• Nuclear Engineering and Technology
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• 제43권1호
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• pp.83-88
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• 2011

To define the effect of strain rate variation from 0.04% to 0.004%/s on environmental fatigue of CF8M cast stainless steel, which is used as a primary piping material in nuclear power plants, low-cycle fatigue tests were conducted at operating pressure and temperature condition of a pressurized water reactor, 15 MPa and $315^{\circ}C$, respectively. A high-pressure and high-temperature autoclave and cylindrical solid fatigue specimens were used for the strain-controlled low-cycle environmental fatigue tests. It was observed that the fatigue life of CF8M stainless steel is shortened as the strain rate decreases. Due to the effect of test temperature, the fatigue data of NUREG-6909 appears a slightly shorter than that obtained by KEPRI at the same stress amplitude of $1{\times}10^3$ MPa. The environmental fatigue correction factor $F_{en}$'s calculated with inputs of the test data increases with high strain amplitude, while the $F_{en}$'s of NUREG-6909 remain constant regardless of strain amplitude.

• The Korean Journal of Ecology
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• 제6권2호
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• pp.81-89
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• 1983

The change of environmental factors with flow rates were studied quantitatively for two rivers, the Nakdong River and the Sin stream, which have different basins in ecosystem structures, during short period after a heavy rain. In the Nakdong River, transparency, DO, alkalinity and hardness were negatively correlated with the flow rate by logarithmic function, but the concentration of SiO2 was relatively constant regardless of the flow chage. In the Sin stream, transparency, alkalinity, hardness and the concentration of NH3-N, NO2-N and SO4= showed negative correlation with the flow rate by logarithmic function. The ratios of maximum to minimum values for aquatic environmental factors during the samller than that for flow rate in the respective rivers (28 in the Nakdong R.; 50 in the Sin S.). Immediately after the heavy rain, the concentrations of NO2-N, NH3-N and PO4-P in the Sin stream were 8, 6 and 1 times as high as those in the Nakdong River, respectively, but in the stable flow state, those became 94, 25 and more than 10 times, respectively. The load for most of the dissolved environmental constituents changed similarly to the flow rate in both rivers. It is notable that, at the stable flow state, the loads for NH3-N (59g/sec) and NO2-N (3.3g/sec) in the Sin stream were 4.3 and 1.3 times as high as those in the Nakdong River.

• 한국지열·수열에너지학회논문집
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• 제20권2호
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• pp.11-23
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• 2024

In order to design a standing column well (SCW) for a sustainable groundwater curtain system for greenhouse heating, we conducted parameter sensitivity tests. These tests simulated the outlet temperature changes of the SCW in a groundwater recirculating greenhouse cultivation system. Our modeling considered ground thermal conductivity and hydrogeological conditions. Specifically, we examined several factors, including SCW length, enhanced thermal conductivity of the ground, and groundwater circulation rate. The simulation results indicated that there was not a significant difference in the heat exchange rate based on the characteristics of enhanced thermal conductivity. However, we anticipate a substantial difference in the case of varying SCW lengths. Therefore, we conclude that the simulation results are primarily influenced by conductive heat exchange values, as the circulating water remains at a constant groundwater level.

• Fibers and Polymers
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• 제2권2호
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• pp.98-107
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• 2001

The phase transition behavior isothermal micro-phase separation kinetics of polyester-based thermoplastic elastomer were studied using the synchrotron X-ray scattering(SAXS) method. The structural changes occurring during heating period were investigated by determining the changes of the one-dimensional correlation function, interfacial thickness and Porod constant. Based on the abrupt increases of the domain spacing and interfacial thickness, a major structural change occurring well below the melting transition temperature is suggested. Those changes are explained in terms of melting of the thermodynamically unstable hard domains or/and the interdiffusion of the hard and soft segments in the interfacial regions. SAXS profile changes during the micro-phase separation process were also clearly observed at various temperatures and the separation rate was found to be sensitively affected by the temperature. The peak position of maximum scattering intensity stayed constant during the entire course of the phase separation process. The scattering data during the isothermal phase separation process was interpreted with the Cahn-Hilliard diffusion equation. The experimental data obtained during the early stage of the phase separation seems to satisfy the Cahn-Hilliard spinodal mechanism. The transition temperature obtained from the extrapolation of the diffusion coefficient to zero value turned out to be about 147$\pm$$2^{\circ}$, which is close to the order-disorder transition temperature obtained from the Porod analysis. The transition temperature was also estimated from the inveriant growth rate. By extrapolating the inveriant growth rate to zero, a transition temperature of about 145$\pm$$\pm$$2^{\circ}$ was obtained.

