• Title/Summary/Keyword: coating properties

Search Result 2,855, Processing Time 0.025 seconds

Effect of Pyrolysis Fuel Oil Based Carbon Coating onto CFX Cathode on High-rate Performance of Lithium Primary Batteries (불화탄소 전극의 열분해 연료유 기반 탄소 코팅이 리튬일차전지의 고율속 성능에 미치는 영향)

  • Sangyeop Lee;Naeun Ha;Seongjae Myeong;Chaehun Lim;Sei-Hyun Lee;Young-Seak Lee
    • Applied Chemistry for Engineering
    • /
    • v.35 no.4
    • /
    • pp.321-328
    • /
    • 2024
  • The performance of carbon fluoride-based lithium primary batteries (Li/CFX) is limited due to poor rate capability resulting from the low conductivity of carbon fluoride, which is used as the active material. Therefore, in this study, we applied a carbon coating using pyrolysis fuel oil on carbon fluoride to overcome this limitation and considered its electrochemical performance. An amorphous carbon layer was formed on the surface of the carbon fluoride through carbon coating, and the surface physicochemical properties of the carbon fluoride were meticulously considered based on the heat treatment temperature. The advanced research chemical 1000 heat treated at 450 ℃ (ARC@C450) sample, which was commercial carbon fluoride heat-treated at 450 ℃, showed the largest increase in the concentration of sp2 carbon bonds (62%) and the highest formation of semi-ionic C-F bonds. Also, the primary battery using the ARC@C450 sample as a cathode active material exhibited stable discharge capability at the highest rate of 5 C (392 mAh/g), and the Rct value was reduced by 53% compared to the untreated sample. Therefore, we proposed pyrolysis fuel oil-based carbon coating as a method to overcome the low conductivity of carbon fluoride, and the carbon-coated carbon fluoride showed excellent rate performance, suggesting its potential application in high-power primary batteries.

Synthesis of Poly(epoxy-imide)-Nano Silica Hybrid Film via CS Sol-gel Process and Their Dielectric Properties (CS졸을 이용한 Poly(epoxy-imide)-나노 Silica 하이브리드 필름의 합성과 유전특성)

  • Han, Se-Won;Han, Dong-Hee;Kang, Dong-Pil;Kang, Young-Taec
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.20 no.1
    • /
    • pp.35-40
    • /
    • 2007
  • The new PEI(poly(epoxy-imide))-nano Silica film has been synthesized via in situ CS sol process, and the chemical bonding and microstructure of nano silica dispersed in resin were examined by FT-IR, TAG and SEM. The dielectric properties of these hybrid films over a given temperature and frequency ranges have been studied in a point of view of stable chemical bonding of nano Silica filler. The results from IR spectra and SEM photograph indicated that PEI-Silica hybrid film prepared with nano CS sol process has been synthesized in uniform and chemical bonding. The decrease property of dielectric constant with CS content, tangent loss consistent of given frequency and temperature has been explained in terms of the chain movement of polymer through chemical bonging and size effect of nano silica. The new PEI-CS sol hybrid film with such stable chemical and dielectric properties was expected to be used as a high functional coating application in ET, IT and electric power products.

Effect of Calendering Variables on the Properties of Coated paper (캘린더 처리조건이 도공지 품질에 미치는 영향)

  • 이용규;김창근;이광섭
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.33 no.2
    • /
    • pp.49-57
    • /
    • 2001
  • This study was performed to identify the effect of calendering variables on the properties of coated paper such as sheet gloss, surface roughness, opacity, etc. The effect of calendering variables including the number of nips, pressure, machine speed and moisture content on the properties of coated paper was investigated. The calender was installed with two steel rolls and one cotton-made roll. With this calender, the coated sheets were passed through the calender from 1 to 4 times, applying the linear pressure on calender rolls, 5 through 100kg/cm and operating the machine speed 3 to 12m/min. Also, the moisture content of coated sheet was varied about 5 and 10%. It was found that sheet gloss and surface roughness of coated paper was increased with increasing the number of passing nips, linear roll pressure and the moisture content of coated paper. But it was shown that the opacity and brightness of coated paper were decreased under the above conditions due to the blackening. It was also suggested that the soft nip possibly increased the thermoplasticity of coating layer with the heat of steel roll, resulting in the reinforcement of surface properties positively. The sheet gloss and surface roughness of coated paper could be improved by the longer dwell time over the rolls.

