• Title/Summary/Keyword: constant rate of change

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Study on the single bubble growth at saturated pool boiling (포화상태 풀비등시 단일기포의 성장에 관한 연구)

  • Kim, Jeong-Bae;Lee, Han-Choon;Oh, Byung-Do;Kim, Moo-Hwan
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1933-1938
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    • 2004
  • Nucleate boiling experiments with constant wall temperature of heating surface were performed using R113 for almost saturated pool boiling conditions. A microscale heater array and Wheatstone bridge circuits were used to maintain a constant wall temperature condition and to measure the heat flow rate with high temporal and spatial resolutions. Bubble images during the bubble growth were taken as 5000 frames a sec using a high-speed CCD camera synchronized with the heat flow rate measurements. The geometry of the bubble during growth time could be obtained from the captured bubble images. The bubble growth behavior was analyzed using the new dimensionless parameters for each growth regions to permit comparisons with previous results at the same scale. We found that the new dimensionless parameters can describe the whole growth region as initial and later respectively. The comparisons showed good agreement in the initial and thermal growth regions. The required heat flow rate for the volume change of the observed bubble was estimated to be larger than the instantaneous heat flow rate measured at the wall. Heat, which is different from the instantaneous heat supplied through the heating wall, can be estimated as being transferred through the interface between bubble and liquid even with saturated pool conditions. This phenomenon under a saturated pool condition needs to be analyzed and the data from this study can supply the good experimental data with the precise boundary condition (constant wall temperature).

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$CO_2$ Production in Fermentation of Dongchimi (Pickled Radish Roots, Watery Radish Kimchi) (동치미의 발효중 $CO_2$ 발생특성)

  • 이동선;이영순
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.6
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    • pp.1021-1027
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    • 1997
  • $CO_2$production in fermentation of dongchimi was measured and interrelated with changes in pH and titratable acidity. The effects of salt content and temperature on $CO_2$production rate were analysed. Fermentation of dongchimi showed drastic pH decrease in early stage and subsequent levelling off around 3.9, with linearly increased acidity up to 0.3~0.4% optimum quality. $CO_2$production of dongchimi could be analysed to consist of two consecutive stages of constant rate. The first stage $CO_2$production of higher rate moved to the second stage of lower rate when acidity rose beyond 0.3%. When compared to those of 1 and 2% salt content, dongchimi of 3% salt showed lower $CO_2$production rate in the 1st stage and slower acidity change through the whole fermentation period. However, it resulted in the product of highest $CO_2$accumulation at optimal ripeness because of consistent $CO_2$production of longer 1st stage period and relatively high $CO_2$production rate in 2nd stage. $CO_2$production depended on temperature less compared to acidity change(activation energy: 57.3 and 44.3kJ/mol for $CO_2$production of 1st and 2nd stages, respectively; 79.3kJ/mol for acidity change), which means higher ratio of $CO_2$production rate relative to acidity increase at lower temperature. Slower increase in acidity at low temperature also was shown to extend the period of 1st stage $CO_2$production. Therefore, low temperature fermentation was effective in producing the high $CO_2$content dongchimi at adequate acidity, which is desirable organoleptically.

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Process Modeling and Optimization Studies in Drying of Current Transformers

  • Bhattacharya, Subhendu;D'Melo, Dawid;Chaudhari, Lokesh;Sharma, Ram Avatar;Swain, Sarojini
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.6
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    • pp.273-277
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    • 2012
  • The vacuum drying process for drying of paper in current transformers was modeled with an aim to develop an understanding of the drying mechanism involved and also to predict the water collection rates. A molecular as well as macroscopic approach was adopted for the prediction of drying rate. Ficks law of diffusion was adopted for the prediction of drying rates at macroscopic levels. A steady state and dynamic mass transfer simulation was performed. The bulk diffusion coefficient was calculated using weight loss experiments. The accuracy of the solution was a strong function of the relation developed to determine the equilibrium moisture content. The actually observed diffusion constant was also important to predict the plant water removal rate. Thermo gravimetric studies helped in calculating the diffusion constant. In addition, simulation studies revealed the formation of perpetual moisture traps (loops) inside the CT. These loops can only be broken by changing the temperature or pressure of the system. The change in temperature or pressure changes the kinetic or potential energy of the effusing vapor resulting in breaking of the loop. The cycle was developed based on this mechanism. Additionally, simulation studies also revealed that the actual mechanism of moisture diffusion in CT's is by surface jumps initiated by surface diffusion balanced against the surrounding pressure. Every subsequent step in the cycle was to break such loops. The effect of change in drying time on the electrical properties of the insulation was also assessed. The measurement of capacitance at the rated voltage and one third of the rated voltage demonstrated that the capacitance change is within the acceptance limit. Hence, the new cycle does not affect the electrical performance of the CT.