• 폴리머
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• 제29권1호
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• pp.59-63
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• 2005

FTIR을 이용하여 폴리(카프로락톤 다이올)과 지방족 이소시아네이트간의 반응속도에 관한 연구를 수행하였다. NCO 피크(2265 $cm^{-1}$)의 흡광도 변화를 통하여 반응속도를 해석하였다. 그 결과, 폴리(카프로락톤 다이올)과 이소시아네이트간의 반응은 전체적으로 단순 2차 반응속도법과 일치함이 확인되었고, 반응온도의 증가에 따라 속도 상수는 증가하였다. 반응속도 상수로부터 구한 활성화에너지는 hexamethylene diisocyanate의 경우 25.4~30.9 kJ/mol, cyclohexylmethane diisocyanate의 경우 16.8~22.1 kJ/mol로 각각 나타났다.

• The Korean Journal of Physiology
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• 제29권1호
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• pp.81-89
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• 1995

The effects of prolactin and vasopressin on the regulation of amniotic fluid (AF) volume and its $Na^{+}$ concentration $([Na^{+}])$ through the membrane surrounding the AF during increase in AF volume due to fetal urination were studied. About 70% of AF volume was replaced with normal isotonic saline solution. Isotonic saline solution (0.5 ml) containing Censored and LiCl was introduced into each amniotic sac. Vasopressin (25 ng/ml) or prolactin (1 mg/ml) of AF was then injected into experimental amniotic sac. The concentrations of Congored, $Li^{+}$, and $Na^{+}$ were measured at 30 and 60 min intervals after injection. Af samples with decreased Censored concentration ([CR]) during the period of 30 - 60 min were analyzed. The percentage change of $[Na^{+}]$ and the rate of $Li^{+}$ movement during this period were calculated, and the effects of vasopressin and prolactin on them were evaluated. Fellowing results were obtained: 1. The rate of reduction of [CR] in the AF was retarded by vasopressin or prolactin injection. 2. The rate of reduction of $[Li^{+}]$ in the AF was also retarded by vasopressin or prolactin injection. 3. The rate of reduction of $[Li^{+}]$ in the AF was less retarded by vasopressin than that of [CR]. 4. $[Na^{+}]$ changed to approach to the normal level, but this was markedly retarded by prolactin injection. 5. Direction of $Li^{+}$ movement was correlated with the change in $[Na^{+}]$ but it always moved out of the amniotic sac even when the $[Na^{+}]$ increased in vasopressin injected AF. From the above results, it is suggested that vasopressin in the AF triggers the fetus to urinate, and then the membranes surrounding the AF regulate osmolarity by efflux of $Na^{+}$. We suggest that prolactin facilitates water outflow across the amniotic membrane during increase in AF volume, in contrast to a constant volume, whereas regulation of $[Na^{+}]$ is partly restricted by prolactin.

• International Journal of Vascular Biomedical Engineering
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• 제1권2호
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• pp.13-19
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• 2003

