• Journal of Environmental Science International
• /
• v.27 no.2
• /
• pp.83-90
• /
• 2018

In this study, zeolite (Z-C2) was synthesized using a fusion/hydrothermal method on coal fly ash (FA) discharged from a thermal power plant in the Ulsan area and then analyzed via scanning electron microscopy (SEM) and X-ray diffraction (XRD). The Z-C2 was characterized in terms of mineralogical composition and morphological analysis. The XRD results showed that its peaks had the characteristics of Na-A zeolite in the range of $2{\theta}$ of 7.18~34.18. The SEM images confirmed that the Na-A zeolite crystals had a chamfered-edge crystal structure almost identical to that of the commercial zeolite. The adsorption kinetics of Cu, Co, Mn and Zn ions by Z-C2 were described better by the pseudo-second-order kinetic model more than by the pseudo-first-order kinetic model. The Langmuir model fitted the adsorption isotherm data better than the Freundlich model did. The maximum adsorption capacities of Cu, Co, Mn and Zn ions obtained from the Langmuir model were in the following order : Cu (94.7 mg/g) > Co (77.7 mg/g) > Mn (57.6 mg/g) > Zn (51.1 mg/g). These adsorption capacities are regarded as excellent compared to those of commercial zeolite.

• Journal of the Korean Ceramic Society
• /
• v.39 no.3
• /
• pp.259-264
• /
• 2002

In this study, sintering properties of Artificial Lightweight aggregates(ALAs) prepared from coal ash as a function of sintering temperature (900$^{\circ}$C, 1000$^{\circ}$C, 1100$^{\circ}$C) and time (2min, 5min, 10min) when limestone added as lightweight mineral was investigated. Increasing the sintering temperature resulted simultaneously from a decline of quartz mineral as well as growth of mullite mineral. Addition of limestone to ALAs newly formed sintered minerals such as clinoptilolite and plagioclase. Sintering effect of ALAs prepared from coal ash and limestone was more affected by a sintering temperature than time. As sintering temperature and time increae, transition of macropore to micropore and formation of closed pores were happened, consequently shrank the total pore volume of ALAs. The surface of ALAs sintered at 1000$^{\circ}$C for 5min was nearly not detected open pores due toe amalgamation effect of molten slag layer but homogeneous distributions of closed pores with micro-scale were examined in cross sectional area ALAs. Sintering temperature and time which present the most adequate state, in the preparation of ALAs, are corresponded to 1000$^{\circ}$C and 5min, respectively.

• Plant Journal
• /
• v.11 no.2
• /
• pp.45-51
• /
• 2015

In this paper, studied condenser operating management which is affecting power plants efficiency considering the cost of poor quality. Sea water temperature and condenser pressure have clear correlation in S power plants. As the sea water temperature changes, condenser pressure changed -1.7~+20 mmHg from design condenser pressure(38.1 mmHg). Use the heat rate correction curve from manufactory company, realized that efficiency and cost of poor quality changed 0.0201%, 12,830 won/h at Unit #1,2 but 0.0155%, 9,832 won/h when condenser pressure 1 mmHg rise. Also, checked that it is changed depend on seasonal corresponding operation, plant ageing and the point of preventive maintenance like overhaul maintenance. This study said if we considered complying with management range and planning overhaul maintenance, then it could help reducing operating maintenance losses minimum 2.5 billion won per 1 year (case : Unit #1, forty days maintenance).

• Journal of Korean Society for Atmospheric Environment
• /
• v.23 no.4
• /
• pp.440-448
• /
• 2007

Although the anthracite power plant is an important source of greenhouse gas, research on this type of power plant has not been conducted much. The present study investigated the entire anthracite power plants in Korea and analyzed the emitted gas in connection with GC/FD and a methanizer in order to develop $CO_2$ emission factors. The study also sampled the anthracite to analyze the amount of carbon and hydrogen using an element analyzer, and to measure the calorie using an automatic calorie analyzer. The emission factors computed through the fuel analysis was 30.45 kg/GJ and that computed through the $CO_2$ gas analysis was 26.48 kg/GJ. The former is approximately about 15% higher than the latter. When compared the carbon content factors of anthracite with that of bituminous coal, the value of anthracite was 24% higher Compared with IPCC values, the emission factors by the fuel was 14% higher, and that by the emitted $CO_2$ gas was about 1.2% lower. More research is needed on our own emission factors of various energy-consuming facilities in order to stand on a higher position in international negotiations regarding the treaties on climate changes.

• Resources Recycling
• /
• v.19 no.2
• /
• pp.3-9
• /
• 2010

In most coal fired power plants, fly ashes collected from each of hoppers in the electrostatic precipitator are transported and stored in a silo. However the properties of the fly ashes collected from each of hoppers in electrostatic precipitator varies with the distance of the collection field from the boiler. The more distance hopper gets fly ash with larger specific surface area. Therefore, in electrostatic precipitator the hopper itself is expected to have the effect of classifying fly ashes. This study examines the physical, chemical and mineralogical properties of fly ash, collected from each of hoppers attached to an electrostatic precipitator in the coal fired power plant and looks into the possibility of the electrostatic precipitator being used as a classifier. Also, the study reviewed the possibility of acquiring high quality fly ash.