  • PDF

Characteristics of Fancy Veneer Plywood Floor using Green Tea Leaves Powder (녹차잎분말을 사용한 마루판의 특성)

  • Kang, Seog-Goo;Lee, Hwa-Hyoung
    • Journal of the Korea Furniture Society
    • /
    • v.21 no.4
    • /
    • pp.284-292
    • /
    • 2010
  • This research was carried out to examine the properties of fancy cherry veneer overlaid on the PF resin bonded Meranti plywood floor, which 2.5% green tea leaf powder was applied in the UV varnishes and the adhesives for scavenging the volatile organic compounds. The results were as follows: 1. The various properties of the treated samples, such as density, moisture content, thickness swelling, bending strength(MOR), adhesion shear strength, surface abrasion, curling, cyclic delamination test with boiling water, boiling property, cold-resistance and heat resistance, acid resistance and alkali resistance, and anti-contamination property showed no significant difference between the properties of the control samples. 2.5% green tea leaf powder treated floor gave a little better results than the control for surface scratch test. 2. In case of QUV and weathering test, no difference between the treated sample and control was found. 3. The floor was discolored by adding 10% green tea leaf powder to UV coating, and the floor was also discolored to light green during by the soaking test. The color of floor was not changed up to 5% addition level.

  • PDF

Characteristic Properties of TiN Thin Films Prepared by DC Magnetron Sputtering Method for Hard Coatings (Hard Coating 응용을 위한 DC 마그네트론 스퍼터링 방법을 이용하여 증착한 TiN 박막의 특성에 대한 연구)

  • Kim, Young-Ryeol;Park, Yong-Seob;Choi, Won-Seok;Hong, Byung-You
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.21 no.7
    • /
    • pp.660-664
    • /
    • 2008
  • Titanium nitride (TiN) thin films are widely used for hard coatings due to their superior hardness, chemical stability, low friction and good adhesion properties. In this study, we investigated the effect of DC power on the characteristics of TiN thin films deposited on Si and glass substrates by DC magnetron sputtering using TiN target. We made TiN films of 300 nm thickness with various DC powers. The structural properties of films are investigated by x-ray diffractions (XRD) and tribological properties are measured by nano-indentation, nano-scratch tester. The rms roughness was measured by atomic forced microscopy (AFM). In the result, TiN films had the smooth surface and exhibited (111) directions with the increase of DC Power. Also, especially in case of 175 W DC power, TiN film exhibited the maximum hardness about 8 GPa, and the critical load near 25.

Synthesis of the Multifunctional Core/Intermediate/Shell Nanoparticles: Tunable Magnetic and Photoluminescence Properties (자성 및 발광 특성이 조절 가능한 다기능 코어/중간체/쉘 나노 입자 합성)

  • Kim, Mun-Kyoung;Kim, Seyun;Moon, Kyoung-Seok;Shin, Weon Ho;Jeong, Hyung Mo
    • Journal of Powder Materials
    • /
    • v.26 no.6
    • /
    • pp.463-470
    • /
    • 2019
  • Fe3O4/SiO2/YVO4:Eu3+ multifunctional nanoparticles are successfully synthesized by facile stepwise sol-gel processes. The multifunctional nanoparticles show a spherical shape with narrow size distribution (approximately 40 nm) and the phosphor shells are well crystallized. The Eu3+ shows strong photoluminescence (red emission at 619 nm, absorbance at 290 nm) due to an effective energy transfer from the vanadate group to Eu. Core-shell structured multifunctional nanoparticles have superparamagnetic properties at 300 K. Furthermore, the core-shell nanoparticles have a quick response time for the external magnetic field. These results suggest that the photoluminescence and magnetic properties could be easily tuned by either varying the number of coating processes or changing the phosphor elements. The nanoparticles may have potential applications for appropriate fields such as laser systems, optical amplifiers, security systems, and drug delivery materials.