A Study on High Temperature Creep and Stress Relaxation Properties of Zr-4 (Zr-4의 고온 크리프 및 응력이완 특성에 관한 연구)

  • Oh, Sea-Kyoo;Park, Chung-Bae;Han, Sang-Deok
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.28 no.1
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    • pp.71-78
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    • 1992
  • Zr-4 used for a cladding and an end plug of reactor component has creep deformation under operation at high temperature. Creep is regarded as the time dependent deformation of a material under constant applied stress. Although the major source of the deformation of zirconium component in water-cooled reactors is irradiation creep, the thermal creep may give a rise to significant deformation in reactor component especially at relatively high temperatures and at various constant stresses, and therefore it must be predicted accurately. Stress relaxation is the time dependent change of stress at constant strain and it is a process related intimately to creep. In this paper, the creep behavior and stress relaxation of Zr-4 is examined at the temperature of 50$0^{\circ}C$ that is 40% of the absolute melting temperature of Zr-4 under the stress below yield stress and under the various constant strains. The results obtained are summarized as follows: 1) With an increase of stress, the steady state creep rate increases and the creep rupture time decreases. 2) The steady state creep rate $\varepsilon$(%/s) for the stress $\sigma$sub(c) (kgf/mm super(2)) of Zr-4 increases outstandingly. All the empirical equations computed for Zr-4 increases outstandingly. All the empirical equations computed for Zr-4 are in accord with Norton's model equation($\varepsilon$=K$\sigma$ sub(c) super (n)). The constants of materials computed are as follows: K=3.9881$\times$10 super(-5), n=1.9608 3) The rupture time T sub(r) (hr) decreases linearly with the increase of stress on the log-log scaled graph. The empirical equations computed for Zr-4 are in accord with Bailey's model equation (T sub(r)=K sub(1)$\sigma$sub(c) super(m)). The constants of materials computed are as follows: K sub(1)=1.2875$\times$10 super(16), m=-3.467 4) It seems clear that the strain could be quantitatively dependent on the high temperature creep properties such as creep stress, rupture time, steady state creep rate and total creep rate. It is found that these relationships are linear on the log-log graph. 5) In stress relaxation test, as the critical constant strain that can be allowed to the specimen is larger, stress relaxation becomes more rapid, and as the constant strain is smaller, the stress relaxation becomes slower.

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An Approximate Analytical Solution for the Unsteady Close-Contact Melting on a Flat Surface with Constant Heat Flux (등열유속에 의한 평판위 비정상 접촉융해에 대한 근사적 해석해)

  • Yoo, Hoseon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.12
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    • pp.1726-1734
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    • 1998
  • This paper focuses on the unsteady close-contact melting phenomenon occurring between a phase change material kept at its melting temperature and a flat surface on which constant heat flux is imposed. Based on the same simplifications and framework of analysis as the case of constant surface temperature, an approximate analytical solution which depends only on the liquid-to-solid density ratio is successfully derived. In order to keep consistency with the known solution procedure, both the dimensionless wall heat flux and the Stefan number are properly redefined. The obtained solution proves to agree quite well with the published numerical data and to be capable of resolving the fundamental features of unsteady close-contact melting, especially in the presence of the solid-liquid density difference. The density ratio directly affects the film growth rate and the initial value of solid descending velocity, thereby controlling the duration of unsteady process. The effects of other parameters can be evaluated readily from the steady solution which is implied in the normalized result. Since the dimensionless surface temperature for the present boundary condition increases from zero to unity along the evolution path of the liquid film thickness, the unsteady process lasts longer than that for the case of isothermal heating.

