• Title/Summary/Keyword: concentration measure

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Evaluation of Concentration Polarization at Feed in the Permeation of VOCs/$N_2$ mixtures through PDMS membrane (VOCs/질소 혼합물 증기투과시 공급액부 경계층에서의 농도분극 분석을 위한 모델식 확립)

  • 염충균;이상학;최정환;이정민
    • Membrane Journal
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    • v.11 no.2
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    • pp.74-82
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    • 2001
  • By using a phenomenological approach, model equations incorporating the resistance-in¬series concept were established to evaluate quantitatively concentration polarization in the boundary layer in feed adjacent to the membrane surface in the vapor permeation and separation of volatile organic compounds (VOCS)/$N_2$ mixture through po]y(dimethylsiloxane) (PDMS) membrane. The vapor permeations of various VOCS/$N_2$ mixtures through PDMS membrane were carried out at various feed flow rates. Chlorinated hydrocarbons, such as, methylene chloride, chlorofonn, 1,2-clichloroethane and 1,1,2-trichloroethane were used as organic vapor. By fitting the model equations to the experimental penneation data. the model parameters were detennined. respectively. Both the mass transfer coefficient of VOC across tbe boundary layer and concentration polarization modulus as a measure of the extent of concentration polarization were eitimated Quantitatively by the mooe1 equations with the determined model parameters. From the analysis on the detennined model parameters, the boundary layer resistance due to the concentration polarization of VOCs component was found to be more significant when the condensability of voe was greater. This study seeks to emphasize the importance of the boundary resistance on the vapor penneation of the vapor/gas mixtures with high permeability and high selectivity towards the minor component VOC.

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Effects of Silane Concentration on the Silica-Silica Interaction Parameter (αF) of the Silica / Natural Rubber Compound (실란농도가 실리카 / 천연고무 복합소재의 실리카 입자간 상호 관계 계수 (αF)에 미치는 영향의 비교)

  • Kim, Sung-Min;Jang, Mi-Kyeong;Choi, Chang-Yong;Nah, Jae-Woon;Kim, Kwang-Jea
    • Elastomers and Composites
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    • v.47 no.1
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    • pp.23-29
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    • 2012
  • The silica-silica interaction parameter (${\alpha}_F$) of the silane treated silica filled natural rubber (NR) compound was investigated. As silane (TESPT) concentration increased from 2 to 12% (2, 4, 6, 8, 10, 12%), the ${\alpha}_F$ value increased at the same silica concentration (10, 20, 30, and 40 phr). It seemed the sulfur atoms in TESPT acted as a crosslinking agent in the compound. As silica concentration increased from 10 to 40 phr, the ${\alpha}_F$ value increased at the same silane concentration due to increased silica-silica interaction.

The Study on the Level of Air Pollution at Four Department Stores in Pusan Area (부산지역 4개 백화점의 공기오염도에 관한 조사연구)

  • Moon, D.H.;Rhee, HW.;Lee, C.U.
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.1 no.2
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    • pp.164-180
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    • 1991
  • For the purpose of contributing to the promotion of health of the employees working at the same kind of department store or similar type of business and the people utilizing them and preparing the basic data for the establishment of mangagement measure by assessing the level of air pollusion at indoor and outodoor of four department store among the distribution service business in Pusan area, authors measured the concentration of sulfur dioxide, nitrogen dioxide, formaldehyde and total suspanded particle according to the measuring height of variable at indoor and outodoor from Aug. 1990. to sep. an. d Jan, 1991 to Feb.: for each two months in summer and winter, and studied by dividing the variable factor into atmospheric factor (temperature, humidity and air velociy) The results are as follows ; 1. The mean concentration of air pollutants at indoor to total subjects was nitrogen dioxide 31.1ppb, sulfur dioxide 51.7ppb, formaldehyde 162.lppb and total suspanded particle $67.7{\mu}g/m^3$, and it was higher in winter than in summer (P>0.05) 2. The mean concentration of formaldehyde to total subjects was higher indoors than outdoors (P<0.001), in case of nitrogen dioxide there was no significant difference and sulfur dioxide and total suspanded particle were higher outdoors than indoors (P<0.05) 3. The concentration of nitrogen dioxide and sulfur dioxide proved to be a adverse correlation, reducing with height. 4. According to the result questioned about the exposure concentration of pollutant and the general symptom caused by the pollutant, nitorgen dioxide and symptom proved to be a positive correlation (P<0.09).

