• Title/Summary/Keyword: contact effect

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Change in Mineralogical Characteristics of the Laminated Diatomaceous Siliceous Mudstone by the Treatment of Consolidants (엽층리가 발달된 규조토성 규질이암의 강화제에 의한 광물학적 특성변화)

  • Do, Jin Young
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.1
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    • pp.51-64
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    • 2022
  • For effective preservation of the rocks, which bearing plant fossils at Gumkwangdong Formation, Pohang, the properties of rock and treatment of chemicals were examined in an artificial weathering test. The rocks are diatomaceous siliceous mudstone, which contain a small amount of smectite and has developed laminated layers. The rocks react with water, the d001 spacing of smectite was increased. On the one hand, the physical properties of the rock samples, such as surface hardness, improved after the application of ethyl silicate-based stone strengthener. On the other hand, the spacing of interlayer of swelling clay minerals decreased and spacing of laminae layer increased. When the ethyl silicate-based stone strengthener was applied after pretreatment with a swelling inhibitor, interlayer and spacing of laminae changes were similar to those when only the stone strengthener was treated. The effect of the swelling inhibitor was almost negligible. When the rocks that have been conserved with chemicals react with water, spacing of laminae has widened much, whereas when the rocks was in contact with moisture only, there was little change. In addition, if it is placed in the outdoor after conservation treatment, although it occurs slightly slower than the untreated rock, the separation of the lamination layer and the pulverization of the rock occur within a very short time. Consolidation is required to improve the physical properties of fossil rock, but when exposed to rain and undergoing freeze-thaw process, the effect is lost very quickly. Therefore, regardless of the chemical treatment, it is a priority to prevent direct rainfall contact with the rock.

Effect of Surface Modification of Calcium Carbonate Nanoparticles by Octyltrimethoxysilane on the Stability of Emulsion and Foam (실란 커플링제 옥틸트리메톡시실란에 의해 표면 개질된 탄산칼슘 나노입자가 에멀젼 및 기포 안정성에 미치는 영향)

  • Lim, Jong Choo;Park, Ki Ho;Lee, Jeong Min;Shin, Hee Dong
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.386-393
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    • 2022
  • In this study, the surface modification of calcium carbonate (CaCO3) nanoparticles by a silane coupling agent, octyltrimethoxysilane (OTMS), was investigated and characterized using Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TGA) analysis. Both floating tests and contact angle measurements were also conducted to study the effect of OTMS concentration on the hydrophobicity of CaCO3 nanoparticles. It was found that the active ratio for the CaCO3 nanoparticles modified by 1 wt% of OTMS was 97.0 ± 0.5%, indicating that OTMS is a very effective silane coupling agent in enhancing the hydrophobicity of the CaCO3 nanoparticle surface. The most stable foam was generated with 1 wt% of CaCO3 nanoparticles in aqueous solutions at 1 wt% of OTMS, where the contact angle of water was found to be 91.8 ± 0.7°. It was also found that the most stable emulsion drops were formed at the same OTMS concentration. These results suggest that CaCO3 nanoparticles modified by a silane coupling agent OTMS are a powerful candidate for a foam stabilizer or an emulsifier in many industrial applications.

Study on the Effect of Emissivity for Estimation of the Surface Temperature from Drone-based Thermal Images (드론 열화상 화소값의 타겟 온도변환을 위한 방사율 영향 분석)

  • Jo, Hyeon Jeong;Lee, Jae Wang;Jung, Na Young;Oh, Jae Hong
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.40 no.1
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    • pp.41-49
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    • 2022
  • Recently interests on the application of thermal cameras have increased with the advance of image analysis technology. Aside from a simple image acquisition, applications such as digital twin and thermal image management systems have gained popularity. To this end, we studied the effect of emissivity on the DN (Digital Number) value in the process of derivation of a relational expression for converting DN to an actual surface temperature. The DN value is a number representing the spectral band value of the thermal image, and is an important element constituting the thermal image data. However, the DN value is not a temperature value indicating the actual surface temperature, but a brightness value indicating high and low heat as brightness, and has a non-linear relationship with the actual surface temperature. The reliable relationship between DN and the actual surface temperature is critical for a thermal image processing. We tested the relationship between the actual surface temperature and the DN value of the thermal image, and then the radiation adjustment was performed to better estimate actual surface temperatures. As a result, the relation graph between the actual surface temperature and the DN value similarly show linear pattern with the relation graph between the radiation-controlled non-contact thermometer and the DN value. And the non-contact temperature after adjusting the emissivity was closer to the actual surface temperature than before adjusting the emissivity.