• Journal of Energy Engineering
• /
• v.25 no.3
• /
• pp.1-8
• /
• 2016

North Korea is currently undergoing an economic crisis of industrial productivity reduction, which resulted from decreased energy production and economic sanctions due to conflicts with the international society. This paper examined the technological status of North Korea's natural gas and coal industries which are essential sectors for recovery of the economy and North-South cooperation on energy industry. This paper also analyzed investment strategies in North Korean energy industries and calculated the size of economic ripple effect of the investment on North and South Korea. In order to analyze the effect of the investment on North Korean economy, we constructed an inter-industry relation table of North Korea for year 2014 and used an input-output model. The ripple effect of the investment in natural gas and coal industries turned out to be 1.012 billion dollars and 2.742 billion dollars respectively. In order to analyze the ripple effect of the investment on South Korean economy, we constructed an inter-industry relation table of South Korea for year 2013 and used a demand-driven model for inter-industry analysis. As a result, production, added-value and employment inducement coefficients of the investment were calculated as 2.02073, 0.62697 and 8.99409 for the natural gas industry and 2.02130, 0.62701 and 9.00413 for the coal industry respectively.

• Resources Recycling
• /
• v.19 no.6
• /
• pp.43-50
• /
• 2010

The crisis of energy gives rise to the growing concerns over continuing uncertainty in the energy market. Under these circumstances, there are also increasing interests on coals. In particular, Low Rank Coal (LRC) is receiving gradual attentions from green industry. But due to is high moisture content range from 30 - 60%, drying process has to be preceded before being utilized as power plant. In this study drying kinetics of LRC is induced by using a fixed-bed reactor. The drying kinetics was evaluated in from of the particle size, the inlet gas temperature, the drying time, the gas velocity, and the LID ratio. The consideration of the reynold's number was taken for correction of gas velocity, particle size and LID was taken for correction of reactor diameter, packing height of coal. As being seen as characteristic of drying coal, it can be found that fixed-bed reactor can contributed to active drying of free water. In this sense, it could be considered that phase boundary reaction is appropriate mechanism.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.11 no.1
• /
• pp.55-61
• /
• 2023

This study aims to develop CLSM fill material for emergency restoration using landfill coal ash. As a result of examining physical properties such as particle size distribution and fines content of landfill coal ash, bottom ash, fly ash, and general soil were mixed, and SP was found to have a density of 2.03 and a residual particle pass rate of 7.8 %. CLSM materials that secure fluidity in unit quantities without using chemical admixtures such as glidants and water reducing agents have a high risk of material separation due to bleeding. As a result of this experiment, it was found that the bleeding ratio did not satisfy the standard in the case of the specimen with a large amount of fly ash and a lot of addition of mixing water. As a result of the compressive strength test, the strength development of 0.5 MPa or more for 4 hours was found to be satisfactory for the specimens using hemihydrate gypsum with a unit binder amount of 200 or more, and the remaining gypsum showed poor strength development. Although it is judged that landfill coal ash can be used as a CLSM material, it is necessary to identify and apply the physical and chemical characteristics of coal ash buried in the ash treatment plant of each power generation company.

• Korean Chemical Engineering Research
• /
• v.56 no.1
• /
• pp.6-13
• /
• 2018

Utilizing the heat of cooling water discharge of coal-fired power plant, pipeline investment costs for businesses that supply heat to agricultural facilities near power plants increase in proportion to installation distance. On one hand, the distance from the power plant is a factor that brings difficulties to secure economic efficiency. On the other, if the installation distance is short, there is a problem of securing the heating demands, facility houses, which causes economical efficiency to suffer. In this study, the economic efficiency of 1km length of standard heat pipeline was evaluated. The sensitivity of the heat pipe to the new length variation was analyzed at the level of government subsidy, amount of heating demand and the incremental rate of pipeline with additional government subsidy. As a result of the analysis, it was estimated that NPV 131 million won and IRR 15.73%. The sensitivity analysis showed that NPV was negative when the length of heat pipe facility exceeded 2.6 km. If the government supports 50% of the initial investment, the efficiency is secured within the estimated length of 5.3 km, and if it supports 80%, the length increases within 11.4 km. If the heat demand is reduced to less than 62% at the new length of the standard heat pipe, it is expected economic efficiency is not obtained. If the ratio of government subsidies to initial investment increases, the elasticity of the new bloc will increase, and the fixed investment, which is the cost of capital investment for one unit of heating demand, will decrease. This would result in a reduction in the cost of production per unit, and it would be possible to supply heat at a cheaper price level to the facility farming. Government subsidies will result in the increased economic availability of hot plumbing facilities and additional efficiencies due to increased demand. The greater government subsidies to initial investment, the less farms cost due to the decrease in the price per unit. The results of the study are significant in terms of the economic evaluation of the effectiveness of the government subsidy for the thermal power plant heat utilization project. The implication can be applied to any related pilot to come.

• Journal of Energy Engineering
• /
• v.14 no.2 s.42
• /
• pp.147-152
• /
• 2005

Calculation equations of fired fuel comsumption rating at boiler can lead from combustion anal-ysis and boiler heat balance using mass & energy conservations. By comparing calculation equation results with those of measurement, we can confirm the deviation of fuel consumption rate, and correction rate, and correction degree, and can also establish the proven technology to apply the equation at the site. We applied fuel rate equation to the operating power plant and recorded $2.4\%\;&\;1.5\%$ of deviation at each coal and oil fired boilers. This range of deviation is regarded as trustable to apply the fuel consumption equation to the actual site.