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Enhanced Natural Purification of Crude Oil Contaminated Tidal Flat (원유로 오염된 갯벌 지역의 자연정화 기능 향상 기술의 개발)

  • Kim, Young-A;Sung, Ki-June
    • Journal of Soil and Groundwater Environment
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    • v.16 no.5
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    • pp.24-30
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    • 2011
  • Tidal flats which are ecologically sensitive, are hard to remediate once they are contaminated by oil spill accidents. Traditional oil remediation measures focus on removal efficiency, and their improper implementation can adversely affect crude oil contaminated coastal areas and greatly disrupt the structure and functions of crude oil contaminated tidal flats. In this study, the oil degradation due to the implementation of remediation measures naturally enhanced using air and natural oil sorbents was evaluated in the lower strata of tidal flats. The effects of air and natural oil sorbents on oil degradation for two concentration levels (< 500 ppm and > 500 ppm) were tested at artificially contaminated tidal flats. Fifty days after these treatments, the natural oil sorbent treatment showed the lowest total petroleum hydrocarbon (TPH) concentration ($4.46{\pm}1.47%$) at the low concentration level, whereas both air and natural oil sorbent treatments showed high degradation efficiencies at the high concentration level ($29.30{\pm}4.39%$). Although the phosphatase activity decreased for all treatments, there was no significant difference between the decreases for the different treatments; on the other hand, B-glucosidase activities were high for both air and natural oil sorbent treatments. Although degradation efficiencies decreased as the concentration increased, the air provision and natural oil sorbent treatment could be an effective ecological restoration measure for oil contaminated tidal flats while minimizing the environmental impact of the remediation efforts.

An Analysis of Degree of Visitor Concentration of Forested National Parks Using the Gini Coefficients and Lorenz Curve (지니계수와 로렌츠곡선을 이용한 산악형 국립공원의 탐방집중도 분석)

  • Han, Sang-Yoel
    • Journal of Korean Society of Forest Science
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    • v.95 no.4
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    • pp.476-483
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    • 2006
  • This study tried to estimate the concentration indices of 15 forested national parks using Gini coefficient and Lorenz curve which can be measure the degree of inequality. The concentration indices were estimated by two parts which are yearly index for the periods of 1997-2005 and travel origin area(city or province) distribution index each national park. The empirical results were as follows: first, yearly Gini coefficients showed severe inequality. Particularly, 2004 and 2005 Gini coefficients were .453 and .446. which are intensive inequality compared with other years. Second, in travel origin area distribution each national park, Gini coefficients of Bukhansan and Kyeryungsan national park were .916 and .855 which are the great inequality compared with other national parks. The other hand, Gini coefficients of Dukyusan and Byunsanbando national parks were .508 and .628 which are the lowest inequality. The national park policy manager should find out the factors of concentration and deconcentration each year and national park and decided the visitor distribution policy which visitor size and scope for balancing the natural resources use.

Monitoring of Nitrogen Ion in Nitrifying Biofilm using an Ion Selective Microelectrode (이온선택성 미소전극을 이용한 질산화 생물막내의 질소 이온의 농도 모니터링)

  • Seon, Ji-Yun;Byun, Im-Gyu;Lee, Tae-Ho;Park, Tae-Joo
    • KSBB Journal
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    • v.25 no.1
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    • pp.85-90
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    • 2010
  • An ion selective microelectrode (ISME) was fabricated to measure concentrations of ammonium (${NH_4}^+$-N) and nitrate (${NO_3}^-$-N) according to the depth of nitrifying biofilm. The limits of detectability and validity of results were investigated to evaluate the ISME. The electromotive force (EMF) was directly proportional to the ion concentration, and average detection limits of ${NH_4}^+$ and ${NO_3}^-$ ISME were $10^{-5.14}$ and $10^{-5.18}$ M, respectively. The concentrations of ${NH_4}^+ $-N and ${NO_3}^-$-N in various depths on the nitrifying biofilm were measured by the ISME. When a modified Ludzack-Ettinger (MLE) process was operated at an HRT of 6 h, concentration gradients of ${NH_4}^+$-N in the bulk solution and biofilm at depths of $100\;{\mu}m$ decreased by $70\;{\mu}M$, while ${NO_3}^-$-N increased by $101\;{\mu}M$ and remained constant thereafter. At an HRT of 4 h, concentration gradients of ${NH_4}^+$-N at depths of $500\;{\mu}m$ decreased by $160\;{\mu}M$ and ${NO_3}^-$-N increased by $162;{\mu}M$ and remained constant thereafter. As HRT decreased, the concentration gradients of ${NH_4}^+$-N and ${NO_3}^-$-N between bulk solution and biofilm was higher due to the increase of nitrogen load. Also, the concentration gradients of the ${NH_4}^+$-N and ${NO_3}^-$-N of biofilm in the second aerobic tank were lower than those of the first aerobic tank, suggesting differences of nitrogen load and concentrations of DO between the first and second aerobic tank.

