Dynamic behavior at low temperatures showed that an oil drop size decreased linearly with time due to solubilization into micelles and the solubilization rate decreased with an increase in the chain length of a hydrocarbon oil. On the other hand, both spontaneous emulsification of water into oil phase and expansion of oil drop with time were observed because of diffusion of surfactant and water into oil phase. Under conditions of a 3 phase region including a middle-phase ${\mu}E$, both rapid solubilization and emulsification of oil into aqueous surfactant solution were found mainly due to the existence of ultra-low interfacial tension. Interfacial tensions were measured as a function of time for n-decane oil drops brought into contact with 1 wt% surfactant solution at $25^{\circ}C$. Both equilibrium interfacial tension and equilibration time were found to increase with an increase in the chain length of a hydrocarbon oil.

Efficiency of Activated Carbon Treatment Processing on Raw Water Purification for Nakdong River (활성탄을 이용한 낙동강 상수원수의 수처리 효과)

  • Lim, Young-Sung;Kang, Gwan-Ho;Lee, Hong-Jae;Seo, Dong-Cheol;Heo, Jong-Soo;Sohn, Bo-Kyoon;Cho, Ju-Sik
    • Korean Journal of Environmental Agriculture
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    • v.21 no.3
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    • pp.208-215
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    • 2002
  • This study was carried out to evaluate the pollutant removal efficiencies of the advanced drinking water treatment using activated carbon process. for raw water, Nakdong river was used. from the activated carbon adsorption experiment the fellowing results were obtained The efficiency of water treatment enhanced with increase in empty bed contact time. Variation of pH was not detected to the bed depth, but DO content gradually decreased with the bed depth. Removal efficiency of $KMnO_4$ consumption, UV254 absorption, DOC and THMFP also were increased by increasing in the bed depth. Transition of adsorption zone from upper parts of the bed to the lower parts were detected as treatment periods increased. Large portion of DOCs were degraded and removed by the microbes growing on the surface of activated carbons. Cell numbers of microbes were estimated over $1.1\times10^7\;cell/cm^3$ at the depth of 20 cm from the surface 126 days after starting operation. The results shown that the activated carbon Inter was successfully acted as a biofilm filter.

Dynamic Behavior Study Using Videomicroscopy in Systems Containing Nonpolar Hydrocarbon Oil and C10E5 Nonionic Surfactant Solution (Videomicroscopy를 이용한 C10E5 비이온 계면활성제 수용액과 비극성 탄화수소 오일 사이의 동적 거동에 관한 연구)

  • Bae, Min-Jung;Lim, Jong-Choo
    • Applied Chemistry for Engineering
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    • v.20 no.5
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    • pp.473-478
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    • 2009
  • Phase equilibrium and dynamic behavior studies were performed on systems containing $C_{10}E_5$ nonionic surfactant solutions and nonpolar hydrocarbon oils. The phase behavior showed an oil in water (O/W) microemulsion (${\mu}E$) in equilibrium with excess oil phase at low temperatures and a water in oil (W/O) ${\mu}E$ in equilibrium with excess water phase at high temperatures. For intermediate temperatures a three-phase region containing excess water, excess oil, and a middle-phase microemulsion was observed and the transition temperature was found to increase with an increase in the chain length of a hydrocarbon oil. Dynamic behavior at low temperatures showed that an oil drop size decreased linearly with time due to solubilization into micelles and the solubilization rate decreased with an increase in the chain length of a hydrocarbon oil. On the other hand, both spontaneous emulsification of water into oil phase and expansion of oil drop were observed because of diffusion of surfactant and water into oil phase. Under conditions of a 3 phase region including a middle-phase ${\mu}E$, both rapid solubilization and emulsification of oil into aqueous solutions were found mainly due to the existence of ultra-low interfacial tension. Interfacial tensions were measured as a function of time for n-decane oil drops brought into contact with 1 wt% surfactant solution at $25^{\circ}C$. Both equilibrium interfacial tension and equilibration time increased with an increase in the chain length of a hydrocarbon oil.