Effect of sequence variations within DNA melting region on the rate of formation of open complexes at $\lambdaP_{R}$ promoter ($\lambdaP_{R}$ 프로모터 열린복합체 형성에 미치는 DNA melting 부위 염기서열의 영향)

  • 정현채;노정혜
    • Korean Journal of Microbiology
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    • v.28 no.1
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    • pp.19-26
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    • 1990
  • To examine the effects of sequence variations near the transcriptional start site on the rate of formation of the open complexes at bacteriophage $\lambda P_{R}$ promoter, two mutant promoters were created by site-specific mutagenesis using synthetic oligonucleotides. Mutant I coatains changes at positions -3 and -4 from TT to CC, thus having a 6-bp long G/C stretch between -10 region and transciptional start site (+1). Mutant II has changes at positions -5 and -6 from GG to AA, thereby having a 9-bp long A/T stretch between positions -11 and -3. Selective filter binding assays were performed to measure the rate of formation of the open complexes between the wild-type or two mutant $P_{R}$ promoters on 664 bp fragments and E. coli RNA polymerase at two temperatures. At 37.deg.C, the wild-type and two mutants showed similar rates for the formation of open complex. The second order rate constant $k_{a}$ and $\tau _{int}$, as determined from the .tau.-plot analysis, were $(6.0\pm0.4)\times10^{6}M^{-1}sec^{-1}$ and $11\pm5$sec, respectively. At 18.deg.C, however, the wild-type and two mutant promoters showed differences in the kinetic parameters. k for the wild-type promoter was (2.2$\pm$0.1)\times 10^{6}M^{-1}sec^{-1}$ and $\tau _{int}$ was 76$\pm$sec. Mutant I and II exhibited differences mainly in the rate of isomerization ($\tau_{int,I}=91\pm$10 sec, int,II=34$\pm$ sec), whereas the second order rate constant $k_{a}$ was similar to the wild type value. This result implies that at $18^{\circ}C$, the isomerization rate is determined by both protein conformational change and DNA melting, which are separable kinetically according to the 3-step mechanism of Roe et al.(1984,1985), and that the base changes affected mainly the rate of DNA melting as predicted.lting as predicted.

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Studies on the Bioavailability of Berberine Preparations (베르베린 제제의 생체 이용율에 관한 연구)

  • Yang, Jae-Heon;Kim, Young-Il
    • Journal of Pharmaceutical Investigation
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    • v.22 no.1
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    • pp.55-62
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    • 1992
  • In order to measure the bioavailability of Coptidis Rhizoma preparations, berberine was extracted by the mixture (1:1 v/v) of methanol and water from Coptidis Rhizoma and formulated into pills with some excipients. Disintegration time, dissolution rate, intestinal absorption rate, antibacterial effect, and serum concentration were measured. All pills were disintegrated about 60 minutes in gastric and intestinal juices and disintegration time did not change upon storage at $40^{\circ}C$ for 30 days. The pills manufactured using the extract which was extracted with the solvent containing dilute sulfuric acid showed faster dissolution and absorption from the small intestine than the other samples. It also showed not only the largest area under the serum concentration time curve and relative bioavailability, but also more potent antibacterial effect against gram-positive and gram-negative bacterias than the other samples. The correlation of the dissolution rate with absorption rate constant or $t_{max}$ showed a significant linear relationship.