Characteristics of Size Distribution and Fugitive Emissions of Particulate Matter in Foundries (주물사업장의 입자상물질 입경분포 및 비산배출 특성)

  • Park, Jeong-Ho;Jang, Min-Jae;Kim, Hyoung-Kab
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.26 no.1
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    • pp.30-37
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    • 2016
  • Objectives: This study was performed to measure and evaluate the concentration, size distribution and fugitive emission of particulate matter from process operations at foundries. Methods: Particle matter was collected from three foundries, and samples were also collected from a background site for calculating the fugitive emission concentration of the foundries. For the collection of the samples, a Nanosampler cascade impactor was used. Results: The concentration of TSP in the samples collected from the three foundries was $0.675{\sim}1.222mg/m^3$, $PM_{10}$ was $0.525{\sim}1.018mg/m^3$ and $PM_{2.5}$ was $0.192{\sim}0.615mg/m^3$. The mass size distribution was bimodal or monomodal with maximum peak at two stage(size $2.5{\sim}10{\mu}m$). The mass median aerodynamic diameter(MMAD) was $1.80{\sim}3.98{\mu}m$. The fugitive emission concentration of TSP varies in the range of 0.65 to $1.21mg/m^3$, which exceeds the emission standard of fugitive dust($0.5mg/m^3$). Conclusions: Particle concentration and size is an important industrial hygiene factor to protect foundry workers. Furthermore, the presence of high emission of particulate pollutants has a significant negative impact on the ambient air of the study area. Therefore, it is important to improve both the process and prevention facility in oder to reduce particulate pollutants in foundries.

Preparation of Phenoxy-Methylamino Cosubstituted Polyphosphazene Diagnostic Membranes for Blood Glucose Measurements (혈당 측정을 위한 페녹시-메틸아미노기가 함께 치환된 폴리포스파젠 진단막의 제조)

  • Kwon, Suk-Ky
    • Membrane Journal
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    • v.24 no.4
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    • pp.268-275
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    • 2014
  • The water-insoluble poly(phenoxy-methylamino)phosphazene has been synthesized and investigated as the new type of diagnostic membrane for the measurements of blood glucose level. Final absorbances at 680 nm through activated polyphosphazene membranes were measured at various concentration of glucose in blood. The end-point results of varing absorbance values according to time (K/S) were used to obtain glucose concentration. The effects of substitution rates with hydrophilic methylamino groups and hydrophobic phenoxy groups on the measurements of glucose concentration were studied. Dose-response slope (DRS) values between glucose concentration and K/S values increased as the hydrophilic substitution rates increased. However, in less than 5% of the hydrophilic substitution rates, DRS values are too low, and in more than 25% of the hydrophilic substitution rates, because DRS increased rapidly, it was difficult to measure exact concentration level of glucose.

Development of Light Transmission Fluctuation for Particle Measurement in Solid-Gas Two Phase Flows

  • YANG, Bin;WANG, Zhan-ping;HE, Yuan;CAI, Xiao-Shu
    • Particle and aerosol research
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    • v.12 no.1
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    • pp.21-26
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    • 2016
  • In order to realize In-line and convenient measurement for solid-gas two phase flows, Light Transmission Fluctuation (LTF) based on the random variation of transmitted light intensity, light scattering theory and cross-correlation method was presented for online measurement of particle size, concentration and velocity. The statistical relationship among transmitted light intensity, particle size and particle number in measurement zone was described by Beer-Lambert Law. Accordingly, the particle size and concentration were determined from the fluctuation signal of transmitted light intensity. Simultaneously, the particle velocity was calculated by cross-correlation analysis of two neighboring light beams. By considering the influence of concentration variation in industrial applications, the improved algorithm based on spectral analysis of transmitted light intensity was proposed to improve measurement accuracy and stability. Therefore, the online measurement system based on LTF was developed and applied to measure pulverized coal in power station and raw material in cement plant. The particle size, concentration and velocity of powder were monitored in real-time. It can provide important references for optimal control, energy saving and emission reduction of energy-intensive industries.

Effects of Atmospheric Composition Substitution and Pressure on Soot Formation of Jet-A1 Droplet Flames (대기조성 치환 및 압력이 Jet A1 액적화염의 매연입자 생성에 미치는 영향에 관한 연구)

  • Nam, Won-Sik;Ryu, Myung-Ho;Lee, Jong Won;Park, Seul-Hyun
    • Fire Science and Engineering
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    • v.33 no.5
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    • pp.13-18
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    • 2019
  • In this study, the soot formation characteristics of Jet-A1 liquid fuel droplet flames were investigated by measuring the soot concentration under atmospheric conditions similar to the working environment of the Korea Space Launch Vehicle (KSLV) To obtain the desired atmospheric conditions, the oxygen concentration in the combustion chamber was maintained at 30% and the pressure was varied between 0.1 and 0.06 MPa. The full-field light extinction technique was used to measure the concentration of soot particles generated by applying the identical to 2-mm-diameter Jet-A1 fuel droplets. The soot concentration of the Jet-A1 droplet flames was the highest in the nitrogen-substituted atmosphere and the lowest in the carbon dioxide-substituted atmosphere, despite the pressure. the pressure was decreased the measured soot concentrations reduced as a function of Pn.