• 한국표면공학회지
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• 제52권6호
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• pp.321-325
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• 2019

Triso-type coating layers of silicon carbide and graphite on UO₂ paticulate nuclear fuel were prepared by using fluidized bed type chemical vapor deposition and self-propagating high temperature synthesis methods to make a coated nuclear fuel of a power plant for hydrogen mass-production. The source and carrier gases were the mixture of methyltrichlorosilane and propane, and inert argon. Chemical analysis and microstructure observation showed that the coated layers were inner graphite, middle silicon carbide and outer graphite. The elastic modulus and nano-hardness of the silicon carbide layer were 503 [GPa] and 36 [GPa], respectively.

• Journal of the Korean Wood Science and Technology
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• 제25권4호
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• pp.10-16
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• 1997

This study was carried out to improve coating structure by controlling the electrostatic interaction of coating components and by changing the coating structure of coated paper prepared with amphoteric and anionic latices. The results indicated that amphoteric latex copolymerized with carboxylic and amine groups had stronger interaction with other coating components than anionic latex with branched carboxylic group by controlling pH. These properties of amphoteric latex showed positive effects on viscosity rheology, and supernatant sediment of coating color. The coated paper using amphoteric latex had also produced more porous and smoother coverage of the coating layer than that using anionic latex. This porous and smooth coating layer showed better optical properties and printability than those of anionic latex such as opacity, porosity, ink set-off, and wet ink receptivity.

• 한국표면공학회지
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• 제34권4호
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• pp.337-341
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• 2001

TiN coating of high speed end mill is recently generalized. The study of coating layer using ion plating is mainly about the coating method and the why of the longer life of coated tools. In CNC machning process, metal cutting isn't carry out until the tools including the end-mill and so on are fractured. Namely, it is difficult precision processing when the cutting force of the cutting tool is near the limit the fracture cutting force. So, the estimate of the life by wear and fracture is important. Therefore, this study is about the method to estimate the capacity of the coating layer in relation to the tendency of cutting force and the influence of the cutting capacity of coated end-mill by the condition N2, Ar, temperature. The cutting length is in inverse proportion to the cutting force ratio. So, the life of the TiN coated end mill can be predicated by the ratio of the increase of the cutting force.

• 한국표면공학회지
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• 제15권4호
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• pp.208-217
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• 1982

To study the effect of TiC coating on weight change, microhardness, wear and heat - resistance of TiC layer, chemical vapour deposition on the various substrates has been carried out with the gaseous mixture of TiCl4, toluene, and H2 in the temperature range of 900 - 1000$^{\circ}C$. The results obtained are as follows ; (1) There is a limited value of carrier and reductant H2 gas flow rate, above which deteriorate effect on the TiC depoition arises (2) Increased thickness of TiC layer was resulted with increasing temperature and time. Better deposition was obtained with stainless steels and the best results were introduced by cobalt coating of substrates. (3) Wear resistance of the TiC coated specimen improved markedly. Heat resistivity of the coated steel showed excellent result, whereas the coated stainless Steels were infer-ior to the substrate.

• Nuclear Engineering and Technology
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• 제49권5호
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• pp.1031-1043
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• 2017

A structural model for stress distributions of coated Zircaloy subjected to realistic incore pressure difference, thermal expansion, irradiation-induced axial growth, and creep has been developed in this study. In normal operation, the structural integrity of coating layers is anticipated to be significantly challenged with increasing burnup. Strain mismatch between the zircaloy and the coated layer, due to their different irradiation-induced axial growth, and creep deformation are found to be the most dominant causes of stress. This study suggests that the compatibility of the high temperature irradiation-induced strains (axial growth and creep) between zircaloy and the coating layer and the capability to undergo plastic strain should be taken as key metrics, along with the traditional focus on chemical protectiveness.

• 대한금속재료학회지
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• 제49권2호
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• pp.192-196
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• 2011

The multi-layered thin film with an ITO/Ag/ITO structure was produced on PET by using magnetron reactive sputtering method. First, 30 nm of ITO thin film was coated on PET by using normal temperature process. Then 20-52 nm of the Ag thin film was coated. Lastly, 30 nm of ITO thin film was coated on Ag layer. The sample of the 20 nm Ag thin film showed more than 70% transmission and a $2.7{\Omega}/{\Box}$ sheet resistance. When compared to the existing single-layered transparent conducting thin film, multi-layered film was found to be superior with about $5{\Omega}/{\Box}$ less sheet resistance. However, since the Ag layer became thinner, the band gap energy needs to be increased to more than 3.5 eV.

