• Membrane and Water Treatment
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• 제13권4호
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• pp.191-199
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• 2022

In industrial production, the development of traditional polyamide nanofiltration (NF) membrane was limited due to its poor oxidation resistance, complex preparation process and high cost. In this study, a composite NF membrane with high flux, high separation performance, high oxidation resistance and simple process preparation was prepared by the method of dilute solution dip coating. And the sulfonated polysulfone was used for dip coating. The results indicated that the concentration of glycerin, the pore size of the based membrane, the composition of the coating solution, and the post-treatment process had important effects on the structure and performance of the composite NF membrane. The composite NF membrane prepared without glycerol protecting based membrane had a low flux, when the concentration of glycerin increased from 5% to 15%, the pure water flux of the composite NF membrane increased from 46.4 LMH to 108.2 LMH, and the salt rejection rate did not change much. By optimizing the coating system, the rejection rate of Na₂SO₄ and PEG1000 was higher than 90%, the pure water flux was higher than 40 LMH (60psi), and it can withstand 20,000 ppm.h NaClO solution cleaning. When the post treatment processes was adjusted, the salt rejection rate of NaCl solution (250 ppm) reached 45.5%, and the flux reached 62.2 LMH.

• Mass Spectrometry Letters
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• 제15권1호
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• pp.1-25
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• 2024

Protein glycosylation, a highly significant and ubiquitous post-translational modification (PTM) in eukaryotic cells, has attracted considerable research interest due to its pivotal role in a wide array of essential biological processes. Conducting a comprehensive analysis of glycoproteins is imperative for understanding glycoprotein bio-functions and identifying glycosylated biomarkers. However, the complexity and heterogeneity of glycan structures, coupled with the low abundance and poor ionization efficiencies of glycopeptides have all contributed to making the analysis and subsequent identification of glycans and glycopeptides much more challenging than any other biopolymers. Nevertheless, the significant advancements in enrichment techniques, chromatographic separation, and mass spectrometric methodologies represent promising avenues for mitigating these challenges. Numerous substrates and multifunctional materials are being designed for glycopeptide enrichment, proving valuable in glycomics and glycoproteomics. Mass spectrometry (MS) is pivotal for probing protein glycosylation, offering sensitivity and structural insight into glycopeptides and glycans. Additionally, enhanced MS-based glycopeptide characterization employs various separation techniques like liquid chromatography, capillary electrophoresis, and ion mobility. In this review, we highlight recent advances in enrichment methods and MS-based separation techniques for analyzing different types of protein glycosylation. This review also discusses various approaches employed for glycan release that facilitate the investigation of the glycosylation sites of the identified glycoproteins. Furthermore, numerous bioinformatics tools aiding in accurately characterizing glycan and glycopeptides are covered.

• Macromolecular Research
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• 제16권8호
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• pp.676-681
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• 2008

The $\pi$-complex membranes of poly(styrene-b-(ethylene-co-butylene)-b-styrene) (SEBS) of two silver salts of $AgBF_4$ and $AgCF_3SO_3$ were prepared and tested for the separation of the propylene/propane mixtures. The Fourier-transform infrared (FT-IR) spectra of these complexes showed that the silver salts were dissolved in SEBS up to a silver mole fraction of 0.14, due to $\pi$-complexation between the aromatic C=C bonds of styrene blocks and silver ions. Above this solubility limit, ion pairs and high-order ionic aggregates began to form, so that silver salts were distributed unselectively in both the EB and PS blocks. The domain size of the PS blocks was enlarged up to this critical concentration with increasing silver concentration without structural transitions, as confirmed by small angle x-ray scattering (SAXS). These structural properties of the SEBS/silver salt complexes may explain the lower separation properties for propylene/propane mixtures compared to poly(styrene-b-butadiene-b-styrene)(SBS)/silver salt complex membranes.

• 한국막학회:학술대회논문집
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• 한국막학회 1998년도 춘계 총회 및 학술발표회
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• pp.89-92
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• 1998

1. Introduction : Among many azeotropic compounds, pyridine which forms an azeotropic mixture with three moles of water boiling at 92-93$\circ$C is very useful synthetic intermediate in laboratory and industry. With conventional separation method, the dehydration of pyridine aqueous solution is difficult and requires strong drying chemicals. To overcome these difficulties, several researchers have investigated on the separation of pyridine from aqueous solution through polymer membranes. Kujawski reported several ion-exchang membranes containing carboxylic and sulfonic fuctional group for dehydration of aqueous pyridine solution [1]. We have applied the idea of activation of water tranport through ion-dipole interactions between polymer membrane and aclueous feed. Our previous studies reported on the in-situ complex membrane to separate water from aqueous pyridine solution based on simple acid'-base theory [2, 3]. Water transport was enhanced through in-situ complex formation between the , acid moiety in the membrane and the incoming pyridine moiety in the feed.

• Journal of Pharmaceutical Investigation
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• 제19권2호
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• pp.99-107
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• 1989

In order to develop a pediatric liquid preparation with sustained release properties, dextromethorphan hydrobromide (DEXT) was complexed with strong cation exchange resin (CG 120) and the-complex was coated with Eudragit RS using a phase separation method by non-solvent addition. The effect of pH, ionic strength of the release medium and drug/resin ratio on the release rate of DEXT was studied. The release rate of free drug from the uncoated complex, and coated complexes with 9.5 and 18.5% Eudragit RS in artificial gastric juice were measured. The release rate from the uncoated complex was faster with higher pH, higher ionic strength of the release medium and higher drug/resin ratio. The release rate from the coated complex could be controlled by the amount of coating material, and the surface after release did not rupture into.

