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Microstructure and Nano-hardness of SiC/C Multi-coated Layers on a Particulate Nuclear Fuel

입자 핵연료의 SiC/C 다층 도포층의 미세조직 및 극미세 경도 평가

  • Choi, Young (Department of Materials Science and Engineering, Dankook University)
  • 최용 (단국대학교 신소재공학과)
  • Received : 2019.11.20
  • Accepted : 2019.12.23
  • Published : 2019.12.31

Abstract

Triso-type coating layers of silicon carbide and graphite on UO2 paticulate nuclear fuel were prepared by using fluidized bed type chemical vapor deposition and self-propagating high temperature synthesis methods to make a coated nuclear fuel of a power plant for hydrogen mass-production. The source and carrier gases were the mixture of methyltrichlorosilane and propane, and inert argon. Chemical analysis and microstructure observation showed that the coated layers were inner graphite, middle silicon carbide and outer graphite. The elastic modulus and nano-hardness of the silicon carbide layer were 503 [GPa] and 36 [GPa], respectively.

Keywords

References

  1. D. Olander D, "Nuclear Fuels-Present and Future". Journal of Nuclear Materials, 389 (2009) pp. 1-22. https://doi.org/10.1016/j.jnucmat.2009.01.297
  2. N. Rohbeck, D. Tsivoulas, I. P. Shapiro, "In-situ Nano-indentation of Irradiated Silicon Carbide in TRISO Particle Fuel up to $500^{\circ}C$". Journal of Nuclear Materials, 465 (2015) pp. 692-694. https://doi.org/10.1016/j.jnucmat.2015.06.035
  3. S. Knol, S. Groot, P. Hania, M. Hannink "Irradiation of HTR Coated Particles at High Temperatures", Nuclear Engineering and Design, 251 (2012) pp. 150-156. https://doi.org/10.1016/j.nucengdes.2011.10.050
  4. Bong G. Kim, Yong Choi, Jung W. Lee, Young W. Lee, Gil M. Kim, "Characterization of a Silicon Carbide Thin Layer Prepared by a Self-propagating High Temperature Synthesis Reaction", Thin Solid Films, 375 (2000) pp. 82-86. https://doi.org/10.1016/S0040-6090(00)01266-9
  5. Seonho Noha, Dong-hee Leeb, Kwangheon Parkb, "Development of a Metal Cladding with Protective SiC Composites and the Characteristics on High temperature Oxidation", Journal of the Korean Institute of Surface Engineering, 48(5) (2015), pp.218-226. https://doi.org/10.5695/JKISE.2015.48.5.218
  6. S. J. Xu, J. G. Zhou, and B. Z. Zhang, "Effect of Deposition Temperature on the Properties of Pyrolytic SiC," Journal of Nuclear Materials, 224 (1995), pp. 12-16. https://doi.org/10.1016/0022-3115(95)00039-9
  7. T. Chanadee. "SHS Synthesis of Si-SiC Composite Powders using Mg and Reactants from Industrial Waste", Metals and Materials International, 23(6) (2017) pp 1188-1196. https://doi.org/10.1007/s12540-017-7111-0
  8. B. Reznik, "Microstructure and Mechanical Properties of Carbon-Carbon Composites with Multilayered Pyrocarbon Matrix", Materials Letters 52 (2002), pp.14-19. https://doi.org/10.1016/S0167-577X(01)00357-3
  9. M. Masanta, P. Ganesh, R. Kaul, A. R. Choudhury, "Microstructure and Mechanical Properties of $TiB_2-TiC-Al_2O_3-SiC$ Composite Coatings Developed by Combined SHS, Sol-Gel and Laser Technology", Surface and Coatings Technology, 204 (2010) pp. 3471-3480. https://doi.org/10.1016/j.surfcoat.2010.04.018
  10. J. Tan, P. J. Meadows, D. Zhang, "Young's Modulus Measurements of SiC Coatings on Spherical Particles by Using Nano-indentation", J Nucl Mater 393 (2009), pp. 22-29. https://doi.org/10.1016/j.jnucmat.2009.05.001
  11. K. Qianhua, Y. Wenyi, K. Guozheng, S. Qingping, "Oliver-Pharr Indentation Method in Determining Elastic Moduli of Shape Memory Alloys-A Phase Transformable Material", Journal of the Mechanics and Physics of Solids, 61(1) (2013) pp. 2015-2033 https://doi.org/10.1016/j.jmps.2013.05.007
  12. Nadia Rohbeck, Dimitrios Tsivoulas, Ian P. Shapiro, Ping Xiao, Steven Knol, Jean Michel Escleine, Marc Perez, Bing Liu, "Comparison Study of Silicon Carbide Coatings Produced at Different Deposition Conditions with Use of High Temperature Nano-indentation", Journal Matererials Science, 52 (2017) pp. 1868-1882. https://doi.org/10.1007/s10853-016-0476-5