• 대한금속재료학회지
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• 제47권9호
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• pp.550-557
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• 2009

In this study, bronze or SUS304 powders blended with 10 wt.% diamond particles were used to prepare metal/diamond composite materials deposited by cold spraying. The effects of matrix metal, diamond partical size, and the thickness of the Ni coating on the diamond were studied on Al 6061 substrate. The results showed that the hardness of the metal/diamond composite coating layers was higher than that of the same composite materials when using the sintering method. The fraction of diamond content in the coated layer increased when the metal matrix was soft. When the size of the diamond particles was reduced, the fraction of the diamond particles increased. In addition, in the case of diamond with a thicker Ni-coated layer, the fracturing of diamonds was mitigated in the composite coating layers.

• Korean Chemical Engineering Research
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• 제50권1호
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• pp.118-127
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• 2012

고분자전해질 연료전지용 분리판 소재로 스텐레스 강의 내식성과 전기전도성을 향상시키기 위해 표면을 TiN(titanium nitride) 또는 Ti/TiN(titanium/titanium nitride)으로 코팅하여 연료전지 운전환경에서 표면 코팅층의 물성 변화를 조사하였다. 200시간의 연료전지 운전에서 표면 코팅층의 부식, 균열(crack), 박리, 표면 화학조성 변화 등을 분석하여 코팅된 TiN 또는 Ti/TiN 박막의 역할을 규명하고자 하였다. 스텐레스 강 분리판의 전기전도도와 부식저항성은 소재 표면에 질화층 박막을 코팅함으로써 증가하였으나 연료전지 환경하에서 운전시 코팅된 박막의 부식과 박리현상이 SUS316L-Ti/TiN을 제외하고 현저히 발생하였다. TiN 코팅층과 하부 기재 사이에 Ti 중간층을 도입함으로써 TiN 박막의 밀착성이 향상되고 또한 코팅층의 두께 증가로 부식 위험성이 감소하는 것을 관찰하였다.

• 한국재료학회지
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• 제26권3호
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• pp.109-116
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• 2016

To achieve the fabrication of high-quality Ag-coated Cu particles through a wet chemical process, we reported herein pretreatment conditions using an ammonium-based mixed solvent for the removal of a $Cu_2O$ layer on Cu particles that were oxidized in air for 1 hr at $200^{\circ}C$ or for 3 days at room temperature. Furthermore, we discussed the results of post-Ag plating with respect to removal level of the oxide layer. X-ray diffraction results revealed that the removal rate of the oxide layer is directly proportional to the concentration of the pretreatment solvent. With the results of Auger electron spectroscopy using oxidized Cu plates, the concentrations required to completely remove 50-nm-thick and 2-nm-thick oxides within 5 min were determined to be X2.5 and X0.13. However, the optimal concentrations in an actual Ag plating process using Cu powder increased to X0.4 and X0.5, respectively, because the oxidation in powder may be accelerated and the complete removal of oxide should be tuned to the thickest oxide layer among all the particles. Back-scattered electron images showed the formation of pure fine Ag particles instead of a uniform and smooth Ag coating in the Ag plating performed after incomplete removal of the oxide layer, indicating that the remaining oxide layer obstructs heterogeneous nucleation and plating by reduced Ag atoms.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 춘계학술대회논문집
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• pp.99-104
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• 2003

TiN coated films show a good mechanical properties, high thermal properties and wear, erosion and corrosion resistance and are widely used as a coating materials in tools, ornaments, parts and semiconductors. In spite of these good properties, the fracture of TiN coated films occur during use. The fracture of TiN thin films is related to their microstructure. Especially, the life of TiN coated layer is related to the texture of the TiN films. One researcher suggested that the corrosion and erosion resistance of the TiN thin films is related to a uniform and dense structure of films. In this study, we studied the relationships between textures and friction coefficient, erosion and corrosion in TiN coated films. The flatness of (115) texture surface of TiN thin films is flatter than that of (111) texture surface. The friction coefficient of (115) texture surface of TiN thin films is similar with that of (111) texture surface. The wear resistance of (115) texture surface of TiN thin films is better than that of (111) texture surface. The erosion and corrosion resistance of (115) texture surface of TiN thin films is better than that of (111) torture surface. As well as texture, the wear, erosion and corrosion of TiN thin films has to consider defects such as pinholes, cracks, surface roughness and open columnar structure. The life of TiN coated products is influenced by the properties of wear, erosion, and corrosion resistance of TiN thin films and is related to texture of TiN coated films, density of pinholes and cracks, density of structure, and surface flatness.