Preparation of Styrene-Ethyl acylate Core-shell Structured Detection Materials for aMeasurement of the Wall Contamination by Emulsion Polymerization

  • Hwang, Ho-Sang;Seo, Bum-Kyoung;Lee, Dong-Gyu;Lee, Kune-Woo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2009.06a
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    • pp.84-85
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    • 2009
  • New approaches for detecting, preventing and remedying environmental damage are important for protection of the environment. Procedures must be developed and implemented to reduce the amount of waste produced in chemical processes, to detect the presence and/or concentration of contaminants and decontaminate fouled environments. Contamination can be classified into three general types: airborne, surface and structural. The most dangerous type is airborne contamination, because of the opportunity for inhalation and ingestion. The second most dangerous type is surface contamination. Surface contamination can be transferred to workers by casual contact and if disturbed can easily be made airborne. The decontamination of the surface in the nuclear facilities has been widely studied with particular emphasis on small and large surfaces. The amount of wastes being produced during decommissioning of nuclear facilities is much higher than the total wastes cumulated during operation. And, the process of decommissioning has a strong possibility of personal's exposure and emission to environment of the radioactive contaminants, requiring through monitoring and estimation of radiation and radioactivity. So, it is important to monitor the radioactive contamination level of the nuclear facilities for the determination of the decontamination method, the establishment of the decommissioning planning, and the worker's safety. But it is very difficult to measure the surface contamination of the floor and wall in the highly contaminated facilities. In this study, the poly(styrene-ethyl acrylate) [poly(St-EA)] core-shell composite polymer for measurement of the radioactive contamination was synthesized by the method of emulsion polymerization. The morphology of the poly(St-EA) composite emulsion particle was core-shell structure, with polystyrene (PS)as the core and poly(ethyl acrylate) (PEA) as the shell. Core-shell polymers of styrene (St)/ethyl acrylate (EA) pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl sulfate (SOS) as an emulsifier using ammonium persulfate (APS) as an initiator. The polymer was made by impregnating organic scintillators, 2,5-diphenyloxazole (PPO) and 1,4-bis[5-phenyl-2-oxazol]benzene (POPOP). Related tests and analysis confirmed the success in synthesis of composite polymer. The products are characterized by IT-IR spectroscopy, TGA that were used, respectively, to show the structure, the thermal stability of the prepared polymer. Two-phase particles with a core-shell structure were obtained in experiments where the estimated glass transition temperature and the morphologies of emulsion particles. Radiation pollution level the detection about under using examined the beta rays. The morphology of the poly(St-EA) composite polymer synthesized by the method of emulsion polymerization was a core-shell structure, as shown in Fig. 1. Core-shell materials consist of a core structural domain covered by a shell domain. Clearly, the entire surface of PS core was covered by PEA. The inner region was a PS core and the outer region was a PEA shell. The particle size distribution showed similar in the range 350-360 nm.

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Analysis on letter and expressions in the elementary mathematics textbooks (초등수학 교과서에 제시된 문자와 식 내용 분석 -6차와 2007년 교육과정을 중심으로-)

  • Kim, Sung Ae;Kim, Sung Joon
    • Journal of Elementary Mathematics Education in Korea
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    • v.17 no.1
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    • pp.105-128
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    • 2013
  • One of the biggest changes in 2007 Curriculum Revision is introduction of letter, equation, direct proportion and inverse proportion in fifth and sixth grade of mathematics. The purpose of this study is to provide some implications about teaching-learning method for introduction of letters, teaching and learning activities of equation between the 6th Curriculum and 2007 Curriculum Revision. The below conclusions were drawn from findings obtained in this study. First, the letter and expression were learned in fifth and sixth grade until 6th Curriculum and were learned in seventh grade in middle school of 7th Curriculum. But letter, equation are introduced in 2007 Curriculum Revision again. The overall contents of letter and expression were learned on the 'Relationship' domain in the 6th Curriculum, it were learned on the 'Letter and expression' domain in the 7th Curriculum and is learned on the 'Regularity and problem-solving' domain in the 2007 Curriculum Revision. Second, teaching method of these contents was to promise some definitions at first and then to solve exercises in the 6th Curriculum. But leaning was forced to improve student's problem-solving in the 7th Curriculum. To reduce student's pressure offers at a minimum mathematics terms and to provide problem situations to students who contact daily, it is emphasized on learner's communication in the 2007 Curriculum Revision. We want to be easily connected elementary mathematics and higher mathematics through this study about letter, equation. We recognized how we teach the letter and expression to reduce misconceptions and draw a transition from arithmetic thinking to algebraic thinking and want to be continue of another studies.

