• Title/Summary/Keyword: coal gasification slag

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Effects of critical viscosity temperature and flux feeding ratio on the slag flow behavior on the wall of a coal gasifier (석탄 가스화시 회분의 임계점도온도 및 플럭스 비율 변화에 따른 벽면 슬래그 거동 특성 분석)

  • Ye, Insoo;Ryu, Changkook;Kim, Bongkeun
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.21-24
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    • 2014
  • In the entrained-flow coal gasifier, coal ash turns into a molten slag most of which deposits onto the wall to form liquid and solid layers. Critical viscosity refers to the viscosity at the interface of the two layers. The slag layers play an important role in protecting the wall from physical/chemical attack from the hot syngas and in continuously discharging the ash to the slag tap at the bottom of the gasifier. For coal with high ash melting point and slag viscosity, CaO-based flux is added to coal to lower the viscosity. This study evaulates the effect of critical viscosity temperature and ash/flux ratio on the slag behavior using numerical modelling in a commercial gasifier. The changes in the slag layer thickness, heat transfer rate, surface temperature and velocity profiles were analyzed to understand the underlying mechanism of slag flow and heat transfer.

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Effects of Slag Composition on the Microphase Change of a Chromia Refractory under Gasification Conditions (가스화 조건에서 슬래그 성분이 크롬계 내화재 미세구조 변화에 미치는 영향)

  • Oh, Myong-Sook;Kim, Han-Bom;Park, Woo-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.441-444
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    • 2007
  • The inside wall of a coal gasifier is lined with refractory, and the corrosion of the refractory by coal sag is an important parameter affecting the refractory lifetime and the replacement period. This paper examines the changes in microstructure of a chromia refractory due to chemical reactions with penetrating slag as a function of slag composition. The effects of CaO and $Fe_2O_3$ concentrations were studied using Datong and KIDECO slag. Static corrosion experiments were carried out, the percent slag penetration and changes in the microstructure were determined by SEM/EDX analyses. FactSage equilibrium calculations were carried out to determine the equilibrium products and the predictions were compared with experimental observations.

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A Study on the Coal Gasification Slag as Fine Aggregate for Concrete - Focus on Chemical Properties - (콘크리트용 잔골재로서 석탄가스화복합발전 슬래그의 활용성 검토 - 화학적 특성을 중심으로 -)

  • Hyun, Seong-Yong;Han, Jun-Hui;Lee, Yung-Jun;Shin, Yong-Sub;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.191-192
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    • 2018
  • This study is a fundamental study to utilize CGS from the IGCC as a fine aggregate for concrete. According to the study, the chemical composition of KS F 2527 was reviewed. The results showed that the KS F 2527 standard was generally satisfied, but the content of the sulfur trioxide(SO3) exceeded the limit set by the molten slag. The possibility was found to be a fine metal based on chemicals other than sulfur trioxide(SO3).

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Physical Properties of Concrete According to Changing in The Types of Premix Cements and the Mixing Rate of CGS. (프리믹스 시멘트 종류 변화 및 CGS 치환에 따른 콘크리트의 물리적 특성)

  • Kim, Su-Hoo;Han, Soo-Hwan;Lim, Gun-Su;Hyun, Seung-Yong;Kim, Jong;Han, Min-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.63-64
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    • 2021
  • In this study, Coal gasification slag(CGS) was replaced with fine aggregate to verify the physical properties of the concrete according to the change in cement types. As a result of the study, the use of CGS resulted in a decrease of superplasticizer and an decrease of AE agent. In addition, when 50% of mixed cement and CGS were replaced, the initial strength expression was delayed, and the strength enhancing effect was judged to be weak.

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Operation Characteristics of Gasification/Melting Pilot Plants for Synthesis Gas Production using Coal and Waste (석탄 및 폐기물로부터 합성가스 제조를 위한 가스화용융 Pilot Plant 운전특성)

  • Chung, Seok-Woo;Yun, Yong-Seung;Yoo, Young-Don
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.561-564
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    • 2005
  • Gasification has been regarded as a very important technology to decrease environmental pollution and to obtain higher efficiency. The gasification process converts carbon containing feedstock into a synthesis gas, composed primarily of CO and $H_2$. And the synthesis gas can be used as a source for power generation or chemical material production. Through more than nine years, IAE developed and upgraded several gasification/melting pilot plant system, and obtained a good quality synthesis gas. This paper illustrates the gasification characteristics and operation results of two 3 ton/day synthesis gas production facilities. One is entrained-bed slagging type coal gasifier system which is normally operated in the temperature range of $1,400\~1,450^{\circ}C,\;8\~10$ bar pressure. And the other is fixed-bed type gasification/melting furnace system using MSW and industrial wastes as a feedstock.