Effect of Surface Modification of CaCO3 Nanoparticles by a Silane Coupling Agent Propyltrimethoxysilane on the Stability of Emulsion and Foam (실란 커플링제 프로필트리메톡시실란에 의해 표면 개질된 CaCO3 나노입자가 에멀젼과 기포 안정성에 미치는 영향에 관한 연구)

  • Lee, YeJin;Park, KiHo;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.31 no.1
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    • pp.49-56
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    • 2020
  • In this study, surface modification of CaCO3 nanoparticles by a silane coupling agent propyltrimethoxysilane (PTMS) was conducted and the effect of surface hydrophobicity on the stability of foam and emulsion was studied in order to test the potential applicability as a foam stabilizer or an emulsifier. The surface modification of CaCO3 nanoparticles by PTMS was confirmed by FT-IR, DSC and TGA analysis. The atomic concentration of CaCO3 particle surface treated by PTMS has been also identified by using XRD and XPS analyses. Both floating tests and contact angle measurements were also performed to examine the effect of PTMS concentration on the surface modification of CaCO3 nanoparticles.

An Experimental Study for the Scale Effects on Shear Behavior of Rock Joint (절리면 전단거동의 크기효과에 관한 실험적 연구)

  • Lee, Sang-Eun
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.3
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    • pp.31-41
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    • 2006
  • The scale effect of specimens on the shear behavior of joints is studied by performing direct shear tests on six different sizes in Granite. The peak and residual shear stress, shear displacement, shear stiffness, and dilation angle are measured with the different normal stress(0.29~2.65MPa) and roughness parameters. It is also shown that both the joint roughness coefficient(JRC) and the joint compression strength(JCS) reduce with increasing joint length. A series of shear tests show about 56~67% reduction in peak shear stress, and about 18~44% in residual shear stress, respectively as the contact area of joint increases from 12.25 to $361cm^2$. Also the variation of dilation angle is $27^{\circ}$ at normal stress of 0.29 MPa and $6^{\circ}$ at normal stress of 2.65 MPa, respectively. The envelopes considering scale effect for JRC are made for the peak shear strength of rock joint in comparison with the Barton's equation.

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The Effect of Service Employees'Emotional Intelligence on Service-Oriented OCB through Deep Acting (서비스 직원의 감성지능이 서비스지향 조직시민행동에 미치는 영향: 내면연기의 매개효과성)

  • Yang, Yinyan;Ahn, Hee-Kyu;Shin, Ho-Chul
    • Journal of Korean Society for Quality Management
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    • v.46 no.3
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    • pp.659-676
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    • 2018
  • Purpose: Although emotional intelligence(EI) is seemingly related to the service-oriented citizenship behaviors(OCB) of contact employees who are directly interacting with customers, there are only a few studies examining the relationship between the two. This study attempts to provide empirical evidence for a link between EI and service-oriented OCB. In addition, when EI affects service-oriented OCB, this present study identifies which emotional labor strategy between surface acting and deep acting is to be chosen. Methods: The data of EI, service-oriented OCB, surface acting, and deep acting were collected from 142 sales employees who provided services in four large domestic department stores. Hierarchical regression analyses were performed to verify empirically the main effects between EI and service-oriented OCB and mediating effects of emotional labor strategy. Results: The results show that EI is significantly related to service-oriented OCB in the current sample. Results also indicate that the deep acting rather than surface acting reveals a mediating effect in the process of EI affecting service-oriented OCB. Conclusion: The results of this study shows that EI which has a conceptual basis for OCB, can be extended to service-oriented OCB, The results also contribute to expanding the understanding of the relationship between EI and service-oriented OCB by testing the effect of EI on service-oriented OCB through deep acting. Theoretical and practical implications are reviewed, and limitations of the study and suggestions for future research are addressed.