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Study of changes in the kinetic parameters of corrosion on the macrocell current induced by the repair of reinforced concrete structures - Results of numerical simulation

  • Mostafa Haghtalab;Vahed Ghiasi;Aliakbar Shirzadi Javid
    • Computers and Concrete
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    • v.32 no.3
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    • pp.287-302
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    • 2023
  • Corrosion of reinforcing bars in reinforced concrete structures due to chloride attack in environments containing chloride ions is one of the most important factors in the destruction of concrete structures. According to the abundant reports that the corrosion rate around the repair area has increased due to the macro-cell current known as the incipient anode, it is necessary to understand the effective parameters. The main objective of this paper is to investigate the effect of the kinetic parameters of corrosion including the cathodic Tafel slope, exchange current density, and equilibrium potential in repair materials on the total corrosion rate and maximum corrosion rate in the patch repair system. With the numerical simulation of the patch repair system and concerning the effect of parameters such as electromotive force (substrate concrete activity level), length of repair area, and resistivity of substrate and repair concrete, and with constant other parameters, the sensitivity of the macro-cell current caused by changes in the kinetic parameters of corrosion of the repairing materials has been investigated. The results show that the maximum effect on the macro-cell current values occurred with the change of cathodic Tafel slope, and the effect change of exchange current density and the equilibrium potential is almost the same. In the low repair extant and low resistivity of the repairing materials, with the increase in the electromotive force (degree of substrate concrete activity) of the patch repair system, the sensitivity of the total corrosion current reduces with the reduction in the cathode Tafel slope. The overall corrosion current will be very sensitive to changes in the kinetic parameters of corrosion. The change in the cathodic Tafel slope from 0.16 to 0.12 V/dec and in 300 mV the electromotive force will translate into an increase of 200% of the total corrosion current. While the percentage of this change in currency density and equilibrium potential is 53 and 43 percent, respectively. Moreover, by increasing the electro-motive force, the sensitivity of the total corrosion current decreases or becomes constant. The maximum corrosion does not change significantly based on the modification of the corrosion kinetic parameters and the modification will not affect the maximum corrosion in the repair system. Given that the macro-cell current in addition to the repair geometry is influenced by the sections of reactions of cathodic, anodic, and ohmic drop in repair and base concrete materials, in different parameters depending on the dominance of each section, the sensitivity of the total current and maximum corrosion in each scenario will be different.

A Study on Two Phase Heat Exchange of Plate Type PCM Container (판형 상변화 물질 용기의 2상 열교환 현상 연구)

  • Kim, S.H.;Cho, S.W.;Lee, C.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.576-582
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    • 1996
  • This work studies qualitative thermal characteristics of PCM cold storage medium container and its surrounding streams. Experimental parameters are initial PCM temperature and cold water flow rate. A mathematical modeling was establised to estimate temperature distribution and the cooling process. We found that the phase-change temperatures of PCM varies from 6 to $8^{\circ}C$ which is constant for other materials and that the dominant heat transfer resistance is that on the container side taking about 3/4 of the total resistance. The one dimensional mathematical model predicts experimental data quit well.

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Modeling of Fine Sediment Transport under Multiple Breakwaters of Surface-Piercing Type

  • Lee, J. L.;Oh, M. R.
    • Proceedings of the Korea Water Resources Association Conference
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    • 2004.05b
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    • pp.557-562
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    • 2004
  • A surface-piercing barrier model is presented for understanding morphological development in the sheltered region and investigating the main factors causing the severe accumulation. Surface-piercing structures like vertical barriers, surface docks and floating breakwaters are recently favored from the point of view of a marine scenario since they do not in general partition the natural sea. The numerical solutions are compared with experimental data on wave profiles and morphological change rates within a rectangular harbor of a constant depth protected by surface-piercing thin breakwaters as a simplified problem. Our numerical study involves several modules: 1) wave dynamics analyzed by a plane-wave approximation, 2) suspended sediment transport combined with sediment erosion-deposition model, and 3) concurrent morphological changes. Scattering waves are solved by using a plane wave method without inclusion of evanescent modes. Evanescent modes are only considered in predicting the reflection ratio against the vertical barrier and energy losses due to vortex shedding from the lower edge of plate are taken into account. A new relationship to relate the near-bed concentration to the depth-mean concentration is presented by analyzing the vertical structure of concentration. The numerical solutions were also compared with experimental data on morphological changes within a rectangular harbor of constant water depth. Through the numerical experiments, the vortex-induced flow appears to be not ignorable in predicting the morphological changes although the immersion depth of a plate is not deep.

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