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Evaluation of Chloride Ion Penetration Resistance of Coal Gasification Slag Replaced Concrete (석탄가스화 용융 슬래그 치환 콘크리트의 염화이온 침투 저항성 검토)

  • Cho, Hyeon-Seo;Kim, Min-Hyouck;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.166-167
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    • 2019
  • In this study, to test the performance of concrete used as a concrete admixture as a recycling method of CGS, gypsum was mixed and the chloride ion penetration resistance test of CGS and BFS substituted concrete was conducted. As a result, it was found that without gypsum type test specimen, the CGS sustituted test specimens had lower chloride ion penetration resistance than the BFS substituted specimens. When gypsum was added, it was confirmed that the chloride ion penetration resistance was poor regardless of the type of admixture. In addition, it was confirmed that both admixtures were less resistant to chloride ion penetration than OPC, regardless of the presence of gypsum. However, considering the uneven quality variation of coal, which greatly affects the quality of CGS, further research is needed.

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Properties of Cement Mortar Using CGS as Mixed Fine Aggregate (CGS를 잔골재로 혼합 사용하는 모르타르의 공학적 특성)

  • Han, Jun Hui;Lee, Young Jun;Hyun, Seung Yong;Park, Kyung Taek;Han, Min Cheol;Han, Cheon Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.138-139
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    • 2018
  • This study is a basic review of the basic characteristics of mortar as a result of the use of concrete as a fine aggregate for CGS(coal gasification slag) generated from the IGCC(integrated gasification combined cycle). The analysis shows that CGS and crushed sand + seal sand mix is the best combination of CGS combined with about 75 % of CGS based on the effects of promoting liquidity and strength. This is expected to be a positive factor in securing the strength and flexibility of concrete given the optimal mix of CGS, and may also contribute to the improvement of quality.

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The operation Characteristic of Pilot-scale 2-Stage Coal gasifier (Pilot 규모 2단 형상 가스화기 운전특성 실험)

  • Hong, Jin-Pyo;Chung, Jae-Hwa;Seo, Seok-Bin;Chi, Jun-Hwa;Lee, Seung-Jun;Chung, Suk-Woo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.528-532
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    • 2009
  • Integrated Gasification Combined Cycle (IGCC) power plant converts coal to syngas, which is mainly composed with hydrogen and carbon monoxide, by the gasification process and produces electric power by the gas and steam turbine combined cycle power plant. The purpose of this study is to investigate the influence of gasification process to type and structure of gasifier. For this purpose, the performance characteristics of gasification reaction are analyzed with the operation characteristic of pilot-scale 2-stage coal gasifier. It is found that gasification reaction, floating characteristic of melted slag, particle stick of inside of the gasifier, particle stick and deposit of Syngas cooler are the causes in the different performance characteristics.

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A Study on the Coal Gasification Slag as Fine Aggregate for Concrete - Focus on Physical Properties and hazardous materials content characteristics - (콘크리트용 잔골재로서 석탄가스화복합발전 슬래그의 활용성 검토 - 물리적 성질 및 유해물질 함유량 특성을 중심으로 -)

  • Hyun, Seong-Yong;Han, Jun-Hui;Lee, Jae-Jin;Shin, Yong-Sub;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.56-57
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    • 2018
  • This study is a fundamental consideration for using CGS from the IGCC as a fine aggregate for concrete. For the review, the physical properties and hazardous materials content of KS F 2527 were considered. The results showed that KS F 2527 standard was generally satisfied, making it possible to confirm the possibility that it is a fine metal considering its physical properties and hazardous materials content characteristics.

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Entrained-Flow Coal Water Slurry Gasification (분류층 습식 석탄가스화 기술)

  • Ra, HoWon;Lee, SeeHoon;Yoon, SangJun;Choi, YoungChan;Kim, JaeHo;Lee, JaeGoo
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.129-139
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    • 2010
  • Coal gasification process, which had developed originally to convert coal from hydrogen and carbon monoxide, has used and developed in many countries because of environmental advantages such as carbon dioxide storage, decrease of pollutants and so on. Generally entrained-flow gasification process using pulverized coal under $75{\mu}m$ is used in Integrated Gas Combined Cycle(IGCC) because of easy scale up and high efficiency of energy conversion. Especially entrained-flow gasifers with coal water slurry have been used in many applications due to its fully developed technologies. In this paper, several technologies for coal-water slurry gasification that involves slurry preparation, burner, gasifier, slag melting and numerical simulation for plant design and operation were investigated. Entrained-flow gasification with coal water slurry can be used for synfuel production, SNG, chemicals as well as IGCC. To develop hybrid gasification process and use different types of coal, it is necessary to develop new technologies that will increase efficiency of the process.