Axial Fatigue Behavior of Structural Cables (구조용 케이블의 축방향 피로거동)

  • Suh, Jeong In;Chang, Sung Pil
    • Journal of Korean Society of Steel Construction
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    • v.10 no.4 s.37
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    • pp.589-600
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    • 1998
  • This study was planned to verify the usefulness of Latin square design method in fatigue tests of cables and to see the axial fatigue behavior of wire ropes being used as hangers in suspension bridges. Three parameters : mean stress, stress range. and specimen length, were adopted for verification. The effects of these parameters are in argument except for stress range. Three classes in each parameter were used. Triple replication was performed in each cell to increase the number of replication (or degree of freedoms). The major cause of fatigue failure was fretting fatigue at trellis contact point. Three chosen parameters were proved to be significant. It was verified that the effect of stress range was in agreement with expectation, but the effect of specimen length was contrary to the expectation. It was also observed that the effect of mean stress depended upon the chosen level. Therefore Latin square design method is effective for verifying the parameters that affect fatigue behaviour under orthogonality conditions.

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Plasma Treatment Effect of Organic/Organic Core-Shell Acrylic Adhesive Binder (II) (Organic/Organic Core-Shell 아크릴 접착바인더의 플라즈마 처리영향 (II))

  • Seul, Soo-Duk
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.89-96
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    • 2010
  • Adhesive binders with core-shell structure of organic/organic pair were prepared by emulsion polymerization of acrylic monomers, such as methyl methacrylate(MMA), ethyl acrylate(EA), n-butyl acrylate(BA), and styrene(St). Ammonium persulfate (APS) was used as an water soluble initiator in the presence of an anionic surfactant, sodium dodecyl benzene sulfonate (SDBS). Non-woven fabric and leather were impregnated with the adhesive binder. The surface of the impregnated fabric and leather were treated with plasma technique and then kinetics analysis and mechanical properties were measured. The conversions of the polymerization of core-shell binder (MMA/EA, MMA/BA) were greater than 90%. When the core-shell binder was prepared at equimolar conditions, the increasing effect of the core-shell binder on the state peel strength of the impregnated and plasma-treated non-woven/non-woven fabric has the order of MMA/St, EA/BA, BA/MMA, EA/St, and EA/MMA. When the core-shell binder was prepared at non-equimolar conditions, the increasing effect of the core-shell binder on the state peel strength of the non-woven fabric/leather has the order of MMA/BA, BA/EA, MMA/EA, St/MMA, and EA/St.

[ $PFC^{3D}$ ] Modeling of Stress Wave Propagation Using The Hopkinson's Effect ($PFC^{3D}$ 상에서의 홉킨슨 효과를 이용한 응력파의 전파모델링)

  • Choi Byung-Hee;Ryu Chang-ha
    • Explosives and Blasting
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    • v.23 no.3
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    • pp.27-42
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    • 2005
  • An explosion modeling technique was developed by using the spherical discrete element code, $PFC^{3D}$, which can be used to model the dynamic stress wave propagation phenomenon. The modeling technique is simply based on an idea that the explosion pressure should be applied to a $PFC^{3D}$ particle assembly not in the form of an external force (body force), but in the form of a contact force (surface force). The stress wave propagation modeling was conducted by simulating the experimental approach based on the Hopkinson's effect combined with the spatting phenomenon that had previously been developed to determine the dynamic tensile strength of Inada granite. As a result, the stress wave velocity obtained by the proposed modeling technique was 4167 m/s, which is merely $3\%$ lower than the actual wave velocity of 4300 m/s for an Inada granite.

A Study on the Influence of Emotional Labor and Social Support on Airline Call Center Agent Burnout (항공사 콜센터 상담원의 감정노동과 사회적 지원이 소진에 미치는 영향 연구)

  • Kwon, Mi-Kyung;Yoon, Sun-Young
    • Journal of Advanced Navigation Technology
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    • v.15 no.5
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    • pp.808-822
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    • 2011
  • In the subject experiment of this paper, contrary to the existing thesis about the emotional labor of people in the face-to-face service industry, I have chosen call center agents as they are primary first point of contact with customers in the airline industry. The main purpose of this experiment is to understand the relationship in between workplace burnout and emotional labor. In this study, I have investigated the following concepts; the effect of mediation on emotional labor, the different levels of emotional labor, and recommendations for improvement of competitive power to the call center agent as a member of the organization. The main results of experiment are as follows. First, the emotional labor given by the airline call center agents affects the rate of burnout. Second, support from workplace superiors showed that mediation had an effect on the relationship between emotional labor and burnout, however support from co-workers had no effect whatsoever. It is hope that this paper would supply information to give a competitive edge for airline call centers and their agents.