Endothelial release of nitric oxide (NO) contributes to the regulation of vascular tone by inducing vascular relaxation. To estimate the blood flow-dependent nitric oxide level and half-life (T1/2) of nitric oxide in vivo state, we investigated the change of aortic NO currents during the change of aortic blood flow rate using NO-selective electrode system and electromagnetic flowmeter in the aorta of anesthetized rats. Resting mean aortic blood flow rate was $49.6{\pm}5.6ml/min$ in the anesthetized rats. NO currents in the aorta were increased by the elevation of blood pressure and/or blood flow rate. When the aortic blood flow was occluded by the clamping, aortic NO currents were decreased. The difference of NO concentration between resting state and occluded state was $1.34{\pm}0.26{\mu}M$ (n=7). This NO concentration was estimated as blood flow-dependent nitric oxide concentration in the rats. Also, while the aortic blood flow was occluded, NO currents were decreased with exponential pattern with $12.84{\pm}2.15$ seconds of time constant and $7.70{\pm}1.07$ seconds of half-life. To summarize, this study suggested that blood flow-dependent NO concentration and half-life of nitric oxide were about $1.3{\mu}M$ and 7.7 seconds, respectively, in the aorta of anesthetized rats. The nitric oxide-selective electrode system is useful for the direct and continuous measurement of NO in vivo state.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제44회 KOSCO SYMPOSIUM 초록집
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• pp.199-200
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• 2012

An experimental study on geometric optimization was conducted to develop a hybrid/dual swirl jet combustor for a micro-gas turbine. A hybrid concept indicating a combination of swirling jet partially premixed and premixed flames were adopted to achieve high flame stability as well as clean combustion. Location of pilot nozzle, angle and direction of swirl vane were varied as main parameters with a constant fuel flow rate for each nozzle. The results showed that the variation in location of pilot nozzle resulted in significant change in swirl intensity due to the change in flow area near burner exit, and thus, optimized nozzle location was determined on the basis of CO and NOx emissions under conditions of co-swirl flow and swirl $angle=30^{\circ}$. The increase in swirl angle (from $30^{\circ}$ to $45^{\circ}$) enhanced the emission performances, in particular, with a significant reduction of CO emission near lean-flammability limit. It was observed that the CO emission near lean-flammability limit was further reduced through the counter-swirl flow. However, there was not significant change in the NOx emission in the operating conditions (i.e. equivalence ratio of 0.6~0.7) between the co- and the counter-swirl flow.

• 대한수학교육학회지:학교수학
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• 제18권1호
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• pp.43-59
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• 2016

본 사례 연구의 목적은 대수 문장제의 해결에서 드러나는 학생간의 차이를 공변적 관점에서 탐색하는 것이다. 영재 사사교육 프로그램에 참여한 중학교 3학년 4명의 학생을 대상으로 약 7개월간에 걸쳐 다양한 대수 문장제 해결을 위한 수업을 실시하였고, 수집된 자료를 분석한 결과 변화율이 일정하게 변화하는 상황을 포함하는 대수 문장제의 해결에서 '동희'와 '정희'의 차이점이 발견되었다. 이에 본 연구는 '동희'와 '정희'의 비율 관계를 포함하는 대수 문장제의 해결과 문제에 제시된 상황을 일반화하는 모든 행위에 주목하여, 이러한 행위로부터 추론된 두 변량 사이의 변화 관계에 대한 인식을 Moore와 Carlson(2012)이 제시한 공변 추론 수준에 비추어 비교, 분석하였다.

• Bulletin of the Korean Chemical Society
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• 제18권9호
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• pp.961-965
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• 1997

1H NMR spectra of 3,3-dimethylpiperidine (1) at -70 to 30 ℃ exhibit gradual change from slow to rapid exchange between two alternate chair forms. The exchange rate constant was determined as a function of temperature by simulating the line shape of the signal from the two methyl groups using the modified Bloch equations. The resulting free energy of activation is ΔG* = 44.4±1.9 kJ mol-1 at 298 K. The 1H NMR spectrum of a D2O or dimethylsulfoxide-d6 (DMSO-d6) solution containing 1 and [SiW11CoⅡO39]6- exhibits separate signals for the free ligand and the complex, indicating that the ligand exchange is slow on the NMR time scale. In D2O the piperidine ring is frozen as a chair form even at room temperature with the cobalt ion bonded to the axial position of the nitrogen atom. When DMSO-d6 is added to the D2O solution, the NMR spectral change suggests that a rapid exchange occurs between the chair form and another conformer. It is proposed that the conformation of ^b1^b coordinated to [SiW11CoⅡO39]6- in DMSO-d6 is close to a twist form.