• Clinics in Shoulder and Elbow
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• 제15권2호
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• pp.143-147
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• 2012

상부 견갑 현수 복합체(Superior shoulder suspensory complex)의 3중 붕괴는 몇몇 저자들에 의해서만 보고된 극히 드문 손상이다. 저자들은 오구돌기, 견갑극 골절 및 견봉-쇄골 관절의 탈구가 동반된 상부 견갑 현수 복합체의 3중 붕괴 환자를 경험하였기에 보고하고자 한다. 본 환자의 경우 견봉-상완 및 오구-상완 간격을 유지하기 위하여 관혈적 정복 및 내고정을 시행하여 상부 견갑 현수 복합체의 3중 붕괴 모두를 해부학적으로 복원하여 치료하였다. 술 후 6개월에 증상 없이 관절운동범위를 모두 회복하였다. 최종 추시인 5년에는 상부 견갑 현수 복합체의 기능이 완전히 회복된 것을 확인할 수 있었으며, 환자는 수술 결과에 대하여 크게 만족하였다.

• 대한화학회지
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• 제35권5호
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• pp.534-538
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• 1991

흡착 분리 방법을 이용하여 고순도 삼염화실란(TCS) 중의 미량 붕소 농도를 분광광도법적으로 측정하는 방법을 제안하였다. TCS중의 붕소 화합물과 복합체를 잘 형성하고 황산-quinalizarin계 발색 시약에 잘 녹으며 측정시 간섭 효과를 나타내지 않는 Lewis 염기성 물질로 NaCl이 선택되었다. 이러한 흡착 분리 방법을 통해 TCS분석 도중에 실리카겔 및 기포가 생성되는 문제를 방지할 수 있었는데, 반도체급 TCS중의 붕소 농도는 ${\pm}$20%의 표준편차 범위내에서 6.1 ${\mu}$g/l로 측정되었다. 반면 NaCl로 붕소화합물을 제거시킨 정제된 TCS 중의 붕소 농도는 0.2 ${\mu}$g/l이어서 NaCl의 우수한 흡착 성능을 확인할 수 있었다. 또한 NaCl이 TCS 정제 중 붕소 제거에 효과적임을 다른 잘 알려진 흡착제들과 비교 분석하였다.

• 한국환경복원기술학회지
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• 제10권6호
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• pp.88-98
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• 2007

The control of nonpoint source pollution from the urban paved areas with high imperviousness in is required to improve the water quality of aquatic resources. This research investigated the characteristics of urban runoffs and evaluate the effectiveness of the continuous deflective separation systems for stormwater best management practice. The systems were installed in the vicinity of a high-level road, an apartment complex, and the Cheonggye stream. Stormwater runoff was sampled in these sites. Biochemical oxygen demand ($BOD_5$), total suspended solid (TSS), total nitrogen (T-N), and total phosphorus (T-P) were analyzed. The removal efficiency of $BOD_5$, TSS, and T-P for the road was 10.9-81.0%, 11.7-93.4%, 0-37.5%, respectively. That of $BOD_5$, TSS, T-N, and T-P for the complex was 12.5-65.8%, 26.5-77.6%, 1.8-28.7%, and 20.0-37.5%, respectively. The abatement efficiency $BOD_5$, TSS, T-N, and T-P for the stream was 7.2-85.2%, 41.7-98.2%, 11.3-65.6%, and 2.0-71.5%, respectively. This study shows that the systems can be used to remove $BOD_5$ and TSS from urban runoffs efficiently.

• 한국산업융합학회 논문집
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• 제3권1호
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• pp.77-82
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• 2000

The stereoselective ligand exchange reaction of trans-$[Co(SS-epm)Cl_2]^+$ and racemic propane-1,2-diamine (rac-pn) produces the complex that is identified as $[CO(N)_6]^{3+}$ type of $[Co(SS-epm)(pn)]^{3+}$ by absorption spectrum. It is conceivable that the reaction mechanism involves substitution and isomerization. The calculated and experimentally determined ratios of the complexed enantiomeric substrates at equilibrium were as follows: $[Co(SS-epm)(pn)]^{3+}$,calcd 32 % / 68 %, exptl 19 % / 81 % R-pn / S-pn. It has been shown that the employment of molecular mechanics calculations as a predictive tool may lead to the design of chiral complexes that may be applied to the separation of racemic mixtures of simple bidentate ligands.

• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2005년도 공동학술대회 논문집
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• pp.233-236
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• 2005

천부 탄성파 탐사 기록에서 신호부를 약화시키는 레일리파를 제거하고, 초동 인지가 어려운 S파 신호를 강화하는 방법을 제시하고자 다성분 복소트레이스 분석법에 기초한 분극 필터를 작성하였다. 이 분극필터의 효율성을 시험하기 위해서 단순한 수평 2층 모델 자료를 유한차분법으로 합성하였다. 그 결과 타원운동을 하는 레일리파가 비교적 잘 제거되고 선형운동의 P파와 S파도 효과적으로 분리됨을 볼 수 있었다.