Structural and Electrical Properties of Sol-gel Derived BFO/PZT Thin Films with Variation of Solvents (솔-젤법으로 제작한 BFO/PZT 박막의 용매에 따른 구조적, 전기적 특성)

  • Cho, Chang-Hyun;Lee, Ju
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.24 no.11
    • /
    • pp.895-899
    • /
    • 2011
  • Multiferroic BFO/PZT(5/95) multilayer films were fabricated by spin-coating method on the Pt/Ti/$SiO_2$/Si substrate alternately using BFO and PZT(9/95) alkoxide solutions. The structural and dielectric properties were investigated with variation of the solvent and the number of coatings. All films showed the typical XRD patterns of the perovskite polycrystalline structure without presence of the second phase such as $Bi_2Fe_4O_3$. BFO/PZT multilayer thin films showed the typical dielectric relaxation properties with increase an applied frequency. The average thickness of 6-coated BFO/PZT multilayer film was about 600 nm. The dielectric properties such as dielectric constant, dielectric loss and remnant polarization were superior to those of single composition BFO film, and those values for BFO/PZT multilayer film were 1199, 0.23% and 12 ${\mu}C/cm^2$.

Evaluation of Tailorability of Adhesive Fabrics for Men's Suit (신사복의 접착포에 대한 형태 안정성 평가)

  • Kim, Jung-Sook
    • Fashion & Textile Research Journal
    • /
    • v.8 no.5
    • /
    • pp.585-590
    • /
    • 2006
  • In the variation of physical properties of adhesive fabrics, the objective of this study is to analyze fitness of fusible interlining to four sorts of fabrics for men's suit with various structural parameters. Four fusible interlinings are used for adhering to fabrics for men's suit. Mechanical properties of these 16 adhesive fabrics fused with these interlinings are measured by KES-FB system for analysing appearance and wearing properties of garments and for examining the fitness of fusible interlining to the fabrics for men's suit. The variation of bending property for adhesive fabrics are found to be higher in the order of interlining 1(Cotton30/Rayon70, plain), interlining 2(Polyester30/Rayon70, warp knit), interlining 4(Polyester, shingosen fabrics with drawing textured yarn) and interlining 3(Polyester, double dot coating interlining). The variation of adhesive effect shows the same results with bending property and shows negative relation with extensibility in weft direction per extensibility in warp direction(EM2/EM1). The variation of peel strength of adhesive fabrics, woolen fabrics in the case of face fabrics and interlining 3 in the case of interlining shows the largest value respectively.

Influences of Wet-Pressing Types on Internal Structure of Paper (습부압착 방식이 종이의 내부구조에 미치는 영향)

  • Lee Jin-Ho;Park Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.37 no.4 s.112
    • /
    • pp.32-37
    • /
    • 2005
  • To Increase the productivity of a paper machine, the maximization of the machine speed is a kind of simple way As the machine speed increases, more intense wet pressing is required to persist the outlet consistency of press part and reduce the water removal of dryer part. With more intense pressing, there are concerns that the quality of paper will be affected. This study was carried out to evaluate the influence of wet-pressing on internal structure of paper, The nip pressure at the first and third nip in triple nip press was controlled. Paper structures, strength properties and pore properties were evaluated. As a result, first nip pressure more strongly influenced the paper structural properties than third nip pressure in triple nip pressing condition. Because of the high water content and low wet-web strength of paper web in first nip, increasing the first nip pressure induced the incipient crushing of wet-web and then caused a potential of web break during the following coating or printing processes.

Effect of Al Alloy Composition on Physical and Crystallographical Properties of Plasma Electrolytic Oxidized Coatings II. Crystallographic Analysis of PEO Layer (플라즈마 전해 산화 코팅에 있어서 알루미늄 합금 모재 성분의 물리적, 결정학적 영향 II. PEO 층의 결정상 분석)

  • Kim, Bae-Yeon;Lee, Deuk-Yong;Shin, Min-Chul;Shin, Hyun-Gyoo;Kim, Byeong-Kon;Kim, Sung-Youp;Kim, Kwang-Youp
    • Journal of the Korean Ceramic Society
    • /
    • v.47 no.4
    • /
    • pp.283-289
    • /
    • 2010
  • Physical properties of Plasma electrolytic oxidized 8 different kinds of Al alloys, A-1100, A-2024, A-5052, A-6061, A-6063, A-7075, ACD-7B and ACD-12 were investigated. The electrolyte for PEO was $Na_2SiO_3$ and NaOH and some alkali earthen metal salts system solution. $\eta$-alumina, as well as $\gamma$-alumina, was main crystal phase, which were ever reported. Also, $Al_{4.95}Si_{1.05}O_{9.52}$ was found only in this research. So we can conclude that the process conditions of PEO apparatus and composition and concentration of its electrolyte affects crystal structure and physical properties of PEO layers much more than the compositions of Al alloy.