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$1{times}8$ Array of GaAs/AlGaAs quantum well infrared photodetector with 7.8$\mu\textrm{m}$ peak response ($1{times}8$ 배열, 7.8 $\mu\textrm{m}$ 최대반응 GaAs/AlGaAs 양자우물 적외선 검출기)

  • 박은영;최정우;노삼규;최우석;박승한;조태희;홍성철;오병성;이승주
    • Korean Journal of Optics and Photonics
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    • v.9 no.6
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    • pp.428-432
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    • 1998
  • We fabricated 1$\times$8 array of GaAs/AlGaAs quantum well infrared photodetectors for the long wavelength infrared detection which is based on the bound-continuum intersubband transition, and characterized its electrical and optical properties. The device was grown on SI-GaAs(100) by the molecular beam epitaxy and consisted of 25 period of 40 ${\AA} $ GaAs well and 500 ${\AA} $ $Al_{0.28} Ga_{0.72}$ As barrier. To reduce the possibility of interface states only the center 20 ${\AA} $ of the well was doped with Si ($N_D=2{\times}10^{18} cm^{-3}$). We etched the sample to make square mesas of 200$\times$200 $\mu\textrm{m}^2$ and made an ohmic contact on each pixel with Au/Ge. Current-voltage characteristics and photoresponse spectrum of each detector reveal that the array was highly uniform and stable. The spectral responsivity and the detectivity $D^*$ were measured to be 180,260 V/W and $4.9{\times}10^9cm\sqrt{Hz}/W$ respectively at the peak wavelength of $\lambda$ =7.8 $\mu\textrm{m}$ and at T=10 K.

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Study of Hydrophobic and Barrier Properties of Vinyltriethoxysilane Modified Poly (Vinyl Alcohol) / Poly (Acrylic Acid) Films (비닐트리에톡시실란으로 개질된 폴리비닐알코올 / 폴리아크릴산 필름의 내수성 및 차단성 연구)

  • Kim, Eun-Ji;Park, Jae-Hyung;Paik, In-Kyu
    • Clean Technology
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    • v.18 no.1
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    • pp.57-62
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    • 2012
  • Aqueous poly (vinyl alcohol) (PVA) solution was modified by using hydrophobic vinyltriethoxysilane (VTEOS) and then adding different amounts of poly (acrylic acid) (PAA) to the resulting solution. Thermal and mechanical properties, contact angle, water vapor transmission rate (MVTR) and oxygen gas transmission rate ($O_2TR$) of the film samples fabricated by these solutions were investigated. The glass transition temperature (Tg) of the VTEOS-modified films was sightly increased and the value remained unchanged according to the amount of PAA. The tensile strength of the VTEOS-modified films was found to be 9.48~10.72 $kg/mm^2$ which showed no significant difference compared with that of PVA. The film prepared with VTEOS-modified PVA/PAA (= 90/10), of which the swelling and solubility were measured to be 198% and 0%, respectively, showed improved water-resistance. The MVTR and $O_2TR$ for the PET film (thickness 50 ${\mu}m$) coated with VTEOS-modified PVA/PAA (= 90/10) film (thickness 2.5 ${\mu}m$) were measured to be 11.04 $g/m^2/day$ and 3.1 $cc/m^2/day$, respectively.